Safety Data Sheet Revision Number: 003.0 Issue date: 08/05/2014 IDH number: 495541 Product name: LOCTITE MR 5414 BLACK WEATHERSTRIP ADHESIVE known as LOCTITE? BLACK WEATHERSTRIP AD Page 1 of 7 1. PRODUCT AND COMPANY IDENTIFICATION Product name: LOCTITE MR 5414 BLACK WEATHERSTRIP ADHESIVE known as LOCTITE? BLACK WEATHERSTRIP AD IDH number: 495541 Product type: Contact adhesive Item number: 37532 Restriction of Use: None identified Region: United States Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067 Telephone: (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW DANGER: HIGHLY FLAMMABLE LIQUID AND VAPOR. MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS. HAZARD CLASS HAZARD CATEGORY FLAMMABLE LIQUID 2 SKIN IRRITATION 2 EYE IRRITATION 2A SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3 ASPIRATION HAZARD 1 PICTOGRAM(S) Precautionary Statements Prevention: Keep away from heat,sparks, open flames, hot surfaces - no smoking. Keep container tightly closed. No release into water. Use explosion-proof equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing vapors, mist, or spray. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves, eye protection, and face protection. Response: IF SWALLOWED: Immediately call a physician or poison control center. If on skin (or hair): Take off immediately all contaminated clothing. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. Call a poison control center or physician if you feel unwell. Do NOT induce vomiting. If skin irritation occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing. In case of fire: Use foam, dry chemical or carbon dioxide to extinguish. Storage: Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. IDH number: 495541 Product name: LOCTITE MR 5414 BLACK WEATHERSTRIP ADHESIVE known as LOCTITE? BLACK WEATHERSTRIP AD Page 2 of 7 Keep cool. Store locked up. Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* Methyl ethyl ketone 78-93-3 10 - 30 Toluene 108-88-3 10 - 30 Acetone 67-64-1 10 - 30 n-Hexane 110-54-3 10 - 30 Magnesium oxide 1309-48-4 5 - 10 Silica, amorphous, fumed, crystal-free 112945-52-5 5 - 10 Resin Proprietary 5 - 10 Carbon black 1333-86-4 0.1 - 1 * Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Move to fresh air in case of accidental inhalation of vapours. If breathing is difficult, give oxygen. If symptoms develop and persist, get medical attention. If not breathing, give artificial respiration. Skin contact: Wash with soap and water. If symptoms develop and persist, get medical attention. Eye contact: In case of contact with the eyes, rinse immediately with plenty of water for 15 minutes, and seek immediate medical attention. Ingestion: If material is ingested, immediately contact a physician or poison control center. Symptoms: See Section 11. 5. FIRE FIGHTING MEASURES Extinguishing media: Foam, dry chemical or carbon dioxide. Special firefighting procedures: Wear a self-contained breathing apparatus with a full face piece operated in pressure-demand or other positive pressure mode. Unusual fire or explosion hazards: Closed containers may rupture (due to build up of pressure) when exposed to extreme heat. Hazardous combustion products: Oxides of carbon. Irritating vapors. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Do not allow material to contaminate ground water system. IDH number: 495541 Product name: LOCTITE MR 5414 BLACK WEATHERSTRIP ADHESIVE known as LOCTITE? BLACK WEATHERSTRIP AD Page 3 of 7 Clean-up methods: Wipe up with adsorbent material (e.g. cloth, fleece). Scrape up spilled material and place in a closed container for disposal. 7. HANDLING AND STORAGE Handling: When using, do not eat, drink or smoke. Keep away from heat, spark and flame. Storage: Store away from ignition sources. Keep in a cool, well ventilated area. Keep container closed. For information on product shelf life contact Henkel Customer Service at (800) 243-4874. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Methyl ethyl ketone 200 ppm TWA 300 ppm STEL 200 ppm (590 mg/m3) PEL None None Toluene 20 ppm TWA 200 ppm TWA 300 ppm Ceiling 500 ppm MAX. CONC 10 minutes None None Acetone 750 ppm STEL 500 ppm TWA 1,000 ppm (2,400 mg/m3) PEL None None n-Hexane 50 ppm TWA (SKIN) 500 ppm (1,800 mg/m3) PEL None None Magnesium oxide 10 mg/m3 TWA Inhalable fraction. 15 mg/m3 PEL Total particulate. None None Silica, amorphous, fumed, crystal-free 10 mg/m3 TWA Inhalable dust. 3 mg/m3 TWA Respirable fraction. 20 MPPCF TWA 0.8 mg/m3 TWA None None Resin None None None None Carbon black 3 mg/m3 TWA Inhalable fraction. 3.5 mg/m3 PEL None None Engineering controls: Local exhaust ventilation is recommended when general ventilation is not sufficient to control airborne contamination. Ensure adequate ventilation, especially in confined areas. Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Skin protection: Use impermeable gloves and protective clothing as necessary to prevent skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Black Odor: Solvent Odor threshold: Not available. pH: Not available. Vapor pressure: Not available. Boiling point/range: Not available. Melting point/ range: Not available. Vapor density: Not available. Flash point: -24 ?C (-11.2 ?F) IDH number: 495541 Product name: LOCTITE MR 5414 BLACK WEATHERSTRIP ADHESIVE known as LOCTITE? BLACK WEATHERSTRIP AD Page 4 of 7 Flammable/Explosive limits - lower: Not available. Flammable/Explosive limits - upper: Not available. Autoignition temperature: Not available. Evaporation rate: Not available. Solubility in water: Not available. Partition coefficient (n-octanol/water): Not available. VOC content: 51.00 %; 452.00 g/l Viscosity: Not available. Decomposition temperature: Not available. 10. STABILITY AND REACTIVITY Stability: Stable Hazardous reactions: Will not occur. Hazardous decomposition products: Oxides of carbon. Irritating organic vapours. Incompatible materials: Acids and bases. Oxidizing agents. Reactivity: Not available. Conditions to avoid: Heat, flames, sparks and other sources of ignition. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion IDH number: 495541 Product name: LOCTITE MR 5414 BLACK WEATHERSTRIP ADHESIVE known as LOCTITE? BLACK WEATHERSTRIP AD Page 5 of 7 Potential Health Effects/Symptoms Inhalation: Vapours may cause drowsiness and dizziness. Skin contact: Causes skin irritation. Eye contact: Causes serious eye irritation. Ingestion: This product may be fatal if it is swallowed. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Methyl ethyl ketone Oral LD50 (RAT) = 2,300 - 3,500 mg/kg Oral LD50 (RAT) = 4,500 - 6,800 mg/kg Dermal LD50 (RABBIT) = > 8,000 mg/kg Inhalation LC50 (RAT, 4 h) = 11700 ppm Irritant, Central nervous system Toluene Oral LD50 (RAT) = 2.6 g/kg Oral LD50 (RAT) = 5,000 mg/kg Dermal LD50 (RABBIT) = 12,124 mg/kg Inhalation LC50 (RAT, 1 h) = 26700 ppm Inhalation LC50 (RAT, 2 h) = 12200 ppm Inhalation LC50 (RAT, 4 h) = 8000 ppm Behavioral, Cardiac, Central nervous system, Developmental, Ear, Irritant Acetone Oral LD50 (RABBIT) = 5,340 mg/kg Oral LD50 (RAT) = 5,800 mg/kg Oral LD50 (RAT) = 9,800 mg/kg Dermal LD50 (RABBIT) = 20,000 mg/kg Inhalation LC50 (RAT, 8 h) = 50.1 mg/l Inhalation LC50 (RAT, 4 h) = 76 mg/l Blood, Central nervous system, Irritant, Reproductive n-Hexane Oral LD50 (RAT) = 24 mg/kg Oral LD50 (RAT) = 43.5 mg/kg Oral LD50 (RAT) = 28,710 mg/kg Dermal LD50 (RABBIT) = > 2,000 mg/kg Inhalation LC50 (RAT, 4 h) = 73860 ppm Developmental, Irritant, Lung, Nervous System, Reproductive Magnesium oxide None Blood, Central nervous system, Immune system, Irritant Silica, amorphous, fumed, crystal-free None Nuisance dust Resin None Irritant, Allergen Carbon black Oral LD50 (RAT) = > 8,000 mg/kg Respiratory, Some evidence of carcinogenicity Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Methyl ethyl ketone No No No Toluene No No No Acetone No No No n-Hexane No No No Magnesium oxide No No No Silica, amorphous, fumed, crystal-free No No No Resin No No No Carbon black No Group 2B No 12. ECOLOGICAL INFORMATION Ecological information: Not available. IDH number: 495541 Product name: LOCTITE MR 5414 BLACK WEATHERSTRIP ADHESIVE known as LOCTITE? BLACK WEATHERSTRIP AD Page 6 of 7 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal. Hazardous waste number: D001: Ignitable. D035: Methyl Ethyl Ketone. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Adhesives Hazard class or division: 3 Identification number: UN 1133 Packing group: II DOT Hazardous Substance(s): Toluene, Methyl ethyl ketone International Air Transportation (ICAO/IATA) Proper shipping name: Adhesives Hazard class or division: 3 Identification number: UN 1133 Packing group: II Water Transportation (IMO/IMDG) Proper shipping name: ADHESIVES Hazard class or division: 3 Identification number: UN 1133 Packing group: II 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 (b) Export Notification: None above reporting de minimis CERCLA/SARA Section 302 EHS: None above reporting de minimis CERCLA/SARA Section 311/312: Immediate Health, Delayed Health, Fire CERCLA/SARA Section 313: This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Methyl ethyl ketone (CAS# 78-93-3). Toluene (CAS# 108-88-3). n-Hexane (CAS# 110-54-3). CERCLA Reportable quantity: Methyl ethyl ketone (CAS# 78-93-3) 5,000 lbs. (2,270 kg) Toluene (CAS# 108-88-3) 1,000 lbs. (454 kg) Acetone (CAS# 67-64-1) 5,000 lbs. (2,270 kg) n-Hexane (CAS# 110-54-3) 5,000 lbs. (2,270 kg) California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format. IDH number: 495541 Product name: LOCTITE MR 5414 BLACK WEATHERSTRIP ADHESIVE known as LOCTITE? BLACK WEATHERSTRIP AD Page 7 of 7 Prepared by: Catherine Bimler, Regulatory Affairs Specialist Issue date: 08/05/2014 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (?Henkel?) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user?s responsibility to determine the suitability of Henkel?s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel?s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel?s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits.