Safety Data Sheet Revision Number: 004.0 Issue date: 08/06/2014 IDH number: 495572 Product name: LOCTITE MR GS2 GASKET SEALANT known as LOCTITE? GASKET SEALANT 2 Page 1 of 6 1. PRODUCT AND COMPANY IDENTIFICATION Product name: LOCTITE MR GS2 GASKET SEALANT known as LOCTITE? GASKET SEALANT 2 IDH number: 495572 Product type: Sealant Item number: 37544 Restriction of Use: None identified Region: United States Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067 Telephone: (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW DANGER: CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE DAMAGE. MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED. HAZARD CLASS HAZARD CATEGORY SKIN IRRITATION 2 SERIOUS EYE DAMAGE 1 RESPIRATORY SENSITIZATION 1 SKIN SENSITIZATION 1 PICTOGRAM(S) Precautionary Statements Prevention: Avoid breathing dust or fumes. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wear eye and face protection. Wear protective gloves. In case of inadequate ventilation wear respiratory protection. Response: IF ON SKIN: Wash with plenty of soap and water. IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. Immediately call a poison control center or physician. If skin irritation or rash occurs: Get medical attention. If experiencing respiratory symptoms: Call a poison center or physician. Take off contaminated clothing. Storage: Not prescribed Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. IDH number: 495572 Product name: LOCTITE MR GS2 GASKET SEALANT known as LOCTITE? GASKET SEALANT 2 Page 2 of 6 Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* Kaolin 1332-58-7 30 - 60 Castor oil, oxidized 68187-84-8 10 - 30 Rosin 8050-09-7 10 - 30 Methyl acetate 79-20-9 10 - 30 Titanium dioxide 13463-67-7 1 - 5 Quartz (SiO2) 14808-60-7 0.1 - 1 Carbon black 1333-86-4 0.1 - 1 * Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and footwear. Wash clothing before reuse. Get medical attention. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Ingestion: Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention. Symptoms: See Section 11. 5. FIRE FIGHTING MEASURES Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide. Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Unusual fire or explosion hazards: Uncontrolled polymerization may occur at high temperatures resulting in explosions or rupture of storage containers. In case of fire, keep containers cool with water spray. Hazardous combustion products: Aldehydes. Oxides of carbon. Carboxylic acids. Irritating vapours. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Do not allow product to enter sewer or waterways. IDH number: 495572 Product name: LOCTITE MR GS2 GASKET SEALANT known as LOCTITE? GASKET SEALANT 2 Page 3 of 6 Clean-up methods: Remove all sources of ignition. Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective equipment during clean- up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Scrape up spilled material and place in a closed container for disposal. Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up. 7. HANDLING AND STORAGE Handling: Use only with adequate ventilation. Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Refer to Section 8. Storage: Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use. For information on product shelf life contact Henkel Customer Service at (800) 243-4874. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Kaolin 2 mg/m3 TWA Respirable fraction. 15 mg/m3 PEL Total dust. 5 mg/m3 PEL Respirable fraction. None None Castor oil, oxidized None None None None Rosin Exposure by all routes should be carefully controlled to levels as low as possible. Included in the regulation but with no data values. See regulation for further details None None None Methyl acetate 200 ppm TWA 250 ppm STEL 200 ppm (610 mg/m3) PEL None None Titanium dioxide 10 mg/m3 TWA 15 mg/m3 PEL Total dust. None None Quartz (SiO2) 0.025 mg/m3 TWA Respirable fraction. 2.4 MPPCF TWA Respirable. 0.1 mg/m3 TWA Respirable. 0.3 mg/m3 TWA Total dust. None None Carbon black 3 mg/m3 TWA Inhalable fraction. 3.5 mg/m3 PEL None None Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Respiratory protection: Use a NIOSH approved supplied air respirator if the potential to exceed established exposure limits exists. Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Safety showers and eye wash stations should be available. IDH number: 495572 Product name: LOCTITE MR GS2 GASKET SEALANT known as LOCTITE? GASKET SEALANT 2 Page 4 of 6 Skin protection: Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to prevent skin contact. Butyl rubber gloves. Neoprene gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Paste Color: Black Odor: Ester-like Odor threshold: Not available. pH: Not available. Vapor pressure: Not available. Boiling point/range: Not available. Melting point/ range: Not available. Specific gravity: 1.55 at 25 ?C (77?F) Vapor density: Not available. Flash point: Product is a solid. (ASTM D 4359) Flammable/Explosive limits - lower: Not determined Flammable/Explosive limits - upper: Not determined Autoignition temperature: Not available. Evaporation rate: Not available. Solubility in water: Partially soluble Partition coefficient (n-octanol/water): Not available. VOC content: 0.3 %; 4.65 g/l Viscosity: Not available. Decomposition temperature: Not available. 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions of storage and use. Hazardous reactions: None under normal processing. Hazardous decomposition products: Oxides of carbon. Aldehydes. Carboxylic acids. Irritating vapours. Incompatible materials: Strong oxidizing agents. Amines. Ammonia. Strong acids. Sulfuric acid. Nitric acid. Reactivity: Not available. Conditions to avoid: Heat, flames, sparks and other sources of ignition. Store away from incompatible materials. Elevated temperatures. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion IDH number: 495572 Product name: LOCTITE MR GS2 GASKET SEALANT known as LOCTITE? GASKET SEALANT 2 Page 5 of 6 Potential Health Effects/Symptoms Inhalation: May cause allergic respiratory reaction. These symptoms, which can include chest tightness, wheezing, cough, shortness of breath or asthma attack, could be immediate or delayed (up to several hours after exposure). May cause irritation to nose and throat. Skin contact: Causes skin irritation. May cause allergic skin reaction. Eye contact: Causes serious eye damage. Ingestion: May cause irritation to the gastrointestinal tract, mouth and mucous membranes. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Kaolin Oral LD50 (RAT) = > 5,000 mg/kg Dermal LD50 (RAT) = > 5,000 mg/kg Nuisance dust Castor oil, oxidized None No Records Rosin None Allergen, Irritant, Respiratory Methyl acetate Oral LD50 (RABBIT) = 3.7 g/kg Blood, Central nervous system, Eyes, Irritant Titanium dioxide None Irritant, Respiratory, Some evidence of carcinogenicity Quartz (SiO2) None Immune system, Lung, Some evidence of carcinogenicity Carbon black Oral LD50 (RAT) = > 8,000 mg/kg Respiratory, Some evidence of carcinogenicity Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Kaolin No No No Castor oil, oxidized No No No Rosin No No No Methyl acetate No No No Titanium dioxide No Group 2B No Quartz (SiO2) Known To Be Human Carcinogen. Group 1 No Carbon black No Group 2B No 12. ECOLOGICAL INFORMATION Ecological information: Not available. 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal. Hazardous waste number: Not a RCRA hazardous waste. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None International Air Transportation (ICAO/IATA) Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None IDH number: 495572 Product name: LOCTITE MR GS2 GASKET SEALANT known as LOCTITE? GASKET SEALANT 2 Page 6 of 6 Water Transportation (IMO/IMDG) Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 (b) Export Notification: Blown castor oil (CAS# 68187-84-8). CERCLA/SARA Section 302 EHS: None above reporting de minimis CERCLA/SARA Section 311/312: Immediate Health, Delayed Health CERCLA/SARA Section 313: None above reporting de minimis CERCLA Reportable quantity: Methyl acetate (CAS# 79-20-9) 100 lbs. (45.4 kg) California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format. Prepared by: Sheila Gines, Regulatory Affairs Specialist Issue date: 08/06/2014 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (?Henkel?) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user?s responsibility to determine the suitability of Henkel?s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel?s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel?s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits.