1. IDENTIFICATION Product identifier Product Name Spray Nine Poly Scrub? 3.8 lbs. Other means of identification Product Code 13104 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Hand Cleaner or Soap - Heavy Duty Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label elements Emergency Overview Hazards not otherwise classified (HNOC) Not applicable Other Information _____________________________________________________________________________________________ Page 1 / 7 Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Revision Date 22-Apr-2015 SAFETY DATA SHEET Version 1 The product contains no substances which at their given concentration, are considered to be hazardous to health Odor LemonAppearance Green Physical state Paste _____________________________________________________________________________________________ Not applicable Unknown acute toxicity 36.9658% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret WATER 7732-18-5 30 - 60 * ETHYLENE HEXENE COPOLYMER 25213-02-9 10 - 30 * ETHOXYLATED C11-C16 ALCOHOL 127036-24-2 3 - 7 * PROPYLENE GLYCOL 57-55-6 1 - 5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact None under normal use conditions. Inhalation None under normal use conditions. Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Avoid contact with eyes. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical None in particular. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. _____________________________________________________________________________________________ Page 2 / 7 13104 - Spray Nine Poly Scrub? 3.8 lbs. Revision Date 22-Apr-2015 _____________________________________________________________________________________________ 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Avoid contact with eyes. Environmental precautions Environmental precautions See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes. Conditions for safe storage, including any incompatibilities Storage Conditions Keep container tightly closed in a dry and well-ventilated place. Keep from freezing. Incompatible materials Strong oxidizing agents 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls None under normal use conditions Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection None under normal use conditions. Respiratory protection None under normal use conditions. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties _____________________________________________________________________________________________ Page 3 / 7 Revision Date 22-Apr-201513104 - Spray Nine Poly Scrub? 3.8 lbs. _____________________________________________________________________________________________ Physical state Paste Appearance Green Odor Lemon Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) <1% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Keep from freezing. Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation No known effect. _____________________________________________________________________________________________ Page 4 / 7 Decomposition temperature No information available Butyl acetate = 1 Revision Date 22-Apr-2015 Kinematic viscosity No information available Flammability (solid, gas) No information available Dynamic viscosity No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: No information available Values Lower flammability limit: No information available Vapor pressure No information available Boiling point / boiling range 100 ?C / 212 ?F No data available Vapor density >1 Remarks ? Method Air = 1 Relative density No information available Flash point Water solubility Soluble in water None 13104 - Spray Nine Poly Scrub? 3.8 lbs. Solubility in other solvents No information available pH Partition coefficient No information available 5.5-7.5 Evaporation rate <1 Autoignition temperature No information available _____________________________________________________________________________________________ Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact No known hazard in contact with skin. Ingestion Ingestion may cause irritation to mucous membranes. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 WATER 7732-18-5 > 90 mL/kg ( Rat ) - - PROPYLENE GLYCOL 57-55-6 = 20000 mg/kg ( Rat ) = 20800 mg/kg ( Rabbit ) - Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. IARC (International Agency for Research on Cancer) Not classifiable as a human carcinogen Target Organ Effects Eyes. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 504374 mg/kg ATEmix (dermal) 655556 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity 39.0758% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea PROPYLENE GLYCOL 57-55-6 19000: 96 h Pseudokirchneriella subcapitata mg/L EC50 51600: 96 h Oncorhynchus mykiss mg/L LC50 static 41 - 47: 96 h Oncorhynchus mykiss mL/L LC50 static 51400: 96 h Pimephales promelas mg/L LC50 static 710: 96 h Pimephales promelas mg/L LC50 1000: 48 h Daphnia magna mg/L EC50 Static 10000: 24 h Daphnia magna mg/L EC50 Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. _____________________________________________________________________________________________ Page 5 / 7 Revision Date 22-Apr-201513104 - Spray Nine Poly Scrub? 3.8 lbs. _____________________________________________________________________________________________ Contaminated packaging Do not reuse container. US EPA Waste Number Not applicable 14. TRANSPORT INFORMATION DOT Proper shipping name: Not regulated IATA Proper shipping name: Not regulated IMDG Proper shipping name: Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Not Listed. ENCS Not Listed. IECSC Complies KECL Not Listed. PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) _____________________________________________________________________________________________ Page 6 / 7 13104 - Spray Nine Poly Scrub? 3.8 lbs. Revision Date 22-Apr-2015 _____________________________________________________________________________________________ CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania PROPYLENE GLYCOL 57-55-6 X - X SODIUM SULFATE 7757-82-6 - X X Key Acid Blue FG Dye 3844-45-9 - X - U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 22-Apr-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet _____________________________________________________________________________________________ Page 7 / 7 Revision Date 22-Apr-2015 - HMIS NFPA Health hazards 1 Flammability 0 Physical hazards 0 Personal protection B Health hazards 1 13104 - Spray Nine Poly Scrub? 3.8 lbs. Flammability 0 Instability 0