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Page: 1 SAFETY DATA SHEET Revision Date: 05/19/2017 Print Date: 10/29/2018 SDS Number: R0172170 Valvoline? Multi-Vehicle Multi-Purpose Red Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV615 Version: 1.3 1 / 15 29 CFR 1910.1200 (OSHA HazCom 2012) SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Trade name : Valvoline? Multi-Vehicle Multi-Purpose Red Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries Details of the supplier of the safety data sheet Valvoline LLC 100 Valvoline Way Lexington, KY 40509 United States of America (USA) 1-800-TEAMVAL Emergency telephone number 1-800-VALVOLINE (1-800-825-8654) Regulatory Information Number 1-800-TEAMVAL Product Information 1-800-TEAMVAL SECTION 2. HAZARDS IDENTIFICATION GHS Classification This material is not considered hazardous under the OSHA Hazard Communication Standard (HazCom 2012). GHS label elements This material is not considered hazardous under the OSHA Hazard Communication Standard (HazCom 2012). Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components Chemical name CAS-No. Classification Concentration (%) DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC 64742-65-0 Asp. Tox. 1; H304 74.9999 ASPHALT 8052-42-4 This material is not considered hazardous under the OSHA Hazard 24.9999 Page: 2 SAFETY DATA SHEET Revision Date: 05/19/2017 Print Date: 10/29/2018 SDS Number: R0172170 Valvoline? Multi-Vehicle Multi-Purpose Red Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV615 Version: 1.3 2 / 15 Communication Standard (HazCom 2012). DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHT 64742-52-5 This material is not considered hazardous under the OSHA Hazard Communication Standard (HazCom 2012). 9.9999 SECTION 4. FIRST AID MEASURES General advice : No hazards which require special first aid measures. If inhaled : If breathed in, move person into fresh air. If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of skin contact : First aid is not normally required. However, it is recommended that exposed areas be cleaned by washing with soap and water. In case of eye contact : Remove contact lenses. Protect unharmed eye. If swallowed : Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Most important symptoms and effects, both acute and delayed : Acute aspiration of large amounts of oil-laden material may produce a serious aspiration pneumonia. Patients who aspirate these oils should be followed for the development of long-term sequelae. Repeated aspiration of small quantities of mineral oil can produce chronic inflammation of the lungs (i.e. lipoid pneumonia) that may progress to pulmonary fibrosis. Symptoms are often subtle and radiological changes appear worse than clinical abnormalities. Occasionally, persistent cough, irritation of the upper respiratory tract, shortness of breath with exertion, fever, and bloody sputum occur. Inhalation exposure to oil mists below current workplace exposure limits is unlikely to cause pulmonary abnormalities. Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through Page: 3 SAFETY DATA SHEET Revision Date: 05/19/2017 Print Date: 10/29/2018 SDS Number: R0172170 Valvoline? Multi-Vehicle Multi-Purpose Red Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV615 Version: 1.3 3 / 15 the skin may include: stomach or intestinal upset (nausea, vomiting, diarrhea) irritation (nose, throat, airways) Notes to physician : No hazards which require special first aid measures. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Water spray Foam Carbon dioxide (CO2) Dry chemical Specific hazards during firefighting : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion products : carbon dioxide and carbon monoxide Sulphur oxides Hydrocarbons Aldehydes Ketones Nitrogen oxides (NOx) Specific extinguishing methods : Product is compatible with standard fire-fighting agents. Further information : Standard procedure for chemical fires. Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions : Prevent further leakage or spillage if safe to do so. Methods and materials for containment and cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. Page: 4 SAFETY DATA SHEET Revision Date: 05/19/2017 Print Date: 10/29/2018 SDS Number: R0172170 Valvoline? Multi-Vehicle Multi-Purpose Red Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV615 Version: 1.3 4 / 15 Other information : Comply with all applicable federal, state, and local regulations. SECTION 7. HANDLING AND STORAGE Advice on safe handling : Smoking, eating and drinking should be prohibited in the application area. For personal protection see section 8. Materials to avoid : No materials to be especially mentioned. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis ASPHALT 8052-42-4 TWA 0.5 mg/m3 Fume, inhalable fraction (benzene soluble aerosol) ACGIH C 5 mg/m3 Fumes NIOSH REL PEL 5 mg/m3 Fumes CAL PEL DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHT 64742-52-5 TWA 5 mg/m3 Mist OSHA Z-1 TWA 5 mg/m3 Inhalable fraction ACGIH TWA 5 mg/m3 Mist OSHA P0 TWA 5 mg/m3 Mist NIOSH REL ST 10 mg/m3 Mist NIOSH REL PEL 5 mg/m3 particulate CAL PEL Hazardous components without workplace control parameters Components CAS-No. DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC 64742-65-0 Page: 5 SAFETY DATA SHEET Revision Date: 05/19/2017 Print Date: 10/29/2018 SDS Number: R0172170 Valvoline? Multi-Vehicle Multi-Purpose Red Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV615 Version: 1.3 5 / 15 Engineering measures : General room ventilation should be adequate for normal conditions of use. However, if unusual operating conditions exist, provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally required. Eye protection : Not required under normal conditions of use. Wear splash- proof safety goggles if material could be misted or splashed into eyes. Skin and body protection : Wear as appropriate: Safety shoes Wear resistant gloves (consult your safety equipment supplier). Hygiene measures : General industrial hygiene practice. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : gel Physical state : liquid Colour : red Odour : No data available Odour Threshold : No data available pH : No data available Melting point/freezing point : No data available Boiling point/boiling range : 640 ?F / 338 ?C Flash point : 471 ?F / 244 ?C Evaporation rate : No data available Flammability (solid, gas) : No data available Page: 6 SAFETY DATA SHEET Revision Date: 05/19/2017 Print Date: 10/29/2018 SDS Number: R0172170 Valvoline? Multi-Vehicle Multi-Purpose Red Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV615 Version: 1.3 6 / 15 Upper explosion limit : No data available Lower explosion limit : No data available Vapour pressure : < 0.01 mmHg (20 ?C) Relative vapour density : No data available Relative density : 0.95 (15.6 ?C) Density : 0.90 g/cm3 (20 ?C) Solubility(ies) Water solubility : negligible Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Auto-ignition temperature : > 315 ?C Thermal decomposition : No data available Viscosity Viscosity, dynamic : No data available Viscosity, kinematic : > 20.5 mm2/s (40 ?C) Oxidizing properties : No data available SECTION 10. STABILITY AND REACTIVITY Reactivity : No decomposition if stored and applied as directed. Chemical stability : Stable under recommended storage conditions. Possibility of hazardous reactions : Product will not undergo hazardous polymerization. Conditions to avoid : None known. Incompatible materials : Strong oxidizing agents Hazardous decomposition Page: 7 SAFETY DATA SHEET Revision Date: 05/19/2017 Print Date: 10/29/2018 SDS Number: R0172170 Valvoline? Multi-Vehicle Multi-Purpose Red Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV615 Version: 1.3 7 / 15 products carbon dioxide and carbon monoxide Hydrocarbons Sulphur oxides SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation Skin contact Eye Contact Ingestion Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate (Rat): 3,019 mg/kg Acute dermal toxicity : Acute toxicity estimate (Rabbit): 169,492 mg/kg Components: DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute dermal toxicity : LD50 (Rabbit): > 5,000 mg/kg ASPHALT: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : Assessment: Not classified as acutely toxic by inhalation under GHS. Remarks: Information given is based on data obtained from similar substances. Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg Assessment: Not classified as acutely toxic by dermal absorption under GHS. DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHT: Acute oral toxicity : LD50 (Rat): > 5 g/kg Acute inhalation toxicity : LC50 (Rat): > 5.53 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: OECD Test Guideline 403 Assessment: Not classified as acutely toxic by inhalation under GHS. Page: 8 SAFETY DATA SHEET Revision Date: 05/19/2017 Print Date: 10/29/2018 SDS Number: R0172170 Valvoline? Multi-Vehicle Multi-Purpose Red Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV615 Version: 1.3 8 / 15 Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Assessment: Not classified as acutely toxic by dermal absorption under GHS. Remarks: No mortality observed at this dose. Skin corrosion/irritation Not classified based on available information. Product: Result: No skin irritation Components: DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC: Result: Slight, transient irritation ASPHALT: Species: Rabbit Result: No skin irritation Remarks: Information given is based on data obtained from similar substances. DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHT: Species: Rabbit Result: No skin irritation Serious eye damage/eye irritation Not classified based on available information. Product: Result: No eye irritation Remarks: Unlikely to cause eye irritation or injury. Components: DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC: Result: Slight, transient irritation ASPHALT: Species: Rabbit Remarks: May irritate eyes. DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHT: Species: Rabbit Result: Slight, transient irritation Respiratory or skin sensitisation Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information. Components: ASPHALT: Test Type: Buehler Test Page: 9 SAFETY DATA SHEET Revision Date: 05/19/2017 Print Date: 10/29/2018 SDS Number: R0172170 Valvoline? Multi-Vehicle Multi-Purpose Red Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV615 Version: 1.3 9 / 15 Species: Guinea pig Assessment: Does not cause skin sensitisation. DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHT: Species: Guinea pig Assessment: Does not cause skin sensitisation. Method: OECD Test Guideline 406 Germ cell mutagenicity Not classified based on available information. Components: ASPHALT: Genotoxicity in vitro : Result: Positive results were obtained in some in vitro tests. Carcinogenicity Not classified based on available information. Reproductive toxicity Not classified based on available information. STOT - single exposure Not classified based on available information. STOT - repeated exposure Not classified based on available information. Aspiration toxicity Not classified based on available information. Product: No aspiration toxicity classification Components: DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC: May be fatal if swallowed and enters airways. Further information Product: Remarks: No data available SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Ecotoxicology Assessment Acute aquatic toxicity : Not classified based on available information. Chronic aquatic toxicity : Not classified based on available information. Components: ASPHALT: Toxicity to fish : Remarks: No toxicity at the limit of solubility QSAR Page: 10 SAFETY DATA SHEET Revision Date: 05/19/2017 Print Date: 10/29/2018 SDS Number: R0172170 Valvoline? Multi-Vehicle Multi-Purpose Red Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV615 Version: 1.3 10 / 15 Toxicity to daphnia and other aquatic invertebrates : Remarks: No toxicity at the limit of solubility QSAR Toxicity to algae : Remarks: No toxicity at the limit of solubility QSAR Toxicity to fish (Chronic toxicity) : Remarks: No toxicity at the limit of solubility QSAR DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHT: Toxicity to fish : LL50 (Pimephales promelas (fathead minnow)): > 100 mg/l Exposure time: 96 h Test Type: static test Test substance: WAF Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EL50 (Daphnia magna (Water flea)): > 10,000 mg/l Exposure time: 48 h Test Type: static test Test substance: WAF Method: OECD Test Guideline 202 Toxicity to algae : NOEL (Pseudokirchneriella subcapitata (green algae)): >= 100 mg/l End point: Growth inhibition Exposure time: 72 h Test Type: static test Test substance: WAF Method: OECD Test Guideline 201 Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEL (Daphnia (water flea)): 10 mg/l Exposure time: 21 d Test Type: semi-static test Test substance: WAF Method: OECD Test Guideline 211 Persistence and degradability ASPHALT: Biodegradability : Result: Not readily biodegradable. DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHT: Biodegradability : Result: Inherently biodegradable. Biodegradation: 31 % Exposure time: 28 d Method: OECD Test Guideline 301F No data available Bioaccumulative potential No data available Page: 11 SAFETY DATA SHEET Revision Date: 05/19/2017 Print Date: 10/29/2018 SDS Number: R0172170 Valvoline? Multi-Vehicle Multi-Purpose Red Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV615 Version: 1.3 11 / 15 Mobility in soil No data available Other adverse effects No data available Product: Additional ecological information : No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods General advice : Dispose of in accordance with all applicable local, state and federal regulations. Contaminated packaging : Empty remaining contents. SECTION 14. TRANSPORT INFORMATION International transport regulations REGULATION ID NUMBER PROPER SHIPPING NAME *HAZARD CLASS SUBSIDIARY HAZARDS PACKING GROUP MARINE POLLUTANT / LTD. QTY. U.S. DOT - ROAD Not dangerous goods CFR_RAIL_C Not dangerous goods U.S. DOT - INLAND WATERWAYS Not dangerous goods TDG_ROAD_C Not dangerous goods TDG_RAIL_C Not dangerous goods TDG_INWT_C Page: 12 SAFETY DATA SHEET Revision Date: 05/19/2017 Print Date: 10/29/2018 SDS Number: R0172170 Valvoline? Multi-Vehicle Multi-Purpose Red Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV615 Version: 1.3 12 / 15 Not dangerous goods INTERNATIONAL MARITIME DANGEROUS GOODS Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER Not dangerous goods MX_DG Not dangerous goods *ORM = ORM-D, CBL = COMBUSTIBLE LIQUID Marine pollutant no Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : No SARA Hazards SARA 313 This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop 65 Proposition 65 warnings are not required for this product based on the results of a risk assessment. The components of this product are reported in the following inventories: TSCA : On TSCA Inventory AICS : On the inventory, or in compliance with the inventory Page: 13 SAFETY DATA SHEET Revision Date: 05/19/2017 Print Date: 10/29/2018 SDS Number: R0172170 Valvoline? Multi-Vehicle Multi-Purpose Red Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV615 Version: 1.3 13 / 15 DSL : All components of this product are on the Canadian DSL ENCS : On the inventory, or in compliance with the inventory KECI : On the inventory, or in compliance with the inventory PICCS : On the inventory, or in compliance with the inventory IECSC : On the inventory, or in compliance with the inventory Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA) SECTION 16. OTHER INFORMATION Further information Revision Date: 05/19/2017 NFPA: HMIS III: NFPA Flammable and Combustible Liquids Classification Combustible Liquid Class IIIB Full text of H-Statements H304 May be fatal if swallowed and enters airways. Sources of key data used to compile the Safety Data Sheet Valvoline internal data including own and sponsored test reports Flammability H e a lt h In s ta b ility 0 1 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 0 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page: 14 SAFETY DATA SHEET Revision Date: 05/19/2017 Print Date: 10/29/2018 SDS Number: R0172170 Valvoline? Multi-Vehicle Multi-Purpose Red Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV615 Version: 1.3 14 / 15 The UNECE administers regional agreements implementing harmonised classification for labelling (GHS) and transport. The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This SDS has been prepared by Valvoline's Environmental Health and Safety Department (1-800-VALVOLINE). List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-statement : Hazard Statement IATA : International Air Transport Association. IATA-DGR : Dangerous Goods Regulation by the ?International Air Transport Association? (IATA). ICAO : International Civil Aviation Organization ICAO-TI (ICAO) : Technical Instructions by the ?International Civil Aviation Organization? IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization logPow : octanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population LDxx : Lethal Dose, for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit P-Statement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic PPE : Personal Protective Equipment STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity TLV : Threshold Limit Value TWA : Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act DOT : Department of Transportation FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association Page: 15 SAFETY DATA SHEET Revision Date: 05/19/2017 Print Date: 10/29/2018 SDS Number: R0172170 Valvoline? Multi-Vehicle Multi-Purpose Red Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV615 Version: 1.3 15 / 15 NIOSH : National Institute for Occupational Safety and Health OSHA : Occupational Safety and Health Administration PMRA : Health Canada Pest Management Regulatory Agency RTK : Right to Know WHMIS : Workplace Hazardous Materials Information System