Page: 1 SAFETY DATA SHEET Revision Date: 08/31/2018 Print Date: 10/30/2018 SDS Number: R0296766 ZEREX? G05? Antifreeze Coolant ZXG051 Version: 1.6 1 / 22 29 CFR 1910.1200 (OSHA HazCom 2012) SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Trade name : ZEREX? G05? Antifreeze Coolant Details of the supplier of the safety data sheet Valvoline LLC 100 Valvoline Way Lexington, KY 40509 United States of America (USA) 1-800-TEAMVAL (1-800-832-6825) This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency telephone number 1-800-VALVOLINE (1-800-825-8654) Regulatory Information Number 1-800-TEAMVAL (1-800-832-6825) Product Information 1-800-TEAMVAL (1-800-832-6825) SECTION 2. HAZARDS IDENTIFICATION GHS Classification Acute toxicity (Oral) : Category 4 Carcinogenicity : Category 1B Reproductive toxicity : Category 1B Specific target organ systemic toxicity - repeated exposure (Oral) : Category 2 (Kidney, Liver) GHS label elements Hazard pictograms : Signal Word : Danger Hazard Statements : Harmful if swallowed. May cause cancer. May damage fertility or the unborn child. May cause damage to organs (Kidney, Liver) through Page: 2 SAFETY DATA SHEET Revision Date: 08/31/2018 Print Date: 10/30/2018 SDS Number: R0296766 ZEREX? G05? Antifreeze Coolant ZXG051 Version: 1.6 2 / 22 prolonged or repeated exposure if swallowed. Precautionary Statements : Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. IF exposed or concerned: Get medical advice/ attention. Storage: Store locked up. Disposal: Dispose of contents/ container to an approved waste disposal plant. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components Chemical name CAS-No. Classification Concentration (%) ETHYLENE GLYCOL 107-21-1 Acute Tox. 4; H302 STOT RE 2; H373 >=90.00 - <= 100.00 DIETHYLENE GLYCOL 111-46-6 Acute Tox. 4; H302 STOT RE 2; H373 >=1.50 - < 5.00 SODIUM BENZOATE 532-32-1 Eye Irrit. 2A; H319 >=1.50 - < 5.00 DISODIUM TETRABORATE 1330-43-4 Repr. 1B; H360 >=1.50 - < 5.00 SODIUM NITRITE 7632-00-0 Ox. Sol. 2; H272 Acute Tox. 3; H301 >=0.10 - < 0.50 Page: 3 SAFETY DATA SHEET Revision Date: 08/31/2018 Print Date: 10/30/2018 SDS Number: R0296766 ZEREX? G05? Antifreeze Coolant ZXG051 Version: 1.6 3 / 22 Eye Irrit. 2A; H319 Carc. 1B; H350 SODIUM NITRATE 7631-99-4 Ox. Sol. 3; H272 Eye Irrit. 2A; H319 Carc. 1B; H350 >=0.10 - < 0.50 SECTION 4. FIRST AID MEASURES General advice : Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. If inhaled : If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of skin contact : First aid is not normally required. However, it is recommended that exposed areas be cleaned by washing with soap and water. In case of eye contact : Flush eyes with water as a precaution. Remove contact lenses. Protect unharmed eye. If eye irritation persists, consult a specialist. If swallowed : Obtain medical attention. Rinse mouth with water. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Most important symptoms and effects, both acute and delayed : Effects of acute ethylene glycol poisoning appear in three fairly distinct stages. The initial stage occurs shortly after exposure, lasts 6-12 hours, and is characterized by central nervous system effects (transient exhilaration, nausea, vomiting, and in severe cases, coma, convulsions, and possible death). The second stage lasts from 12-36 hours after exposure and is initiated by the onset of coma. This phase is characterized by tachypnia, tachycardia, mild hypotension, cyanosis, and in severe cases, pulmonary edema, bronchopneumonia, cardiac enlargement, and congestive failure. The final stage occurs 24-72 post- Page: 4 SAFETY DATA SHEET Revision Date: 08/31/2018 Print Date: 10/30/2018 SDS Number: R0296766 ZEREX? G05? Antifreeze Coolant ZXG051 Version: 1.6 4 / 22 exposure and is characterized by renal failure, ranging from a mild increase in blood urea nitrogen and creatinine followed by recovery, to complete anuria with acute tubular necrosis that can lead to death. Oxaluria is found in most cases. The most significant laboratory finding in ethylene glycol intoxication is severe metabolic acidosis. Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include: stomach or intestinal upset (nausea, vomiting, diarrhea) irritation (nose, throat, airways) Cough pain in the abdomen and lower back cyanosis (causes blue coloring of the skin and nails from lack of oxygen) lung edema (fluid buildup in the lung tissue) acute kidney failure (sudden slowing or stopping of urine production) Convulsions Harmful if swallowed. May cause cancer. May damage fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure if swallowed. Notes to physician : This product contains ethylene glycol. Ethanol decreases the metabolism of ethylene glycol to toxic metabolites. Ethanol should be administered as soon as possible in cases of severe poisoning since the elimination half-life of ethylene glycol is 3 hours. If medical care will be delayed several hours, give the patient three to four 1-ounce oral "shots" of 86- proof or higher whiskey before or during transport to the hospital. Fomepizole (4-methylpyrazole) is an effective antagonist of alcohol dehydrogenase, and as such, may be used as an antidote in the treatment of ethylene glycol poisoning. Hemodialysis effectively removes ethylene glycol and its metabolites from the body. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Water spray Foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing : High volume water jet Page: 5 SAFETY DATA SHEET Revision Date: 08/31/2018 Print Date: 10/30/2018 SDS Number: R0296766 ZEREX? G05? Antifreeze Coolant ZXG051 Version: 1.6 5 / 22 media Specific hazards during firefighting : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion products : Alcohols Aldehydes carbon dioxide and carbon monoxide ethers toxic fumes Hydrocarbons Sodium oxides Specific extinguishing methods : Product is compatible with standard fire-fighting agents. Product is compatible with standard fire-fighting agents. Further information : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Ensure adequate ventilation. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. Other information : Comply with all applicable federal, state, and local regulations. SECTION 7. HANDLING AND STORAGE Page: 6 SAFETY DATA SHEET Revision Date: 08/31/2018 Print Date: 10/30/2018 SDS Number: R0296766 ZEREX? G05? Antifreeze Coolant ZXG051 Version: 1.6 6 / 22 Advice on safe handling : Do not breathe vapours/dust. Do not smoke. Container hazardous when empty. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. Smoking, eating and drinking should be prohibited in the application area. For personal protection see section 8. Dispose of rinse water in accordance with local and national regulations. Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis ETHYLENE GLYCOL 107-21-1 C 50 ppm 125 mg/m3 OSHA P0 C 40 ppm 100 mg/m3 Vapour CAL PEL TWA 25 ppm Vapour ACGIH STEL 50 ppm Vapour ACGIH STEL 10 mg/m3 Inhalable fraction, Aerosol only ACGIH DIETHYLENE GLYCOL 111-46-6 TWA 10 mg/m3 US WEEL DISODIUM TETRABORATE 1330-43-4 TWA 1 mg/m3 NIOSH REL PEL 5 mg/m3 CAL PEL TWA 10 mg/m3 OSHA P0 TWA 2 mg/m3 Inhalable fraction (Borate) ACGIH STEL 6 mg/m3 Inhalable fraction (Borate) ACGIH Page: 7 SAFETY DATA SHEET Revision Date: 08/31/2018 Print Date: 10/30/2018 SDS Number: R0296766 ZEREX? G05? Antifreeze Coolant ZXG051 Version: 1.6 7 / 22 Engineering measures : Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Personal protective equipment Respiratory protection : A NIOSH-approved air-purifying respirator with an appropriate cartridge and/or filter may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits (if applicable) or if overexposure has otherwise been determined. Protection provided by air- purifying respirators is limited. Use a positive pressure, air- supplied respirator if there is any potential for uncontrolled release, exposure levels are not known or any other circumstances where an air-purifying respirator may not provide adequate protection. In the case of vapour formation use a respirator with an approved filter. Hand protection Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye protection : Not required under normal conditions of use. Wear splash- proof safety goggles if material could be misted or splashed into eyes. Skin and body protection : Wear as appropriate: Impervious clothing Safety shoes Choose body protection according to the amount and concentration of the dangerous substance at the work place. Wear resistant gloves (consult your safety equipment supplier). Hygiene measures : Wash hands before breaks and at the end of workday. When using do not eat or drink. When using do not smoke. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state : liquid Colour : light yellow Odour : mild Odour Threshold : No data available Page: 8 SAFETY DATA SHEET Revision Date: 08/31/2018 Print Date: 10/30/2018 SDS Number: R0296766 ZEREX? G05? Antifreeze Coolant ZXG051 Version: 1.6 8 / 22 pH : Average 6.5 Melting point/freezing point : No data available Boiling point/boiling range : 330 ?F / 166 ?C (1013 hPa) Flash point : > 250.0 ?F / > 121.1 ?C Method: closed cup Evaporation rate : > 1 Ethyl Ether Flammability (solid, gas) : No data available Upper explosion limit : 15.3 %(V) Lower explosion limit : 3.2 %(V) Vapour pressure : 1.1 mmHg (20 ?C) Relative vapour density : > 1AIR=1 Relative density : No data available Density : Average 1.1362 g/cm3 (15.56 ?C) Solubility(ies) Water solubility : No data available Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Thermal decomposition : No data available Viscosity Viscosity, dynamic : No data available Viscosity, kinematic : No data available Oxidizing properties : No data available SECTION 10. STABILITY AND REACTIVITY Reactivity : No decomposition if stored and applied as directed. Page: 9 SAFETY DATA SHEET Revision Date: 08/31/2018 Print Date: 10/30/2018 SDS Number: R0296766 ZEREX? G05? Antifreeze Coolant ZXG051 Version: 1.6 9 / 22 Chemical stability : Stable under recommended storage conditions. Possibility of hazardous reactions : Product will not undergo hazardous polymerization. Conditions to avoid : excessive heat Exposure to moisture Incompatible materials : Acids Aldehydes Alkali metals Alkaline earth metals Bases iron salts strong alkalis Strong oxidizing agents Sulphur compounds Hazardous decomposition products Alcohols Aldehydes carbon dioxide and carbon monoxide ethers Hydrocarbons Organic acids Sodium oxides toxic fumes ketones SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Skin contact Eye Contact Ingestion Acute toxicity Harmful if swallowed. Product: Acute oral toxicity : Remarks: Ingestion of medications contaminated with diethylene glycol has caused kidney failure and death in humans. Products containing diethylene glycol should be considered toxic by ingestion. Acute toxicity estimate: 512.68 mg/kg Method: Calculation method Acute dermal toxicity : Remarks: Skin absorption of this material (or a component) Page: 10 SAFETY DATA SHEET Revision Date: 08/31/2018 Print Date: 10/30/2018 SDS Number: R0296766 ZEREX? G05? Antifreeze Coolant ZXG051 Version: 1.6 10 / 22 may be increased through injured skin. Components: ETHYLENE GLYCOL: Acute oral toxicity : LD0 (Human): estimated 1.56 g/kg Assessment: The component/mixture is classified as acute oral toxicity, category 4. Acute inhalation toxicity : LC50 (Rat): 10.9 mg/l Exposure time: 1 h Test atmosphere: dust/mist Assessment: No adverse effect has been observed in acute inhalation toxicity tests. Acute dermal toxicity : LD50 (Rabbit): 9,530 mg/kg Acute toxicity (other routes of administration) : LD50 (Rat): 5,010 mg/kg Application Route: Intraperitoneal DIETHYLENE GLYCOL: Acute oral toxicity : LD50 (Human): Expected 1,120 mg/kg Target Organs: Kidney Acute inhalation toxicity : LC50 (Rat): > 4.6 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: No adverse effect has been observed in acute inhalation toxicity tests. Acute dermal toxicity : LD50 (Rabbit): 13,300 mg/kg SODIUM BENZOATE: Acute oral toxicity : LD50 (Rat, male and female): 3,450 mg/kg Acute inhalation toxicity : LC50 (Rat): > 12.2 mg/l Exposure time: 4 h Test atmosphere: dust/mist Remarks: Information given is based on data obtained from similar substances. DISODIUM TETRABORATE: Acute inhalation toxicity : LC50 (Rat): > 2.03 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: OECD Test Guideline 403 Assessment: No adverse effect has been observed in acute inhalation toxicity tests. Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Assessment: No adverse effect has been observed in acute Page: 11 SAFETY DATA SHEET Revision Date: 08/31/2018 Print Date: 10/30/2018 SDS Number: R0296766 ZEREX? G05? Antifreeze Coolant ZXG051 Version: 1.6 11 / 22 dermal toxicity tests. SODIUM NITRITE: Acute oral toxicity : LD50 (Rat): 180 mg/kg Acute inhalation toxicity : LC50 (Rat): 5.5 mg/l Exposure time: 4 h Test atmosphere: dust/mist SODIUM NITRATE: Acute oral toxicity : LD50 (Rat): ca. 3,430 mg/kg Method: OECD Test Guideline 401 Skin corrosion/irritation Not classified based on available information. Components: ETHYLENE GLYCOL: Species : Rabbit Result : No skin irritation DIETHYLENE GLYCOL: Species : Human Result : Slight, transient irritation SODIUM BENZOATE: Assessment : Slight, transient irritation Result : Slight, transient irritation DISODIUM TETRABORATE: Species : Rabbit Result : No skin irritation SODIUM NITRITE: Assessment : No skin irritation Result : No skin irritation SODIUM NITRATE: Species : Rabbit Method : OECD Test Guideline 404 Result : No skin irritation Remarks : Information given is based on data obtained from similar substances. Serious eye damage/eye irritation Not classified based on available information. Product: Remarks : Unlikely to cause eye irritation or injury. Components: ETHYLENE GLYCOL: Result : Slight, transient irritation Page: 12 SAFETY DATA SHEET Revision Date: 08/31/2018 Print Date: 10/30/2018 SDS Number: R0296766 ZEREX? G05? Antifreeze Coolant ZXG051 Version: 1.6 12 / 22 DIETHYLENE GLYCOL: Species : Rabbit Result : Slight, transient irritation SODIUM BENZOATE: Species : Rabbit Result : Irritating to eyes. Method : OECD Test Guideline 405 DISODIUM TETRABORATE: Result : Slight, transient irritation SODIUM NITRITE: Result : Irritating to eyes. Assessment : Irritating to eyes. SODIUM NITRATE: Species : Rabbit Result : Irritating to eyes. Method : OECD Test Guideline 405 Respiratory or skin sensitisation Skin sensitisation Not classified based on available information. Respiratory sensitisation Not classified based on available information. Components: ETHYLENE GLYCOL: Test Type : Maximisation Test Species : Guinea pig Assessment : Does not cause skin sensitisation. DIETHYLENE GLYCOL: Test Type : Maximisation Test Species : Guinea pig Method : Directive 67/548/EEC, Annex V, B.6. Result : Did not cause sensitisation on laboratory animals. DISODIUM TETRABORATE: Test Type : Buehler Test Species : Guinea pig Assessment : Does not cause skin sensitisation. Method : OECD Test Guideline 406 Germ cell mutagenicity Not classified based on available information. Components: ETHYLENE GLYCOL: Genotoxicity in vitro : Test Type: Ames test Test system: Salmonella typhimurium Page: 13 SAFETY DATA SHEET Revision Date: 08/31/2018 Print Date: 10/30/2018 SDS Number: R0296766 ZEREX? G05? Antifreeze Coolant ZXG051 Version: 1.6 13 / 22 Metabolic activation: with and without metabolic activation Result: negative DIETHYLENE GLYCOL: Genotoxicity in vitro : Test Type: Ames test Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative GLP: yes Test system: Chinese hamster ovary cells Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 479 Result: negative GLP: yes Genotoxicity in vivo : Test Type: In vivo micronucleus test Species: Mouse Method: OECD Test Guideline 474 Result: negative GLP: yes Carcinogenicity May cause cancer. IARC Group 2A: Probably carcinogenic to humans Sodium nitrite Not Assigned (nitrite (ingested) under conditions that result in endogenous nitrosation) Group 2A: Probably carcinogenic to humans Sodium nitrate Not Assigned (nitrate (ingested) under conditions that result in endogenous nitrosation) OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA?s list of regulated carcinogens. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity May damage fertility or the unborn child. Components: DISODIUM TETRABORATE: Reproductive toxicity - Assessment : Clear evidence of adverse effects on sexual function and fertility, and/or on development, based on animal experiments STOT - single exposure Not classified based on available information. STOT - repeated exposure May cause damage to organs (Kidney, Liver) through prolonged or repeated exposure if swallowed. Page: 14 SAFETY DATA SHEET Revision Date: 08/31/2018 Print Date: 10/30/2018 SDS Number: R0296766 ZEREX? G05? Antifreeze Coolant ZXG051 Version: 1.6 14 / 22 Components: ETHYLENE GLYCOL: Exposure routes : Ingestion Target Organs : Kidney, Liver Assessment : May cause damage to organs through prolonged or repeated exposure. DIETHYLENE GLYCOL: Exposure routes : Ingestion Target Organs : Kidney Assessment : May cause damage to organs through prolonged or repeated exposure. Aspiration toxicity Not classified based on available information. Product: No aspiration toxicity classification Experience with human exposure Components: ETHYLENE GLYCOL: Ingestion : Target Organs: Kidney DIETHYLENE GLYCOL: General Information : Liver Kidney Further information Product: Remarks : No data available SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Ecotoxicology Assessment Short-term (acute) aquatic hazard : Acute aquatic toxicity Category 3; Harmful to aquatic life. Long-term (chronic) aquatic hazard : Not classified based on available information. Components: ETHYLENE GLYCOL: Toxicity to fish : LC50 (Lepomis macrochirus (Bluegill sunfish)): 27,540 mg/l Exposure time: 96 h Test Type: static test LC50 (Pimephales promelas (fathead minnow)): 8,050 mg/l Page: 15 SAFETY DATA SHEET Revision Date: 08/31/2018 Print Date: 10/30/2018 SDS Number: R0296766 ZEREX? G05? Antifreeze Coolant ZXG051 Version: 1.6 15 / 22 Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : LC50 (Daphnia magna (Water flea)): > 10,000 mg/l Exposure time: 48 h Test Type: static test Toxicity to algae : EC50 (Pseudokirchneriella subcapitata (green algae)): 6,500 - 13,000 mg/l End point: Growth inhibition Exposure time: 7 Days Toxicity to fish (Chronic toxicity) : NOEC (Pimephales promelas (fathead minnow)): 32,000 mg/l Exposure time: 7 d Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): 24,000 mg/l Exposure time: 7 d DIETHYLENE GLYCOL: Toxicity to daphnia and other aquatic invertebrates : LC50 (Daphnia magna (Water flea)): > 10,000 mg/l Exposure time: 24 h Test Type: static test Method: DIN 38412 SODIUM BENZOATE: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): > 100 mg/l Exposure time: 96 h Test Type: static test Method: Static Remarks: Mortality Toxicity to daphnia and other aquatic invertebrates : LC50 (Daphnia magna (Water flea)): > 100 mg/l Exposure time: 96 h Test Type: static test Method: Static Remarks: Mortality DISODIUM TETRABORATE: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 79.7 mg/l Exposure time: 96 h Remarks: Information refers to the main component. Toxicity to algae : NOEC (Pseudokirchneriella subcapitata (green algae)): 17.5 mg/l End point: Growth inhibition Exposure time: 72 h Test Type: static test Method: OECD Test Guideline 201 Remarks: Information refers to the main component. Toxicity to fish (Chronic : NOEC (Danio rerio (zebra fish)): 5.6 mg/l Page: 16 SAFETY DATA SHEET Revision Date: 08/31/2018 Print Date: 10/30/2018 SDS Number: R0296766 ZEREX? G05? Antifreeze Coolant ZXG051 Version: 1.6 16 / 22 toxicity) Exposure time: 34 d Test Type: semi-static test Method: OECD Test Guideline 210 Remarks: Information refers to the main component. SODIUM NITRITE: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 2.35 - 3.81 mg/l Exposure time: 96 h Test Type: flow-through test LC50 (Oncorhynchus mykiss (rainbow trout)): 0.54 - 26.3 mg/l Exposure time: 96 h Test Type: flow-through test Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 15.4 mg/l Exposure time: 48 h Test Type: static test Method: OECD Test Guideline 202 Toxicity to algae : EC50 (Desmodesmus subspicatus (green algae)): > 100 mg/l Exposure time: 72 h Test Type: Growth inhibition Method: OECD Test Guideline 201 Toxicity to fish (Chronic toxicity) : NOEC (Ictalurus catus (catfish)): 6.16 mg/l Exposure time: 31 d Test Type: flow-through test Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Aquatic invertebrates): 9.86 mg/l Exposure time: 80 d Test Type: static test Toxicity to bacteria : EC10 (activated sludge): 210 mg/l Exposure time: 3 h Test Type: Static Method: OECD Test Guideline 209 SODIUM NITRATE: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 1,355 - 2,063 mg/l Exposure time: 96 h Method: Static Remarks: Mortality Toxicity to daphnia and other aquatic invertebrates : LC50 (Daphnia magna (Water flea)): 3,581 mg/l Exposure time: 48 h Method: Static LC50 (Daphnia magna (Water flea)): 665 mg/l Exposure time: 96 h Page: 17 SAFETY DATA SHEET Revision Date: 08/31/2018 Print Date: 10/30/2018 SDS Number: R0296766 ZEREX? G05? Antifreeze Coolant ZXG051 Version: 1.6 17 / 22 Method: Static Persistence and degradability Components: ETHYLENE GLYCOL: Biodegradability : Result: Readily biodegradable. Biodegradation: 90 - 100 % Exposure time: 10 d Method: OECD Test Guideline 301 DIETHYLENE GLYCOL: Biodegradability : Result: Readily biodegradable. Biodegradation: 70 - 80 % Exposure time: 28 d Method: OECD Test Guideline 301B SODIUM BENZOATE: Biodegradability : Result: Readily biodegradable. Biodegradation: 88 % Exposure time: 28 d Method: OECD Test Guideline 301 DISODIUM TETRABORATE: Biodegradability : Result: The methods for determining biodegradability are not applicable to inorganic substances. SODIUM NITRITE: Biodegradability : Result: The methods for determining biodegradability are not applicable to inorganic substances. No data available Bioaccumulative potential Components: ETHYLENE GLYCOL: Bioaccumulation : Species: Crayfish (Procambarus) Bioconcentration factor (BCF): 0.27 Exposure time: 61 d Concentration: 1000 mg/l Method: Flow through Partition coefficient: n- octanol/water : log Pow: -1.36 DIETHYLENE GLYCOL: Bioaccumulation : Species: Leuciscus idus (Golden orfe) Bioconcentration factor (BCF): 100 Partition coefficient: n- octanol/water : log Pow: -1.47 SODIUM NITRITE: Page: 18 SAFETY DATA SHEET Revision Date: 08/31/2018 Print Date: 10/30/2018 SDS Number: R0296766 ZEREX? G05? Antifreeze Coolant ZXG051 Version: 1.6 18 / 22 Partition coefficient: n- octanol/water : log Pow: -3.700 (25 ?C) No data available Mobility in soil Components: SODIUM NITRITE: Stability in soil : Remarks: Not expected to adsorb on soil. No data available Other adverse effects No data available Product: Additional ecological information : An environmental hazard cannot be excluded in the event of unprofessional handling or disposal., Harmful to aquatic life. Components: SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods General advice : The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company. Dispose of in accordance with all applicable local, state and federal regulations. Contaminated packaging : Empty remaining contents. Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. SECTION 14. TRANSPORT INFORMATION International transport regulations REGULATION ID NUMBER PROPER SHIPPING NAME *HAZARD CLASS SUBSIDIARY HAZARDS PACKING GROUP MARINE POLLUTANT / LTD. QTY. U.S. DOT - ROAD Not dangerous goods Page: 19 SAFETY DATA SHEET Revision Date: 08/31/2018 Print Date: 10/30/2018 SDS Number: R0296766 ZEREX? G05? Antifreeze Coolant ZXG051 Version: 1.6 19 / 22 CFR_RAIL_C Not dangerous goods U.S. DOT - INLAND WATERWAYS Not dangerous goods TDG_ROAD_C Not dangerous goods TDG_RAIL_C Not dangerous goods TDG_INWT_C Not dangerous goods INTERNATIONAL MARITIME DANGEROUS GOODS Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER Not dangerous goods MX_DG Not dangerous goods *ORM = ORM-D, CBL = COMBUSTIBLE LIQUID Marine pollutant no Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. SECTION 15. REGULATORY INFORMATION Page: 20 SAFETY DATA SHEET Revision Date: 08/31/2018 Print Date: 10/30/2018 SDS Number: R0296766 ZEREX? G05? Antifreeze Coolant ZXG051 Version: 1.6 20 / 22 EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) ETHYLENE GLYCOL 107-21-1 5000 5315 SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Acute toxicity (any route of exposure) Reproductive toxicity Specific target organ toxicity (single or repeated exposure) California Prop. 65 The components of this product are reported in the following inventories: DSL : All components of this product are on the Canadian DSL AICS : On the inventory, or in compliance with the inventory ENCS : Not in compliance with the inventory KECI : Not in compliance with the inventory PICCS : Not in compliance with the inventory IECSC : On the inventory, or in compliance with the inventory TSCA : On TSCA Inventory TSCA list The following substance(s) is/are subject to TSCA 12(b) export notification requirements: SODIUM NITRITE 7632-00-0 SECTION 16. OTHER INFORMATION Further information Revision Date: 08/31/2018 NFPA: HMIS III: Page: 21 SAFETY DATA SHEET Revision Date: 08/31/2018 Print Date: 10/30/2018 SDS Number: R0296766 ZEREX? G05? Antifreeze Coolant ZXG051 Version: 1.6 21 / 22 NFPA Flammable and Combustible Liquids Classification Combustible Liquid Class IIIB Full text of H-Statements H272 May intensify fire; oxidizer. H301 Toxic if swallowed. H302 Harmful if swallowed. H319 Causes serious eye irritation. H350 May cause cancer. H360 May damage fertility or the unborn child. H373 May cause damage to organs through prolonged or repeated exposure if swallowed. Sources of key data used to compile the Safety Data Sheet Valvoline internal data including own and sponsored test reports The UNECE administers regional agreements implementing harmonised classification for labelling (GHS) and transport. The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This SDS has been prepared by Valvoline's Environmental Health and Safety Department (1-800-VALVOLINE). List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade Flammability H e a lt h In s ta b ility 1 1 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 1* Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page: 22 SAFETY DATA SHEET Revision Date: 08/31/2018 Print Date: 10/30/2018 SDS Number: R0296766 ZEREX? G05? Antifreeze Coolant ZXG051 Version: 1.6 22 / 22 GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-statement : Hazard Statement IATA : International Air Transport Association. IATA-DGR : Dangerous Goods Regulation by the ?International Air Transport Association? (IATA). ICAO : International Civil Aviation Organization ICAO-TI (ICAO) : Technical Instructions by the ?International Civil Aviation Organization? IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization logPow : octanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population LDxx : Lethal Dose, for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit P-Statement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic PPE : Personal Protective Equipment STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity TLV : Threshold Limit Value TWA : Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act DOT : Department of Transportation FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association NIOSH : National Institute for Occupational Safety and Health OSHA : Occupational Safety and Health Administration PMRA : Health Canada Pest Management Regulatory Agency RTK : Right to Know WHMIS : Workplace Hazardous Materials Information System