DUPLI-COLOR? Scratch Fix All-in-1? White Pearl - see 'DC-CC' SDS Not available. Liquid. (216) 566-2917 SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer : Dupli-Color Products Company Cleveland, OH 44115 Relevant identified uses of the substance or mixture and uses advised against Not applicable. ATY1626 ATY1626Product code : Product Information Telephone Number : (800) 247-3270 Regulatory Information Telephone Number : (216) 566-2902 Transportation Emergency Telephone Number : (800) 424-9300 Section 2. Hazards identification FLAMMABLE LIQUIDS - Category 2 ACUTE TOXICITY (oral) - Category 4 SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION (Unborn child) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 ASPIRATION HAZARD - Category 1 Classification of the substance or mixture : Signal word : Danger Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 1.7% OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version : 3 1/17 Section 2. Hazards identification Precautionary statements Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection. Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage : Store locked up. Store in a well-ventilated place. Keep cool. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Hazards not otherwise classified :None known. Highly flammable liquid and vapor. Harmful if swallowed. Causes serious eye irritation. Causes skin irritation. Suspected of damaging the unborn child. Suspected of causing cancer. May be fatal if swallowed and enters airways. May cause respiratory irritation. May cause drowsiness or dizziness. May cause damage to organs through prolonged or repeated exposure. :Hazard statements Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. : Section 3. Composition/information on ingredients Other means of identification : Not available. Substance/mixture CAS number/other identifiers : Mixture Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version : 3 2/17 Section 3. Composition/information on ingredients Methyl Ethyl Ketone 27.22 78-93-3 Toluene 22.03 108-88-3 Methyl Isobutyl Ketone 5.42 108-10-1 Ethanol 3.15 64-17-5 Titanium Dioxide 1.65 13463-67-7 2-Propanol 1.09 67-63-0 Ethylbenzene 0.12 100-41-4 Ingredient name CAS number% by weight There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Harmful if swallowed. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. :Ingestion Skin contact : Causes skin irritation. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Potential acute health effects Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version : 3 3/17 Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides metal oxide/oxides Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard. Use dry chemical, CO?, water spray (fog) or foam. Extinguishing media : : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version : 3 4/17 Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version : 3 5/17 Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : : Methyl Ethyl Ketone ACGIH TLV (United States, 3/2015). TWA: 200 ppm 8 hours. TWA: 590 mg/m? 8 hours. STEL: 300 ppm 15 minutes. STEL: 885 mg/m? 15 minutes. NIOSH REL (United States, 10/2013). TWA: 200 ppm 10 hours. TWA: 590 mg/m? 10 hours. STEL: 300 ppm 15 minutes. STEL: 885 mg/m? 15 minutes. OSHA PEL (United States, 2/2013). TWA: 200 ppm 8 hours. TWA: 590 mg/m? 8 hours. Toluene OSHA PEL Z2 (United States, 2/2013). TWA: 200 ppm 8 hours. CEIL: 300 ppm AMP: 500 ppm 10 minutes. NIOSH REL (United States, 10/2013). TWA: 100 ppm 10 hours. TWA: 375 mg/m? 10 hours. STEL: 150 ppm 15 minutes. STEL: 560 mg/m? 15 minutes. ACGIH TLV (United States, 3/2015). TWA: 20 ppm 8 hours. Methyl Isobutyl Ketone ACGIH TLV (United States, 3/2015). TWA: 20 ppm 8 hours. STEL: 75 ppm 15 minutes. NIOSH REL (United States, 10/2013). TWA: 50 ppm 10 hours. TWA: 205 mg/m? 10 hours. STEL: 75 ppm 15 minutes. STEL: 300 mg/m? 15 minutes. OSHA PEL (United States, 2/2013). TWA: 100 ppm 8 hours. TWA: 410 mg/m? 8 hours. Ethanol ACGIH TLV (United States, 3/2015). STEL: 1000 ppm 15 minutes. NIOSH REL (United States, 10/2013). Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits (OSHA United States) Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version : 3 6/17 Section 8. Exposure controls/personal protection TWA: 1000 ppm 10 hours. TWA: 1900 mg/m? 10 hours. OSHA PEL (United States, 2/2013). TWA: 1000 ppm 8 hours. TWA: 1900 mg/m? 8 hours. Titanium Dioxide ACGIH TLV (United States, 3/2015). TWA: 10 mg/m? 8 hours. OSHA PEL (United States, 2/2013). TWA: 15 mg/m? 8 hours. Form: Total dust 2-Propanol ACGIH TLV (United States, 3/2015). TWA: 200 ppm 8 hours. STEL: 400 ppm 15 minutes. NIOSH REL (United States, 10/2013). TWA: 400 ppm 10 hours. TWA: 980 mg/m? 10 hours. STEL: 500 ppm 15 minutes. STEL: 1225 mg/m? 15 minutes. OSHA PEL (United States, 2/2013). TWA: 400 ppm 8 hours. TWA: 980 mg/m? 8 hours. Ethylbenzene ACGIH TLV (United States, 3/2015). TWA: 20 ppm 8 hours. NIOSH REL (United States, 10/2013). TWA: 100 ppm 10 hours. TWA: 435 mg/m? 10 hours. STEL: 125 ppm 15 minutes. STEL: 545 mg/m? 15 minutes. OSHA PEL (United States, 2/2013). TWA: 100 ppm 8 hours. TWA: 435 mg/m? 8 hours. Methyl Ethyl Ketone CA Alberta Provincial (Canada, 4/2009). 15 min OEL: 300 ppm 15 minutes. 8 hrs OEL: 200 ppm 8 hours. 8 hrs OEL: 590 mg/m? 8 hours. 15 min OEL: 885 mg/m? 15 minutes. CA British Columbia Provincial (Canada, 5/2015). TWA: 50 ppm 8 hours. STEL: 100 ppm 15 minutes. CA Ontario Provincial (Canada, 7/2015). TWA: 200 ppm 8 hours. STEL: 300 ppm 15 minutes. CA Quebec Provincial (Canada, 1/2014). TWAEV: 50 ppm 8 hours. TWAEV: 150 mg/m? 8 hours. STEV: 100 ppm 15 minutes. STEV: 300 mg/m? 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 300 ppm 15 minutes. TWA: 200 ppm 8 hours. Toluene CA Alberta Provincial (Canada, 4/2009). Absorbed through skin. 8 hrs OEL: 50 ppm 8 hours. Ingredient name Exposure limits Occupational exposure limits (Canada) Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version : 3 7/17 Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. 8 hrs OEL: 188 mg/m? 8 hours. CA British Columbia Provincial (Canada, 5/2015). TWA: 20 ppm 8 hours. CA Ontario Provincial (Canada, 7/2015). TWA: 20 ppm 8 hours. CA Quebec Provincial (Canada, 1/2014). Absorbed through skin. TWAEV: 50 ppm 8 hours. TWAEV: 188 mg/m? 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). Absorbed through skin. STEL: 60 ppm 15 minutes. TWA: 50 ppm 8 hours. Environmental exposure controls : Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version : 3 8/17 Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. Not available. 0.92 1.5 [Air = 1] 1.6 kPa (12.079 mm Hg) [at 20?C] Not available. Not available.Odor pH Not available.Color Evaporation rate 5.6 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: 2?C (35.6?F) [Pensky-Martens Closed Cup] Not available. Not available. Viscosity Kinematic (room temperature): <0.205 cm2/s (<20.5 cSt) Kinematic (40?C (104?F)): <0.205 cm2/s (<20.5 cSt) Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : 77?C (170.6?F) Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Lower: 1% Upper: 19% Decomposition temperature : Not available. Heat of combustion : 23.26 kJ/g Aerosol product Molecular weight : Not applicable. Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version : 3 9/17 Section 11. Toxicological information Acute toxicity Methyl Ethyl Ketone LD50 Dermal Rabbit 6480 mg/kg - LD50 Oral Rat 2737 mg/kg - Toluene LC50 Inhalation Vapor Rat 49 g/m? 4 hours LD50 Oral Rat 636 mg/kg - Methyl Isobutyl Ketone LD50 Oral Rat 2080 mg/kg - Ethanol LC50 Inhalation Vapor Rat 124700 mg/m? 4 hours LD50 Oral Rat 7 g/kg - 2-Propanol LD50 Dermal Rabbit 12800 mg/kg - LD50 Oral Rat 5000 mg/kg - Ethylbenzene LD50 Dermal Rabbit >5000 mg/kg - LD50 Oral Rat 3500 mg/kg - Product/ingredient name Result Species Dose Exposure Irritation/Corrosion Methyl Ethyl Ketone Skin - Mild irritant Rabbit - 24 hours 14 milligrams - Skin - Moderate irritant Rabbit - 24 hours 500 milligrams - Toluene Eyes - Mild irritant Rabbit - 0.5 minutes 100 milligrams - Eyes - Mild irritant Rabbit - 870 Micrograms - Eyes - Severe irritant Rabbit - 24 hours 2 milligrams - Skin - Mild irritant Pig - 24 hours 250 microliters - Skin - Mild irritant Rabbit - 435 milligrams - Skin - Moderate irritant Rabbit - 24 hours 20 milligrams - Skin - Moderate irritant Rabbit - 500 