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Page: 1 SAFETY DATA SHEET Revision Date: 09/07/2018 Print Date: 10/29/2018 SDS Number: R0163801 All Fleet? SAE 40 Engine Oil VV400 Version: 1.3 1 / 14 29 CFR 1910.1200 (OSHA HazCom 2012) SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Trade name : All Fleet? SAE 40 Engine Oil Details of the supplier of the safety data sheet Valvoline LLC 100 Valvoline Way Lexington, KY 40509 United States of America (USA) 1-800-TEAMVAL (1-800-832-6825) This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency telephone number 1-800-VALVOLINE (1-800-825-8654) Regulatory Information Number 1-800-TEAMVAL (1-800-832-6825) Product Information 1-800-TEAMVAL (1-800-832-6825) SECTION 2. HAZARDS IDENTIFICATION GHS Classification Not a hazardous substance or mixture. GHS label elements Not a hazardous substance or mixture. Other hazards The following percentage of the mixture consists of ingredient(s) with unknown acute toxicity: 4.4639 % SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components Chemical name CAS-No. Classification Concentration (%) DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC 64742-54-7 Not a hazardous substance or mixture. >=80.00 - < 90.00 DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC 64742-65-0 Asp. Tox. 1; H304 >=1.00 - < 1.50 ZINC BIS[O-(6- 93819-94-4 Skin Irrit. 2; H315 >=1.00 - < 1.50 Page: 2 SAFETY DATA SHEET Revision Date: 09/07/2018 Print Date: 10/29/2018 SDS Number: R0163801 All Fleet? SAE 40 Engine Oil VV400 Version: 1.3 2 / 14 METHYLHELPTYL)]BIS[O-SEC- BUTYL)]BIS(DITHIOPHOSPATE) Eye Dam. 1; H318 SECTION 4. FIRST AID MEASURES General advice : Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. If inhaled : If breathed in, move person into fresh air. If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of skin contact : Remove contaminated clothing. If irritation develops, get medical attention. If on skin, rinse well with water. Wash contaminated clothing before re-use. In case of eye contact : Immediately flush eye(s) with plenty of water. Remove contact lenses. Protect unharmed eye. If swallowed : Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Most important symptoms and effects, both acute and delayed : Acute aspiration of large amounts of oil-laden material may produce a serious aspiration pneumonia. Patients who aspirate these oils should be followed for the development of long-term sequelae. Repeated aspiration of small quantities of mineral oil can produce chronic inflammation of the lungs (i.e. lipoid pneumonia) that may progress to pulmonary fibrosis. Symptoms are often subtle and radiological changes appear worse than clinical abnormalities. Occasionally, persistent cough, irritation of the upper respiratory tract, shortness of breath with exertion, fever, and bloody sputum occur. Inhalation exposure to oil mists below current workplace exposure limits is unlikely to cause pulmonary abnormalities. Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include: stomach or intestinal upset (nausea, vomiting, diarrhea) irritation (nose, throat, airways) Notes to physician : No hazards which require special first aid measures. Page: 3 SAFETY DATA SHEET Revision Date: 09/07/2018 Print Date: 10/29/2018 SDS Number: R0163801 All Fleet? SAE 40 Engine Oil VV400 Version: 1.3 3 / 14 SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Water spray Foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing media : High volume water jet Specific hazards during firefighting : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion products : carbon dioxide and carbon monoxide Hydrocarbons zinc oxide Sulphur oxides hydrogen sulfide mercaptans Specific extinguishing methods : Product is compatible with standard fire-fighting agents. Further information : Standard procedure for chemical fires. Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions : Prevent further leakage or spillage if safe to do so. Methods and materials for containment and cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. Other information : Comply with all applicable federal, state, and local regulations. Page: 4 SAFETY DATA SHEET Revision Date: 09/07/2018 Print Date: 10/29/2018 SDS Number: R0163801 All Fleet? SAE 40 Engine Oil VV400 Version: 1.3 4 / 14 SECTION 7. HANDLING AND STORAGE Advice on safe handling : Do not breathe vapours/dust. Do not smoke. Container hazardous when empty. Avoid contact with skin and eyes. Smoking, eating and drinking should be prohibited in the application area. For personal protection see section 8. Dispose of rinse water in accordance with local and national regulations. Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC 64742-65-0 TWA 5 mg/m3 Mist OSHA Z-1 TWA 5 mg/m3 Inhalable fraction ACGIH TWA 5 mg/m3 Mist OSHA P0 TWA 5 mg/m3 Mist NIOSH REL ST 10 mg/m3 Mist NIOSH REL PEL 5 mg/m3 particulate CAL PEL Engineering measures : Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Personal protective equipment Respiratory protection : Respiratory protection is not required under normal conditions of use. Hand protection Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Page: 5 SAFETY DATA SHEET Revision Date: 09/07/2018 Print Date: 10/29/2018 SDS Number: R0163801 All Fleet? SAE 40 Engine Oil VV400 Version: 1.3 5 / 14 Eye protection : Wear chemical splash goggles when there is the potential for exposure of the eyes to liquid, vapor or mist. Skin and body protection : Wear as appropriate: Impervious clothing Safety shoes Choose body protection according to the amount and concentration of the dangerous substance at the work place. Wear resistant gloves (consult your safety equipment supplier). Hygiene measures : Wash hands before breaks and at the end of workday. When using do not eat or drink. When using do not smoke. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state : liquid Colour : amber Odour : hydrocarbon-like Odour Threshold : No data available pH : No data available Melting point/freezing point : No data available Boiling point/boiling range : 600.01 ?F / 315.56 ?C (1,013.333333 hPa) Calculated Phase Transition Liquid/Gas Flash point : > 390 ?F / > 199 ?C Method: Cleveland open cup Evaporation rate : No data available Flammability (solid, gas) : No data available Upper explosion limit : 7 %(V) Calculated Explosive Limit Lower explosion limit : 0.9 %(V) Calculated Explosive Limit Vapour pressure : 0.1 hPa (20 ?C) Calculated Vapor Pressure Relative vapour density : No data available Relative density : 0.890 (15.6 ?C) Page: 6 SAFETY DATA SHEET Revision Date: 09/07/2018 Print Date: 10/29/2018 SDS Number: R0163801 All Fleet? SAE 40 Engine Oil VV400 Version: 1.3 6 / 14 Density : 0.880 g/cm3 (15.6 ?C) Solubility(ies) Water solubility : No data available Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Thermal decomposition : No data available Viscosity Viscosity, dynamic : No data available Viscosity, kinematic : 14.5 mm2/s Oxidizing properties : No data available SECTION 10. STABILITY AND REACTIVITY Reactivity : No decomposition if stored and applied as directed. Chemical stability : Stable under recommended storage conditions. Possibility of hazardous reactions : Product will not undergo hazardous polymerization. Conditions to avoid : excessive heat Incompatible materials : Strong oxidizing agents Hazardous decomposition products carbon dioxide and carbon monoxide hydrogen sulfide Sulphur oxides zinc oxide fumes mercaptans SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Skin contact Page: 7 SAFETY DATA SHEET Revision Date: 09/07/2018 Print Date: 10/29/2018 SDS Number: R0163801 All Fleet? SAE 40 Engine Oil VV400 Version: 1.3 7 / 14 Eye Contact Ingestion Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Acute dermal toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Acute oral toxicity : LD50 (Rat): > 15 g/kg Acute dermal toxicity : LD50 (Rabbit): > 5 g/kg DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute dermal toxicity : LD50 (Rabbit): > 5,000 mg/kg ZINC BIS[O-(6-METHYLHELPTYL)]BIS[O-SEC-BUTYL)]BIS(DITHIOPHOSPATE): Acute oral toxicity : LD50 (Rat): 2,600 mg/kg Acute dermal toxicity : LD50 (Rabbit): > 3,160 mg/kg Method: OECD Test Guideline 402 Assessment: Not classified as acutely toxic by dermal absorption under GHS. Skin corrosion/irritation Not classified based on available information. Product: Remarks : May cause skin irritation in susceptible persons. Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Assessment : Slight, transient irritation Result : Slight, transient irritation DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC: Assessment : Slight, transient irritation Result : Slight, transient irritation ZINC BIS[O-(6-METHYLHELPTYL)]BIS[O-SEC-BUTYL)]BIS(DITHIOPHOSPATE): Species : Guinea pig Method : OECD Test Guideline 404 Result : Irritating to skin. Remarks : Information given is based on data obtained from similar substances. Page: 8 SAFETY DATA SHEET Revision Date: 09/07/2018 Print Date: 10/29/2018 SDS Number: R0163801 All Fleet? SAE 40 Engine Oil VV400 Version: 1.3 8 / 14 Serious eye damage/eye irritation Not classified based on available information. Product: Remarks : Vapours may cause irritation to the eyes, respiratory system and the skin. Causes serious eye irritation. Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Result : No eye irritation Assessment : No eye irritation DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC: Result : Slight, transient irritation Assessment : Slight, transient irritation ZINC BIS[O-(6-METHYLHELPTYL)]BIS[O-SEC-BUTYL)]BIS(DITHIOPHOSPATE): Species : Rabbit Result : Corrosive Remarks : Information given is based on data obtained from similar substances. Respiratory or skin sensitisation Skin sensitisation Not classified based on available information. Respiratory sensitisation Not classified based on available information. Germ cell mutagenicity Not classified based on available information. Components: ZINC BIS[O-(6-METHYLHELPTYL)]BIS[O-SEC-BUTYL)]BIS(DITHIOPHOSPATE): Genotoxicity in vitro : Test Type: Ames test Test system: Salmonella typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative Remarks: Information given is based on data obtained from similar substances. Genotoxicity in vivo : Test Type: Micronucleus test Species: Mouse Method: OECD Test Guideline 474 Result: negative Remarks: Information given is based on data obtained from similar substances. Carcinogenicity Not classified based on available information. Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Carcinogenicity - : Classified based on DMSO extract content < 3% (Regulation Page: 9 SAFETY DATA SHEET Revision Date: 09/07/2018 Print Date: 10/29/2018 SDS Number: R0163801 All Fleet? SAE 40 Engine Oil VV400 Version: 1.3 9 / 14 Assessment (EC) 1272/2008, Annex VI, Part 3, Note L) IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA?s list of regulated carcinogens. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. STOT - single exposure Not classified based on available information. STOT - repeated exposure Not classified based on available information. Aspiration toxicity Not classified based on available information. Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: No aspiration toxicity classification DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC: May be fatal if swallowed and enters airways. Further information Product: Remarks : No data available SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Toxicity to fish : LL50 (Fish): > 100 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EL50 (Aquatic invertebrates): > 10,000 mg/l Exposure time: 48 h Toxicity to algae : EL50 (Algae, algal mat (Algae)): > 100 mg/l Exposure time: 72 h Toxicity to fish (Chronic toxicity) : NOEC (Fish): 10 mg/l Toxicity to daphnia and other aquatic invertebrates : NOEC (Aquatic invertebrates): 10 mg/l Page: 10 SAFETY DATA SHEET Revision Date: 09/07/2018 Print Date: 10/29/2018 SDS Number: R0163801 All Fleet? SAE 40 Engine Oil VV400 Version: 1.3 10 / 14 (Chronic toxicity) Ecotoxicology Assessment Short-term (acute) aquatic hazard : Not classified based on available information. Long-term (chronic) aquatic hazard : Not classified based on available information. ZINC BIS[O-(6-METHYLHELPTYL)]BIS[O-SEC-BUTYL)]BIS(DITHIOPHOSPATE): Toxicity to fish : LL50 (Oncorhynchus mykiss (rainbow trout)): 4.5 mg/l Exposure time: 96 h Test Type: semi-static test Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 5.4 mg/l Exposure time: 48 h Test Type: static test Toxicity to algae : EC50 (Selenastrum capricornutum (green algae)): 2.1 mg/l End point: Growth inhibition Exposure time: 72 h Test Type: static test No data available Persistence and degradability Components: ZINC BIS[O-(6-METHYLHELPTYL)]BIS[O-SEC-BUTYL)]BIS(DITHIOPHOSPATE): Biodegradability : Result: Not readily biodegradable. Biodegradation: 1.5 % Exposure time: 28 d Method: OECD Test Guideline 301B No data available Bioaccumulative potential Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Partition coefficient: n- octanol/water : log Pow: Expected > 7 ZINC BIS[O-(6-METHYLHELPTYL)]BIS[O-SEC-BUTYL)]BIS(DITHIOPHOSPATE): Partition coefficient: n- octanol/water : log Pow: 0.59 - 1.2 (23 ?C) No data available Mobility in soil Components: No data available Other adverse effects No data available Product: Additional ecological : No data available Page: 11 SAFETY DATA SHEET Revision Date: 09/07/2018 Print Date: 10/29/2018 SDS Number: R0163801 All Fleet? SAE 40 Engine Oil VV400 Version: 1.3 11 / 14 information Components: SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods General advice : Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company. Dispose of in accordance with all applicable local, state and federal regulations. Contaminated packaging : Empty remaining contents. Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. SECTION 14. TRANSPORT INFORMATION International transport regulations REGULATION ID NUMBER PROPER SHIPPING NAME *HAZARD CLASS SUBSIDIARY HAZARDS PACKING GROUP MARINE POLLUTANT / LTD. QTY. U.S. DOT - ROAD Not dangerous goods CFR_RAIL_C Not dangerous goods U.S. DOT - INLAND WATERWAYS Not dangerous goods TDG_ROAD_C Not dangerous goods TDG_RAIL_C Not dangerous goods Page: 12 SAFETY DATA SHEET Revision Date: 09/07/2018 Print Date: 10/29/2018 SDS Number: R0163801 All Fleet? SAE 40 Engine Oil VV400 Version: 1.3 12 / 14 TDG_INWT_C Not dangerous goods INTERNATIONAL MARITIME DANGEROUS GOODS Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER Not dangerous goods MX_DG Not dangerous goods *ORM = ORM-D, CBL = COMBUSTIBLE LIQUID Marine pollutant no Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act SARA 311/312 Hazards : Acute Health Hazard California Prop. 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. The components of this product are reported in the following inventories: TSCA : On TSCA Inventory DSL : All components of this product are on the Canadian DSL AICS : On the inventory, or in compliance with the inventory ENCS : On the inventory, or in compliance with the inventory Page: 13 SAFETY DATA SHEET Revision Date: 09/07/2018 Print Date: 10/29/2018 SDS Number: R0163801 All Fleet? SAE 40 Engine Oil VV400 Version: 1.3 13 / 14 KECI : On the inventory, or in compliance with the inventory PICCS : On the inventory, or in compliance with the inventory IECSC : On the inventory, or in compliance with the inventory SECTION 16. OTHER INFORMATION Further information Revision Date: 09/07/2018 NFPA: HMIS III: NFPA Flammable and Combustible Liquids Classification Combustible Liquid Class IIIB Full text of H-Statements H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H318 Causes serious eye damage. Sources of key data used to compile the Safety Data Sheet Valvoline internal data including own and sponsored test reports The UNECE administers regional agreements implementing harmonised classification for labelling (GHS) and transport. The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This SDS has been prepared by Valvoline's Environmental Health and Safety Department (1-800-VALVOLINE). Flammability H e a lt h In s ta b ility 1 1 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 2 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page: 14 SAFETY DATA SHEET Revision Date: 09/07/2018 Print Date: 10/29/2018 SDS Number: R0163801 All Fleet? SAE 40 Engine Oil VV400 Version: 1.3 14 / 14 List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-statement : Hazard Statement IATA : International Air Transport Association. IATA-DGR : Dangerous Goods Regulation by the ?International Air Transport Association? (IATA). ICAO : International Civil Aviation Organization ICAO-TI (ICAO) : Technical Instructions by the ?International Civil Aviation Organization? IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization logPow : octanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population LDxx : Lethal Dose, for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit P-Statement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic PPE : Personal Protective Equipment STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity TLV : Threshold Limit Value TWA : Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act DOT : Department of Transportation FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association NIOSH : National Institute for Occupational Safety and Health OSHA : Occupational Safety and Health Administration PMRA : Health Canada Pest Management Regulatory Agency RTK : Right to Know WHMIS : Workplace Hazardous Materials Information System