PERFECT MATCH Premium Automotive Paint Stellar Blue Pearl (8L7) Not available. Aerosol. (216) 566-2917 SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer : Dupli-Color Products Company Cleveland, OH 44115 Relevant identified uses of the substance or mixture and uses advised against Not applicable. BTY1612 BTY1612Product code : Product Information Telephone Number : (800) 247-3270 Regulatory Information Telephone Number : (216) 566-2902 Transportation Emergency Telephone Number : (800) 424-9300 CAS # : Not applicable. Section 2. Hazards identification FLAMMABLE AEROSOLS - Category 1 GASES UNDER PRESSURE - Compressed gas SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION (Unborn child) - Category 1B TOXIC TO REPRODUCTION (Fertility) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 ASPIRATION HAZARD - Category 1 Classification of the substance or mixture : Signal word : Danger Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 10.2% OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue/Date of revision : 3/6/2017 Date of previous issue : 1/10/2017 Version : 6 1/17 Section 2. Hazards identification Precautionary statements Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection. Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist. Wash hands thoroughly after handling. Pressurized container: Do not pierce or burn, even after use. Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F. Store in a well-ventilated place. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Hazards not otherwise classified : None known. Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. Causes skin irritation. May damage the unborn child. Suspected of damaging fertility. Suspected of causing cancer. May be fatal if swallowed and enters airways. May cause respiratory irritation. May cause drowsiness or dizziness. May cause damage to organs through prolonged or repeated exposure. :Hazard statements Please refer to the SDS for additional information. Keep out of reach of children. Keep upright in a cool, dry place. Do not discard empty can in trash compactor. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. : Section 3. Composition/information on ingredients Other means of identification : Not available. Substance/mixture CAS number/other identifiers : Mixture Date of issue/Date of revision : 3/6/2017 Date of previous issue : 1/10/2017 Version : 6 2/17 Section 3. Composition/information on ingredients Methyl Acetate 44 79-20-9 Propane 10.2 74-98-6 Butane 9.8 106-97-8 Toluene 8.47 108-88-3 Methyl Ethyl Ketone 7.1 78-93-3 1-Methoxy-2-Propanol Acetate 6 108-65-6 Ethyl Acetate 2.02 141-78-6 Ethanol 1.47 64-17-5 Cellulose Nitrate 1.4 9004-70-0 Titanium Dioxide 0.27 13463-67-7 Dibutyl Phthalate 0.11 84-74-2 Ingredient name CAS number% by weight There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Skin contact : Causes skin irritation. Causes serious eye irritation.:Eye contact Potential acute health effects Date of issue/Date of revision : 3/6/2017 Date of previous issue : 1/10/2017 Version : 6 3/17 Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. :Ingestion Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Specific hazards arising from the chemical Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard. Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : None known. Suitable extinguishing media : Unsuitable extinguishing media : Date of issue/Date of revision : 3/6/2017 Date of previous issue : 1/10/2017 Version : 6 4/17 Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Protective measures Put on appropriate personal protective equipment (see Section 8). Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50?C. Do not pierce or burn, even after use. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical : Precautions for safe handling Date of issue/Date of revision : 3/6/2017 Date of previous issue : 1/10/2017 Version : 6 5/17 Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. : : (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. Methyl Acetate ACGIH TLV (United States, 3/2016). TWA: 200 ppm 8 hours. TWA: 606 mg/m? 8 hours. STEL: 250 ppm 15 minutes. STEL: 757 mg/m? 15 minutes. NIOSH REL (United States, 10/2013). TWA: 200 ppm 10 hours. TWA: 610 mg/m? 10 hours. STEL: 250 ppm 15 minutes. STEL: 760 mg/m? 15 minutes. OSHA PEL (United States, 6/2016). TWA: 200 ppm 8 hours. TWA: 610 mg/m? 8 hours. Propane NIOSH REL (United States, 10/2013). TWA: 1000 ppm 10 hours. TWA: 1800 mg/m? 10 hours. OSHA PEL (United States, 6/2016). TWA: 1000 ppm 8 hours. TWA: 1800 mg/m? 8 hours. Butane NIOSH REL (United States, 10/2013). TWA: 800 ppm 10 hours. TWA: 1900 mg/m? 10 hours. ACGIH TLV (United States, 3/2016). STEL: 1000 ppm 15 minutes. Toluene OSHA PEL Z2 (United States, 2/2013). TWA: 200 ppm 8 hours. CEIL: 300 ppm AMP: 500 ppm 10 minutes. NIOSH REL (United States, 10/2013). TWA: 100 ppm 10 hours. TWA: 375 mg/m? 10 hours. STEL: 150 ppm 15 minutes. STEL: 560 mg/m? 15 minutes. ACGIH TLV (United States, 3/2016). TWA: 20 ppm 8 hours. Methyl Ethyl Ketone ACGIH TLV (United States, 3/2016). TWA: 200 ppm 8 hours. TWA: 590 mg/m? 8 hours. STEL: 300 ppm 15 minutes. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits (OSHA United States) Date of issue/Date of revision : 3/6/2017 Date of previous issue : 1/10/2017 Version : 6 6/17 Section 8. Exposure controls/personal protection STEL: 885 mg/m? 15 minutes. NIOSH REL (United States, 10/2013). TWA: 200 ppm 10 hours. TWA: 590 mg/m? 10 hours. STEL: 300 ppm 15 minutes. STEL: 885 mg/m? 15 minutes. OSHA PEL (United States, 6/2016). TWA: 200 ppm 8 hours. TWA: 590 mg/m? 8 hours. 1-Methoxy-2-Propanol Acetate AIHA WEEL (United States, 10/2011). TWA: 50 ppm 8 hours. Ethyl Acetate ACGIH TLV (United States, 3/2016). TWA: 400 ppm 8 hours. TWA: 1440 mg/m? 8 hours. NIOSH REL (United States, 10/2013). TWA: 400 ppm 10 hours. TWA: 1400 mg/m? 10 hours. OSHA PEL (United States, 6/2016). TWA: 400 ppm 8 hours. TWA: 1400 mg/m? 8 hours. Ethanol ACGIH TLV (United States, 3/2016). STEL: 1000 ppm 15 minutes. NIOSH REL (United States, 10/2013). TWA: 1000 ppm 10 hours. TWA: 1900 mg/m? 10 hours. OSHA PEL (United States, 6/2016). TWA: 1000 ppm 8 hours. TWA: 1900 mg/m? 8 hours. Cellulose Nitrate None. Titanium Dioxide ACGIH TLV (United States, 3/2016). TWA: 10 mg/m? 8 hours. OSHA PEL (United States, 6/2016). TWA: 15 mg/m? 8 hours. Form: Total dust Dibutyl Phthalate ACGIH TLV (United States, 3/2016). TWA: 5 mg/m? 8 hours. NIOSH REL (United States, 10/2013). TWA: 5 mg/m? 10 hours. OSHA PEL (United States, 6/2016). TWA: 5 mg/m? 8 hours. Methyl Acetate CA Alberta Provincial (Canada, 4/2009). 8 hrs OEL: 606 mg/m? 8 hours. 15 min OEL: 757 mg/m? 15 minutes. 15 min OEL: 250 ppm 15 minutes. 8 hrs OEL: 200 ppm 8 hours. CA British Columbia Provincial (Canada, 5/2015). TWA: 200 ppm 8 hours. STEL: 250 ppm 15 minutes. CA Ontario Provincial (Canada, 7/2015). TWA: 200 ppm 8 hours. STEL: 250 ppm 15 minutes. CA Quebec Provincial (Canada, 1/2014). TWAEV: 200 ppm 8 hours. TWAEV: 606 mg/m? 8 hours. STEV: 250 ppm 15 minutes. Ingredient name Exposure limits Occupational exposure limits (Canada) Date of issue/Date of revision : 3/6/2017 Date of previous issue : 1/10/2017 Version : 6 7/17 Section 8. Exposure controls/personal protection STEV: 757 mg/m? 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 250 ppm 15 minutes. TWA: 200 ppm 8 hours. Propane CA Alberta Provincial (Canada, 4/2009). 8 hrs OEL: 1000 ppm 8 hours. CA British Columbia Provincial (Canada, 5/2015). TWA: 1000 ppm 8 hours. CA Quebec Provincial (Canada, 1/2014). TWAEV: 1000 ppm 8 hours. TWAEV: 1800 mg/m? 8 hours. CA Ontario Provincial (Canada, 7/2015). TWA: 1000 ppm 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 1250 ppm 15 minutes. TWA: 1000 ppm 8 hours. Dibutyl Phthalate CA Alberta Provincial (Canada, 4/2009). 8 hrs OEL: 5 mg/m? 8 hours. CA British Columbia Provincial (Canada, 5/2015). TWA: 5 mg/m? 8 hours. CA Ontario Provincial (Canada, 7/2015). TWA: 5 mg/m? 8 hours. CA Quebec Provincial (Canada, 1/2014). TWAEV: 5 mg/m? 