DUPLI-COLOR? High Performance Wheel Coating Graphite Aerosol. SAFETY DATA SHEET GHS product identifier Product type Section 1. Identification : : DUPLI-COLOR? High Performance Wheel Coating - Graphite Relevant identified uses of the substance or mixture and uses advised against Paint or paint related material. Identified uses Product code : HWP102 Supplier's details : SHERWIN WILLIAMS ARGENTINA I. Y C. S. A. H. Yrigoyen 1579 (B1702FWW) Ciudadela, Buenos Aires, Argentina + 54 11 4469 9700 www.sherwin.com.ar Centro Nacional de Intoxicaciones: 0 800 333 0160 Hospital A. Posadas: (011) 4654 6648 / (011) 4658 7777 Hospital de Pediatr?a Ricardo Guti?rrez: (011) 4962 6666 / (011) 4962 2247 Emergencias con Materiales Peligrosos: 0 800 222 2933 / (011) 4611 2007 :Emergency telephone number: Section 2. Hazards identification AEROSOLS - Category 1 SKIN CORROSION/IRRITATION - Category 3 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 ASPIRATION HAZARD - Category 1 Classification of the substance or mixture : Signal word : Danger Hazard statements : Extremely flammable aerosol. Pressurized container: may burst if heated. Causes serious eye irritation. Causes mild skin irritation. May be fatal if swallowed and enters airways. May cause drowsiness or dizziness. Hazard pictograms : Precautionary statements Prevention : Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Use only outdoors or in a well-ventilated area. Avoid breathing vapor. Wash hands thoroughly after handling. Do not pierce or burn, even after use. GHS label elements General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Date of issue/Date of revision : 03, Aug, 2018 Date of previous issue : No previous validation Version : 1 1/13 SHW-A4-SA-GHS - AR DUPLI-COLOR? High Performance Wheel Coating - Graphite Section 2. Hazards identification Other hazards which do not result in classification : Please refer to the SDS for additional information. Risk of spontaneous combustion. Spraydust, cloth and other contaminated organic material should be wetted and placed in a sealed metal container. Store in a fire-proof place. Response : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Section 3. Composition/information on ingredients Substance/mixture CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture acetone ?25 - ?50 67-64-1 propane ?10 - ?25 74-98-6 butane ?10 - ?25 106-97-8 Solvent naphtha (petroleum), light aliph. ?10 64742-89-8 ethylbenzene <10 100-41-4 xylene ?3 1330-20-7 aluminium powder (stabilised) ?3 7429-90-5 2-butanone oxime <1 96-29-7 cobalt bis(2-ethylhexanoate) <0.25 136-52-7 Zirconium 2-Ethylhexanoate ?0.3 22464-99-9 Ingredient name CAS number% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Section 4. First aid measures Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention if adverse health effects persist or are severe. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Eye contact Skin contact Inhalation : : : Description of necessary first aid measures Date of issue/Date of revision : 03, Aug, 2018 Date of previous issue : No previous validation Version : 1 2/13 SHW-A4-SA-GHS - AR DUPLI-COLOR? High Performance Wheel Coating - Graphite Section 4. First aid measures See toxicological information (Section 11) Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Ingestion : Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Most important symptoms/effects, acute and delayed Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. :Ingestion Skin contact : Causes mild skin irritation. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness Adverse symptoms may include the following: nausea or vomiting Adverse symptoms may include the following: irritation redness : : : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Potential acute health effects Indication of immediate medical attention and special treatment needed, if necessary Date of issue/Date of revision : 03, Aug, 2018 Date of previous issue : No previous validation Version : 1 3/13 SHW-A4-SA-GHS - AR DUPLI-COLOR? High Performance Wheel Coating - Graphite Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides Extremely flammable aerosol. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non- combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". Date of issue/Date of revision : 03, Aug, 2018 Date of previous issue : No previous validation Version : 1 4/13 SHW-A4-SA-GHS - AR DUPLI-COLOR? High Performance Wheel Coating - Graphite Section 6. Accidental release measures material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50?C. Do not pierce or burn, even after use. Do not swallow. Avoid contact with eyes, skin and clothing. Avoid breathing gas. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. : Precautions for safe handling Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits acetone Ministry of Labor, Employment and Social Security. Argentina (Resolution 295,11/2003) (Argentina, 11/2003). TWA: 500 ppm 8 hours. STEL: 750 ppm 15 minutes. propane Ministry of Labor, Employment and Social Security. Argentina (Resolution 295,11/2003) (Argentina, 11/2003). TWA: 2500 ppm 8 hours. butane Ministry of Labor, Employment and Social Security. Argentina (Resolution 295,11/2003) (Argentina, 11/2003). TWA: 800 ppm 8 hours. ethylbenzene Ministry of Labor, Employment and Social Security. Argentina (Resolution 295,11/2003) (Argentina, 11/2003). TWA: 100 ppm 8 hours. STEL: 125 ppm 15 minutes. xylene Ministry of Labor, Employment and Social Security. Argentina (Resolution 295,11/2003) (Argentina, 11/2003). TWA: 100 ppm 8 hours. STEL: 150 ppm 15 minutes. aluminium powder (stabilised) Ministry of Labor, Employment and Social Security. Argentina (Resolution 295,11/2003) (Argentina, 11/2003). TWA: 10 mg/m? 8 hours. Form: dust Ingredient name Exposure limits Date of issue/Date of revision : 03, Aug, 2018 Date of previous issue : No previous validation Version : 1 5/13 SHW-A4-SA-GHS - AR DUPLI-COLOR? High Performance Wheel Coating - Graphite Section 8. Exposure controls/personal protection Individual protection measures Skin protection Nota(s): Contaminated clothing should be washed separately. Nota(s): Closed shoes are recommended for protection. The information contained in this safety data sheet does not constitute the user?s own assessment of workplace risks, as required by other health and safety legislation. The provisions of the national health and safety at work regulations apply to the use of this product at work. Recommended gloves: Nitrile gloves Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection : Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. TWA: 5 mg/m? 8 hours. Form: fume cobalt bis(2-ethylhexanoate) Ministry of Labor, Employment and Social Security. Argentina (Resolution 295,11/2003) (Argentina, 11/2003). TWA: 0.02 mg/m?, (as Co) 8 hours. Zirconium 2-Ethylhexanoate Ministry of Labor, Employment and Social Security. Argentina (Resolution 295,11/2003) (Argentina, 11/2003). TWA: 5 mg/m?, (as Zr) 8 hours. STEL: 10 mg/m?, (as Zr) 15 minutes. Date of issue/Date of revision : 03, Aug, 2018 Date of previous issue : No previous validation Version : 1 6/13 SHW-A4-SA-GHS - AR DUPLI-COLOR? High Performance Wheel Coating - Graphite Section 8. Exposure controls/personal protection If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator. Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Respiratory protection : Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Density Solubility Liquid. Not available. 0.73 g/cm? 101.3 kPa (760 mm Hg) [at 20?C] Not available. Characteristic.Odor pH VariousColor Evaporation rate 5.6 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: -29?C (-20.2?F) [Pensky-Martens Closed Cup] Not available. 7 Viscosity Kinematic (40?C (104?F)): <0.205 cm2/s (<20.5 cSt) Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Lower: 0.9% Upper: 12.8% Decomposition temperature : Not available. Type of aerosol : Spray Heat of combustion : 28.935 kJ/g Aerosol product Vapor density : 1.55 [Air = 1] Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Date of issue/Date of revision : 03, Aug, 2018 Date of previous issue : No previous validation Version : 1 7/13 SHW-A4-SA-GHS - AR DUPLI-COLOR? High Performance Wheel Coating - Graphite Section 11. Toxicological information ** Data of Component ** Acute toxicity Irritation/Corrosion Information on toxicological effects Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. acetone