SAFETY DATA SHEET Revision Date 19-Apr-2016 Version 5 1. IDENTIFICATION Product identifier Product Name ADHESIVE SEALANT BLACK SILICONE 12.9 OZ Other means of identification Product Code 81173 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Sealant Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Serious eye damage/eye irritation Category 2A Skin sensitization Category 1 Carcinogenicity Category 2 Label elements Emergency Overview Manufacturer Address ITW Permatex 6875 Parkland Blvd. Solon, OH 44139 USA Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Warning Causes serious eye irritation May cause an allergic skin reaction Suspected of causing cancer _____________________________________________________________________________________________ Page 1 / 8 _____________________________________________________________________________________________ 81173 - ADHESIVE SEALANT BLACK SILICONE 12.9 OZ Revision Date 19-Apr-2016 Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Avoid breathing dust/fume/gas/mist/vapors/spray Contaminated work clothing should not be allowed out of the workplace Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention Specific treatment (see supplemental first aid instructions on this label) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water If skin irritation or rash occurs: Get medical advice/attention Wash contaminated clothing before reuse Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information - Not applicable Unknown acute toxicity 29.274 % of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 3 - 7 * 2-BUTANONE OXIME 96-29-7 1 - 5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical Appearance Black Physical state Paste Odor Mild _____________________________________________________________________________________________ Page 2 / 8 _____________________________________________________________________________________________ 81173 - ADHESIVE SEALANT BLACK SILICONE 12.9 OZ Revision Date 19-Apr-2016 advice/attention. Skin contact IF ON SKIN:. Wash with soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Use personal protective equipment as required. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical None in particular. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological Information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Ensure adequate ventilation. Flood with water to complete polymerization and scrape off floor. Sweep up and shovel into suitable containers for disposal. Slippery, can cause falls if walked on. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. _____________________________________________________________________________________________ Page 3 / 8 _____________________________________________________________________________________________ 81173 - ADHESIVE SEALANT BLACK SILICONE 12.9 OZ Revision Date 19-Apr-2016 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Keep container tightly closed in a dry and well-ventilated place. Protect from moisture. Incompatible materials Strong oxidizing agents, Acids, Water 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Tight sealing safety goggles. Skin and body protection Wear protective natural rubber, nitrile rubber, Neoprene? or PVC gloves. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations When using do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Paste Appearance Black Odor Mild Odor threshold No information available Property Values Remarks ? Method pH No information available Melting point / freezing point No information available Boiling point / boiling range Not Applicable Polymerization Flash point > 93 ?C / > 200 ?F Tag Closed Cup Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: No information available _____________________________________________________________________________________________ Page 4 / 8 _____________________________________________________________________________________________ 81173 - ADHESIVE SEALANT BLACK SILICONE 12.9 OZ Revision Date 19-Apr-2016 Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) 3.2%, 45.87 g/l Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Excessive heat. Incompatible materials Strong oxidizing agents, Acids, Water Hazardous Decomposition Products Carbon oxides Nitrogen oxides (NOx) Formaldehyde May release 2-butanone oxime (ethyl methyl ketoxime) at elevated temperature 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. May cause sensitization by skin contact. Ingestion Ingestion may cause irritation to mucous membranes. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 > 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 5.2 mg/L ( Rat ) 4 h 2-BUTANONE OXIME = 930 mg/kg ( Rat ) = 0.2 mg/kg ( Rabbit ) = 20 mg/L ( Rat ) 4 h Lower flammability limit: No information available Vapor pressure <5 mm Hg Vapor density 3.0 Air = 1 Relative density 1.43 Water solubility Not applicable Polymerization Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available No data available _____________________________________________________________________________________________ Page 5 / 8 _____________________________________________________________________________________________ 81173 - ADHESIVE SEALANT BLACK SILICONE 12.9 OZ Revision Date 19-Apr-2016 96-29-7 Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 2B - Possibly Carcinogenic to Humans OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Target Organ Effects Eyes, Lymphatic System, Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 14090 mg/kg ATEmix (dermal) 9616 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity 95.074 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 - 45: 96 h Pimephales promelas mg/L LC50 flow-through 2.2: 96 h Lepomis macrochirus mg/L LC50 static 2.4: 96 h Oncorhynchus mykiss mg/L LC50 static 4720: 96 h Den-dronereides heteropoda mg/L LC50 2-BUTANONE OXIME 96-29-7 83: 72 h Desmodesmus subspicatus mg/L EC50 777 - 914: 96 h Pimephales promelas mg/L LC50 flow-through 760: 96 h Poecilia reticulata mg/L LC50 static 320 - 1000: 96 h Leuciscus idus mg/L LC50 static 750: 48 h Daphnia magna mg/L EC50 Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient 2-BUTANONE OXIME 96-29-7 0.65 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. _____________________________________________________________________________________________ Page 6 / 8 _____________________________________________________________________________________________ 81173 - ADHESIVE SEALANT BLACK SILICONE 12.9 OZ Revision Date 19-Apr-2016 Contaminated packaging Do not reuse container. US EPA Waste Number Not applicable 14. TRANSPORT INFORMATION DOT Proper shipping name: Not regulated IATA Proper shipping name: Not regulated IMDG Proper shipping name: Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Not Listed. ENCS Not Listed. IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) _____________________________________________________________________________________________ Page 7 / 8 CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and _____________________________________________________________________________________________ 81173 - ADHESIVE SEALANT BLACK SILICONE 12.9 OZ Revision Date 19-Apr-2016 Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 CARBON BLACK - 1333-86-4 Carcinogen SILICA, QUARTZ - 14808-60-7 Carcinogen U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania LIMESTONE 1317-65-3 X X X CARBON BLACK 1333-86-4 X X X SILICA, QUARTZ 14808-60-7 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable WHMIS Hazard Class D2B - Toxic materials 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 19-Apr-2016 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health hazards 2 Flammability 1 Instability 0 - HMIS Health hazards 2 Flammability 1 Physical hazards 0 Personal protection B _____________________________________________________________________________________________ Page 8 / 8