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 10 mg/m? 15 minutes. TWA: 5 mg/m? 8 hours. Methyl Acetate NOM-010-STPS (Mexico, 4/2016). LMPE-PPT: 200 ppm 8 hours. LMPE-CT: 250 ppm 15 minutes. Propane NOM-010-STPS (Mexico, 4/2016). LMPE-PPT: 1000 ppm 8 hours. Butane NOM-010-STPS (Mexico, 4/2016). LMPE-PPT: 1000 ppm 8 hours. Toluene NOM-010-STPS (Mexico, 4/2016). LMPE-PPT: 20 ppm 8 hours. Methyl Ethyl Ketone NOM-010-STPS (Mexico, 4/2016). LMPE-PPT: 200 ppm 8 hours. LMPE-CT: 300 ppm 15 minutes. Ethyl Acetate NOM-010-STPS (Mexico, 4/2016). LMPE-PPT: 400 ppm 8 hours. Ethanol NOM-010-STPS (Mexico, 4/2016). LMPE-CT: 1000 ppm 15 minutes. Dibutyl Phthalate NOM-010-STPS (Mexico, 4/2016). LMPE-PPT: 5 mg/m? 8 hours. Ingredient name Exposure limits Occupational exposure limits (Mexico) Date of issue/Date of revision : 3/6/2017 Date of previous issue : 1/10/2017 Version : 6 8/17 Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Environmental exposure controls : Section 9. Physical and chemical properties Physical state Melting point Liquid. Not available. Not available.Odor pH Not available.Color Evaporation rate 5.6 (butyl acetate = 1) Flash point Closed cup: -29?C (-20.2?F) [Pensky-Martens Closed Cup] Not available. Not available.Odor threshold : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Not available. Date of issue/Date of revision : 3/6/2017 Date of previous issue : 1/10/2017 Version : 6 9/17 Section 9. Physical and chemical properties Vapor pressure Relative density Vapor density Solubility 0.8 1.5 [Air = 1] 101.3 kPa (760 mm Hg) [at 20?C] Not available. Auto-ignition temperature Not available. Not available. Viscosity Kinematic (40?C (104?F)): <0.205 cm2/s (<20.5 cSt) Partition coefficient: n- octanol/water : : : : : : : Lower and upper explosive (flammable) limits : Lower: 1% Upper: 19% Decomposition temperature : Not available. Type of aerosol : Spray Heat of combustion : 36.32 kJ/g Aerosol product Molecular weight : Not applicable. Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Methyl Acetate LD50 Dermal Rabbit >5 g/kg - LD50 Oral Rat >5 g/kg - Butane LC50 Inhalation Vapor Rat 658000 mg/m? 4 hours Toluene LC50 Inhalation Vapor Rat 49 g/m? 4 hours LD50 Oral Rat 636 mg/kg - Methyl Ethyl Ketone LD50 Dermal Rabbit 6480 mg/kg - LD50 Oral Rat 2737 mg/kg - 1-Methoxy-2-Propanol Acetate LD50 Dermal Rabbit >5 g/kg - LD50 Oral Rat 8532 mg/kg - Ethyl Acetate LD50 Oral Rat 5620 mg/kg - Ethanol LC50 Inhalation Vapor Rat 124700 mg/m? 4 hours LD50 Oral Rat 7 g/kg - Cellulose Nitrate LD50 Oral Rat >5 g/kg - Dibutyl Phthalate LD50 Oral Rat 7499 mg/kg - Product/ingredient name Result Species Dose Exposure Irritation/Corrosion Information on toxicological effects Date of issue/Date of revision : 3/6/2017 Date of previous issue : 1/10/2017 Version : 6 10/17 Section 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Reproductive toxicity Methyl Acetate Eyes - Moderate irritant Rabbit - 24 hours 100 milligrams - Skin - Mild irritant Rabbit - 24 hours 500 milligrams - Skin - Moderate irritant Rabbit - 24 hours 20 milligrams - Toluene Eyes - Mild irritant Rabbit - 0.5 minutes 100 milligrams - Eyes - Mild irritant Rabbit - 870 Micrograms - Eyes - Severe irritant Rabbit - 24 hours 2 milligrams - Skin - Mild irritant Pig - 24 hours 250 microliters - Skin - Mild irritant Rabbit - 435 milligrams - Skin - Moderate irritant Rabbit - 24 hours 20 milligrams - Skin - Moderate irritant Rabbit - 500 milligrams - Methyl Ethyl Ketone Skin - Mild irritant Rabbit - 24 hours 14 milligrams - Skin - Moderate irritant Rabbit - 24 hours 500 milligrams - Ethanol Eyes - Mild irritant Rabbit - 24 hours 500 milligrams - Eyes - Moderate irritant Rabbit - 0.066666667 minutes 100 milligrams - Eyes - Moderate irritant Rabbit - 100 microliters - Eyes - Severe irritant Rabbit - 500 milligrams - Skin - Mild irritant Rabbit - 400 milligrams - Skin - Moderate irritant Rabbit - 24 hours 20 milligrams - Titanium Dioxide Skin - Mild irritant Human - 72 hours 300 Micrograms Intermittent - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Classification Toluene - 3 - Ethanol - 1 - Titanium Dioxide - 2B - Product/ingredient name NTPIARCOSHA Date of issue/Date of revision : 3/6/2017 Date of previous issue : 1/10/2017 Version : 6 11/17 Section 11. Toxicological information Teratogenicity Not available. Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Methyl Acetate Category 3 Not applicable. Narcotic effects Propane Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Butane Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Toluene Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Methyl Ethyl Ketone Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Ethyl Acetate Category 3 Not applicable. Narcotic effects Ethanol Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Name Category Name Category Propane Category 2 Not determined Not determined Butane Category 2 Not determined Not determined Toluene Category 2 Not determined Not determined Methyl Ethyl Ketone Category 2 Not determined Not determined Ethanol Category 2 Not determined Not determined Aspiration hazard Name Result Propane ASPIRATION HAZARD - Category 1 Butane ASPIRATION HAZARD - Category 1 Toluene ASPIRATION HAZARD - Category 1 Route of exposure Target organs Route of exposure Target organs Information on the likely routes of exposure Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. :Ingestion Skin contact : Causes skin irritation. Causes serious eye irritation.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics : Not available. Potential acute health effects Date of issue/Date of revision : 3/6/2017 Date of previous issue : 1/10/2017 Version : 6 12/17 Not available. May cause damage to organs through prolonged or repeated exposure.General : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : May damage the unborn child.Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : Suspected of damaging fertility. Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Oral 5647.1 mg/kg Route ATE value Acute toxicity estimates Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Date of issue/Date of revision : 3/6/2017 Date of previous issue : 1/10/2017 Version : 6 13/17 Section 12. Ecological information Bioaccumulative potential Product/ingredient name Aquatic half-life Photolysis Biodegradability Toluene - - Readily Methyl Ethyl Ketone - - Readily 1-Methoxy-2-Propanol Acetate - - Readily Ethyl Acetate - - Readily Ethanol - - Readily Toxicity Methyl Acetate Acute LC50 320000 ?g/l Fresh water Fish - Pimephales promelas 96 hours Toluene Acute EC50 12500 ?g/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours Acute EC50 11600 ?g/l Fresh water Crustaceans - Gammarus pseudolimnaeus - Adult 48 hours Acute EC50 6000 ?g/l Fresh water Daphnia - Daphnia magna - Juvenile (Fledgling, Hatchling, Weanling) 48 hours Acute LC50 5500 ?g/l Fresh water Fish - Oncorhynchus kisutch - Fry 96 hours Chronic NOEC 1000 ?g/l Fresh water Daphnia - Daphnia magna 21 days Methyl Ethyl Ketone Acute EC50 >500000 ?g/l Marine water Algae - Skeletonema costatum 96 hours Acute EC50 5091000 ?g/l Fresh water Daphnia - Daphnia magna - Larvae 48 hours Acute LC50 3220000 ?g/l Fresh water Fish - Pimephales promelas 96 hours Ethyl Acetate Acute EC50 2500000 ?g/l Fresh water Algae - Selenastrum sp. 96 hours Acute LC50 750000 ?g/l Fresh water Crustaceans - Gammarus pulex 48 hours Acute LC50 154000 ?g/l Fresh water Daphnia - Daphnia cucullata 48 hours Acute LC50 212500 ?g/l Fresh water Fish - Heteropneustes fossilis 96 hours Chronic NOEC 2400 ?g/l Fresh water Daphnia - Daphnia magna 21 days Chronic NOEC 75.6 mg/l Fresh water Fish - Pimephales promelas - Embryo 32 days Ethanol Acute EC50 17.921 mg/l Marine water Algae - Ulva pertusa 96 hours Acute EC50 2000 ?g/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 25500 ?g/l Marine water Crustaceans - Artemia franciscana - Larvae 48 hours