Eyes - Mild irritant Human - 186300 parts per million - Eyes - Mild irritant Rabbit - 10 microliters - Eyes - Moderate irritant Rabbit - 24 hours 20 milligrams - Eyes - Severe irritant Rabbit - 20 milligrams - Skin - Mild irritant Rabbit - 24 hours 500 milligrams - Skin - Mild irritant Rabbit - 395 milligrams - ethylbenzene Eyes - Severe irritant Rabbit - 500 milligrams - Skin - Mild irritant Rabbit - 24 hours 15 milligrams - xylene Eyes - Mild irritant Rabbit - 87 milligrams - Eyes - Severe irritant Rabbit - 24 hours 5 milligrams - Skin - Mild irritant Rat - 8 hours 60 microliters - Skin - Moderate irritant Rabbit - 24 hours 500 milligrams - Skin - Moderate irritant Rabbit - 100 Percent - 2-butanone oxime Eyes - Severe irritant Rabbit - 100 microliters - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species acetone LD50 Oral Rat 5800 mg/kg - butane LC50 Inhalation Vapor Rat 658000 mg/m? 4 hours ethylbenzene LD50 Dermal Rabbit >5000 mg/kg - LD50 Oral Rat 3500 mg/kg - xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours LD50 Oral Rat 4300 mg/kg - 2-butanone oxime LD50 Oral Rat 930 mg/kg - cobalt bis(2-ethylhexanoate) LD50 Dermal Rabbit >5 g/kg - LD50 Oral Rat 1.22 g/kg - Zirconium 2-Ethylhexanoate LD50 Dermal Rabbit >5 g/kg - LD50 Oral Rat >5 g/kg - Product/ingredient name Result Species Dose Exposure Date of issue/Date of revision : 03, Aug, 2018 Date of previous issue : No previous validation Version : 1 8/13 SHW-A4-SA-GHS - AR DUPLI-COLOR? High Performance Wheel Coating - Graphite Section 11. Toxicological information Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) acetone Category 3 Not applicable. Narcotic effects xylene Category 3 Not applicable. Respiratory tract irritation Name Category Name Category ethylbenzene Category 2 Not determined hearing organs xylene Category 2 Not determined Not determined Aspiration hazard Name Result Solvent naphtha (petroleum), light aliph. ASPIRATION HAZARD - Category 1 ethylbenzene ASPIRATION HAZARD - Category 1 xylene ASPIRATION HAZARD - Category 1 Route of exposure Target organs Route of exposure Target organs ** Data of Mixture ** Information on the likely routes of exposure Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. :Ingestion Skin contact : Causes mild skin irritation. Causes serious eye irritation.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness Adverse symptoms may include the following: nausea or vomiting Adverse symptoms may include the following: irritation redness : : : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Delayed and immediate effects and also chronic effects from short and long term exposure : Not available. Potential acute health effects Short term exposure Date of issue/Date of revision : 03, Aug, 2018 Date of previous issue : No previous validation Version : 1 9/13 SHW-A4-SA-GHS - AR DUPLI-COLOR? High Performance Wheel Coating - Graphite Section 11. Toxicological information Not available. No known significant effects or critical hazards.General : No known significant effects or critical hazards.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Potential chronic health effects Numerical measures of toxicity Dermal 42305.7 mg/kg Inhalation (gases) 192298.8 ppm Inhalation (vapors) 139.6 mg/l Route ATE value Acute toxicity estimates Potential immediate effects : Not available. Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Section 12. Ecological information Toxicity acetone Acute EC50 7200000 ?g/l Fresh water Algae - Selenastrum sp. 96 hours Acute LC50 6000000 ?g/l Fresh water Crustaceans - Gammarus pulex 48 hours Acute LC50 6900 mg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 5600 ppm Fresh water Fish - Poecilia reticulata 96 hours Chronic NOEC 4.95 mg/l Marine water Algae - Ulva pertusa 96 hours Chronic NOEC 0.016 ml/L Fresh water Crustaceans - Daphniidae 21 days Chronic NOEC 0.1 ml/L Fresh water Daphnia - Daphnia magna - Neonate 21 days Chronic NOEC 0.1 mg/l Fresh water Fish - Fundulus heteroclitus 4 weeks Solvent naphtha (petroleum), light aliph. Acute LC50 >100000 ppm Fresh water Fish - Oncorhynchus mykiss 96 hours ethylbenzene Acute EC50 4600 ?g/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours Acute EC50 3600 ?g/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours Acute EC50 6530 ?g/l Fresh water Crustaceans - Artemia sp. - Nauplii 48 hours Acute EC50 2930 ?g/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours Acute LC50 4200 ?g/l Fresh water Fish - Oncorhynchus mykiss 96 hours xylene Acute LC50 8500 ?g/l Marine water Crustaceans - Palaemonetes pugio 48 hours Acute LC50 13400 ?g/l Fresh water Fish - Pimephales promelas 96 hours aluminium powder (stabilised) Acute LC50 38000 ?g/l Fresh water Daphnia - Daphnia magna 48 hours Product/ingredient name SpeciesResult Exposure Date of issue/Date of revision : 03, Aug, 2018 Date of previous issue : No previous validation Version : 1 10/13 SHW-A4-SA-GHS - AR DUPLI-COLOR? High Performance Wheel Coating - Graphite Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Solvent naphtha (petroleum), light aliph. - 10 to 2500 high xylene - 8.1 to 25.9 low 2-butanone oxime - 2.5 to 5.8 low cobalt bis(2-ethylhexanoate) - 15600 high Zirconium 2-Ethylhexanoate - 2.96 low Product/ingredient name Aquatic half-life Photolysis Biodegradability acetone - - Readily ethylbenzene - - Readily xylene - - Readily Acute LC50 120 ?g/l Fresh water Fish - Oncorhynchus mykiss - Embryo 96 hours Chronic NOEC 9 mg/l Fresh water Aquatic plants - Ceratophyllum demersum 3 days 2-butanone oxime Acute LC50 843000 ?g/l Fresh water Fish - Pimephales promelas 96 hours Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non- recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. :Disposal methods Section 14. Transport information UN number AEROSOLS 2.1 - AEROSOLS, flammable UN1950 2.1 - UN1950 Argentina IMDG IATA UN proper shipping name Transport hazard class(es) Packing group UN1950 AEROSOLS 2 - Date of issue/Date of revision : 03, Aug, 2018 Date of previous issue : No previous validation Version : 1 11/13 SHW-A4-SA-GHS - AR DUPLI-COLOR? High Performance Wheel Coating - Graphite Section 14. Transport information Emergency schedules F-D, S-U -Additional information Environmental hazards Special precautions for user No. No. Transport within user?s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Risk Number: 2 3 No. Tunnel code D Section 15. Regulatory information Safety, health and environmental regulations specific for the product : No known specific national and/or regional regulations applicable to this product (including its ingredients). International regulations Montreal Protocol (Annexes A, B, C, E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Rotterdam Convention on Prior Informed Consent (PIC) Not listed. Chemical Weapon Convention List Schedules I, II & III Chemicals Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed. International lists National inventory Australia : Not determined. Canada : Not determined. China : Not determined. Europe : Not determined. Japan : Japan inventory (ENCS): Not determined. Japan inventory (ISHL): Not determined. Republic of Korea : Not determined. Malaysia : Not determined. New Zealand : Not determined. Philippines : Not determined. Taiwan : Not determined. United States : Not determined. Turkey : Not determined. Thailand : Not determined. Viet Nam : Not determined. Date of issue/Date of revision : 03, Aug, 2018 Date of previous issue : No previous validation Version : 1 12/13 SHW-A4-SA-GHS - AR DUPLI-COLOR? High Performance Wheel Coating - Graphite Section 16. Other information 03, Aug, 2018. History Date of printing Date of issue/Date of revision Version Notice to reader Date of previous issue : : : : Indicates information that has changed from previously issued version. References : Not available. Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 03, Aug, 2018 No previous validation 1 Version of the Product : SHW3 It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Procedure used to derive the classification Classification Justification AEROSOLS - Category 1 On basis of test data SKIN CORROSION/IRRITATION - Category 3 Calculation method SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method ASPIRATION HAZARD - Category 1 Calculation method Date of issue/Date of revision : 03, Aug, 2018 Date of previous issue : No previous validation Version : 1 13/13 SHW-A4-SA-GHS - AR