SAFETY DATA SHEET Revision Date 09-Dec-2015 Version 1 1. IDENTIFICATION Product identifier Product Name FUEL TANK & RADIATOR REPAIR KIT PRS Other means of identification Product Code 09116 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use (Epoxy resin) Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) NOTE: This product is a consumer product and is labeled in accordance with the US Consumer Product Safety Commission regulations which take precedence over OSHA Hazard Communication labeling. The actual container label will not include the label elements below. The labeling below applies to industrial/professional products. Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Skin sensitization Category 1 Label elements Emergency Overview Manufacturer Address ITW Permatex 6875 Parkland Blvd. Solon, OH 44139 USA Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Warning Causes skin irritation Causes serious eye irritation May cause an allergic skin reaction _____________________________________________________________________________________________ Page 1 / 9 _____________________________________________________________________________________________ 09116 - FUEL TANK & RADIATOR REPAIR KIT PRS Revision Date 09-Dec-2015 Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Avoid breathing dust/fume/gas/mist/vapors/spray Contaminated work clothing should not be allowed out of the workplace Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water Take off contaminated clothing and wash before reuse If skin irritation or rash occurs: Get medical advice/attention Precautionary Statements - Storage Store in a well-ventilated place. Keep container tightly closed Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information - Very toxic to aquatic life with long lasting effects - Contains epoxy constituents with an average molecular weight of <= 700 Unknown acute toxicity 74.4 % of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret MAGNESIUM SILICATE 14807-96-6 30 - 60 * BISPHENOL A/EPICHLOROHYDRIN BASED EPOXY RESIN 25068-38-6 10 - 30 * CHLORINATED PARAFFIN 63449-39-8 1 - 5 * SILICA, QUARTZ 14808-60-7 0.1 - 1 * 3,6-DIAZAOCTANETHYLENEDIAMIN 112-24-3 0.1 - 1 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Appearance Gray Physical state Solid Odor Amine _____________________________________________________________________________________________ Page 2 / 9 _____________________________________________________________________________________________ 09116 - FUEL TANK & RADIATOR REPAIR KIT PRS Revision Date 09-Dec-2015 Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash with soap and water. In the case of skin irritation or allergic reactions see a physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical None in particular. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological Information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. _____________________________________________________________________________________________ Page 3 / 9 _____________________________________________________________________________________________ 09116 - FUEL TANK & RADIATOR REPAIR KIT PRS Revision Date 09-Dec-2015 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Incompatible materials Strong oxidizing agents 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH MAGNESIUM SILICATE 14807-96-6 TWA: 2 mg/m3 particulate matter containing no asbestos and <1% crystalline silica, respirable fraction (vacated) TWA: 2 mg/m3 respirable dust <1% Crystalline silica, containing no Asbestos TWA: 20 mppcf if 1% Quartz or more, use Quartz limit IDLH: 1000 mg/m3 TWA: 2 mg/m3 containing no Asbestos and <1% Quartz respirable dust SILICA, QUARTZ 14808-60-7 TWA: 0.025 mg/m3 respirable fraction (vacated) TWA: 0.1 mg/m3 respirable dust : (30)/(%SiO2 + 2) mg/m3 TWA total dust : (250)/(%SiO2 + 5) mppcf TWA respirable fraction : (10)/(%SiO2 + 2) mg/m3 TWA respirable fraction IDLH: 50 mg/m3 respirable dust TWA: 0.05 mg/m3 respirable dust NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Solid Appearance Gray _____________________________________________________________________________________________ Page 4 / 9 _____________________________________________________________________________________________ 09116 - FUEL TANK & RADIATOR REPAIR KIT PRS Revision Date 09-Dec-2015 Odor Amine Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) 0 Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Excessive heat. Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides Nitrogen oxides (NOx) Halogenated compounds Metal oxides 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. Property Values Remarks ? Method pH No information available Melting point / freezing point No information available Boiling point / boiling range No information available Flash point > 95 ?C / > 203 ?F Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: No information available Lower flammability limit: No information available Vapor pressure No information available Vapor density No information available Relative density 1.665 Water solubility No information available Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature >200?C (>392?F) Kinematic viscosity No information available Dynamic viscosity No information available No data available _____________________________________________________________________________________________ Page 5 / 9 _____________________________________________________________________________________________ 09116 - FUEL TANK & RADIATOR REPAIR KIT PRS Revision Date 09-Dec-2015 Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. May cause sensitization by skin contact. Ingestion Ingestion may cause irritation to mucous membranes. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 BISPHENOL A/EPICHLOROHYDRIN BASED EPOXY RESIN 25068-38-6 = 11400 mg/kg ( Rat ) - - CHLORINATED PARAFFIN 63449-39-8 = 26100 mg/kg ( Rat ) > 10 mL/kg ( Rabbit ) - SILICA, QUARTZ 14808-60-7 = 500 mg/kg ( Rat ) - - 3,6-DIAZAOCTANETHYLENEDIAM IN 112-24-3 = 2500 mg/kg ( Rat ) = 550 mg/kg ( Rabbit ) - Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA MAGNESIUM SILICATE 14807-96-6 - Group 3 - - CHLORINATED PARAFFIN 63449-39-8 - Group 2B - X SILICA, QUARTZ 14808-60-7 A2 Group 1 Known X ACGIH (American Conference of Governmental Industrial Hygienists) A2 - Suspected Human Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Group 2B - Possibly Carcinogenic to Humans Not classifiable as a human carcinogen NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Target Organ Effects Central Vascular System (CVS), Eyes, Respiratory system. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 13837 mg/kg ATEmix (dermal) 80759 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity 32.4 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea MAGNESIUM SILICATE 14807-96-6 - 100: 96 h Brachydanio rerio g/L LC50 semi-static - CHLORINATED PARAFFIN 63449-39-8 - 300: 96 h Lepomis macrochirus mg/L LC50 static 100: 96 h Pimephales promelas mg/L LC50 static 94.5 - 271: 96 h Oncorhynchus mykiss mg/L LC50 static 0.1: 96 h Lepomis 102: 24 h Daphnia magna mg/L EC50 _____________________________________________________________________________________________ Page 6 / 9 _____________________________________________________________________________________________ 09116 - FUEL TANK & RADIATOR REPAIR KIT PRS Revision Date 09-Dec-2015 macrochirus mg/L LC50 flow-through 0.0109: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 3,6-DIAZAOCTANETHYLENEDIAM IN 112-24-3 2.5: 72 h Desmodesmus subspicatus mg/L EC50 20: 72 h Pseudokirchneriella subcapitata mg/L EC50 3.7: 96 h Pseudokirchneriella subcapitata mg/L EC50 570: 96 h Poecilia reticulata mg/L LC50 semi-static 495: 96 h Pimephales promelas mg/L LC50 31.1: 48 h Daphnia magna mg/L EC50 Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient CHLORINATED PARAFFIN 63449-39-8 >6 3,6-DIAZAOCTANETHYLENEDIAMIN 112-24-3 -1.4 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number Not applicable 14. TRANSPORT INFORMATION DOT Proper shipping name: Not regulated IATA Proper shipping name: Not regulated IMDG Proper shipping name: Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Not determined ENCS Not determined IECSC Not determined _____________________________________________________________________________________________ Page 7 / 9 _____________________________________________________________________________________________ 09116 - FUEL TANK & RADIATOR REPAIR KIT PRS Revision Date 09-Dec-2015 KECL Not determined PICCS Complies AICS Not determined Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 CHLORINATED PARAFFIN - 63449-39-8 Carcinogen SILICA, QUARTZ - 14808-60-7 Carcinogen U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania MAGNESIUM SILICATE 14807-96-6 X X X CHLORINATED PARAFFIN 63449-39-8 - X - FERROSILICON 8049-17-0 X - - SILICA, QUARTZ 14808-60-7 X X X 3,6-DIAZAOCTANETHYLENEDIAM IN 112-24-3 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable _____________________________________________________________________________________________ Page 8 / 9 WHMIS Hazard Class _____________________________________________________________________________________________ 09116 - FUEL TANK & RADIATOR REPAIR KIT PRS Revision Date 09-Dec-2015 D2A - Very toxic materials, D2B - Toxic materials NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 09-Dec-2015 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health hazards 2 Flammability 1 Instability 0 - HMIS Health hazards 2 Flammability 1 Physical hazards 0 Personal protection B _____________________________________________________________________________________________ Page 9 / 9