Acute LC50 42000 ?g/l Fresh water Fish - Oncorhynchus mykiss 4 days Chronic NOEC 4.995 mg/l Marine water Algae - Ulva pertusa 96 hours Chronic NOEC 100 ul/L Fresh water Daphnia - Daphnia magna - Neonate 21 days Chronic NOEC 0.375 ul/L Fresh water Fish - Gambusia holbrooki - Larvae 12 weeks Cellulose Nitrate Acute EC50 579000 ?g/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours Titanium Dioxide Acute LC50 >1000000 ?g/l Marine water Fish - Fundulus heteroclitus 96 hours Dibutyl Phthalate Acute EC50 3.4 ?g/l Marine water Algae - Karenia brevis 96 hours Acute EC50 2990 ?g/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 480 ?g/l Fresh water Fish - Lepomis macrochirus - Juvenile (Fledgling, Hatchling, Weanling) 96 hours Chronic NOEC 210 ?g/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours Chronic NOEC 500 ?g/l Fresh water Daphnia - Daphnia magna 21 days Chronic NOEC 25 ?g/l Fresh water Fish - Danio rerio - Embryo 5 weeks Product/ingredient name SpeciesResult Exposure Persistence and degradability Date of issue/Date of revision : 3/6/2017 Date of previous issue : 1/10/2017 Version : 6 14/17 Section 12. Ecological information LogPow BCF Potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Toluene - 90 low Ethyl Acetate - 30 low Dibutyl Phthalate - 165.96 low Soil/water partition coefficient (KOC) : Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. :Disposal methods Section 14. Transport information AEROSOLS 2.1 - AEROSOLS 2.1 - UN1950 UN1950 - Emergency schedules (EmS) F-D, S-U DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards No. No. TDG Classification UN1950 AEROSOLS 2.1 - No. Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2. 13-2.17 (Class 2). Mexico Classification UN1950 AEROSOLS 2.1 - No. - IATA UN1950 AEROSOLS, flammable 2.1 - No. - 126 ERG No. 126 126 ERG No. ERG No. Date of issue/Date of revision : 3/6/2017 Date of previous issue : 1/10/2017 Version : 6 15/17 Section 14. Transport information Special precautions for user Transport in bulk according to Annex II of MARPOL and the IBC Code Not available. : Proper shipping name : Ship type : Not available. Pollution category : Not available. Not available. : Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. Section 15. Regulatory information SARA 313 SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 Section 16. Other information History Hazardous Material Information System (U.S.A.) 2 4 0 *Health Flammability Physical hazards Caution: HMIS? ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS? ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS? ratings are to be used with a fully implemented HMIS? program. HMIS? is a registered mark of the National Paint & Coatings Association (NPCA). HMIS? materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. FLAMMABLE AEROSOLS - Category 1 On basis of test data GASES UNDER PRESSURE - Compressed gas Calculation method SKIN CORROSION/IRRITATION - Category 2 Calculation method SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method CARCINOGENICITY - Category 2 Calculation method TOXIC TO REPRODUCTION (Unborn child) - Category 1B Calculation method TOXIC TO REPRODUCTION (Fertility) - Category 2 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method ASPIRATION HAZARD - Category 1 Calculation method Procedure used to derive the classification Classification Justification Date of issue/Date of revision : 3/6/2017 Date of previous issue : 1/10/2017 Version : 6 16/17 Section 16. Other information 3/6/2017Date of printing Date of issue/Date of revision Version It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Notice to reader Date of previous issue : : : : Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 3/6/2017 1/10/2017 6 Date of issue/Date of revision : 3/6/2017 Date of previous issue : 1/10/2017 Version : 6 17/17 BTY1612_SDS_English_US Page 1 Page 2 Page 3 Page 4 Page 5 Page 6 Page 7 Page 8 Page 9 Page 10 Page 11 Page 12 Page 13 Page 14 Page 15 Page 16 Page 17