milligrams - Methyl Isobutyl Ketone Eyes - Moderate irritant Rabbit - 24 hours 100 microliters - Eyes - Severe irritant Rabbit - 40 milligrams - Skin - Mild irritant Rabbit - 24 hours 500 milligrams - Ethanol Eyes - Mild irritant Rabbit - 24 hours 500 milligrams - Eyes - Moderate irritant Rabbit - 0.066666667 minutes 100 milligrams - Eyes - Moderate irritant Rabbit - 100 microliters - Eyes - Severe irritant Rabbit - 500 milligrams - Skin - Mild irritant Rabbit - 400 milligrams - Skin - Moderate irritant Rabbit - 24 hours 20 milligrams - Titanium Dioxide Skin - Mild irritant Human - 72 hours 300 Micrograms Intermittent - 2-Propanol Eyes - Moderate irritant Rabbit - 24 hours 100 - Product/ingredient name Result Score Exposure ObservationSpecies Information on toxicological effects Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version : 3 10/17 Section 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. milligrams Eyes - Moderate irritant Rabbit - 10 milligrams - Eyes - Severe irritant Rabbit - 100 milligrams - Skin - Mild irritant Rabbit - 500 milligrams - Ethylbenzene Eyes - Severe irritant Rabbit - 500 milligrams - Skin - Mild irritant Rabbit - 24 hours 15 milligrams - Sensitization Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Methyl Ethyl Ketone Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Toluene Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Methyl Isobutyl Ketone Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Ethanol Category 3 Not applicable. Respiratory tract irritation and Narcotic effects 2-Propanol Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Ethylbenzene Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Name Category Route of exposure Target organs Classification Toluene - 3 - Methyl Isobutyl Ketone - 2B - Ethanol - 1 - Titanium Dioxide - 2B - 2-Propanol - 3 - Ethylbenzene - 2B - Product/ingredient name NTPIARCOSHA Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version : 3 11/17 Section 11. Toxicological information Name Category Methyl Ethyl Ketone Category 2 Not determined Not determined Toluene Category 2 Not determined Not determined Methyl Isobutyl Ketone Category 2 Not determined Not determined Ethanol Category 2 Not determined Not determined 2-Propanol Category 2 Not determined Not determined Ethylbenzene Category 2 Not determined Not determined Aspiration hazard Name Result Toluene ASPIRATION HAZARD - Category 1 Ethylbenzene ASPIRATION HAZARD - Category 1 Route of exposure Target organs Information on the likely routes of exposure Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Harmful if swallowed. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. :Ingestion Skin contact : Causes skin irritation. Causes serious eye irritation.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Delayed and immediate effects and also chronic effects from short and long term exposure : Not available. Potential acute health effects Short term exposure Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version : 3 12/17 Not available. May cause damage to organs through prolonged or repeated exposure.General : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : Suspected of damaging the unborn child.Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Potential chronic health effects Numerical measures of toxicity Oral 1921.5 mg/kg Route ATE value Acute toxicity estimates Potential immediate effects : Not available. Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Section 12. Ecological information Toxicity Methyl Ethyl Ketone Acute EC50 >500000 ?g/l Marine water Algae - Skeletonema costatum 96 hours Acute EC50 5091000 ?g/l Fresh water Daphnia - Daphnia magna - Larvae 48 hours Acute LC50 3220000 ?g/l Fresh water Fish - Pimephales promelas 96 hours Toluene Acute EC50 12500 ?g/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours Acute EC50 11600 ?g/l Fresh water Crustaceans - Gammarus pseudolimnaeus - Adult 48 hours Acute EC50 6000 ?g/l Fresh water Daphnia - Daphnia magna - Juvenile (Fledgling, Hatchling, Weanling) 48 hours Acute LC50 5500 ?g/l Fresh water Fish - Oncorhynchus kisutch - Fry 96 hours Chronic NOEC 1000 ?g/l Fresh water Daphnia - Daphnia magna 21 days Methyl Isobutyl Ketone Acute LC50 505000 ?g/l Fresh water Fish - Pimephales promelas 96 hours Chronic NOEC 78 mg/l Fresh water Daphnia - Daphnia magna 21 days Chronic NOEC 168 mg/l Fresh water Fish - Pimephales promelas - Embryo 33 days Ethanol Acute EC50 17.921 mg/l Marine water Algae - Ulva pertusa 96 hours Acute EC50 2000 ?g/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 25500 ?g/l Marine water Crustaceans - Artemia franciscana - Larvae 48 hours Acute LC50 42000 ?g/l Fresh water Fish - Oncorhynchus mykiss 4 days Chronic NOEC 4.995 mg/l Marine water Algae - Ulva pertusa 96 hours Chronic NOEC 100 ul/L Fresh water Daphnia - Daphnia magna - Neonate 21 days Chronic NOEC 0.375 ul/L Fresh water Fish - Gambusia holbrooki - Larvae 12 weeks Product/ingredient name SpeciesResult Exposure Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version : 3 13/17 Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Toluene - 90 low Product/ingredient name Aquatic half-life Photolysis Biodegradability Methyl Ethyl Ketone - - Readily Toluene - - Readily Methyl Isobutyl Ketone - - Readily Ethanol - - Readily 2-Propanol - - Readily Ethylbenzene - - Readily Titanium Dioxide Acute LC50 >1000000 ?g/l Marine water Fish - Fundulus heteroclitus 96 hours 2-Propanol Acute LC50 1400000 ?g/l Marine water Crustaceans - Crangon crangon 48 hours Acute LC50 4200 mg/l Fresh water Fish - Rasbora heteromorpha 96 hours Ethylbenzene Acute EC50 4600 ?g/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours Acute EC50 3600 ?g/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours Acute EC50 6530 ?g/l Fresh water Crustaceans - Artemia sp. - Nauplii 48 hours Acute EC50 2930 ?g/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours Acute LC50 4200 ?g/l Fresh water Fish - Oncorhynchus mykiss 96 hours Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version : 3 14/17 Section 14. Transport information PAINT 3 II PAINT 3 II UN1263 UN1263 - Emergency schedules (EmS) F-E, S-E DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL and the IBC Code No. No. Not available. : Proper shipping name : Ship type : Not available. Pollution category : Not available. Not available. : TDG Classification UN1263 PAINT 3 II No. Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2. 18-2.19 (Class 3). Mexico Classification UN1263 PAINT 3 II No. - Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. IATA UN1263 PAINT 3 II No. - 128 ERG No. 128 128 ERG No. ERG No. Section 15. Regulatory information SARA 313 SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet. Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version : 3 15/17 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 Section 16. Other information 6/4/2016 History Date of printing Date of issue/Date of revision Version Notice to reader Date of previous issue : : : : Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 6/4/2016 6/3/2016 3 Hazardous Material Information System (U.S.A.) 2 3 0 *Health Flammability Physical hazards Caution: HMIS? ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS? ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS? ratings are to be used with a fully implemented HMIS? program. HMIS? is a registered mark of the National Paint & Coatings Association (NPCA). HMIS? materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Procedure used to derive the classification Classification Justification FLAMMABLE LIQUIDS - Category 2 On basis of test data ACUTE TOXICITY (oral) - Category 4 Calculation method SKIN CORROSION/IRRITATION - Category 2 Calculation method SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method CARCINOGENICITY - Category 2 Calculation method TOXIC TO REPRODUCTION (Unborn child) - Category 2 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method ASPIRATION HAZARD - Category 1 Calculation method Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version : 3 16/17 Section 16. Other information It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version : 3 17/17 ATY1626_SDS_English_US Page 1 Page 2 Page 3 Page 4 Page 5 Page 6 Page 7 Page 8 Page 9 Page 10 Page 11 Page 12 Page 13 Page 14 Page 15 Page 16 Page 17