BRIGHT BEAUTY? Lacquer Semi-Flat Black Not available. Aerosol. (216) 566-2917 SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer : Dupli-Color Products Company Cleveland, OH 44115 Relevant identified uses of the substance or mixture and uses advised against Not applicable. BBL308 BBL308Product code : Product Information Telephone Number : (800) 247-3270 Regulatory Information Telephone Number : (216) 566-2902 Transportation Emergency Telephone Number : (800) 424-9300 Section 2. Hazards identification FLAMMABLE AEROSOLS - Category 1 GASES UNDER PRESSURE - Compressed gas SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A CARCINOGENICITY - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 ASPIRATION HAZARD - Category 1 Classification of the substance or mixture : Signal word : Danger Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 20% Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 26.3% Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 79. 7% OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue/Date of revision : 4/9/2018 Date of previous issue : 8/9/2017 Version : 8 1/19 BBL308 BRIGHT BEAUTY? Lacquer Semi-Flat Black SHW-85-NA-GHS-US Section 2. Hazards identification Precautionary statements Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection. Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist. Wash hands thoroughly after handling. Pressurized container: Do not pierce or burn, even after use. Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F. Store in a well-ventilated place. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Hazards not otherwise classified : DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue may spontaneously catch fire if improperly discarded. Immediately place rags, steel wool, other waste soaked with this product, and sanding residue in a sealed, water-filled, metal container. Dispose of in accordance with local fire regulations. Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. Causes skin irritation. Suspected of causing cancer. May be fatal if swallowed and enters airways. May cause respiratory irritation. May cause drowsiness or dizziness. May cause damage to organs through prolonged or repeated exposure. :Hazard statements Please refer to the SDS for additional information. Keep out of reach of children. Keep upright in a cool, dry place. Do not discard empty can in trash compactor. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. : Section 3. Composition/information on ingredients Methyl Acetate ?25 - ?50 79-20-9 Methyl Ethyl Ketone ?10 - ?25 78-93-3 Propane ?10 - ?25 74-98-6 Butane ?10 106-97-8 1-Methoxy-2-Propanol Acetate ?5 108-65-6 Acetone ?5 67-64-1 Xylene ?3 1330-20-7 Methyl Isobutyl Ketone ?3 108-10-1 1-Butanol ?2.9 71-36-3 Ingredient name CAS number% by weight Other means of identification : Not available. Substance/mixture CAS number/other identifiers : Mixture Date of issue/Date of revision : 4/9/2018 Date of previous issue : 8/9/2017 Version : 8 2/19 BBL308 BRIGHT BEAUTY? Lacquer Semi-Flat Black SHW-85-NA-GHS-US Section 3. Composition/information on ingredients Carbon Black ?3 1333-86-4 Ethylbenzene <1 100-41-4 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. :Ingestion Skin contact : Causes skin irritation. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Potential acute health effects Date of issue/Date of revision : 4/9/2018 Date of previous issue : 8/9/2017 Version : 8 3/19 BBL308 BRIGHT BEAUTY? Lacquer Semi-Flat Black SHW-85-NA-GHS-US Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Skin contact Ingestion Adverse symptoms may include the following: nausea or vomiting Adverse symptoms may include the following: irritation redness : : See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide Extremely flammable aerosol. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For non-emergency personnel For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue/Date of revision : 4/9/2018 Date of previous issue : 8/9/2017 Version : 8 4/19 BBL308 BRIGHT BEAUTY? Lacquer Semi-Flat Black SHW-85-NA-GHS-US Section 6. Accidental release measures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50?C. Do not pierce or burn, even after use. Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. : Precautions for safe handling Methyl Acetate ACGIH TLV (United States, 3/2017). TWA: 200 ppm 8 hours. TWA: 606 mg/m? 8 hours. STEL: 250 ppm 15 minutes. STEL: 757 mg/m? 15 minutes. NIOSH REL (United States, 10/2016). TWA: 200 ppm 10 hours. TWA: 610 mg/m? 10 hours. STEL: 250 ppm 15 minutes. STEL: 760 mg/m? 15 minutes. OSHA PEL (United States, 6/2016). Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits (OSHA United States) Date of issue/Date of revision : 4/9/2018 Date of previous issue : 8/9/2017 Version : 8 5/19 BBL308 BRIGHT BEAUTY? Lacquer Semi-Flat Black SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection TWA: 200 ppm 8 hours. TWA: 610 mg/m? 8 hours. Methyl Ethyl Ketone ACGIH TLV (United States, 3/2017). TWA: 200 ppm 8 hours. TWA: 590 mg/m? 8 hours. STEL: 300 ppm 15 minutes. STEL: 885 mg/m? 15 minutes. NIOSH REL (United States, 10/2016). TWA: 200 ppm 10 hours. TWA: 590 mg/m? 10 hours. STEL: 300 ppm 15 minutes. STEL: 885 mg/m? 15 minutes. OSHA PEL (United States, 6/2016). TWA: 200 ppm 8 hours. TWA: 590 mg/m? 8 hours. Propane NIOSH REL (United States, 10/2016). TWA: 1000 ppm 10 hours. TWA: 1800 mg/m? 10 hours. OSHA PEL (United States, 6/2016). TWA: 1000 ppm 8 hours. TWA: 1800 mg/m? 8 hours. ACGIH TLV (United States, 3/2017). Oxygen Depletion [Asphyxiant]. Butane NIOSH REL (United States, 10/2016). TWA: 800 ppm 10 hours. TWA: 1900 mg/m? 10 hours. ACGIH TLV (United States, 3/2017). STEL: 1000 ppm 15 minutes. 1-Methoxy-2-Propanol Acetate AIHA WEEL (United States, 10/2011). TWA: 50 ppm 8 hours. Acetone ACGIH TLV (United States, 3/2017). TWA: 250 ppm 8 hours. STEL: 500 ppm 15 minutes. NIOSH REL (United States, 10/2016). TWA: 250 ppm 10 hours. TWA: 590 mg/m? 10 hours. OSHA PEL (United States, 6/2016). TWA: 1000 ppm 8 hours. TWA: 2400 mg/m? 8 hours. Xylene ACGIH TLV (United States, 3/2017). TWA: 100 ppm 8 hours. TWA: 434 mg/m? 8 hours. STEL: 150 ppm 15 minutes. STEL: 651 mg/m? 15 minutes. OSHA PEL (United States, 6/2016). TWA: 100 ppm 8 hours. TWA: 435 mg/m? 8 hours. Methyl Isobutyl Ketone ACGIH TLV (United States, 3/2017). TWA: 20 ppm 8 hours. STEL: 75 ppm 15 minutes. NIOSH REL (United States, 10/2016). TWA: 50 ppm 10 hours. TWA: 205 mg/m? 10 hours. STEL: 75 ppm 15 minutes. STEL: 300 mg/m? 15 minutes. OSHA PEL (United States, 6/2016). TWA: 100 ppm 8 hours. TWA: 410 mg/m? 8 hours. 1-Butanol ACGIH TLV (United States, 3/2017). TWA: 20 ppm 8 hours. NIOSH REL (United States, 10/2016). Date of issue/Date of revision : 4/9/2018 Date of previous issue : 8/9/2017 Version : 8 6/19 BBL308 BRIGHT BEAUTY? Lacquer Semi-Flat Black SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Absorbed through skin. CEIL: 50 ppm CEIL: 150 mg/m? OSHA PEL (United States, 6/2016). TWA: 100 ppm 8 hours. TWA: 300 mg/m? 8 hours. Carbon Black NIOSH REL (United States, 10/2016). TWA: 3.5 mg/m? 10 hours. TWA: 0.1 mg of PAHs/cm? 10 hours. OSHA PEL (United States, 6/2016). TWA: 3.5 mg/m? 8 hours. ACGIH TLV (United States, 3/2017). TWA: 3 mg/m? 8 hours. Form: Inhalable fraction Ethylbenzene ACGIH TLV (United States, 3/2017). TWA: 20 ppm 8 hours. NIOSH REL (United States, 10/2016). TWA: 100 ppm 10 hours. TWA: 435 mg/m? 10 hours. STEL: 125 ppm 15 minutes. STEL: 545 mg/m? 15 minutes. OSHA PEL (United States, 6/2016). TWA: 100 ppm 8 hours. TWA: 435 mg/m? 8 hours. Methyl Acetate CA Alberta Provincial (Canada, 4/2009). 8 hrs OEL: 606 mg/m? 8 hours. 15 min OEL: 757 mg/m? 15 minutes. 15 min OEL: 250 ppm 15 minutes. 8 hrs OEL: 200 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2017). TWA: 200 ppm 8 hours. STEL: 250 ppm 15 minutes. CA Ontario Provincial (Canada, 7/2015). TWA: 200 ppm 8 hours. STEL: 250 ppm 15 minutes. CA Quebec Provincial (Canada, 1/2014). TWAEV: 200 ppm 8 hours. TWAEV: 606 mg/m? 8 hours. STEV: 250 ppm 15 minutes. STEV: 757 mg/m? 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 250 ppm 15 minutes. TWA: 200 ppm 8 hours. Methyl Ethyl Ketone CA Alberta Provincial (Canada, 4/2009). 15 min OEL: 300 ppm 15 minutes. 8 hrs OEL: 200 ppm 8 hours. 8 hrs OEL: 590 mg/m? 8 hours. 15 min OEL: 885 mg/m? 15 minutes. CA British Columbia Provincial (Canada, 6/2017). TWA: 50 ppm 8 hours. STEL: 100 ppm 15 minutes. CA Ontario Provincial (Canada, 7/2015). TWA: 200 ppm 8 hours. STEL: 300 ppm 15 minutes. Ingredient name Exposure limits Occupational exposure limits (Canada) Date of issue/Date of revision : 4/9/2018 Date of previous issue : 8/9/2017 Version : 8 7/19 BBL308 BRIGHT BEAUTY? Lacquer Semi-Flat Black SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection CA Quebec Provincial (Canada, 1/2014). TWAEV: 50 ppm 8 hours. TWAEV: 150 mg/m? 8 hours. STEV: 100 ppm 15 minutes. STEV: 300 mg/m? 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 300 ppm 15 minutes. TWA: 200 ppm 8 hours. Propane CA Alberta Provincial (Canada, 4/2009). 8 hrs OEL: 1000 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2017). TWA: 1000 ppm 8 hours. CA Quebec Provincial (Canada, 1/2014). TWAEV: 1000 ppm 8 hours. TWAEV: 1800 mg/m? 8 hours. CA Ontario Provincial (Canada, 7/2015). TWA: 1000 ppm 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 1250 ppm 15 minutes. TWA: 1000 ppm 8 hours. Butane CA Alberta Provincial (Canada, 4/2009). 8 hrs OEL: 1000 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2017). TWA: 600 ppm 8 hours. STEL: 750 ppm 15 minutes. CA Quebec Provincial (Canada, 1/2014). TWAEV: 800 ppm 8 hours. TWAEV: 1900 mg/m? 8 hours. CA Ontario Provincial (Canada, 7/2015). TWA: 800 ppm 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 1250 ppm 15 minutes. TWA: 1000 ppm 8 hours. Acetone CA Alberta Provincial (Canada, 4/2009). 8 hrs OEL: 1200 mg/m? 8 hours. 15 min OEL: 1800 mg/m? 15 minutes. 8 hrs OEL: 500 ppm 8 hours. 15 min OEL: 750 ppm 15 minutes. CA British Columbia Provincial (Canada, 6/2017). TWA: 250 ppm 8 hours. STEL: 500 ppm 15 minutes. CA Ontario Provincial (Canada, 7/2015). TWA: 500 ppm 8 hours. STEL: 750 ppm 15 minutes. CA Quebec Provincial (Canada, 1/2014). TWAEV: 500 ppm 8 hours. TWAEV: 1190 mg/m? 8 hours. STEV: 1000 ppm 15 minutes. STEV: 2380 mg/m? 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 750 ppm 15 minutes. TWA: 500 ppm 8 hours. Xylene CA Alberta Provincial (Canada, 4/2009). 8 hrs OEL: 100 ppm 8 hours. Date of issue/Date of revision : 4/9/2018 Date of previous issue : 8/9/2017 Version : 8 8/19 BBL308 BRIGHT BEAUTY? Lacquer Semi-Flat Black SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection 15 min OEL: 651 mg/m? 15 minutes. 15 min OEL: 150 ppm 15 minutes. 8 hrs OEL: 434 mg/m? 8 hours. CA British Columbia Provincial (Canada, 6/2017). TWA: 100 ppm 8 hours. STEL: 150 ppm 15 minutes. CA Quebec Provincial (Canada, 1/2014). TWAEV: 100 ppm 8 hours. TWAEV: 434 mg/m? 8 hours. STEV: 150 ppm 15 minutes. STEV: 651 mg/m? 15 minutes. CA Ontario Provincial (Canada, 7/2015). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. Methyl Isobutyl Ketone CA Alberta Provincial (Canada, 4/2009). 8 hrs OEL: 205 mg/m? 8 hours. 8 hrs OEL: 50 ppm 8 hours. 15 min OEL: 75 ppm 15 minutes. 15 min OEL: 307 mg/m? 15 minutes. CA British Columbia Provincial (Canada, 6/2017). TWA: 20 ppm 8 hours. STEL: 75 ppm 15 minutes. CA Ontario Provincial (Canada, 7/2015). TWA: 20 ppm 8 hours. STEL: 75 ppm 15 minutes. CA Quebec Provincial (Canada, 1/2014). TWAEV: 50 ppm 8 hours. TWAEV: 205 mg/m? 8 hours. STEV: 75 ppm 15 minutes. STEV: 307 mg/m? 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 75 ppm 15 minutes. TWA: 50 ppm 8 hours. 1-Butanol CA Alberta Provincial (Canada, 4/2009). 8 hrs OEL: 60 mg/m? 8 hours. 8 hrs OEL: 20 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2017). TWA: 15 ppm 8 hours. C: 30 ppm CA Ontario Provincial (Canada, 7/2015). TWA: 20 ppm 8 hours. CA Quebec Provincial (Canada, 1/2014). Absorbed through skin. STEV: 50 ppm 15 minutes. STEV: 152 mg/m? 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 30 ppm 15 minutes. TWA: 20 ppm 8 hours. Ethylbenzene CA Alberta Provincial (Canada, 4/2009). 8 hrs OEL: 100 ppm 8 hours. 8 hrs OEL: 434 mg/m? 8 hours. 15 min OEL: 543 mg/m? 15 minutes. Date of issue/Date of revision : 4/9/2018 Date of previous issue : 8/9/2017 Version : 8 9/19 BBL308 BRIGHT BEAUTY? Lacquer Semi-Flat Black SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures 15 min OEL: 125 ppm 15 minutes. CA British Columbia Provincial (Canada, 6/2017). TWA: 20 ppm 8 hours. CA Ontario Provincial (Canada, 7/2015). TWA: 20 ppm 8 hours. CA Quebec Provincial (Canada, 1/2014). TWAEV: 100 ppm 8 hours. TWAEV: 434 mg/m? 8 hours. STEV: 125 ppm 15 minutes. STEV: 543 mg/m? 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 125 ppm 15 minutes. TWA: 100 ppm 8 hours. Environmental exposure controls : Methyl Acetate NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 200 ppm 8 hours. STEL: 250 ppm 15 minutes. Methyl Ethyl Ketone NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 200 ppm 8 hours. STEL: 300 ppm 15 minutes. Propane NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 1000 ppm 8 hours. Butane NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 1000 ppm 8 hours. Acetone NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 500 ppm 8 hours. STEL: 750 ppm 15 minutes. Xylene NOM-010-STPS-2014 (Mexico, 4/2016). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. Methyl Isobutyl Ketone NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 50 ppm 8 hours. STEL: 75 ppm 15 minutes. 1-Butanol NOM-010-STPS-2014 (Mexico, 4/2016). Absorbed through skin. TWA: 20 ppm 8 hours. Ethylbenzene NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 20 ppm 8 hours. Ingredient name Exposure limits Occupational exposure limits (Mexico) Date of issue/Date of revision : 4/9/2018 Date of previous issue : 8/9/2017 Version : 8 10/19 BBL308 BRIGHT BEAUTY? Lacquer Semi-Flat Black SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. Not available. 0.79 1.55 [Air = 1] 101.3 kPa (760 mm Hg) [at 20?C] Not available. Not available.Odor pH Not available.Color Evaporation rate 5.6 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: -29?C (-20.2?F) [Pensky-Martens Closed Cup] Not available. Not available. Viscosity Kinematic (40?C (104?F)): <0.205 cm2/s (<20.5 cSt) Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Lower: 1% Upper: 16% Decomposition temperature : Not available. Type of aerosol : Spray Heat of combustion : 34.986 kJ/g Aerosol product Molecular weight : Not applicable. Date of issue/Date of revision : 4/9/2018 Date of previous issue : 8/9/2017 Version : 8 11/19 BBL308 BRIGHT BEAUTY? Lacquer Semi-Flat Black SHW-85-NA-GHS-US Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Methyl Acetate LD50 Dermal Rabbit >5 g/kg - LD50 Oral Rat >5 g/kg - Methyl Ethyl Ketone LD50 Dermal Rabbit 6480 mg/kg - LD50 Oral Rat 2737 mg/kg - Butane LC50 Inhalation Vapor Rat 658000 mg/m? 4 hours 1-Methoxy-2-Propanol Acetate LD50 Dermal Rabbit >5 g/kg - LD50 Oral Rat 8532 mg/kg - Acetone LD50 Oral Rat 5800 mg/kg - Xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours LD50 Oral Rat 4300 mg/kg - Methyl Isobutyl Ketone LD50 Oral Rat 2080 mg/kg - 1-Butanol LC50 Inhalation Vapor Rat 24000 mg/m? 4 hours LD50 Dermal Rabbit 3400 mg/kg - LD50 Oral Rat 790 mg/kg - Carbon Black LD50 Oral Rat >15400 mg/kg - Ethylbenzene LD50 Dermal Rabbit >5000 mg/kg - LD50 Oral Rat 3500 mg/kg - Product/ingredient name Result Species Dose Exposure Irritation/Corrosion Methyl Acetate Eyes - Moderate irritant Rabbit - 24 hours 100 milligrams - Skin - Mild irritant Rabbit - 24 hours 500 milligrams - Skin - Moderate irritant Rabbit - 24 hours 20 milligrams - Methyl Ethyl Ketone Skin - Mild irritant Rabbit - 24 hours 14 milligrams - Skin - Moderate irritant Rabbit - 24 hours 500 milligrams - Acetone Eyes - Mild irritant Human - 186300 parts per million - Eyes - Mild irritant Rabbit - 10 microliters - Eyes - Moderate irritant Rabbit - 24 hours 20 milligrams - Eyes - Severe irritant Rabbit - 20 milligrams - Skin - Mild irritant Rabbit - 24 hours 500 milligrams - Skin - Mild irritant Rabbit - 395 - Product/ingredient name Result Score Exposure ObservationSpecies Information on toxicological effects Date of issue/Date of revision : 4/9/2018 Date of previous issue : 8/9/2017 Version : 8 12/19 BBL308 BRIGHT BEAUTY? Lacquer Semi-Flat Black SHW-85-NA-GHS-US Section 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. milligrams Xylene Eyes - Mild irritant Rabbit - 87 milligrams - Eyes - Severe irritant Rabbit - 24 hours 5 milligrams - Skin - Mild irritant Rat - 8 hours 60 microliters - Skin - Moderate irritant Rabbit - 24 hours 500 milligrams - Skin - Moderate irritant Rabbit - 100 Percent - Methyl Isobutyl Ketone Eyes - Moderate irritant Rabbit - 24 hours 100 microliters - Eyes - Severe irritant Rabbit - 40 milligrams - Skin - Mild irritant Rabbit - 24 hours 500 milligrams - 1-Butanol Eyes - Severe irritant Rabbit - 24 hours 2 milligrams - Eyes - Severe irritant Rabbit - 0.005 Mililiters - Skin - Moderate irritant Rabbit - 24 hours 20 milligrams - Ethylbenzene Eyes - Severe irritant Rabbit - 500 milligrams - Skin - Mild irritant Rabbit - 24 hours 15 milligrams - Sensitization Not available. Specific target organ toxicity (single exposure) Methyl Acetate Category 3 Not applicable. Narcotic effects Methyl Ethyl Ketone Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Propane Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Butane Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Acetone Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Name Category Route of exposure Target organs Classification Xylene - 3 - Methyl Isobutyl Ketone - 2B - Carbon Black - 2B - Ethylbenzene - 2B - Product/ingredient name NTPIARCOSHA Date of issue/Date of revision : 4/9/2018 Date of previous issue : 8/9/2017 Version : 8 13/19 BBL308 BRIGHT BEAUTY? Lacquer Semi-Flat Black SHW-85-NA-GHS-US Section 11. Toxicological information Specific target organ toxicity (repeated exposure) Xylene Category 3 Not applicable. Respiratory tract irritation Methyl Isobutyl Ketone Category 3 Not applicable. Respiratory tract irritation and Narcotic effects 1-Butanol Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Ethylbenzene Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Name Category Methyl Ethyl Ketone Category 2 Not determined Not determined Propane Category 2 Not determined Not determined Butane Category 2 Not determined Not determined Acetone Category 2 Not determined Not determined Xylene Category 2 Not determined Not determined Methyl Isobutyl Ketone Category 2 Not determined Not determined 1-Butanol Category 2 Not determined Not determined Ethylbenzene Category 2 Not determined Not determined Aspiration hazard Name Result Propane ASPIRATION HAZARD - Category 1 Butane ASPIRATION HAZARD - Category 1 Xylene ASPIRATION HAZARD - Category 1 Ethylbenzene ASPIRATION HAZARD - Category 1 Route of exposure Target organs Information on the likely routes of exposure Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. :Ingestion Skin contact : Causes skin irritation. Causes serious eye irritation.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Skin contact Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness Adverse symptoms may include the following: irritation redness : : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness : Not available. Potential acute health effects Date of issue/Date of revision : 4/9/2018 Date of previous issue : 8/9/2017 Version : 8 14/19 BBL308 BRIGHT BEAUTY? Lacquer Semi-Flat Black SHW-85-NA-GHS-US Not available. May cause damage to organs through prolonged or repeated exposure.General : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Ingestion Adverse symptoms may include the following: nausea or vomiting : Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Oral 7774.4 mg/kg Dermal 25562.4 mg/kg Inhalation (gases) 35892.3 ppm Inhalation (vapors) 188.7 mg/l Route ATE value Acute toxicity estimates Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Section 12. Ecological information Toxicity Methyl Acetate Acute LC50 320000 ?g/l Fresh water Fish - Pimephales promelas 96 hours Methyl Ethyl Ketone Acute EC50 >500000 ?g/l Marine water Algae - Skeletonema costatum 96 hours Acute EC50 5091000 ?g/l Fresh water Daphnia - Daphnia magna - Larvae 48 hours Acute LC50 3220000 ?g/l Fresh water Fish - Pimephales promelas 96 hours Acetone Acute EC50 7200000 ?g/l Fresh water Algae - Selenastrum sp. 96 hours Acute LC50 6000000 ?g/l Fresh water Crustaceans - Gammarus pulex 48 hours Acute LC50 6900 mg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 5600 ppm Fresh water Fish - Poecilia reticulata 96 hours Chronic NOEC 4.95 mg/l Marine water Algae - Ulva pertusa 96 hours Chronic NOEC 0.016 ml/L Fresh water Crustaceans - Daphniidae 21 days Chronic NOEC 0.1 ml/L Fresh water Daphnia - Daphnia magna - Neonate 21 days Chronic NOEC 0.1 mg/l Fresh water Fish - Fundulus heteroclitus 4 weeks Xylene Acute LC50 8500 ?g/l Marine water Crustaceans - Palaemonetes pugio 48 hours Acute LC50 13400 ?g/l Fresh water Fish - Pimephales promelas 96 hours Methyl Isobutyl Ketone Acute LC50 505000 ?g/l Fresh water Fish - Pimephales promelas 96 hours Chronic NOEC 78 mg/l Fresh water Daphnia - Daphnia magna 21 days Chronic NOEC 168 mg/l Fresh water Fish - Pimephales promelas - Embryo 33 days Product/ingredient name SpeciesResult Exposure Date of issue/Date of revision : 4/9/2018 Date of previous issue : 8/9/2017 Version : 8 15/19 BBL308 BRIGHT BEAUTY? Lacquer Semi-Flat Black SHW-85-NA-GHS-US Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Xylene - 8.1 to 25.9 low Product/ingredient name Aquatic half-life Photolysis Biodegradability Methyl Ethyl Ketone - - Readily Acetone - - Readily Xylene - - Readily Methyl Isobutyl Ketone - - Readily 1-Butanol - - Readily Ethylbenzene - - Readily 1-Butanol Acute EC50 1983000 ?g/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 1730000 ?g/l Fresh water Fish - Pimephales promelas 96 hours Ethylbenzene Acute EC50 4600 ?g/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours Acute EC50 3600 ?g/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours Acute EC50 6530 ?g/l Fresh water Crustaceans - Artemia sp. - Nauplii 48 hours Acute EC50 2930 ?g/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours Acute LC50 4200 ?g/l Fresh water Fish - Oncorhynchus mykiss 96 hours Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. :Disposal methods Section 14. Transport information AEROSOLS AEROSOLS UN1950 UN1950 DOT Classification IMDG UN number UN proper shipping name TDG Classification UN1950 AEROSOLS Mexico Classification UN1950 AEROSOLS IATA UN1950 AEROSOLS, flammable Date of issue/Date of revision : 4/9/2018 Date of previous issue : 8/9/2017 Version : 8 16/19 BBL308 BRIGHT BEAUTY? Lacquer Semi-Flat Black SHW-85-NA-GHS-US Section 14. Transport information 2.1 - 2.1 - - Emergency schedules F-D, S- U Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL and the IBC Code No. No. Not available. : Proper shipping name : Ship type : Not available. Pollution category : Not available. Not available. : 2.1 - No. Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2. 13-2.17 (Class 2). 2.1 - No. - Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. 2.1 - No. - 126 ERG No. 126 126 ERG No. ERG No. Section 15. Regulatory information SARA 313 SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 Section 16. Other information Hazardous Material Information System (U.S.A.) 3 4 3 *Health Flammability Physical hazards The customer is responsible for determining the PPE code for this material. For more information on HMIS? Personal Protective Equipment (PPE) codes, consult the HMIS? Implementation Manual. Date of issue/Date of revision : 4/9/2018 Date of previous issue : 8/9/2017 Version : 8 17/19 BBL308 BRIGHT BEAUTY? Lacquer Semi-Flat Black SHW-85-NA-GHS-US Section 16. Other information 4/9/2018 History Date of printing Date of issue/Date of revision Version It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Notice to reader Date of previous issue : : : : Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 4/9/2018 8/9/2017 8 Caution: HMIS? ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS? ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS? ratings are to be used with a fully implemented HMIS? program. HMIS? is a registered trademark and service mark of the American Coatings Association, Inc. FLAMMABLE AEROSOLS - Category 1 On basis of test data GASES UNDER PRESSURE - Compressed gas Calculation method SKIN CORROSION/IRRITATION - Category 2 Calculation method SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method CARCINOGENICITY - Category 2 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method ASPIRATION HAZARD - Category 1 Calculation method Procedure used to derive the classification Classification Justification Date of issue/Date of revision : 4/9/2018 Date of previous issue : 8/9/2017 Version : 8 18/19 BBL308 BRIGHT BEAUTY? Lacquer Semi-Flat Black SHW-85-NA-GHS-US Date of issue/Date of revision : 4/9/2018 Date of previous issue : 8/9/2017 Version : 8 19/19 BBL308 BRIGHT BEAUTY? Lacquer Semi-Flat Black SHW-85-NA-GHS-US BBL308_SDS_English_US Page 1 Page 2 Page 3 Page 4 Page 5 Page 6 Page 7 Page 8 Page 9 Page 10 Page 11 Page 12 Page 13 Page 14 Page 15 Page 16 Page 17 Page 18 Page 19