JOHNSEN'S ESTER OIL CHARGE R134 3 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 08/04/2017 Supersedes:12/04/2015 Version: 1.2 08/08/2017 EN (English US) 1/7 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : JOHNSEN'S ESTER OIL CHARGE R134 3 OZ. Product code : 6725 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Oil Charge 1.3. Details of the supplier of the safety data sheet Technical Chemical Company P.O. BOX 139 Cleburne, Texas 76033 T 817-645-6088 1.4. Emergency telephone number Emergency number : CHEMTREC 24 Hour 1-800-424-9300, 1-703-527-3887 (International) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Liquefied gas H280 Full text of H statements : see section 16 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS04 Signal word (GHS-US) : Warning Hazard statements (GHS-US) : H280 - Contains gas under pressure; may explode if heated Precautionary statements (GHS-US) : P410+P403 - Protect from sunlight. Store in a well-ventilated place P251 - Pressurized container: Do not pierce or burn, even after use P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F 2.3. Other hazards Other hazards not contributing to the classification : Contact with liquid may cause cold burns/frostbite. Contains gas under pressure; may explode if heated. May Cause frostbite in contact with skin. May Cause frostbite in contact with skin. (Liquid form can be ejected if the aerosol can is not held upright during use.) Warning. Intentional misuse and inhalation abuse may cause cardiac or central nervous systems effects. Warning. 2.4. Unknown acute toxicity (GHS US) No data available SECTION 3: Composition/Information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % GHS-US classification 1,1,1,2-Tetrafluoroethane (CAS No) 811-97-2 50 - 70 Liquefied gas, H280 Ester (CAS No) Proprietary 30 - 50 Not classified Proprietary Inhibitor Package (CAS No) Proprietary 5 - 10 Not classified The exact percentage is a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest. JOHNSEN'S ESTER OIL CHARGE R134 3 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 08/08/2017 EN (English US) 2/7 First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use. Symptoms/injuries after inhalation : Coughing. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. May cause irritation or asthma-like symptoms. May cause drowsiness or dizziness. Symptoms/injuries after skin contact : Blisters. Red skin. Itching. Symptoms/injuries after eye contact : May cause slight eye irritation . Irritation of the eye tissue. Inflammation/damage of the eye tissue. Redness of the eye tissue. Symptoms/injuries after ingestion : May be harmful if swallowed and enters airways. May be fatal if swallowed and enters airways. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture No additional information available 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Other information : NFPA Aerosol Level 1. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. 6.1.1. For non-emergency personnel Protective equipment : Gloves. Safety glasses. Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers. Plug the leak, cut off the supply. Methods for cleaning up : Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Pressurized container: Do not pierce or burn, even after use. Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Wash contaminated clothing before reuse. Wash affected areas thoroughly after handling. Do not eat, drink or smoke when using this product. Remove contaminated clothes. Separate working clothes from town clothes. Launder separately. Always wash hands after handling the product. Take off immediately all contaminated clothing and wash it before reuse. JOHNSEN'S ESTER OIL CHARGE R134 3 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 08/08/2017 EN (English US) 3/7 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Comply with applicable regulations. Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Storage area : Store in a well-ventilated place. 7.3. Specific end use(s) Follow Label Directions. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls : Local exhaust venilation, vent hoods . Ensure good ventilation of the work station. Personal protective equipment : Gloves. Safety glasses. Avoid all unnecessary exposure. Materials for protective clothing : GIVE EXCELLENT RESISTANCE: Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Skin and body protection : Wear suitable protective clothing. Respiratory protection : Wear appropriate mask. Environmental exposure controls : Avoid release to the environment. Consumer exposure controls : Avoid contact during pregnancy/while nursing. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Gas Appearance : Liquid. Color : Colourless to yellow. Odor : Characteristic. Petroleum-like odour. Odor threshold : No data available pH : No data available Relative evaporation rate (butyl acetate=1) : No data available Melting point : No data available Freezing point : No data available Boiling point : No data available Flash point : > 149 ?C Auto-ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : No data available Relative vapor density at 20 ?C : No data available Relative density : 0.99 Solubility : Insoluble in water. Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosion limits : No data available JOHNSEN'S ESTER OIL CHARGE R134 3 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 08/08/2017 EN (English US) 4/7 9.2. Other information VOC content : 0 % Gas group : Liquefied gas SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products Toxic fume. . Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified 1,1,1,2-Tetrafluoroethane (811-97-2) LC50 inhalation rat (mg/l) > 2000 mg/l/4h (Rat; Literature study) LC50 inhalation rat (ppm) > 359300 ppm/4h (Rat; Literature study) Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified Specific target organ toxicity ? single exposure : Not classified Specific target organ toxicity ? repeated exposure : Not classified Aspiration hazard : Not classified Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. Symptoms/injuries after inhalation : Coughing. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. May cause irritation or asthma-like symptoms. May cause drowsiness or dizziness. Symptoms/injuries after skin contact : Blisters. Red skin. Itching. Symptoms/injuries after eye contact : May cause slight eye irritation . Irritation of the eye tissue. Inflammation/damage of the eye tissue. Redness of the eye tissue. Symptoms/injuries after ingestion : May be harmful if swallowed and enters airways. May be fatal if swallowed and enters airways. SECTION 12: Ecological information 12.1. Toxicity 1,1,1,2-Tetrafluoroethane (811-97-2) LC50 fish 1 450 mg/l (LC50; 96 h) EC50 Daphnia 1 980 mg/l (EC50; 48 h) 12.2. Persistence and degradability JOHNSEN'S ESTER OIL CHARGE R134 3 OZ. Persistence and degradability Not established. Ester (Proprietary) Persistence and degradability Not established. JOHNSEN'S ESTER OIL CHARGE R134 3 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 08/08/2017 EN (English US) 5/7 Proprietary Inhibitor Package (Proprietary) Persistence and degradability Not established. 1,1,1,2-Tetrafluoroethane (811-97-2) Persistence and degradability Not readily biodegradable in water. 12.3. Bioaccumulative potential JOHNSEN'S ESTER OIL CHARGE R134 3 OZ. Bioaccumulative potential Not established. Ester (Proprietary) Bioaccumulative potential Not established. Proprietary Inhibitor Package (Proprietary) Bioaccumulative potential Not established. 1,1,1,2-Tetrafluoroethane (811-97-2) BCF other aquatic organisms 1 5 - 58 (BCF) Log Pow 1.06 (OECD 107: Partition Coefficient (n-octanol/water): Shake Flask Method) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN US DOT (ground): UN1078, Refrigerant gases, n.o.s., 2.2, Limited Quantity ICAO/IATA (air): UN1078, Refrigerant gases, n.o.s., 2.2 , Limited Quantity IMO/IMDG (water): UN1078, Refrigerant gases, n.o.s. (1,1,1,2-Tetrafluoroethane), 2.2 Special Provisions: T50 - When portable tank instruction T50 is referenced in Column (7) of the 172.101 Table, the applicable liquefied compressed gases are authorized to be transported in portable tanks in accordance with the requirements of 173.313 of this subchapter. Not applicable 14.2. UN proper shipping name Proper Shipping Name (DOT) : Refrigerant gases, n.o.s. Class (DOT) : 2.2 - Class 2.2 - Non-flammable compressed gas 49 CFR 173.115 Hazard labels (DOT) : 2.2 - Non-flammable gas DOT Symbols : G - Identifies PSN requiring a technical name DOT Special Provisions (49 CFR 172.102) : T50 - When portable tank instruction T50 is referenced in Column (7) of the 172.101 Table, the applicable liquefied compressed gases are authorized to be transported in portable tanks in accordance with the requirements of 173.313 of this subchapter. DOT Packaging Exceptions (49 CFR 173.xxx) : 306 DOT Packaging Non Bulk (49 CFR 173.xxx) : 304 DOT Packaging Bulk (49 CFR 173.xxx) : 314;315 14.3. Additional information Other information : No supplementary information available. Overland transport No additional information available JOHNSEN'S ESTER OIL CHARGE R134 3 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 08/08/2017 EN (English US) 6/7 Transport by sea DOT Vessel Stowage Location : A - The material may be stowed ??on deck?? or ??under deck?? on a cargo vessel and on a passenger vessel. Air transport DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) : 75 kg DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75) : 150 kg SECTION 15: Regulatory information 15.1. US Federal regulations JOHNSEN'S ESTER OIL CHARGE R134 3 OZ. SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Sudden release of pressure hazard Delayed (chronic) health hazard 1,1,1,2-Tetrafluoroethane (811-97-2) Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes Sudden release of pressure hazard Immediate (acute) health hazard 15.2. International regulations CANADA JOHNSEN'S ESTER OIL CHARGE R134 3 OZ. WHMIS Classification Class A - Compressed Gas 1,1,1,2-Tetrafluoroethane (811-97-2) WHMIS Classification Class A - Compressed Gas EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified 15.2.2. National regulations No additional information available 15.3. US State regulations JOHNSEN'S ESTER OIL CHARGE R134 3 OZ. U.S. - California - Proposition 65 - Carcinogens List No U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No Ester (Proprietary) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male Non-significant risk level (NSRL) No No No No Proprietary Inhibitor Package (Proprietary) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male Non-significant risk level (NSRL) No No No No JOHNSEN'S ESTER OIL CHARGE R134 3 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 08/08/2017 EN (English US) 7/7 1,1,1,2-Tetrafluoroethane (811-97-2) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male Non-significant risk level (NSRL) No No No No SECTION 16: Other information Other information : None. Full text of H-phrases: ------ H280 Contains gas under pressure; may explode if heated NFPA health hazard : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. NFPA fire hazard : 0 - Materials that will not burn. NFPA reactivity : 1 - Normally stable, but can become unstable at elevated temperatures and pressures or may react with water with some release of energy, but not violently. HMIS III Rating Health : 2 Moderate Hazard - Temporary or minor injury may occur Flammability : 0 Minimal Hazard Physical : 1 Slight Hazard Personal Protection : B SDS US (GHS HazCom 2012) - TCC The Supplier identified in Section 1 of this SDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable. However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made or implied.