SAFETY DATA SHEET Revision Date 10-Sep-2018 Version 2 1. IDENTIFICATION Product identifier Product Name NON-CHLORINATED BRAKE & PARTS CLEANER 14.5OZ Other means of identification Product Code 82450 Recommended use of the chemical and restrictions on use Recommended Use Brake Cleaner Uses advised against No information available Details of the supplier of the safety data sheet 24-hour emergency phone number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address: This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Specific target organ toxicity (single exposure) Category 3 Aspiration toxicity Category 1 Label elements Emergency Overview Manufacturer Address ITW Permatex 6875 Parkland Blvd. Solon, OH 44139 USA May Also Be Distributed by: ITW Permatex Canada 101-2360 Bristol Circle Oakville, ON Canada L6H 6M5 Telephone: (800) 924-6994 Extremely flammable aerosol Category 1 Gases under pressure Dissolved gas Signal word Danger Causes skin irritation Causes serious eye irritation May cause drowsiness or dizziness May be fatal if swallowed and enters airways _____________________________________________________________________________________________ Page 1 / 9 English chemical name Extremely flammable aerosol _____________________________________________________________________________________________ 82450 - NON-CHLORINATED BRAKE & PARTS CLEANER 14.5OZ Revision Date 10-Sep-2018 Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. - No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use Precautionary Statements - Response Specific treatment (see supplemental first aid instructions on this label) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do NOT induce vomiting Precautionary Statements - Storage Store locked up Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information - Not applicable Unknown acute toxicity 10 % of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance(s) Chemical Name CAS No Weight-% ACETONE 67-64-1 70-90 HEPTANE 142-82-5 7 - 13 CARBON DIOXIDE 124-38-9 5 - 10 Contains gas under pressure; may explode if heated Appearance Clear Physical state Liquid _____________________________________________________________________________________________ Page 2 / 9 English chemical name Odor Solvent _____________________________________________________________________________________________ 82450 - NON-CHLORINATED BRAKE & PARTS CLEANER 14.5OZ Revision Date 10-Sep-2018 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Take off contaminated clothing and wash before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Call a physician or poison control center immediately. Do NOT induce vomiting. Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None Specific hazards arising from the chemical Extremely flammable. Contains gas under pressure; may explode if heated. Vapors may travel to source of ignition and flash back. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Contents under pressure. Do not puncture or incinerate cans. Remove all sources of ignition. Environmental precautions Environmental precautions See section 12 for additional ecological information. Do not flush into surface water or _____________________________________________________________________________________________ Page 3 / 9 English chemical name _____________________________________________________________________________________________ 82450 - NON-CHLORINATED BRAKE & PARTS CLEANER 14.5OZ Revision Date 10-Sep-2018 sanitary sewer system. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Wash contaminated clothing before reuse. Wash thoroughly after handling. Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Contents under pressure. Do not puncture or incinerate cans. Conditions for safe storage, including any incompatibilities Storage Conditions Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F. Store locked up. Incompatible materials Strong oxidizing agents, Amines, Acids 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH ACETONE 67-64-1 STEL: 500 ppm TWA: 250 ppm TWA: 1000 ppm TWA: 2400 mg/m3 (vacated) TWA: 750 ppm (vacated) TWA: 1800 mg/m3 (vacated) STEL: 2400 mg/m3 The acetone STEL does not apply to the cellulose acetate fiber industry. It is in effect for all other sectors (vacated) STEL: 1000 ppm IDLH: 2500 ppm TWA: 250 ppm TWA: 590 mg/m3 HEPTANE 142-82-5 STEL: 500 ppm TWA: 400 ppm TWA: 500 ppm TWA: 2000 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 1600 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 2000 mg/m3 IDLH: 750 ppm Ceiling: 440 ppm 15 min Ceiling: 1800 mg/m3 15 min TWA: 85 ppm TWA: 350 mg/m3 CARBON DIOXIDE 124-38-9 STEL: 30000 ppm TWA: 5000 ppm TWA: 5000 ppm TWA: 9000 mg/m3 (vacated) TWA: 10000 ppm (vacated) TWA: 18000 mg/m3 (vacated) STEL: 30000 ppm (vacated) STEL: 54000 mg/m3 IDLH: 40000 ppm TWA: 5000 ppm TWA: 9000 mg/m3 STEL: 30000 ppm STEL: 54000 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). _____________________________________________________________________________________________ Page 4 / 9 English chemical name Appropriate engineering controls _____________________________________________________________________________________________ 82450 - NON-CHLORINATED BRAKE & PARTS CLEANER 14.5OZ Revision Date 10-Sep-2018 Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective natural rubber, nitrile rubber, Neoprene? or PVC gloves. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Clear Odor Solvent Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) 10% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Property Values Remarks ? Method pH No information available Melting point / freezing point No information available Boiling point / boiling range 56 ?C / 132.8 ?F Flash point -17 ?C / -4 ?F Gives a flame projection at full valve opening or flashback at any degree of valve opening Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: 12.8% Lower flammability limit: 2.5% Vapor pressure No information available Vapor density No information available Relative density 0.8 Water solubility No information available Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available _____________________________________________________________________________________________ Page 5 / 9 English chemical name _____________________________________________________________________________________________ 82450 - NON-CHLORINATED BRAKE & PARTS CLEANER 14.5OZ Revision Date 10-Sep-2018 Chemical stability Stable under recommended storage conditions Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Temperatures >50 ?C / 122 ?F. Incompatible materials Strong oxidizing agents, Amines, Acids Hazardous Decomposition Products Carbon oxides 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. May cause drowsiness or dizziness. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion Potential for aspiration if swallowed. Aspiration may cause pulmonary edema and pneumonitis. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 ACETONE 67-64-1 = 5800 mg/kg ( Rat ) - = 50100 mg/m3 ( Rat ) 8 h HEPTANE 142-82-5 - = 3000 mg/kg ( Rabbit ) = 103 g/m3 ( Rat ) 4 h Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity No information available. Target Organ Effects Central nervous system, Central Vascular System (CVS), Eyes, Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 7250 mg/kg ATEmix (dermal) 30000 mg/kg ATEmix (inhalation-dust/mist) 101 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity 10 % of the mixture consists of component(s) of unknown hazards to the aquatic environment Persistence and degradability No information available. Stable under normal conditions _____________________________________________________________________________________________ Page 6 / 9 English chemical name _____________________________________________________________________________________________ 82450 - NON-CHLORINATED BRAKE & PARTS CLEANER 14.5OZ Revision Date 10-Sep-2018 Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient ACETONE 67-64-1 -0.24 HEPTANE 142-82-5 4.66 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging Do not reuse container. US EPA Waste Number D001 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status ACETONE 67-64-1 Ignitable HEPTANE 142-82-5 Toxic Ignitable 14. TRANSPORT INFORMATION DOT UN/ID No 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 2.1 Emergency Response Guide Number 126 IATA UN/ID No ID 8000 Proper shipping name: Consumer commodity Hazard Class 9 ERG Code 9L IMDG UN/ID No 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 2.1 EmS-No F-D, S-U _____________________________________________________________________________________________ Page 7 / 9 English chemical name _____________________________________________________________________________________________ 82450 - NON-CHLORINATED BRAKE & PARTS CLEANER 14.5OZ Revision Date 10-Sep-2018 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) ACETONE 67-64-1 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ US State Regulations California Proposition 65 This product is not known to contain any chemicals listed as carcinogens or reproductive toxins U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania ACETONE 67-64-1 X X X HEPTANE 142-82-5 X X X CARBON DIOXIDE 124-38-9 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable _____________________________________________________________________________________________ Page 8 / 9 English chemical name _____________________________________________________________________________________________ 82450 - NON-CHLORINATED BRAKE & PARTS CLEANER 14.5OZ Revision Date 10-Sep-2018 WHMIS Hazard Class A Compressed gases, B5 - Flammable aerosol, D2B - Toxic materials 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 10-Sep-2018 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health hazards 2 Flammability 3 Instability 0 - HMIS Health hazards 2 Flammability 3 Physical hazards 0 Personal protection B _____________________________________________________________________________________________ Page 9 / 9 English chemical name