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PENOIL-11_Penetrating_Lubricant.pdf
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Version #: 01 Issue date: 07-30-2018 SDS US 1 / 9 ????? ???????FVP?PENETRATING?OIL? ???????SAFETY?DATA?SHEET? 1. Identification Product number Product identifier Company information Company phone telephone US Emergency telephone US Version # Recommended use Recommended restrictions 2. Hazard(s) identification Physical hazards Health hazards OSHA defined hazards Label elements FVPPENOIL-11 DM451 PENETRATING LUBRICANT Factory Motor Parts 1380 Corporate Center Curve #200 Eagan, MN 55121 866-387-3343 INFOTRAC 1-800-535-5053 01 LUBRICANT None known. Flammable aerosols Aspiration hazard Not classified. Category 1 Category 1 Signal word Danger Hazard statement Extremely flammable aerosol. May be fatal if swallowed and enters airways. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Response If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. Storage Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50?C/122?F. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information None. 3. Composition/information on ingredients Mixtures Chemical name Distillates (petroleum), Hydrotreated Light Propane Acetone Butane Slack Wax (petroleum) Common name and synonyms CAS number % 64742-47-8 40 - 60 74-98-6 10 - 20 67-64-1 2.5 - 10 106-97-8 2.5 - 10 64742-61-6 1 - 2.5 Other components below reportable levels 10 - 20 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. Production?After?7/1/18 Version #: 01 Issue date: 07-30-2018 SDS US 2 / 9 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire fighting equipment/instructions Specific methods General fire hazards If symptoms develop move victim to fresh air. Get medical attention if symptoms persist. Wash off with soap and water. Get medical attention if irritation develops and persists. Rinse with water. Get medical attention if irritation develops and persists. Rinse mouth. Get medical attention if symptoms occur. Aspiration may cause pulmonary edema and pneumonitis. Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Alcohol resistant foam. Powder. Dry chemicals. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire. Contents under pressure. Pressurized container may explode when exposed to heat or flame. During fire, gases hazardous to health may be formed. Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Move containers from fire area if you can do so without risk. Cool containers exposed to heat with water spray and remove container, if no risk is involved. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes. Extremely flammable aerosol. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Environmental precautions 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Refer to attached safety data sheets and/or instructions for use. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Use water spray to reduce vapors or divert vapor cloud drift. Isolate area until gas has dispersed. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Avoid prolonged or repeated contact with skin. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Level 3 Aerosol. Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50?C/122 ?F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Store away from incompatible materials (see Section 10 of the SDS). Version #: 01 Issue date: 07-30-2018 SDS US 3 / 9 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Acetone (CAS 67-64-1) Propane (CAS 74-98-6) US. ACGIH Threshold Limit Values PEL 2400 mg/m3 1000 ppm PEL 1800 mg/m3 1000 ppm Components Type Value Acetone (CAS 67-64-1) Butane (CAS 106-97-8) STEL 500 ppm TWA 250 ppm STEL 1000 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Acetone (CAS 67-64-1) Butane (CAS 106-97-8) Propane (CAS 74-98-6) Biological limit values ACGIH Biological Exposure Indices TWA 590 mg/m3 250 ppm TWA 1900 mg/m3 800 ppm TWA 1800 mg/m3 1000 ppm Components Value Determinant Specimen Sampling Time Acetone (CAS 67-64-1) 25 mg/l Acetone Urine * * - For sampling details, please see the source document. Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Skin protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations Face shield is recommended. Wear safety glasses with side shields (or goggles). Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier. Wear suitable protective clothing. If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. Wear appropriate thermal protective clothing, when necessary. When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Form Color Odor Gas. Aerosol. Not available. Not available. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Version #: 01 Issue date: 07-30-2018 SDS US 4 / 9 Initial boiling point and boiling range 384.07 ?F (195.6 ?C) estimated Flash point -156.0 ?F (-104.4 ?C) PROPELLANT estimated Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) 1 % estimated 6.7 % estimated Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure Not available. Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 485.27 ?F (251.82 ?C) estimated Decomposition temperature Not available. Viscosity Not available. Other information Explosive properties Heat of combustion (NFPA 30B) Oxidizing properties Not explosive. 39.61 kJ/g estimated Not oxidizing. VOC (Weight %) 0.63 % estimated 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. Hazardous polymerization does not occur. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Strong oxidizing agents. Nitrates. Fluorine. Chlorine. No hazardous decomposition products are known. 11. Toxicological information Information on likely routes of exposure Inhalation No adverse effects due to inhalation are expected. Skin contact No adverse effects due to skin contact are expected. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Symptoms related to the physical, chemical and toxicological characteristics Aspiration may cause pulmonary edema and pneumonitis. Information on toxicological effects Acute toxicity May be fatal if swallowed and enters airways. Version #: 01 Issue date: 07-30-2018 SDS US 5 / 9 Components Species Acetone (CAS 67-64-1) Acute Dermal Test Results LD50 Guinea pig > 7426 mg/kg, 24 Hours > 9.4 ml/kg, 24 Hours Rabbit > 7426 mg/kg, 24 Hours > 9.4 ml/kg, 24 Hours Inhalation LC50 Rat 55700 ppm, 3 Hours 132 mg/l, 3 Hours 50.1 mg/l Oral LD50 Rat 5800 mg/kg 2.2 ml/kg Butane (CAS 106-97-8) Acute Inhalation LC50 Mouse 1237 mg/l, 120 Minutes 52 %, 120 Minutes Rat 1355 mg/l Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8) Acute Dermal LD50 Rabbit > 2000 mg/kg > 2000 mg/kg, 24 Hours Inhalation LC50 Rat > 7.5 mg/l, 6 Hours > 4.6 mg/l, 4 Hours Oral LD50 Rat > 5000 mg/kg Propane (CAS 74-98-6) Acute Inhalation LC50 Mouse 1237 mg/l, 120 Minutes 52 %, 120 Minutes Rat 1355 mg/l 658 mg/l/4h Slack Wax (petroleum) (CAS 64742-61-6) Acute Dermal LD50 Rabbit > 2000 mg/kg, 24 Hours Oral LD50 Rat > 5000 mg/kg * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Serious eye damage/eye irritation Prolonged skin contact may cause temporary irritation. Direct contact with eyes may cause temporary irritation. Version #: 01 Issue date: 07-30-2018 SDS US 6 / 9 Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization Germ cell mutagenicity This product is not expected to cause skin sensitization. No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity Not listed. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. US. National Toxicology Program (NTP) Report on Carcinogens Not listed. Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure This product is not expected to cause reproductive or developmental effects. Not classified. Not classified. Aspiration hazard May be fatal if swallowed and enters airways. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Components Acetone (CAS 67-64-1) Aquatic Crustacea Fish EC50 LC50 Species Water flea (Daphnia magna) Rainbow trout,donaldson trout (Oncorhynchus mykiss) Test Results 21.6 - 23.9 mg/l, 48 hours 4740 - 6330 mg/l, 96 hours Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8) Aquatic Fish LC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss) 2.9 mg/l, 96 hours * Estimates for product may be based on additional component data not shown. Persistence and degradability Bioaccumulative potential No data is available on the degradability of this product. Partition coefficient n-octanol / water (log Kow) Acetone -0.24 Butane 2.89 Propane 2.36 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. Version #: 01 Issue date: 07-30-2018 SDS US 7 / 9 14. Transport information DOT UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group UN1950 Aerosols, flammable, (each not exceeding 1 L capacity) 2.1 - 2.1 Not applicable. Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Special provisions Packaging exceptions Packaging non bulk Packaging bulk N82 306 None None This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking. IATA UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group Environmental hazards ERG Code UN1950 Aerosols, flammable 2.1 - 2.1 Not applicable. No. 10L Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling. Other information Passenger and cargo aircraft Cargo aircraft only Packaging Exceptions IMDG UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group Environmental hazards Marine pollutant EmS Allowed with restrictions. Allowed with restrictions. LTD QTY UN1950 AEROSOLS 2.1 - None Not applicable. No. F-D, S-U Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling. Packaging Exceptions Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code LTD QTY Not applicable. Version #: 01 Issue date: 07-30-2018 SDS US 8 / 9 DOT IATA; IMDG 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Acetone (CAS 67-64-1) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous No chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Butane (CAS 106-97-8) Propane (CAS 74-98-6) Safe Drinking Water Act (SDWA) Not regulated. Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Acetone (CAS 67-64-1) 6532 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Acetone (CAS 67-64-1) 35 %WV Version #: 01 Issue date: 07-30-2018 SDS US 9 / 9 DEA Exempt Chemical Mixtures Code Number Acetone (CAS 67-64-1) 6532 US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) Acetone (CAS 67-64-1) Butane (CAS 106-97-8) Slack Wax (petroleum) (CAS 64742-61-6) US. Massachusetts RTK - Substance List Acetone (CAS 67-64-1) Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. New Jersey Worker and Community Right-to-Know Act Acetone (CAS 67-64-1) Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. Pennsylvania Worker and Community Right-to-Know Law Acetone (CAS 67-64-1) Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. Rhode Island RTK Acetone (CAS 67-64-1) Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Domestic Substances List (DSL) Canada Non-Domestic Substances List (NDSL) China Inventory of Existing Chemical Substances in China (IECSC) Europe European Inventory of Existing Commercial Chemical Substances (EINECS) Europe European List of Notified Chemical Substances (ELINCS) Japan Inventory of Existing and New Chemical Substances (ENCS) Korea Existing Chemicals List (ECL) New Zealand New Zealand Inventory Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) Yes Yes No Yes Yes No Yes Yes No No Yes A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 07-30-2018 Version # 01 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.