SAFETY DATA SHEET Revision Date 16-May-2018 Version 4 1. IDENTIFICATION Product identifier Product Name PERMA SHIELD GASKET DRESSING & FLANGE SEALANT 2 FL.OZ Other means of identification Product Code 85420 Recommended use of the chemical and restrictions on use Recommended Use Sealant. Uses advised against No information available Details of the supplier of the safety data sheet 24-hour emergency phone number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Serious eye damage/eye irritation Category 2 Respiratory sensitization Category 1 Skin sensitization Category 1 Specific target organ toxicity (single exposure) Category 3 Specific target organ toxicity (repeated exposure) Category 2 Label elements Emergency Overview Manufacturer Address ITW Permatex 6875 Parkland Blvd. Solon, OH 44139 USA May Also Be Distributed by: ITW Permatex Canada 101-2360 Bristol Circle Oakville, ON Canada L6H 6M5 Telephone: (800) 924-6994 Flammable liquids Category 2 Signal word Danger Causes serious eye irritation May cause allergy or asthma symptoms or breathing difficulties if inhaled May cause an allergic skin reaction May cause drowsiness or dizziness May cause damage to organs through prolonged or repeated exposure _____________________________________________________________________________________________ Page 1 / 9 Highly flammable liquid and vapor _____________________________________________________________________________________________ 85420 - PERMA SHIELD GASKET DRESSING & FLANGE SEALANT 2 FL.OZ Revision Date 16-May-2018 Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling In case of inadequate ventilation wear respiratory protection Contaminated work clothing should not be allowed out of the workplace Do not breathe dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Wear protective gloves/protective clothing/eye protection/face protection Keep away from heat/sparks/open flames/hot surfaces. - No smoking Keep container tightly closed Use non-sparking tools Take precautionary measures against static discharge Keep cool Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention Specific treatment (see supplemental first aid instructions on this label) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention If skin irritation or rash occurs: Get medical advice/attention Wash contaminated clothing before reuse IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing In case of fire: Use CO2, dry chemical, or foam to extinguish. Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep container tightly closed Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information - Not applicable Unknown acute toxicity 9.96 % of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance(s) Chemical Name CAS No Weight-% ACETONE 67-64-1 30 - 60 DIPHENYLMETHANEDIISOCYANAT E 101-68-8 1 - 5 Appearance Blue Physical state Liquid Odor Ketone _____________________________________________________________________________________________ Page 2 / 9 _____________________________________________________________________________________________ 85420 - PERMA SHIELD GASKET DRESSING & FLANGE SEALANT 2 FL.OZ Revision Date 16-May-2018 ~DIPHENYLMETHANE-4,4 -DI-ISOCYANANTE ~ 5873-54-1 0.1 - 1 ETHANOL 64-17-5 0.1 - 1 Any concentration shown as a range is due to batch variation. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical Highly flammable. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. ELIMINATE all ignition sources (no smoking, _____________________________________________________________________________________________ Page 3 / 9 _____________________________________________________________________________________________ 85420 - PERMA SHIELD GASKET DRESSING & FLANGE SEALANT 2 FL.OZ Revision Date 16-May-2018 flares, sparks or flames in immediate area). Use personal protective equipment as required. Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Conditions for safe storage, including any incompatibilities Storage Conditions Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Incompatible materials Strong oxidizing agents, Bases, Reducing agents, Amines 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH ACETONE 67-64-1 STEL: 500 ppm TWA: 250 ppm TWA: 1000 ppm TWA: 2400 mg/m3 (vacated) TWA: 750 ppm (vacated) TWA: 1800 mg/m3 (vacated) STEL: 2400 mg/m3 The acetone STEL does not apply to the cellulose acetate fiber industry. It is in effect for all other sectors (vacated) STEL: 1000 ppm IDLH: 2500 ppm TWA: 250 ppm TWA: 590 mg/m3 DIPHENYLMETHANEDIISOCYANA TE 101-68-8 TWA: 0.005 ppm (vacated) Ceiling: 0.02 ppm regulated under Methylene bisphenyl isocyanate (vacated) Ceiling: 0.2 mg/m3 regulated under Methylene bisphenyl isocyanate Ceiling: 0.02 ppm Ceiling: 0.2 mg/m3 IDLH: 75 mg/m3 Ceiling: 0.020 ppm 10 min Ceiling: 0.2 mg/m3 10 min TWA: 0.005 ppm TWA: 0.05 mg/m3 ETHANOL 64-17-5 STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). _____________________________________________________________________________________________ Page 4 / 9 _____________________________________________________________________________________________ 85420 - PERMA SHIELD GASKET DRESSING & FLANGE SEALANT 2 FL.OZ Revision Date 16-May-2018 Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective natural rubber, nitrile rubber, Neoprene? or PVC gloves. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Blue Odor Ketone Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) <1% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Property Values Remarks ? Method pH No information available Melting point / freezing point No information available Boiling point / boiling range 54 ?C / 129 ?F Flash point -18 ?C / 0 ?F Evaporation rate < 1 Butyl acetate = 1 Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: 12.8% Lower flammability limit: 2.6% Vapor pressure No information available Vapor density >1 Air = 1 Relative density 1.04 Water solubility Partially soluble Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available _____________________________________________________________________________________________ Page 5 / 9 _____________________________________________________________________________________________ 85420 - PERMA SHIELD GASKET DRESSING & FLANGE SEALANT 2 FL.OZ Revision Date 16-May-2018 Chemical stability Stable under recommended storage conditions Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Incompatible materials Strong oxidizing agents, Bases, Reducing agents, Amines Hazardous Decomposition Products Carbon oxides Nitrogen oxides (NOx) Isocyanates 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause sensitization by inhalation. May cause drowsiness or dizziness. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. May cause sensitization by skin contact. Ingestion Ingestion may cause irritation to mucous membranes. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 ACETONE 67-64-1 = 5800 mg/kg ( Rat ) - = 50100 mg/m3 ( Rat ) 8 h DIPHENYLMETHANEDIISOCYANA TE 101-68-8 = 31600 mg/kg ( Rat ) = 9200 mg/kg ( Rat ) - = 369 mg/m3 ( Rat ) 4 h ETHANOL 64-17-5 = 7060 mg/kg ( Rat ) - = 124.7 mg/L ( Rat ) 4 h Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA DIPHENYLMETHANEDIISO CYANATE 101-68-8 - Group 3 - - ETHANOL 64-17-5 A3 - Known X ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Not classifiable as a human carcinogen NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) Stable under normal conditions _____________________________________________________________________________________________ Page 6 / 9 _____________________________________________________________________________________________ 85420 - PERMA SHIELD GASKET DRESSING & FLANGE SEALANT 2 FL.OZ Revision Date 16-May-2018 X - Present Target Organ Effects Central nervous system, Eyes, Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 14160 mg/kg ATEmix (dermal) 665704 mg/kg ATEmix (inhalation-dust/mist) 119.4 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity 13.4675 % of the mixture consists of component(s) of unknown hazards to the aquatic environment Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient ACETONE 67-64-1 -0.24 ETHANOL 64-17-5 -0.32 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging Do not reuse container. US EPA Waste Number D001 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status ACETONE 67-64-1 Ignitable ETHANOL 64-17-5 Toxic Ignitable 14. TRANSPORT INFORMATION DOT UN/ID no 1133 Proper shipping name: Adhesives, Limited Quantity (LQ) Hazard Class 3 Packing Group II _____________________________________________________________________________________________ Page 7 / 9 _____________________________________________________________________________________________ 85420 - PERMA SHIELD GASKET DRESSING & FLANGE SEALANT 2 FL.OZ Revision Date 16-May-2018 Emergency Response Guide Number 128 IATA UN/ID no ID 8000 Proper shipping name: Consumer commodity Hazard Class 9 ERG Code 9L IMDG UN/ID no 1133 Proper shipping name: Adhesives, Limited Quantity (LQ) Hazard Class 3 Packing Group II EmS-No F-E, S-D 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Not determined ENCS Not determined IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % DIPHENYLMETHANE DIISOCYANATE [ISOMERS AND HOMOLOGUES] - 9016-87-9 1.0 DIPHENYLMETHANEDIISOCYANATE - 101-68-8 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Yes Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) _____________________________________________________________________________________________ Page 8 / 9 CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) _____________________________________________________________________________________________ 85420 - PERMA SHIELD GASKET DRESSING & FLANGE SEALANT 2 FL.OZ Revision Date 16-May-2018 Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) ACETONE 67-64-1 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ DIPHENYLMETHANEDIISOCYANA TE 101-68-8 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 ETHANOL - 64-17-5 Carcinogen Developmental ? Ethanol is only a considered a Proposition 65 developmental hazard when it is ingested as an alcoholic beverage U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania ACETONE 67-64-1 X X X DIPHENYLMETHANE DIISOCYANATE [ISOMERS AND HOMOLOGUES] 9016-87-9 X - - DIPHENYLMETHANEDIISOCYANA TE 101-68-8 X X X ETHANOL 64-17-5 X X X ~DIPHENYLMETHANE-4,4 -DI-ISOCYANANTE ~ 2536-05-2 X - - U.S. EPA Label Information EPA Pesticide Registration Number Not applicable WHMIS Hazard Class B2 - Flammable liquid, D2B - Toxic materials 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 16-May-2018 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health hazards 2 Flammability 3 Instability 0 - HMIS Health hazards 2 Flammability 3 Physical hazards 0 Personal protection B _____________________________________________________________________________________________ Page 9 / 9