page 1 of 5 HMIS Codes Health 2* Flammability 3 Reactivity 0 DATE OF PREPARATION Nov 13, 2013 MATERIAL SAFETY DATA SHEET AFM0229 06 00 SECTION 1 ? PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER AFM0229 PRODUCT NAME DUPLI-COLOR? Scratch Fix All-in-1?, Oxford White - see 'DC-CC' MSDS MANUFACTURER'S NAME THE SHERWIN-WILLIAMS CO. DUPLI-COLOR Products Group Cleveland, OH 44115 Telephone Numbers and Websites Product Information (800) 247-3270 www.duplicolor.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or * accident) SECTION 2 ? COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 18 108-88-3 Toluene ACGIH TLV 20 PPM 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 2 64-17-5 Ethanol ACGIH TLV 1000 PPM 44 mm OSHA PEL 1000 PPM 23 78-93-3 Methyl Ethyl Ketone ACGIH TLV 200 PPM 90.6 mm ACGIH TLV 300 PPM STEL OSHA PEL 200 PPM OSHA PEL 300 PPM STEL 9 108-10-1 Methyl Isobutyl Ketone ACGIH TLV 50 PPM 16 mm ACGIH TLV 75 PPM STEL OSHA PEL 50 PPM OSHA PEL 75 PPM STEL 22 763-69-9 Ethyl 3-Ethoxypropionate ACGIH TLV Not Available 1.11 mm OSHA PEL Not Available 7 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction SECTION 3 ? HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. 2-Component MSDS. Clearcoat DC-CC MSDS is attached. AFM0229 page 2 of 5 UEL 19.0 LEL 1.0 FLASH POINT 36 ?F PMCC May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: the liver the urinary system the cardiovascular system the reproductive system SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 ? FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 ? FIRE FIGHTING MEASURES FLAMMABILITY CLASSIFICATION RED LABEL -- Flammable, Flash below 100 ?F (38 ?C) EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 ? ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 ? HANDLING AND STORAGE STORAGE CATEGORY DOL Storage Class IB PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Contents are FLAMMABLE. Keep away from heat, sparks, and open flame. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. SECTION 8 ? EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper AFM0229 page 3 of 5 containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. SECTION 9 ? PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 7.88 lb/gal 944 g/l SPECIFIC GRAVITY 0.95 BOILING POINT 172 - 342 ?F 77 - 172 ?C MELTING POINT Not Available VOLATILE VOLUME 83% EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER Not Available VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 5.91 lb/gal 708 g/l Less Water and Federally Exempt Solvents 5.91 lb/gal 708 g/l Emitted VOC SECTION 10 ? STABILITY AND REACTIVITY STABILITY ? Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 ? TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Methyl Ethyl Ketone may increase the nervous system effects of other solvents. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." AFM0229 page 4 of 5 TOXICOLOGY DATA CAS No. Ingredient Name 108-88-3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 64-17-5 Ethanol LC50 RAT 4HR Not Available LD50 RAT 7060 mg/kg 78-93-3 Methyl Ethyl Ketone LC50 RAT 4HR Not Available LD50 RAT 2740 mg/kg 108-10-1 Methyl Isobutyl Ketone LC50 RAT 4HR Not Available LD50 RAT 2080 mg/kg 763-69-9 Ethyl 3-Ethoxypropionate LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 ? ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 ? DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 ? TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) 5 Liters (1.3 Gallons) and Less may be Classed as LTD. QTY. OR ORM-D Larger Containers are Regulated as: UN1263, PAINT, 3, PG II, (ERG#128) DOT (Dept of Transportation) Hazardous Substances & Reportable Quantities Ethyl methyl ketone 5000 lb RQ Toluene 1000 lb RQ Bulk Containers may be Shipped as (check reportable quantities): UN1263, PAINT, 3, PG II, (ERG#128) Canada (TDG) UN1263, PAINT, CLASS 3, PG II, (ERG#128) IMO 5 Liters (1.3 Gallons) and Less may be Shipped as Limited Quantity. UN1263, PAINT, CLASS 3, PG II, (2 C c.c.), EmS F-E, S-E IATA/ICAO UN1263, PAINT, 3, PG II SECTION 15 ? REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION(40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element 108-88-3 Toluene 18 108-10-1 Methyl Isobutyl Ketone 9 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. AFM0229 page 5 of 5 SECTION 16 ? OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. page 1 of 5 HMIS Codes Health 2 Flammability 3 Reactivity 0 DATE OF PREPARATION Nov 13, 2013 MATERIAL SAFETY DATA SHEET DC-CC 04 00 SECTION 1 ? PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER DC-CC PRODUCT NAME DUPLI-COLOR? Scratch Fix All-in-1? Clear Top Coat MANUFACTURER'S NAME THE SHERWIN-WILLIAMS CO. DUPLI-COLOR Products Group Cleveland, OH 44115 Telephone Numbers and Websites Product Information (800) 247-3270 www.duplicolor.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or * accident) SECTION 2 ? COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 37 108-88-3 Toluene ACGIH TLV 20 PPM 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 2 110-82-7 Cyclohexane ACGIH TLV 100 PPM 100 mm OSHA PEL 300 PPM 6 64-17-5 Ethanol ACGIH TLV 1000 PPM 44 mm OSHA PEL 1000 PPM 14 78-93-3 Methyl Ethyl Ketone ACGIH TLV 200 PPM 90.6 mm ACGIH TLV 300 PPM STEL OSHA PEL 200 PPM OSHA PEL 300 PPM STEL 8 108-10-1 Methyl Isobutyl Ketone ACGIH TLV 50 PPM 16 mm ACGIH TLV 75 PPM STEL OSHA PEL 50 PPM OSHA PEL 75 PPM STEL 3 763-69-9 Ethyl 3-Ethoxypropionate ACGIH TLV Not Available 1.11 mm OSHA PEL Not Available SECTION 3 ? HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. DC-CC page 2 of 5 UEL 19.0 LEL 1.0 FLASH POINT 36 ?F PMCC Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: the liver the urinary system the cardiovascular system the reproductive system SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 ? FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 ? FIRE FIGHTING MEASURES FLAMMABILITY CLASSIFICATION RED LABEL -- Flammable, Flash below 100 ?F (38 ?C) EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 ? ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 ? HANDLING AND STORAGE STORAGE CATEGORY DOL Storage Class IB PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Contents are FLAMMABLE. Keep away from heat, sparks, and open flame. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. SECTION 8 ? EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other DC-CC page 3 of 5 hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. SECTION 9 ? PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 7.53 lb/gal 901 g/l SPECIFIC GRAVITY 0.91 BOILING POINT 172 - 342 ?F 77 - 172 ?C MELTING POINT Not Available VOLATILE VOLUME 75% EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER Not Available VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 5.27 lb/gal 632 g/l Less Water and Federally Exempt Solvents 5.27 lb/gal 632 g/l Emitted VOC SECTION 10 ? STABILITY AND REACTIVITY STABILITY ? Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 ? TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. Methyl Ethyl Ketone may increase the nervous system effects of other solvents. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. DC-CC page 4 of 5 TOXICOLOGY DATA CAS No. Ingredient Name 108-88-3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 110-82-7 Cyclohexane LC50 RAT 4HR Not Available LD50 RAT Not Available 64-17-5 Ethanol LC50 RAT 4HR Not Available LD50 RAT 7060 mg/kg 78-93-3 Methyl Ethyl Ketone LC50 RAT 4HR Not Available LD50 RAT 2740 mg/kg 108-10-1 Methyl Isobutyl Ketone LC50 RAT 4HR Not Available LD50 RAT 2080 mg/kg 763-69-9 Ethyl 3-Ethoxypropionate LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 ? ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 ? DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 ? TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) 5 Liters (1.3 Gallons) and Less may be Classed as LTD. QTY. OR ORM-D Larger Containers are Regulated as: UN1263, PAINT, 3, PG II, (ERG#128) DOT (Dept of Transportation) Hazardous Substances & Reportable Quantities Butyl benzyl phthalate 100 lb RQ Toluene 1000 lb RQ Bulk Containers may be Shipped as (check reportable quantities): RQ, UN1263, PAINT, 3, PG II, (BUTYL BENZYL PHTHALATE), (ERG#128) Canada (TDG) UN1263, PAINT, CLASS 3, PG II, (ERG#128) IMO 5 Liters (1.3 Gallons) and Less may be Shipped as Limited Quantity. UN1263, PAINT, CLASS 3, PG II, (2 C c.c.), EmS F-E, S-E IATA/ICAO UN1263, PAINT, 3, PG II SECTION 15 ? REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION(40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element 108-88-3 Toluene 37 110-82-7 Cyclohexane 2 108-10-1 Methyl Isobutyl Ketone 8 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. DC-CC page 5 of 5 SECTION 16 ? OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information.