Page: 1 SAFETY DATA SHEET Revision Date: 07/31/2016 Print Date: 11/1/2016 SDS Number: R0394062 Valvoline? MERCON V AUTOMATIC TRANSMISSION FLUID 822345 Version: 1.4 1 / 16 29 CFR 1910.1200 (OSHA HazCom 2012) SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Trade name : Valvoline? MERCON V AUTOMATIC TRANSMISSION FLUID Recommended use of the chemical and restrictions on use Details of the supplier of the safety data sheet Valvoline LLC 3499 Blazer Parkway Lexington, KY 40509 United States of America This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency telephone number 1-800-VALVOLINE Regulatory Information Number 1-800-TEAMVAL Product Information 1-800-TEAMVAL SECTION 2. HAZARDS IDENTIFICATION GHS Classification Eye irritation : Category 2A Skin sensitization : Category 1 GHS Label element Hazard pictograms : Signal Word : Warning Hazard Statements : May cause an allergic skin reaction. Causes serious eye irritation. Precautionary Statements : Prevention: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. Wash skin thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Wear eye protection/ face protection. Wear protective gloves. Page: 2 SAFETY DATA SHEET Revision Date: 07/31/2016 Print Date: 11/1/2016 SDS Number: R0394062 Valvoline? MERCON V AUTOMATIC TRANSMISSION FLUID 822345 Version: 1.4 2 / 16 Response: IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation or rash occurs: Get medical advice/ attention. If eye irritation persists: Get medical advice/ attention. Wash contaminated clothing before reuse. Disposal: Dispose of contents/ container to an approved waste disposal plant. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Chemical nature : Defatter Hazardous components Chemical Name CAS-No. Classification Concentration (%) HYDROTREATED LIGHT PARAFFINIC DISTILLATE 64742-55-8 Not a hazardous substance or mixture. 40.27 POLYALKYLMETHACRYLATE Eye Irrit. 2A; H319 13.25 MINERAL OIL Not a hazardous substance or mixture. 13.25 HYDROTREATED LIGHT PARAFFINIC DISTILLATE 64742-55-8 Asp. Tox. 1; H304 5.23 METHACRYLATE COPOLYMER Eye Irrit. 2A; H319 1.10 ALKOXYLATED LONG-CHAIN ALKYL AMINE Acute Tox. 4; H302 Skin Corr. 1B; H314 Eye Dam. 1; H318 0.11 Page: 3 SAFETY DATA SHEET Revision Date: 07/31/2016 Print Date: 11/1/2016 SDS Number: R0394062 Valvoline? MERCON V AUTOMATIC TRANSMISSION FLUID 822345 Version: 1.4 3 / 16 Skin Sens. 1; H317 Aquatic Acute 3; H402 Aquatic Chronic 3; H412 ALKYL METHACRYLATE Skin Irrit. 2; H315 Eye Irrit. 2A; H319 Skin Sens. 1; H317 STOT SE 3; H335 Aquatic Acute 1; H400 Aquatic Chronic 1; H410 0.11 SECTION 4. FIRST AID MEASURES General advice : Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. If inhaled : If breathed in, move person into fresh air. If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of skin contact : Remove contaminated clothing. If irritation develops, get medical attention. If on skin, rinse well with water. First aid is not normally required. However, it is recommended that exposed areas be cleaned by washing with soap and water. Wash contaminated clothing before re-use. In case of eye contact : Immediately flush eye(s) with plenty of water. Remove contact lenses. Protect unharmed eye. If swallowed : Do not give milk or alcoholic beverages. Page: 4 SAFETY DATA SHEET Revision Date: 07/31/2016 Print Date: 11/1/2016 SDS Number: R0394062 Valvoline? MERCON V AUTOMATIC TRANSMISSION FLUID 822345 Version: 1.4 4 / 16 Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Most important symptoms and effects, both acute and delayed : Acute aspiration of large amounts of oil-laden material may produce a serious aspiration pneumonia. Patients who aspirate these oils should be followed for the development of long-term sequelae. Repeated aspiration of small quantities of mineral oil can produce chronic inflammation of the lungs (i.e. lipoid pneumonia) that may progress to pulmonary fibrosis. Symptoms are often subtle and radiological changes appear worse than clinical abnormalities. Occasionally, persistent cough, irritation of the upper respiratory tract, shortness of breath with exertion, fever, and bloody sputum occur. Inhalation exposure to oil mists below current workplace exposure limits is unlikely to cause pulmonary abnormalities. Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include: stomach or intestinal upset (nausea, vomiting, diarrhea) irritation (nose, throat, airways) May cause an allergic skin reaction. Causes serious eye irritation. Notes to physician : No hazards which require special first aid measures. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Water spray Foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing media : High volume water jet Specific hazards during firefighting : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion products : carbon dioxide and carbon monoxide Hydrocarbons nitrogen oxides (NOx) Specific extinguishing methods : Product is compatible with standard fire-fighting agents. Page: 5 SAFETY DATA SHEET Revision Date: 07/31/2016 Print Date: 11/1/2016 SDS Number: R0394062 Valvoline? MERCON V AUTOMATIC TRANSMISSION FLUID 822345 Version: 1.4 5 / 16 Further information : Standard procedure for chemical fires. Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. Methods and materials for containment and cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. Other information : Comply with all applicable federal, state, and local regulations. SECTION 7. HANDLING AND STORAGE Advice on safe handling : Do not breathe vapours/dust. Do not smoke. Persons susceptible to skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used. Container hazardous when empty. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. Smoking, eating and drinking should be prohibited in the application area. For personal protection see section 8. Dispose of rinse water in accordance with local and national regulations. Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place. Electrical installations / working materials must comply with the technological safety standards. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Page: 6 SAFETY DATA SHEET Revision Date: 07/31/2016 Print Date: 11/1/2016 SDS Number: R0394062 Valvoline? MERCON V AUTOMATIC TRANSMISSION FLUID 822345 Version: 1.4 6 / 16 Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis HYDROTREATED LIGHT PARAFFINIC DISTILLATE 64742-55-8 REL 5 mg/m3 Mist. NIOSH/GUID E STEL 10 mg/m3 Mist. NIOSH/GUID E PEL 5 mg/m3 Mist. OSHA_TRA NS MINERAL OIL REL 5 mg/m3 Mist. NIOSH/GUID E STEL 10 mg/m3 Mist. NIOSH/GUID E PEL 5 mg/m3 Mist. OSHA_TRA NS TWA 5 mg/m3 Mist. TN OEL TWA 5 mg/m3 Inhalable fraction. ACGIH HYDROTREATED LIGHT PARAFFINIC DISTILLATE 64742-55-8 REL 5 mg/m3 Mist. NIOSH/GUID E STEL 10 mg/m3 Mist. NIOSH/GUID E PEL 5 mg/m3 Mist. OSHA_TRA NS Engineering measures : Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Personal protective equipment Hand protection Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye protection : Wear chemical splash goggles when there is the potential for exposure of the eyes to liquid, vapor or mist. Skin and body protection : Wear as appropriate: impervious clothing Safety shoes Choose body protection according to the amount and concentration of the dangerous substance at the work place. Discard gloves that show tears, pinholes, or signs of wear. Wear resistant gloves (consult your safety equipment supplier). Hygiene measures : Wash hands before breaks and at the end of workday. When using do not eat or drink. Page: 7 SAFETY DATA SHEET Revision Date: 07/31/2016 Print Date: 11/1/2016 SDS Number: R0394062 Valvoline? MERCON V AUTOMATIC TRANSMISSION FLUID 822345 Version: 1.4 7 / 16 When using do not smoke. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state : liquid Colour : red Odour : No data available Odour Threshold : No data available pH : No data available Melting point/freezing point : No data available Boiling point/boiling range : No data available Flash point : 410 ?F / 210 ?C Evaporation rate : No data available Flammability (solid, gas) : No data available Upper explosion limit : 6 %(V) Calculated Explosive Limit Lower explosion limit : 1 %(V) Calculated Explosive Limit Vapour pressure : 0.0133333 hPa (21.11 ?C) Calculated Vapor Pressure Relative vapour density : No data available Relative density : No data available Density : 0.858 g/cm3 (15.56 ?C) Solubility(ies) Water solubility : negligible Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Thermal decomposition : No data available Viscosity Viscosity, dynamic : No data available Page: 8 SAFETY DATA SHEET Revision Date: 07/31/2016 Print Date: 11/1/2016 SDS Number: R0394062 Valvoline? MERCON V AUTOMATIC TRANSMISSION FLUID 822345 Version: 1.4 8 / 16 Viscosity, kinematic : 7.4 mm2/s (100 ?C) Oxidizing properties : No data available SECTION 10. STABILITY AND REACTIVITY Reactivity : No decomposition if stored and applied as directed. Chemical stability : Stable under recommended storage conditions. Possibility of hazardous reactions : Product will not undergo hazardous polymerization. Conditions to avoid : excessive heat Incompatible materials : Strong oxidizing agents Hazardous decomposition products carbon dioxide and carbon monoxide Hydrocarbons SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation Skin contact Eye Contact Ingestion Acute toxicity Not classified based on available information. Components: ALKOXYLATED LONG-CHAIN ALKYL AMINE: Acute oral toxicity : Assessment: The component/mixture is classified as acute oral toxicity, category 4. Skin corrosion/irritation Not classified based on available information. Product: Remarks: May cause skin irritation in susceptible persons. Result: Repeated exposure may cause skin dryness or cracking. Components: HYDROTREATED LIGHT PARAFFINIC DISTILLATE: Page: 9 SAFETY DATA SHEET Revision Date: 07/31/2016 Print Date: 11/1/2016 SDS Number: R0394062 Valvoline? MERCON V AUTOMATIC TRANSMISSION FLUID 822345 Version: 1.4 9 / 16 Result: Mildly irritating to skin POLYALKYLMETHACRYLATE: Result: Not irritating to skin MINERAL OIL: Result: Mildly irritating to skin HYDROTREATED LIGHT PARAFFINIC DISTILLATE: Result: Mildly irritating to skin METHACRYLATE COPOLYMER: Result: Not irritating to skin ALKOXYLATED LONG-CHAIN ALKYL AMINE: Result: Corrosive to skin ALKYL METHACRYLATE: Result: Irritating to skin Serious eye damage/eye irritation Causes serious eye irritation. Product: Remarks: Vapours may cause irritation to the eyes, respiratory system and the skin., Causes serious eye irritation. Components: HYDROTREATED LIGHT PARAFFINIC DISTILLATE: Result: Mildly irritating to eyes POLYALKYLMETHACRYLATE: Result: Irritating to eyes MINERAL OIL: Result: Mildly irritating to eyes HYDROTREATED LIGHT PARAFFINIC DISTILLATE: Result: Mildly irritating to eyes METHACRYLATE COPOLYMER: Result: Irritating to eyes ALKOXYLATED LONG-CHAIN ALKYL AMINE: Result: Corrosive to eyes ALKYL METHACRYLATE: Result: Irritating to eyes Respiratory or skin sensitisation Skin sensitisation: May cause an allergic skin reaction. Respiratory sensitisation: Not classified based on available information. Components: Page: 10 SAFETY DATA SHEET Revision Date: 07/31/2016 Print Date: 11/1/2016 SDS Number: R0394062 Valvoline? MERCON V AUTOMATIC TRANSMISSION FLUID 822345 Version: 1.4 10 / 16 ALKOXYLATED LONG-CHAIN ALKYL AMINE: Assessment: May cause sensitization by skin contact. ALKYL METHACRYLATE: Assessment: May cause sensitization by skin contact. Germ cell mutagenicity Not classified based on available information. Carcinogenicity Not classified based on available information. Reproductive toxicity Not classified based on available information. STOT - single exposure Not classified based on available information. Components: ALKYL METHACRYLATE: Assessment: May cause respiratory irritation. STOT - repeated exposure Not classified based on available information. Aspiration toxicity Not classified based on available information. Components: HYDROTREATED LIGHT PARAFFINIC DISTILLATE: May be fatal if swallowed and enters airways. Further information Product: Remarks: No data available Carcinogenicity: IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity ALKOXYLATED LONG-CHAIN ALKYL AMINE: Ecotoxicology Assessment Acute aquatic toxicity : Harmful to aquatic life. Page: 11 SAFETY DATA SHEET Revision Date: 07/31/2016 Print Date: 11/1/2016 SDS Number: R0394062 Valvoline? MERCON V AUTOMATIC TRANSMISSION FLUID 822345 Version: 1.4 11 / 16 Chronic aquatic toxicity : Harmful to aquatic life with long lasting effects. ALKYL METHACRYLATE: Ecotoxicology Assessment Acute aquatic toxicity : Very toxic to aquatic life. Chronic aquatic toxicity : Very toxic to aquatic life with long lasting effects. Persistence and degradability No data available Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available Product: Additional ecological information : No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods General advice : Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company. Dispose of in accordance with all applicable local, state and federal regulations. Contaminated packaging : Empty remaining contents. Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. SECTION 14. TRANSPORT INFORMATION International transport regulations REGULATION ID NUMBER PROPER SHIPPING NAME *HAZARD CLASS SUBSIDIARY HAZARDS PACKING GROUP MARINE POLLUTANT / LTD. QTY. Page: 12 SAFETY DATA SHEET Revision Date: 07/31/2016 Print Date: 11/1/2016 SDS Number: R0394062 Valvoline? MERCON V AUTOMATIC TRANSMISSION FLUID 822345 Version: 1.4 12 / 16 U.S. DOT - ROAD Not dangerous goods CFR_RAIL_C Not dangerous goods U.S. DOT - INLAND WATERWAYS Not dangerous goods TDG_ROAD_C Not dangerous goods TDG_RAIL_C Not dangerous goods TDG_INWT_C Not dangerous goods INTERNATIONAL MARITIME DANGEROUS GOODS Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER Not dangerous goods MX_DG Not dangerous goods *ORM = ORM-D, CBL = COMBUSTIBLE LIQUID Marine pollutant no Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. Page: 13 SAFETY DATA SHEET Revision Date: 07/31/2016 Print Date: 11/1/2016 SDS Number: R0394062 Valvoline? MERCON V AUTOMATIC TRANSMISSION FLUID 822345 Version: 1.4 13 / 16 SECTION 15. REGULATORY INFORMATION SARA 311/312 Hazards : Acute Health Hazard SARA 313 Component(s)SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Pennsylvania Right To Know HEAVY PARAFFINIC DISTILLATE 64742-54-7 30.00 - 50.00 % HYDROTREATED LIGHT PARAFFINIC DISTILLATE 64742-55-8 30.00 - 50.00 % POLYALKYLMETHACRYLATE Not Assigned 10.00 - 20.00 % MINERAL OIL Not Assigned 10.00 - 20.00 % HYDROTREATED LIGHT PARAFFINIC DISTILLATE 64742-55-8 5.00 - 10.00 % New Jersey Right To Know HEAVY PARAFFINIC DISTILLATE 64742-54-7 30.00 - 50.00 % HYDROTREATED LIGHT PARAFFINIC DISTILLATE 64742-55-8 30.00 - 50.00 % POLYALKYLMETHACRYLATE Not Assigned 10.00 - 20.00 % MINERAL OIL Not Assigned 10.00 - 20.00 % HYDROTREATED LIGHT PARAFFINIC DISTILLATE 64742-55-8 5.00 - 10.00 % California Prop 65 Proposition 65 warnings are not required for this product based on the results of a risk assessment. The components of this product are reported in the following inventories: TSCA : On TSCA Inventory DSL : All components of this product are on the Canadian DSL. AICS : Not in compliance with the inventory ENCS : On the inventory, or in compliance with the inventory KECI : On the inventory, or in compliance with the inventory PICCS : On the inventory, or in compliance with the inventory Page: 14 SAFETY DATA SHEET Revision Date: 07/31/2016 Print Date: 11/1/2016 SDS Number: R0394062 Valvoline? MERCON V AUTOMATIC TRANSMISSION FLUID 822345 Version: 1.4 14 / 16 IECSC : Not in compliance with the inventory Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA) SECTION 16. OTHER INFORMATION Further information Revision Date: 07/31/2016 NFPA: HMIS III: NFPA Flammable and Combustible Liquids Classification Combustible Liquid Class IIIB Full text of H-Statements referred to under sections 2 and 3. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H400 Very toxic to aquatic life. H402 Harmful to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. Further information Flammability H e a lt h In s ta b ility 2 1 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 2 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page: 15 SAFETY DATA SHEET Revision Date: 07/31/2016 Print Date: 11/1/2016 SDS Number: R0394062 Valvoline? MERCON V AUTOMATIC TRANSMISSION FLUID 822345 Version: 1.4 15 / 16 Sources of key data used to compile the Safety Data Sheet Valvoline internal data including own and sponsored test reports The UNECE administers regional agreements implementing harmonised classification for labelling (GHS) and transport. The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This SDS has been prepared by Valvoline's Environmental Health and Safety Department (1-800-825-8654). List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-statement : Hazard Statement IATA : International Air Transport Association. IATA-DGR : Dangerous Goods Regulation by the ?International Air Transport Association? (IATA). ICAO : International Civil Aviation Organization ICAO-TI (ICAO) : Technical Instructions by the ?International Civil Aviation Organization? IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization logPow : octanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population LDxx : Lethal Dose, for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit P-Statement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic PPE : Personal Protective Equipment STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity TLV : Threshold Limit Value TWA : Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act DOT : Department of Transportation FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association Page: 16 SAFETY DATA SHEET Revision Date: 07/31/2016 Print Date: 11/1/2016 SDS Number: R0394062 Valvoline? MERCON V AUTOMATIC TRANSMISSION FLUID 822345 Version: 1.4 16 / 16 NIOSH : National Institute for Occupational Safety and Health OSHA : Occupational Safety and Health Administration PMRA : Health Canada Pest Management Regulatory Agency RTK : Right to Know WHMIS : Workplace Hazardous Materials Information System