Safety Data Sheet Revision Number: 006.1 Issue date: 11/25/2015 IDH number: 495536 Product name: LOCTITE SI 596 RTV SILICONE VERMELHO known as Loctite(R) RTV Red Sensor- Safe Page 1 of 9 1. PRODUCT AND COMPANY IDENTIFICATION Product name: LOCTITE SI 596 RTV SILICONE VERMELHO known as Loctite(R) RTV Red Sensor-Safe IDH number: 495536 Product type: Sealant Item number: 37528 Restriction of Use: None identified Region: United States Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067 Telephone: (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW WARNING: CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE IRRITATION. HAZARD CLASS HAZARD CATEGORY SKIN IRRITATION 2 EYE IRRITATION 2A SKIN SENSITIZATION 1 PICTOGRAM(S) Precautionary Statements Prevention: Avoid breathing vapors, mist, or spray. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wear eye and face protection. Wear protective gloves. Response: IF ON SKIN: Wash with plenty of water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation or rash occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing. Storage: Not prescribed Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS IDH number: 495536 Product name: LOCTITE SI 596 RTV SILICONE VERMELHO known as Loctite(R) RTV Red Sensor- Safe Page 2 of 9 Hazardous Component(s) CAS Number Percentage* Distillates (petroleum), hydrotreated middle 64742-46-7 5 - 10 Silicon dioxide 7631-86-9 5 - 10 Silicone Resin Proprietary 1 - 5 Diiron trioxide 1309-37-1 1 - 5 Substituted Silane Proprietary 1 - 5 Acetic acid 64-19-7 0.1 - 1 Substituted silane Proprietary 0.1 - 1 Hazardous Component(s) CAS Number Percentage* Dimethyl siloxane, hydroxyterminated 70131-67-8 60 - 100 Distillates (petroleum), hydrotreated middle 64742-46-7 5 - 10 Silicon dioxide 7631-86-9 5 - 10 Siloxanes and Silicones, di-Me 63148-62-9 1 - 5 Diiron trioxide 1309-37-1 1 - 5 Methylsilanetriyl triacetate 4253-34-3 1 - 5 Triacetoxyethylsilane 17689-77-9 1 - 5 Acetic acid 64-19-7 0.1 - 1 Gamma-glycidoxypropyl trimethoxysilane 2530-83-8 0.1 - 1 Barium sulfate 7727-43-7 0.1 - 1 Silicic acid, ethyl ester 11099-06-2 0.1 - 1 Silicon dioxide 7631-86-9 0.1 - 1 Amorphous fumed silica 68611-44-9 0.1 - 1 Tetraethyl silicate 78-10-4 0 - 0.1 Ethanol 64-17-5 0 - 0.1 Chromium 7440-47-3 0 - 0.1 Nickel 7440-02-0 0 - 0.1 Methanol 67-56-1 0 - 0.1 Arsenic 7440-38-2 0 - 0.1 * Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. If symptoms develop and persist, get medical attention. Skin contact: Wipe off paste with paper towel or cloth. Wash with soap and water. If skin irritation persists, call a physician. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If eye irritation persists, consult a specialist. Ingestion: Do not induce vomiting. If a person feels unwell or symptoms of skin irritation appear, consult a physician. Symptoms: See Section 11. Notes to physician: Treat symptomatically. 5. FIRE FIGHTING MEASURES Extinguishing media: Foam, dry chemical or carbon dioxide. Special firefighting procedures: None Unusual fire or explosion hazards: None IDH number: 495536 Product name: LOCTITE SI 596 RTV SILICONE VERMELHO known as Loctite(R) RTV Red Sensor- Safe Page 3 of 9 Hazardous combustion products: Silica mist. Formaldehyde. Acrid smoke and fumes. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Do not allow product to enter sewer or waterways. Clean-up methods: Maintain good ventilation for large spills. Store in a partly filled, closed container until disposal. Spilled material will solidify. Scrape up as much material as possible. 7. HANDLING AND STORAGE Handling: Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Storage: Keep container closed. Store in a dry area below 90? F. For information on product shelf life contact Henkel Customer Service at (800) 243-4874. IDH number: 495536 Product name: LOCTITE SI 596 RTV SILICONE VERMELHO known as Loctite(R) RTV Red Sensor- Safe Page 4 of 9 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Distillates (petroleum), hydrotreated middle 5 mg/m3 TWA Inhalable fraction. 5 mg/m3 PEL Mist. None None Silicon dioxide 6 mg/m3 TWA 20 MPPCF TWA 0.8 mg/m3 TWA None 3 mg/m3 TWA Respirable fraction. Silicone Resin None None None None Diiron trioxide 5 mg/m3 TWA Respirable fraction. 