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JOHNSEN'S A/C FLUSH 32 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 05/02/2017 Supersedes:12/04/2015 Version: 1.2 02/05/2017 EN (English) 1/11 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : JOHNSEN'S A/C FLUSH 32 FL.OZ. Product code : 6545-6 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : A/C Flush 1.3. Details of the supplier of the safety data sheet Technical Chemical Company P.O. BOX 139 Cleburne, Texas 76033 T 817-645-6088 1.4. Emergency telephone number Emergency number : CHEMTREC 24 Hour 1-800-424-9300, 1-703-527-3887 (International) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Flam. Liq. 2 H225 Skin Irrit. 2 H315 Eye Irrit. 2 H319 Repr. 2 H361 STOT SE 3 H336 STOT RE 2 H373 Asp. Tox. 1 H304 Full text of H statements : see section 16 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS02 GHS07 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H225 - Highly flammable liquid and vapour H304 - May be fatal if swallowed and enters airways H315 - Causes skin irritation H319 - Causes serious eye irritation H336 - May cause drowsiness or dizziness H361 - Suspected of damaging fertility or the unborn child H373 - May cause damage to organs through prolonged or repeated exposure Precautionary statements (GHS-US) : P201 - Obtain special instructions P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat,sparks,open flames,hot surfaces. - No smoking P233 - Keep container tightly closed P240 - Ground/Bond container and receiving equipment P241 - Use explosion-proof electrical, ventilating, lighting equipment P242 - Use only non-sparking tools P243 - Take precautionary measures against static discharge P260 - Do not breathe dust, fumes, gas,mist, vapor spray P261 - Avoid breathing dust,fume,gas,mist,vapor spray P264 - Wash affected areas thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves,protective clothing,eye protection,face protection P301+P310 - If swallowed: Immediately call a poison control center, doctor,physician. P302+P352 - If on skin: Wash with plenty of soap and water P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P308+P313 - If exposed or concerned: Get medical advice/attention JOHNSEN'S A/C FLUSH 32 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 02/05/2017 EN (English) 2/11 P312 - Call a POISON CONTROL CENTER, doctor, if you feel unwell. P314 - Get medical advice/attention if you feel unwell P321 - Specific treatment: See section 4.1 on SDS P331 - Do NOT induce vomiting P332+P313 - If skin irritation occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P362+P364 - Take off contaminated clothing and wash it before reuse P370+P378 - In case of fire: See Section 5.1 Extinguishing Media P403+P233 - Store in a well-ventilated place. Keep container tightly closed P403+P235 - Store in a well-ventilated place. Keep cool P405 - Store locked up P501 - Dispose of contents/container to appropriate waste disposal facility, in accordance with local, regional, national, international regulations. 2.3. Other hazards Other hazards not contributing to the classification : None under normal conditions. 2.4. Unknown acute toxicity (GHS US) 75 percent of the mixture consists of ingredient(s) of unknown acute toxicity (Oral) 75 percent of the mixture consists of ingredient(s) of unknown acute toxicity (Dermal) SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % GHS-US classification Heptane, Branched Cyclic (CAS No) 426260-76-6 72 - 75 Flam. Liq. 1, H224 Skin Irrit. 2, H315 STOT SE 3, H336 Asp. Tox. 1, H304 Aquatic Chronic 3, H412 n-Heptane (CAS No) 142-82-5 18.75 - 33.75 Flam. Liq. 2, H225 Skin Irrit. 2, H315 STOT SE 3, H336 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 2-Propanol (CAS No) 67-63-0 10 - 30 Flam. Liq. 2, H225 Eye Irrit. 2A, H319 STOT SE 3, H336 Toluene (CAS No) 108-88-3 0.75 - 3 Flam. Liq. 2, H225 Skin Irrit. 2, H315 Repr. 2, H361 STOT SE 3, H336 STOT RE 2, H373 Asp. Tox. 1, H304 The exact percentage is a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. IF exposed or concerned: Get medical advice/attention. First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Suspected of damaging fertility or the unborn child. Causes damage to organs. Symptoms/injuries after inhalation : May cause drowsiness or dizziness. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Symptoms/injuries after skin contact : Causes skin irritation. Itching. Skin rash/inflammation. Red skin. Symptoms/injuries after eye contact : Causes serious eye irritation. Inflammation/damage of the eye tissue. Irritation of the eye tissue. Redness of the eye tissue. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. JOHNSEN'S A/C FLUSH 32 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 02/05/2017 EN (English) 3/11 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Highly flammable liquid and vapour. Explosion hazard : May form flammable/explosive vapour-air mixture. 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking. 6.1.1. For non-emergency personnel Protective equipment : Gloves. Safety glasses. Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Avoid breathing dust,fume,gas,mist,vapor spray. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers. Plug the leak, cut off the supply. Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Handle empty containers with care because residual vapours are flammable. Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. No open flames. No smoking. Use only non-sparking tools. Obtain special instructions . Do not handle until all safety precautions have been read and understood. Avoid breathing dust,fume,gas,mist,vapor spray. Use only outdoors or in a well-ventilated area. Hygiene measures : Wash affected areas thoroughly after handling. Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse. Remove contaminated clothes. Separate working clothes from town clothes. Launder separately. Take off immediately all contaminated clothing and wash it before reuse. Always wash hands after handling the product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating, lighting equipment. Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep in fireproof place. Keep container tightly closed. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Heat sources. 7.3. Specific end use(s) Follow Label Directions. JOHNSEN'S A/C FLUSH 32 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 02/05/2017 EN (English) 4/11 SECTION 8: Exposure controls/personal protection 8.1. Control parameters Toluene (108-88-3) USA ACGIH ACGIH TWA (mg/m?) 75 mg/m? USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (ppm) 200 ppm USA OSHA OSHA PEL (Ceiling) (ppm) 300 ppm n-Heptane (142-82-5) USA ACGIH ACGIH TWA (ppm) 400 ppm (Heptane, all isomers; USA; Time-weighted average exposure limit 8 h; TLV - Adopted Value) USA ACGIH ACGIH STEL (ppm) 500 ppm (Heptane, all isomers; USA; Short time value; TLV - Adopted Value) Heptane, Branched Cyclic (426260-76-6) USA ACGIH ACGIH TWA (ppm) 400 ppm USA ACGIH ACGIH STEL (ppm) 500 ppm USA OSHA OSHA PEL (TWA) (ppm) 500 ppm 2-Propanol (67-63-0) USA ACGIH ACGIH TWA (mg/m?) 980 mg/m? USA ACGIH ACGIH TWA (ppm) 400 ppm USA ACGIH ACGIH STEL (mg/m?) 1225 mg/m? USA ACGIH ACGIH STEL (ppm) 500 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 980 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 400 ppm 8.2. Exposure controls Appropriate engineering controls : Local exhaust venilation, vent hoods . Ensure good ventilation of the work station. Personal protective equipment : Gloves. Safety glasses. Avoid all unnecessary exposure. Materials for protective clothing : GIVE EXCELLENT RESISTANCE: Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Skin and body protection : Wear suitable protective clothing. Respiratory protection : Where exposure through inhalation may occur from use, respiratory protection equipment is recommended. Wear respiratory protection. Environmental exposure controls : Avoid release to the environment. Consumer exposure controls : Avoid contact during pregnancy/while nursing. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Liquid. Colour : Colourless to light yellow. Odour : Solvent-like odour. Lemon. Odour threshold : No data available pH : No data available Relative evaporation rate (butylacetate=1) : No data available Melting point : No data available Freezing point : No data available Boiling point : 82 ?C Flash point : 2 ?C Auto-ignition temperature : No data available JOHNSEN'S A/C FLUSH 32 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 02/05/2017 EN (English) 5/11 Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapour pressure : No data available Relative vapour density at 20 ?C : 2.1 Relative density : 0.79 Relative density of saturated gas/air mixture : 1.05 Density : 785 kg/m? Solubility : Poorly soluble in water. Water: Poor Ethanol: Complete Ether: Complete Acetone: soluble Log Pow : No data available Log Kow : No data available Viscosity, kinematic : 2.5316 mm?/s (25 ?C) Viscosity, dynamic : 0.002 Pa.s (25 ?C) Explosive properties : No data available Oxidising properties : No data available Explosive limits : 2 - 13 vol % 50 - 335 g/m? 9.2. Other information VOC content : 100 % Gas group : Liquefied gas SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Highly flammable liquid and vapour. May form flammable/explosive vapour-air mixture. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. Open flame. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products Toxic fume. . Carbon monoxide. Carbon dioxide. May release flammable gases. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified as hazardous Toluene (108-88-3) LD50 oral rat 5580 mg/kg bodyweight (Rat; Equivalent or similar to OECD 401; Literature study; 5580 mg/kg bodyweight; Rat; Experimental value) LD50 dermal rabbit > 5000 mg/kg bodyweight LD50 quoted as 14.1 mL/kg (12267 mg/kg using density of 0.87) LC50 inhalation rat (mg/l) > 28.1 mg/l/4h (Rat; Air, Literature study) n-Heptane (142-82-5) LD50 oral rat > 15000 mg/kg (Rat; Equivalent or similar to OECD 401; Literature study; >5000 mg/kg bodyweight; Rat; Read-across) LD50 dermal rabbit > 3160 mg/kg (Rabbit; Literature study; Equivalent or similar to OECD 402; >2000 mg/kg bodyweight; Rabbit; Read-across) LC50 inhalation rat (mg/l) 103 mg/l/4h (Rat; Literature study) LC50 inhalation rat (ppm) 25000 ppm/4h (Rat; Literature study) Heptane, Branched Cyclic (426260-76-6) LD50 oral rat > 15000 mg/kg (Rat; Equivalent or similar to OECD 401; Literature study; >5000 mg/kg bodyweight; Rat; Read-across) LD50 dermal rabbit > 3160 mg/kg (Rabbit; Literature study; Equivalent or similar to OECD 402; >2000 mg/kg bodyweight; Rabbit; Read-across) JOHNSEN'S A/C FLUSH 32 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 02/05/2017 EN (English) 6/11 Heptane, Branched Cyclic (426260-76-6) LC50 inhalation rat (mg/l) 103 mg/l/4h (Rat; Literature study) LC50 inhalation rat (ppm) 25000 ppm/4h (Rat; Literature study) 2-Propanol (67-63-0) LD50 dermal rabbit 12870 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402; 16.4; Rabbit) LC50 inhalation rat (mg/l) 73 mg/l/4h (Rat) Skin corrosion/irritation : Causes skin irritation. Serious eye damage/irritation : Causes serious eye irritation. Respiratory or skin sensitisation : Not classified as hazardous Germ cell mutagenicity : Not classified as hazardous Based on available data, the classification criteria are not met Carcinogenicity : Not classified as hazardous Toluene (108-88-3) IARC group 3 2-Propanol (67-63-0) IARC group 3 Reproductive toxicity : Suspected of damaging fertility or the unborn child. Specific target organ toxicity (single exposure) : May cause drowsiness or dizziness. Specific target organ toxicity (repeated exposure) : May cause damage to organs through prolonged or repeated exposure. Aspiration hazard : May be fatal if swallowed and enters airways. Potential adverse human health effects and symptoms : Based on available data, the classification criteria are not met. Symptoms/injuries after inhalation : May cause drowsiness or dizziness. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Symptoms/injuries after skin contact : Causes skin irritation. Itching. Skin rash/inflammation. Red skin. Symptoms/injuries after eye contact : Causes serious eye irritation. Inflammation/damage of the eye tissue. Irritation of the eye tissue. Redness of the eye tissue. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. SECTION 12: Ecological information 12.1. Toxicity n-Heptane (142-82-5) EC50 Daphnia 1 0.2 mg/l (LC50; Other; 96 h; Chaetogammarus marinus; Semi-static system; Salt water; Experimental value) 2-Propanol (67-63-0) LC50 fish 2 9640 mg/l (LC50; OECD 203: Fish, Acute Toxicity Test; 96 h; Pimephales promelas; Flow- through system; Fresh water; Experimental value) EC50 Daphnia 2 13299 mg/l (EC50; Other; 48 h; Daphnia magna) 12.2. Persistence and degradability JOHNSEN'S A/C FLUSH 32 FL.OZ. Persistence and degradability Not established. Toluene (108-88-3) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Low potential for adsorption in soil. Biochemical oxygen demand (BOD) 2.15 g O? /g substance Chemical oxygen demand (COD) 2.52 g O? /g substance ThOD 3.13 g O? /g substance BOD (% of ThOD) 0.69 n-Heptane (142-82-5) Persistence and degradability Readily biodegradable in water. Forming sediments in water. Biodegradable in the soil. Low potential for adsorption in soil. Photolysis in the air. Not established. Biochemical oxygen demand (BOD) 1.92 g O? /g substance Chemical oxygen demand (COD) 0.06 g O? /g substance ThOD 3.52 g O? /g substance BOD (% of ThOD) > 0.5 (5 days; Literature study) Heptane, Branched Cyclic (426260-76-6) Persistence and degradability May cause long-term adverse effects in the environment. JOHNSEN'S A/C FLUSH 32 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 02/05/2017 EN (English) 7/11 2-Propanol (67-63-0) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under anaerobic conditions. No (test)data on mobility of the substance available. Biochemical oxygen demand (BOD) 1.19 g O? /g substance Chemical oxygen demand (COD) 2.23 g O? /g substance ThOD 2.4 g O? /g substance 12.3. Bioaccumulative potential JOHNSEN'S A/C FLUSH 32 FL.OZ. Bioaccumulative potential Not established. Toluene (108-88-3) BCF fish 2 90 (BCF; 72 h; Leuciscus idus; Static system; Fresh water) Log Pow 2.73 (Experimental value; Other; 20 ?C) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). n-Heptane (142-82-5) BCF other aquatic organisms 1 552 (BCF; BCFBAF v3.00) Log Pow 4.66 (Experimental value; 4.5; Literature study) Bioaccumulative potential Potential for bioaccumulation (4 ? Log Kow ? 5). Not established. Heptane, Branched Cyclic (426260-76-6) Bioaccumulative potential Not established. 2-Propanol (67-63-0) Log Pow 0.05 (Weight of evidence approach; Other; 25 ?C) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). 12.4. Mobility in soil Toluene (108-88-3) Surface tension 0.03 N/m (20 ?C) n-Heptane (142-82-5) Surface tension 0.019 N/m (25 ?C; 0.020 N/m; 20 ?C) Log Koc log Koc,SRC PCKOCWIN v2.0; 2.38; Calculated value 2-Propanol (67-63-0) Surface tension 0.021 N/m (25 ?C) 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to appropriate waste disposal facility, in accordance with local, regional, national, international regulations. Additional information : Handle empty containers with care because residual vapours are flammable. Ecology - waste materials : Avoid release to the environment. Hazardous waste due to toxicity. JOHNSEN'S A/C FLUSH 32 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 02/05/2017 EN (English) 8/11 SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN US DOT (ground): UN1993, Flammable liquids, n.o.s. (Heptane, 2-Propanol), 3, II, Limited Quantity ICAO/IATA (air): UN1993, Flammable liquids, n.o.s. (Heptane, 2-Propanol), 3 , II, Limited Quantity IMO/IMDG (water): UN1993, Flammable liquids, n.o.s. (Heptane, 2-Propanol), 3 (Marine Pollutant-Heptane), II, Limited Quantity Special Provisions: B1 - If the material has a flash point at or above 38 C (100 F) and below 93 C (200 F), then the bulk packaging requirements of 173.241 of this subchapter are applicable. If the material has a flash point of less than 38 C (100 F), then the bulk packaging requirements of 173.242 of this subchapter are applicable. B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure relief devices are authorized on DOT 57 portable tanks. IB3 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized, except for UN2672 (also see Special Provision IP8 in Table 2 for UN2672). T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3) TP1 - The maximum degree of filling must not exceed the degree of filling determined by the following: Degree of filling = 97 / (1 + a (tr - tf)) Where: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. TP29 - A portable tank having a minimum test pressure of 1.5 bar (150.0 kPa) may be used provided the calculated test pressure is 1.5 bar or less based on the MAWP of the hazardous materials, as defined in 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. Not applicable 14.2. UN proper shipping name Proper Shipping Name (DOT) : Flammable liquids, n.o.s. (Heptane, 2-Propanol) Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120 Hazard labels (DOT) : 3 - Flammable liquid DOT Symbols : G - Identifies PSN requiring a technical name Packing group (DOT) : II - Medium Danger DOT Special Provisions (49 CFR 172.102) : B1 - If the material has a flash point at or above 38 C (100 F) and below 93 C (200 F), then the bulk packaging requirements of 173.241 of this subchapter are applicable. If the material has a flash point of less than 38 C (100 F), then the bulk packaging requirements of 173.242 of this subchapter are applicable. B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure relief devices are authorized on DOT 57 portable tanks. IB3 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized, except for UN2672 (also see Special Provision IP8 in Table 2 for UN2672). T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3) TP1 - The maximum degree of filling must not exceed the degree of filling determined by the following: Degree of filling = 97 / (1 + a (tr - tf)) Where: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. TP29 - A portable tank having a minimum test pressure of 1.5 bar (150.0 kPa) may be used provided the calculated test pressure is 1.5 bar or less based on the MAWP of the hazardous materials, as defined in 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. DOT Packaging Exceptions (49 CFR 173.xxx) : 150 DOT Packaging Non Bulk (49 CFR 173.xxx) : 203 DOT Packaging Bulk (49 CFR 173.xxx) : 242 14.3. Additional information Other information : No supplementary information available. Overland transport No additional information available Transport by sea DOT Vessel Stowage Location : A - The material may be stowed ??on deck?? or ??under deck?? on a cargo vessel and on a passenger vessel. Subsidiary risk (IMDG) : Marine Pollutant-Heptane JOHNSEN'S A/C FLUSH 32 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 02/05/2017 EN (English) 9/11 Air transport DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) : 60 L DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75) : 220 L SECTION 15: Regulatory information 15.1. US Federal regulations JOHNSEN'S A/C FLUSH 32 FL.OZ. SARA Section 311/312 Hazard Classes Fire hazard Delayed (chronic) health hazard Immediate (acute) health hazard Toluene (108-88-3) Subject to reporting requirements of United States SARA Section 313 Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States SARA Section 302 SARA Section 311/312 Hazard Classes Delayed (chronic) health hazard Fire hazard Immediate (acute) health hazard Heptane, Branched Cyclic (426260-76-6) Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes Fire hazard Immediate (acute) health hazard Delayed (chronic) health hazard 2-Propanol (67-63-0) Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Fire hazard 15.2. International regulations CANADA JOHNSEN'S A/C FLUSH 32 FL.OZ. WHMIS Classification Class B Division 2 - Flammable Liquid Toluene (108-88-3) Listed on the Canadian DSL (Domestic Substances List) WHMIS Classification Class B Division 2 - Flammable Liquid Class D Division 2 Subdivision A - Very toxic material causing other toxic effects Class D Division 2 Subdivision B - Toxic material causing other toxic effects Heptane, Branched Cyclic (426260-76-6) WHMIS Classification Class B Division 2 - Flammable Liquid Class D Division 2 Subdivision B - Toxic material causing other toxic effects 2-Propanol (67-63-0) Listed on the Canadian DSL (Domestic Substances List) WHMIS Classification Class B Division 2 - Flammable Liquid EU-Regulations Toluene (108-88-3) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Heptane, Branched Cyclic (426260-76-6) 2-Propanol (67-63-0) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] F; R11 Xn; R65 Xi; R36/38 N; R50/53 R67 Full text of R-phrases: see section 16 15.2.2. National regulations JOHNSEN'S A/C FLUSH 32 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 02/05/2017 EN (English) 10/11 Heptane, Branched Cyclic (426260-76-6) All components are either listed on the US TSCA Inventory, or are not regulated under TSCA under 40 CFR 720.30. 2-Propanol (67-63-0) Listed on the AICS (Australian Inventory of Chemical Substances) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on KECI (Korean Existing Chemicals Inventory) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) 15.3. US State regulations JOHNSEN'S A/C FLUSH 32 FL.OZ. U.S. - California - Proposition 65 - Carcinogens List No U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No State or local regulations U.S. - California - Proposition 65 Toluene (108-88-3) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male Non-significant risk level (NSRL) No Yes No No n-Heptane (142-82-5) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male Non-significant risk level (NSRL) No No No No Heptane, Branched Cyclic (426260-76-6) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male Non-significant risk level (NSRL) No No No No 2-Propanol (67-63-0) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male Non-significant risk level (NSRL) No No No No Toluene (108-88-3) State or local regulations U.S. - California - Proposition 65 U.S. - New Jersey - Special Health Hazards Substances List New Jersey Right-to-Know U.S. - Massachusetts - Right To Know List Rhode Island Right to Know U.S. - Michigan - Critical Materials List U.S. - New Jersey - Environmental Hazardous Substances List U.S. - Illinois - Toxic Air Contaminants U.S. - New York - Reporting of Releases Part 597 - List of Hazardous Substances U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List 2-Propanol (67-63-0) State or local regulations U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List SECTION 16: Other information Indication of changes : Revision - See : *. JOHNSEN'S A/C FLUSH 32 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 02/05/2017 EN (English) 11/11 Other information : None. Full text of H-statements: ------ H224 Extremely flammable liquid and vapour ------ H225 Highly flammable liquid and vapour ------ H304 May be fatal if swallowed and enters airways ------ H315 Causes skin irritation ------ H319 Causes serious eye irritation ------ H336 May cause drowsiness or dizziness ------ H361 Suspected of damaging fertility or the unborn child ------ H373 May cause damage to organs through prolonged or repeated exposure ------ H400 Very toxic to aquatic life ------ H410 Very toxic to aquatic life with long lasting effects ------ H412 Harmful to aquatic life with long lasting effects NFPA health hazard : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. NFPA fire hazard : 3 - Liquids and solids that can be ignited under almost all ambient conditions. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health : 2 Moderate Hazard - Temporary or minor injury may occur Flammability : 3 Serious Hazard Physical : 0 Minimal Hazard Personal Protection : B SDS US (GHS HazCom 2012) - TCC The Supplier identified in Section 1 of this SDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable. However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made or implied.