SAFETY DATA SHEET Revision Date 15-Aug-2018 Version 4 1. IDENTIFICATION Product identifier Product Name LIQUID ELECTRICAL TAPE 4 OZ Other means of identification Product Code 85120 Recommended use of the chemical and restrictions on use Recommended Use Sealant Uses advised against No information available Details of the supplier of the safety data sheet 24-hour emergency phone number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address: This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Specific target organ toxicity (single exposure) Category 3 Label elements Emergency Overview Manufacturer Address ITW Permatex 6875 Parkland Blvd. Solon, OH 44139 USA May Also Be Distributed by: ITW Permatex Canada 101-2360 Bristol Circle Oakville, ON Canada L6H 6M5 Telephone: (800) 924-6994 Flammable liquids Category 2 Signal word Danger Causes skin irritation Causes serious eye irritation May cause drowsiness or dizziness May cause respiratory irritation Highly flammable liquid and vapor _____________________________________________________________________________________________ Page 1 / 9 _____________________________________________________________________________________________ 85120 - LIQUID ELECTRICAL TAPE 4 OZ Revision Date 15-Aug-2018 Precautionary Statements - Prevention Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Wear eye/face protection Wash face, hands and any exposed skin thoroughly after handling Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention Specific treatment (see supplemental first aid instructions on this label) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep cool Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information - Not applicable Unknown acute toxicity 37.5 % of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance(s) Chemical Name CAS No Weight-% XYLENE 1330-20-7 15 - 40 METHYL ETHYL KETONE (BUTANONE) 78-93-3 10 - 30 ACETONE 67-64-1 3 - 7 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Appearance Black Physical state Liquid Odor Solvent _____________________________________________________________________________________________ Page 2 / 9 _____________________________________________________________________________________________ 85120 - LIQUID ELECTRICAL TAPE 4 OZ Revision Date 15-Aug-2018 Skin contact IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None Specific hazards arising from the chemical Highly flammable. Vapors may travel to source of ignition and flash back. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters Move containers from fire area if you can do it without risk. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Other Information Water spray may reduce vapor; but may not prevent ignition in closed spaces. Environmental precautions Environmental precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. _____________________________________________________________________________________________ Page 3 / 9 _____________________________________________________________________________________________ 85120 - LIQUID ELECTRICAL TAPE 4 OZ Revision Date 15-Aug-2018 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Conditions for safe storage, including any incompatibilities Storage Conditions Store locked up. Store in a well-ventilated place. Keep cool. Incompatible materials Strong oxidizing agents, Acids, Amines, Ammonia, Caustics, Aldehydes, Peroxides 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH XYLENE 1330-20-7 STEL: 150 ppm TWA: 100 ppm TWA: 100 ppm TWA: 435 mg/m3 (vacated) TWA: 100 ppm (vacated) TWA: 435 mg/m3 (vacated) STEL: 150 ppm (vacated) STEL: 655 mg/m3 - METHYL ETHYL KETONE (BUTANONE) 78-93-3 STEL: 300 ppm TWA: 200 ppm TWA: 200 ppm TWA: 590 mg/m3 (vacated) TWA: 200 ppm (vacated) TWA: 590 mg/m3 (vacated) STEL: 300 ppm (vacated) STEL: 885 mg/m3 IDLH: 3000 ppm TWA: 200 ppm TWA: 590 mg/m3 STEL: 300 ppm STEL: 885 mg/m3 ACETONE 67-64-1 STEL: 500 ppm TWA: 250 ppm TWA: 1000 ppm TWA: 2400 mg/m3 (vacated) TWA: 750 ppm (vacated) TWA: 1800 mg/m3 (vacated) STEL: 2400 mg/m3 The acetone STEL does not apply to the cellulose acetate fiber industry. It is in effect for all other sectors (vacated) STEL: 1000 ppm IDLH: 2500 ppm TWA: 250 ppm TWA: 590 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective natural rubber, nitrile rubber, Neoprene? or PVC gloves. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of _____________________________________________________________________________________________ Page 4 / 9 _____________________________________________________________________________________________ 85120 - LIQUID ELECTRICAL TAPE 4 OZ Revision Date 15-Aug-2018 equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Black Odor Solvent Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) 57.7% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Incompatible materials Strong oxidizing agents, Acids, Amines, Ammonia, Caustics, Aldehydes, Peroxides Hazardous Decomposition Products Carbon oxides Property Values Remarks ? Method pH No information available Melting point / freezing point 80 ?C / 176 ?F Boiling point / boiling range 82 ?C / 180 ?F Flash point 7 ?C / 45 ?F CC (closed cup) Evaporation rate < 1 Ether = 1 Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: No information available Lower flammability limit: No information available Vapor pressure 12.6 kPa Vapor density 2.4 Air = 1 Relative density 0.96 Water solubility No information available Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity 2000 cP Dynamic viscosity No information available Stable under normal conditions _____________________________________________________________________________________________ Page 5 / 9 _____________________________________________________________________________________________ 85120 - LIQUID ELECTRICAL TAPE 4 OZ Revision Date 15-Aug-2018 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. May cause drowsiness or dizziness. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion Ingestion may cause irritation to mucous membranes. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 XYLENE 1330-20-7 = 3500 mg/kg ( Rat ) > 4350 mg/kg ( Rabbit ) > 1700 mg/kg ( Rabbit ) = 29.08 mg/L ( Rat ) 4 h = 5000 ppm ( Rat ) 4 h METHYL ETHYL KETONE (BUTANONE) 78-93-3 = 2483 mg/kg ( Rat ) = 2737 mg/kg ( Rat ) = 5000 mg/kg ( Rabbit ) = 6480 mg/kg ( Rabbit ) = 11700 ppm ( Rat ) 4 h ACETONE 67-64-1 = 5800 mg/kg ( Rat ) - = 50100 mg/m3 ( Rat ) 8 h Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA XYLENE 1330-20-7 - Group 3 - - ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Not classifiable as a human carcinogen Group 2B - Possibly Carcinogenic to Humans OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Chronic toxicity May cause adverse liver effects. Target Organ Effects Central nervous system, Central Vascular System (CVS), Eyes, Respiratory system, Skin, kidney, Liver. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 5399 mg/kg mg/l ATEmix (inhalation-vapor) 40625 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity 38 % of the mixture consists of component(s) of unknown hazards to the aquatic environment Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient _____________________________________________________________________________________________ Page 6 / 9 _____________________________________________________________________________________________ 85120 - LIQUID ELECTRICAL TAPE 4 OZ Revision Date 15-Aug-2018 XYLENE 1330-20-7 2.77 - 3.15 METHYL ETHYL KETONE (BUTANONE) 78-93-3 0.3 ACETONE 67-64-1 -0.24 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging Do not reuse container. US EPA Waste Number D001, D035 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status XYLENE 1330-20-7 Toxic Ignitable METHYL ETHYL KETONE (BUTANONE) 78-93-3 Toxic Ignitable ACETONE 67-64-1 Ignitable 14. TRANSPORT INFORMATION DOT UN/ID No UN1133 Proper shipping name: Adhesives, Limited Quantity (LQ) Hazard Class 3 Packing Group II Emergency Response Guide Number 128 IATA UN/ID No ID 8000 Proper shipping name: Consumer commodity Hazard Class 9 ERG Code 9L IMDG UN/ID No UN1133 Proper shipping name: Adhesives, Limited Quantity (LQ) Hazard Class 3 Packing Group II EmS-No F-E, S-E 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies _____________________________________________________________________________________________ Page 7 / 9 _____________________________________________________________________________________________ 85120 - LIQUID ELECTRICAL TAPE 4 OZ Revision Date 15-Aug-2018 EINECS/ELINCS Complies ENCS Not determined IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % XYLENE - 1330-20-7 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances XYLENE 1330-20-7 100 lb - - X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) XYLENE 1330-20-7 100 lb - RQ 100 lb final RQ RQ 45.4 kg final RQ METHYL ETHYL KETONE (BUTANONE) 78-93-3 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ ACETONE 67-64-1 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ US State Regulations California Proposition 65 WARNING: This product contains a chemical(s) known to the State of California to cause cancer Chemical Name California Proposition 65 CARBON BLACK - 1333-86-4 *Carcinogen (airborne, unbound particles of respirable size) ? *The asterisked chemical(s) listed are not subject to Proposition 65 because they are not airborne in the finished product U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania XYLENE X X X _____________________________________________________________________________________________ Page 8 / 9 _____________________________________________________________________________________________ 85120 - LIQUID ELECTRICAL TAPE 4 OZ Revision Date 15-Aug-2018 1330-20-7 METHYL ETHYL KETONE (BUTANONE) 78-93-3 X X X ACETONE 67-64-1 X X X TALC 14807-96-6 X X X CARBON BLACK 1333-86-4 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable WHMIS Hazard Class B2 - Flammable liquid, D2B - Toxic materials 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 15-Aug-2018 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health hazards 2 Flammability 3 Instability 0 - HMIS Health hazards 2 Flammability 3 Physical hazards 0 Personal protection B _____________________________________________________________________________________________ Page 9 / 9