10 mg/m3 PEL Fume. None None Substituted Silane None None None None Acetic acid 15 ppm STEL 10 ppm TWA 10 ppm (25 mg/m3) PEL None None Substituted silane None None None None Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Dimethyl siloxane, hydroxyterminated None None None None Distillates (petroleum), hydrotreated middle 5 mg/m3 TWA Inhalable fraction. 5 mg/m3 PEL Mist. None None Silicon dioxide 6 mg/m3 TWA 20 MPPCF TWA 0.8 mg/m3 TWA None 3 mg/m3 TWA Respirable fraction. Siloxanes and Silicones, di-Me None None None None Diiron trioxide 5 mg/m3 TWA Respirable fraction. 10 mg/m3 PEL Fume. None None Methylsilanetriyl triacetate None None None None Triacetoxyethylsilane None None None None Acetic acid 15 ppm STEL 10 ppm TWA 10 ppm (25 mg/m3) PEL None None Gamma-glycidoxypropyl trimethoxysilane None None None None Barium sulfate 5 mg/m3 TWA Inhalable fraction. 5 mg/m3 PEL Respirable fraction. 15 mg/m3 PEL Total dust. None None Silicic acid, ethyl ester None None None None Silicon dioxide 6 mg/m3 TWA 20 MPPCF TWA 0.8 mg/m3 TWA None 3 mg/m3 TWA Respirable fraction. Amorphous fumed silica None None None None Tetraethyl silicate 10 ppm TWA 100 ppm (850 mg/m3) PEL None None Ethanol 1,000 ppm STEL 1,000 ppm (1,900 mg/m3) PEL None None Chromium 0.5 mg/m3 TWA (as Cr) 1 mg/m3 PEL (as Cr) None None Nickel 1.5 mg/m3 TWA Inhalable fraction. 1 mg/m3 PEL (as Ni) None None Methanol 200 ppm TWA (SKIN) 250 ppm STEL 200 ppm (260 mg/m3) PEL None None Arsenic 0.01 mg/m3 TWA (as As) 0.01 mg/m3 TWA 0.005 mg/m3 OSHA_ACT None None Engineering controls: Use only with adequate ventilation. Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s). IDH number: 495536 Product name: LOCTITE SI 596 RTV SILICONE VERMELHO known as Loctite(R) RTV Red Sensor- Safe Page 5 of 9 Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Skin protection: Use impermeable gloves and protective clothing as necessary to prevent skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid, Paste Color: Red Odor: Acetic acid Odor threshold: Not available. pH: Not applicable Vapor pressure: 13 hPa (21 ?C (69.8 ?F)) Boiling point/range: Not available. Melting point/ range: Not available. Specific gravity: 1.01 at 20 ?C (68?F) Vapor density: Heavier than air. Flash point: > 93 ?C (> 199.4 ?F) Flammable/Explosive limits - lower: 4 % (acetic acid) Flammable/Explosive limits - upper: 19.9 % (acetic acid) Autoignition temperature: Not available. Evaporation rate: Not available. Solubility in water: Not soluble. Polymerizes in presence of water. Solubility in water: Not determined Partition coefficient (n-octanol/water): Not available. VOC content: 3.08 %; 32 g/l Not available. Viscosity: Not available. Decomposition temperature: Not available. 10. STABILITY AND REACTIVITY Stability: Stable Hazardous reactions: Will not occur. Hazardous decomposition products: Acetic acid is liberated slowly upon contact with moisture. Formaldehyde. Incompatible materials: Acids. Water Bases. Oxidizing agents. Reactivity: Not available. Conditions to avoid: Exposure to moisture. Prolonged heating at temperatures above 150 ?C. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes IDH number: 495536 Product name: LOCTITE SI 596 RTV SILICONE VERMELHO known as Loctite(R) RTV Red Sensor- Safe Page 6 of 9 Potential Health Effects/Symptoms Inhalation: Acetic acid produced during cure may irritate eyes, nose and throat. When heated to temperatures exceeding 300? F (150? C) in the presence of air, silicones may form formaldehyde vapors. Formaldehyde is a potential cancer hazard and a known skin and respiratory sensitizer. Vapors irritate the eyes, nose and throat. Safe handling conditions may be maintained by keeping formaldehyde vapor concentrations below the OSHA permissible limit. Skin contact: Causes skin irritation. May cause allergic skin reaction. Eye contact: Causes serious eye irritation. Ingestion: Not expected to be harmful by ingestion. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Distillates (petroleum), hydrotreated middle None Irritant Silicon dioxide Oral LD50 (RAT) = > 22,500 mg/kg Nuisance dust Silicone Resin None Irritant Diiron trioxide None Allergen, Cardiac, Central nervous system, Irritant, Kidney, Liver, Lung Substituted Silane None Irritant, Allergen Acetic acid Oral LD50 (RABBIT) = 1,200 mg/kg Oral LD50 (RAT) = 3.53 g/kg Oral LD50 (RAT) = 3.31 g/kg Dermal LD50 (RABBIT) = 1,060 mg/kg Inhalation LC50 (RAT, 4 h) = 11.4 mg/l Allergen, Corrosive, Eyes, Gastrointestinal, Immune system, Irritant, Kidney Substituted silane None Allergen, Irritant Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Dimethyl siloxane, hydroxyterminated None No Target Organs Distillates (petroleum), hydrotreated middle None Irritant Silicon dioxide Oral LD50 (RAT) = > 22,500 mg/kg Nuisance dust Siloxanes and Silicones, di-Me None Irritant Diiron trioxide None Allergen, Cardiac, Central nervous system, Irritant, Kidney, Liver, Lung Methylsilanetriyl triacetate None Irritant, Allergen Triacetoxyethylsilane None No Target Organs Acetic acid Oral LD50 (RABBIT) = 1,200 mg/kg Oral LD50 (RAT) = 3.53 g/kg Oral LD50 (RAT) = 3.31 g/kg Dermal LD50 (RABBIT) = 1,060 mg/kg Inhalation LC50 (RAT, 4 h) = 11.4 mg/l Allergen, Corrosive, Eyes, Gastrointestinal, Immune system, Irritant, Kidney Gamma-glycidoxypropyl trimethoxysilane None Allergen, Irritant Barium sulfate None Lung Silicic acid, ethyl ester None No Target Organs Silicon dioxide Oral LD50 (RAT) = > 22,500 mg/kg Nuisance dust Amorphous fumed silica None No Target Organs Tetraethyl silicate None Central nervous system, Irritant, Kidney, Liver, Lung Ethanol Oral LD50 (RAT) = 9.9 g/kg Oral LD50 (RAT) = 6.2 g/kg Oral LD50 (RAT) = 17.8 g/kg Oral LD50 (RAT) = 11.5 g/kg Oral LD50 (RAT) = 10.6 g/kg Oral LD50 (RAT) = 7,060 mg/kg Inhalation LC50 (RAT, 10 h) = 20000 ppm Central nervous system, Irritant Chromium None Irritant, Allergen, Eyes Nickel None Allergen, Carcinogen, Irritant, Kidney, Mutagen, Reproductive, Respiratory IDH number: 495536 Product name: LOCTITE SI 596 RTV SILICONE VERMELHO known as Loctite(R) RTV Red Sensor- Safe Page 7 of 9 Methanol Oral LD50 (RAT) = 5,628 mg/kg Oral LD50 (RABBIT) = 14.4 g/kg Dermal LD50 (RABBIT) = 15,800 mg/kg Inhalation LC50 (RAT, 6 h) = 87.5 mg/l Inhalation LC50 (RAT, 4 h) = 64000 ppm Eyes, Heart, Irritant, Kidney, Liver, Metabolic, Nervous System, Reproductive Arsenic Oral LD50 (RAT) = 763 mg/kg Blood, Carcinogen, Cardiac, Gastrointestinal, Irritant, Kidney, Nervous System, Skin, Vascular Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Distillates (petroleum), hydrotreated middle No No No Silicon dioxide No No No Silicone Resin No No No Diiron trioxide No No No Substituted Silane No No No Acetic acid No No No Substituted silane No No No Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Dimethyl siloxane, hydroxyterminated No No No Distillates (petroleum), hydrotreated middle No No No Silicon dioxide No No No Siloxanes and Silicones, di-Me No No No Diiron trioxide No No No Methylsilanetriyl triacetate No No No Triacetoxyethylsilane No No No Acetic acid No No No Gamma-glycidoxypropyl trimethoxysilane No No No Barium sulfate No No No Silicic acid, ethyl ester No No No Silicon dioxide No No No Amorphous fumed silica No No No Tetraethyl silicate No No No Ethanol No No No Chromium No No No Nickel Reasonably Anticipated to be a Human Carcinogen. No No Methanol No No No Arsenic Known To Be Human Carcinogen. Group 1 Yes 12. ECOLOGICAL INFORMATION Ecological information: Not available. IDH number: 495536 Product name: LOCTITE SI 596 RTV SILICONE VERMELHO known as Loctite(R) RTV Red Sensor- Safe Page 8 of 9 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal. Cured rubber can be incinerated or landfilled following EPA and local regulations. Hazardous waste number: Not a RCRA hazardous waste. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None International Air Transportation (ICAO/IATA) Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None Water Transportation (IMO/IMDG) Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 (b) Export Notification: None above reporting de minimis CERCLA/SARA Section 302 EHS: None above reporting de minimis CERCLA/SARA Section 311/312: Immediate Health CERCLA/SARA Section 313: None above reporting de minimis California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format. Prepared by: Catherine Bimler, Regulatory Affairs Specialist Issue date: 11/25/2015 IDH number: 495536 Product name: LOCTITE SI 596 RTV SILICONE VERMELHO known as Loctite(R) RTV Red Sensor- Safe Page 9 of 9 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (?Henkel?) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user?s responsibility to determine the suitability of Henkel?s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel?s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel?s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits.