Page: 1 SAFETY DATA SHEET Revision Date: 03/15/2018 Print Date: 10/29/2018 SDS Number: R0272517 Valvoline? DRIVE TRAIN SAE 50 Transmission Fluid VV329 Version: 1.3 1 / 13 29 CFR 1910.1200 (OSHA HazCom 2012) SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Trade name : Valvoline? DRIVE TRAIN SAE 50 Transmission Fluid Details of the supplier of the safety data sheet Valvoline LLC 100 Valvoline Way Lexington, KY 40509 United States of America (USA) 1-800-TEAMVAL (1-800-832-6825) Emergency telephone number 1-800-VALVOLINE (1-800-825-8654) Regulatory Information Number 1-800-TEAMVAL (1-800-832-6825) Product Information 1-800-TEAMVAL (1-800-832-6825) SECTION 2. HAZARDS IDENTIFICATION GHS Classification This material is not considered hazardous under the OSHA Hazard Communication Standard (HazCom 2012). GHS label elements This material is not considered hazardous under the OSHA Hazard Communication Standard (HazCom 2012). Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components Chemical name CAS-No. Classification Concentration (%) MINERAL OIL This material is not considered hazardous under the OSHA Hazard Communication Standard (HazCom 2012). 3.9142 ZINC DIALKYL 68649-42-3 Skin Irrit. 2; H315 1.2982 Page: 2 SAFETY DATA SHEET Revision Date: 03/15/2018 Print Date: 10/29/2018 SDS Number: R0272517 Valvoline? DRIVE TRAIN SAE 50 Transmission Fluid VV329 Version: 1.3 2 / 13 DITHIOPHOSPHATE Eye Irrit. 2A; H319 SECTION 4. FIRST AID MEASURES General advice : No hazards which require special first aid measures. If inhaled : If breathed in, move person into fresh air. If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of skin contact : Remove contaminated clothing. If irritation develops, get medical attention. If on skin, rinse well with water. Wash contaminated clothing before re-use. In case of eye contact : Flush eyes with water as a precaution. Remove contact lenses. Protect unharmed eye. If eye irritation persists, consult a specialist. If swallowed : Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Most important symptoms and effects, both acute and delayed : No symptoms known or expected. Notes to physician : No hazards which require special first aid measures. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Water spray Foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing media : High volume water jet Specific hazards during firefighting : Do not allow run-off from fire fighting to enter drains or water courses. Page: 3 SAFETY DATA SHEET Revision Date: 03/15/2018 Print Date: 10/29/2018 SDS Number: R0272517 Valvoline? DRIVE TRAIN SAE 50 Transmission Fluid VV329 Version: 1.3 3 / 13 Hazardous combustion products : carbon dioxide and carbon monoxide Hydrocarbons hydrogen sulfide zinc oxide oxides of sulfur, nitrogen and phosphorus Amines Specific extinguishing methods : Product is compatible with standard fire-fighting agents. Further information : Standard procedure for chemical fires. Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions : Prevent further leakage or spillage if safe to do so. Methods and materials for containment and cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. Other information : Comply with all applicable federal, state, and local regulations. SECTION 7. HANDLING AND STORAGE Advice on safe handling : Avoid contact with skin and eyes. Smoking, eating and drinking should be prohibited in the application area. For personal protection see section 8. Dispose of rinse water in accordance with local and national regulations. Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Page: 4 SAFETY DATA SHEET Revision Date: 03/15/2018 Print Date: 10/29/2018 SDS Number: R0272517 Valvoline? DRIVE TRAIN SAE 50 Transmission Fluid VV329 Version: 1.3 4 / 13 Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis MINERAL OIL REL 5 mg/m3 Mist. NIOSH/GUID E STEL 10 mg/m3 Mist. NIOSH/GUID E NIOSH/GUID E PEL 5 mg/m3 Mist. OSHA_TRA NS OSHA_TRA NS TWA 5 mg/m3 Mist. ACGIH STEL 10 mg/m3 Mist. ACGIH ACGIH TWA 0.2 mg/m3 Inhalable fraction. ACGIHLIS_P ACGIHLIS_P ACGIHLIS_P ACGIHLIS_P Hazardous components without workplace control parameters Components CAS-No. ZINC DIALKYL DITHIOPHOSPHATE 68649-42-3 Engineering measures : Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Personal protective equipment Hand protection Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye protection : Not required under normal conditions of use. Wear splash- proof safety goggles if material could be misted or splashed into eyes. Skin and body protection : Wear as appropriate: Impervious clothing Safety shoes Choose body protection according to the amount and Page: 5 SAFETY DATA SHEET Revision Date: 03/15/2018 Print Date: 10/29/2018 SDS Number: R0272517 Valvoline? DRIVE TRAIN SAE 50 Transmission Fluid VV329 Version: 1.3 5 / 13 concentration of the dangerous substance at the work place. Wear resistant gloves (consult your safety equipment supplier). Hygiene measures : Wash hands before breaks and at the end of workday. When using do not eat or drink. When using do not smoke. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state : liquid Colour : amber Odour : No data available Odour Threshold : No data available pH : No data available Melting point/freezing point : No data available Boiling point/boiling range : No data available Flash point : > 390 ?F / > 199 ?C Method: Cleveland open cup Evaporation rate : No data available Flammability (solid, gas) : No data available Upper explosion limit : 6 %(V) GLP: Calculated Explosive Limit Lower explosion limit : 1 %(V) GLP: Calculated Explosive Limit Vapour pressure : 1.3333333 hPa (20 ?C) Calculated Vapor Pressure Relative vapour density : No data available Relative density : No data available Density : 0.889 g/cm3 (25 ?C) Solubility(ies) Water solubility : negligible Page: 6 SAFETY DATA SHEET Revision Date: 03/15/2018 Print Date: 10/29/2018 SDS Number: R0272517 Valvoline? DRIVE TRAIN SAE 50 Transmission Fluid VV329 Version: 1.3 6 / 13 Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Thermal decomposition : No data available Viscosity Viscosity, dynamic : No data available Viscosity, kinematic : No data available Oxidizing properties : No data available SECTION 10. STABILITY AND REACTIVITY Reactivity : No decomposition if stored and applied as directed. Chemical stability : Stable under recommended storage conditions. Possibility of hazardous reactions : Product will not undergo hazardous polymerization. Conditions to avoid : excessive heat Incompatible materials : Strong oxidizing agents Hazardous decomposition products carbon dioxide and carbon monoxide Hydrocarbons SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation Skin contact Eye Contact Ingestion Acute toxicity Not classified based on available information. Components: MINERAL OIL: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute dermal toxicity : LD50 (Rabbit): > 5,000 mg/kg Page: 7 SAFETY DATA SHEET Revision Date: 03/15/2018 Print Date: 10/29/2018 SDS Number: R0272517 Valvoline? DRIVE TRAIN SAE 50 Transmission Fluid VV329 Version: 1.3 7 / 13 ZINC DIALKYL DITHIOPHOSPHATE: Acute oral toxicity : LD50 (Rat): > 2,000 - 5,000 mg/kg Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Assessment: Not classified as acutely toxic by dermal absorption under GHS. Skin corrosion/irritation Not classified based on available information. Components: MINERAL OIL: Result: No skin irritation ZINC DIALKYL DITHIOPHOSPHATE: Result: Severe skin irritation Result: Irritating to skin. Serious eye damage/eye irritation Not classified based on available information. Product: Remarks: Vapours may cause irritation to the eyes, respiratory system and the skin. Components: MINERAL OIL: Result: No eye irritation ZINC DIALKYL DITHIOPHOSPHATE: Result: Slight, transient irritation Result: Irritating to eyes. Respiratory or skin sensitisation Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information. Germ cell mutagenicity Not classified based on available information. Carcinogenicity Not classified based on available information. Reproductive toxicity Not classified based on available information. STOT - single exposure Not classified based on available information. STOT - repeated exposure Not classified based on available information. Aspiration toxicity Not classified based on available information. Further information Product: Remarks: No data available Page: 8 SAFETY DATA SHEET Revision Date: 03/15/2018 Print Date: 10/29/2018 SDS Number: R0272517 Valvoline? DRIVE TRAIN SAE 50 Transmission Fluid VV329 Version: 1.3 8 / 13 Carcinogenicity: IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA?s list of regulated carcinogens. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Ecotoxicology Assessment Acute aquatic toxicity : Not classified based on available information. Chronic aquatic toxicity : Not classified based on available information. Persistence and degradability No data available Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available Product: Additional ecological information : No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods General advice : Dispose of in accordance with all applicable local, state and federal regulations. Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company. Contaminated packaging : Empty remaining contents. Dispose of as unused product. Empty containers should be taken to an approved waste Page: 9 SAFETY DATA SHEET Revision Date: 03/15/2018 Print Date: 10/29/2018 SDS Number: R0272517 Valvoline? DRIVE TRAIN SAE 50 Transmission Fluid VV329 Version: 1.3 9 / 13 handling site for recycling or disposal. Do not re-use empty containers. SECTION 14. TRANSPORT INFORMATION International transport regulations REGULATION ID NUMBER PROPER SHIPPING NAME *HAZARD CLASS SUBSIDIARY HAZARDS PACKING GROUP MARINE POLLUTANT / LTD. QTY. U.S. DOT - ROAD Not dangerous goods CFR_RAIL_C Not dangerous goods U.S. DOT - INLAND WATERWAYS Not dangerous goods TDG_ROAD_C Not dangerous goods TDG_RAIL_C Not dangerous goods TDG_INWT_C Not dangerous goods INTERNATIONAL MARITIME DANGEROUS GOODS Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER Not dangerous goods MX_DG Page: 10 SAFETY DATA SHEET Revision Date: 03/15/2018 Print Date: 10/29/2018 SDS Number: R0272517 Valvoline? DRIVE TRAIN SAE 50 Transmission Fluid VV329 Version: 1.3 10 / 13 Not dangerous goods *ORM = ORM-D, CBL = COMBUSTIBLE LIQUID Marine pollutant no Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) ETHYL ACRYLATE 140-88-5 1000 * *: Calculated RQ exceeds reasonably attainable upper limit. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : No SARA Hazards SARA 313 ZINC DIALKYL DITHIOPHOSPHATE 68649-42-3 1.29 % Pennsylvania Right To Know Residual oils (petroleum), solvent-dewaxed 64742-62-7 DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC 64742-54-7 MINERAL OIL Not Assigned PROPRIETARY OF HiTEC 8888C Performance Additive Not Assigned New Jersey Right To Know Residual oils (petroleum), solvent-dewaxed 64742-62-7 DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC 64742-54-7 MINERAL OIL Not Assigned PROPRIETARY OF HiTEC 8888C Not Assigned Page: 11 SAFETY DATA SHEET Revision Date: 03/15/2018 Print Date: 10/29/2018 SDS Number: R0272517 Valvoline? DRIVE TRAIN SAE 50 Transmission Fluid VV329 Version: 1.3 11 / 13 Performance Additive CALCIUM LONG-CHAIN ALKYLPHENATE SULFIDE Not Assigned ZINC DIALKYL DITHIOPHOSPHATE 68649-42-3 California Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. The components of this product are reported in the following inventories: DSL : All components of this product are on the Canadian DSL AICS : On the inventory, or in compliance with the inventory ENCS : On the inventory, or in compliance with the inventory KECI : On the inventory, or in compliance with the inventory PICCS : On the inventory, or in compliance with the inventory IECSC : On the inventory, or in compliance with the inventory TSCA : On TSCA Inventory Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA) SECTION 16. OTHER INFORMATION Further information Revision Date: 03/15/2018 NFPA: HMIS III: Page: 12 SAFETY DATA SHEET Revision Date: 03/15/2018 Print Date: 10/29/2018 SDS Number: R0272517 Valvoline? DRIVE TRAIN SAE 50 Transmission Fluid VV329 Version: 1.3 12 / 13 NFPA Flammable and Combustible Liquids Classification Combustible Liquid Class IIIB Full text of H-Statements H315 Causes skin irritation. H319 Causes serious eye irritation. Sources of key data used to compile the Safety Data Sheet Valvoline internal data including own and sponsored test reports The UNECE administers regional agreements implementing harmonised classification for labelling (GHS) and transport. The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This SDS has been prepared by Valvoline's Environmental Health and Safety Department (1-800-VALVOLINE). List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-statement : Hazard Statement IATA : International Air Transport Association. IATA-DGR : Dangerous Goods Regulation by the ?International Air Transport Association? (IATA). ICAO : International Civil Aviation Organization Flammability H e a lt h In s ta b ility 0 1 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 0 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page: 13 SAFETY DATA SHEET Revision Date: 03/15/2018 Print Date: 10/29/2018 SDS Number: R0272517 Valvoline? DRIVE TRAIN SAE 50 Transmission Fluid VV329 Version: 1.3 13 / 13 ICAO-TI (ICAO) : Technical Instructions by the ?International Civil Aviation Organization? IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization logPow : octanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population LDxx : Lethal Dose, for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit P-Statement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic PPE : Personal Protective Equipment STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity TLV : Threshold Limit Value TWA : Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act DOT : Department of Transportation FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association NIOSH : National Institute for Occupational Safety and Health OSHA : Occupational Safety and Health Administration PMRA : Health Canada Pest Management Regulatory Agency RTK : Right to Know WHMIS : Workplace Hazardous Materials Information System