SAFETY DATA SHEET Revision Date 25-Apr-2016 Version 2 1. IDENTIFICATION Product identifier Product Name FUEL TANK REPAIR 1 OZ. Other means of identification Product Code 84334 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use (Epoxy resin) Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Skin sensitization Category 1 Label elements Emergency Overview Manufacturer Address ITW Permatex 6875 Parkland Blvd. Solon, OH 44139 USA Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Warning Causes skin irritation Causes serious eye irritation May cause an allergic skin reaction _____________________________________________________________________________________________ Page 1 / 8 _____________________________________________________________________________________________ 84334 - FUEL TANK REPAIR 1 OZ. Revision Date 25-Apr-2016 Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Avoid breathing dust/fume/gas/mist/vapors/spray Contaminated work clothing should not be allowed out of the workplace Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention Specific treatment (see supplemental first aid instructions on this label) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water Take off contaminated clothing and wash before reuse If skin irritation or rash occurs: Get medical advice/attention Precautionary Statements - Storage Store in a well-ventilated place. Keep container tightly closed Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information - This product contains crystalline silica (quartz) in a non-respirable form. Inhalation of crystalline silica is unlikely to occur from exposure to this product Unknown acute toxicity 69 % of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret BISPHENOL A/EPICHLOROHYDRIN BASED EPOXY RESIN 25068-38-6 10 - 30 * 3,6-DIAZAOCTANETHYLENEDIAMIN 112-24-3 0.1 - 1 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Appearance Gray Physical state Solid Odor Amine _____________________________________________________________________________________________ Page 2 / 8 _____________________________________________________________________________________________ 84334 - FUEL TANK REPAIR 1 OZ. Revision Date 25-Apr-2016 Skin contact IF ON SKIN:. Wash with soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical None in particular. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological Information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Ensure adequate ventilation. Take up mechanically, placing in appropriate containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE _____________________________________________________________________________________________ Page 3 / 8 _____________________________________________________________________________________________ 84334 - FUEL TANK REPAIR 1 OZ. Revision Date 25-Apr-2016 Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Incompatible materials Strong oxidizing agents 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective natural rubber, nitrile rubber, Neoprene? or PVC gloves. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Solid Appearance Gray Odor Amine Odor threshold No information available Property Values Remarks ? Method pH No information available Melting point / freezing point No information available Boiling point / boiling range Not applicable Flash point > 93 ?C / > 200 ?F Setaflash Closed Cup Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: No information available Lower flammability limit: No information available Vapor pressure No information available Vapor density No information available Relative density 1.665 _____________________________________________________________________________________________ Page 4 / 8 _____________________________________________________________________________________________ 84334 - FUEL TANK REPAIR 1 OZ. Revision Date 25-Apr-2016 Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) 0 Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Excessive heat. Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides Nitrogen oxides (NOx) Halogenated compounds Metal oxides 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. May cause sensitization by skin contact. Ingestion Ingestion may cause irritation to mucous membranes. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 BISPHENOL A/EPICHLOROHYDRIN BASED EPOXY RESIN 25068-38-6 = 11400 mg/kg ( Rat ) - - 3,6-DIAZAOCTANETHYLENEDIAM IN 112-24-3 = 2500 mg/kg ( Rat ) = 550 mg/kg ( Rabbit ) - Information on toxicological effects Water solubility No information available Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature >200?C (>392?F) Kinematic viscosity No information available Dynamic viscosity No information available _____________________________________________________________________________________________ Page 5 / 8 No data available _____________________________________________________________________________________________ 84334 - FUEL TANK REPAIR 1 OZ. Revision Date 25-Apr-2016 Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. ACGIH (American Conference of Governmental Industrial Hygienists) A2 - Suspected Human Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Group 2B - Possibly Carcinogenic to Humans Not classifiable as a human carcinogen NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Target Organ Effects Central Vascular System (CVS), Eyes, Respiratory system. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 16755 mg/kg ATEmix (dermal) 54699 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity 32 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea 3,6-DIAZAOCTANETHYLENEDIAM IN 112-24-3 2.5: 72 h Desmodesmus subspicatus mg/L EC50 20: 72 h Pseudokirchneriella subcapitata mg/L EC50 3.7: 96 h Pseudokirchneriella subcapitata mg/L EC50 570: 96 h Poecilia reticulata mg/L LC50 semi-static 495: 96 h Pimephales promelas mg/L LC50 31.1: 48 h Daphnia magna mg/L EC50 Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient 3,6-DIAZAOCTANETHYLENEDIAMIN 112-24-3 -1.4 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number Not applicable _____________________________________________________________________________________________ Page 6 / 8 _____________________________________________________________________________________________ 84334 - FUEL TANK REPAIR 1 OZ. Revision Date 25-Apr-2016 14. TRANSPORT INFORMATION DOT Proper shipping name: Not regulated IATA Proper shipping name: Not regulated IMDG Proper shipping name: Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Not determined ENCS Not determined IECSC Not determined KECL Not determined PICCS Complies AICS Not determined Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations _____________________________________________________________________________________________ Page 7 / 8 _____________________________________________________________________________________________ 84334 - FUEL TANK REPAIR 1 OZ. Revision Date 25-Apr-2016 California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 CHLORINATED PARAFFIN - 63449-39-8 Carcinogen SILICA, QUARTZ - 14808-60-7 Carcinogen U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania MAGNESIUM SILICATE 14807-96-6 X X X FERROSILICON 8049-17-0 X - - CHLORINATED PARAFFIN 63449-39-8 - X - 3,6-DIAZAOCTANETHYLENEDIAM IN 112-24-3 X X X SILICA, QUARTZ 14808-60-7 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable WHMIS Hazard Class D2B - Toxic materials 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 25-Apr-2016 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health hazards 2 Flammability 1 Instability 0 - HMIS Health hazards 2 Flammability 1 Physical hazards 0 Personal protection B _____________________________________________________________________________________________ Page 8 / 8