Safety Data Sheet Revision Number: 004.0 Issue date: 08/06/2014 IDH number: 1533652 Product name: LOCTITE 5113 THREAD SEALANT known as LOCTITE? THREAD SEALANT WITH P Page 1 of 6 1. PRODUCT AND COMPANY IDENTIFICATION Product name: LOCTITE 5113 THREAD SEALANT known as LOCTITE? THREAD SEALANT WITH P IDH number: 1533652 Product type: Sealant Item number: 1533652 Restriction of Use: None identified Region: United States Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067 Telephone: (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW WARNING: FLAMMABLE LIQUID AND VAPOR. CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS. HAZARD CLASS HAZARD CATEGORY FLAMMABLE LIQUID 3 SKIN IRRITATION 2 EYE IRRITATION 2A SKIN SENSITIZATION 1 SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3 PICTOGRAM(S) Precautionary Statements Prevention: Keep away from heat,sparks, open flames, hot surfaces - no smoking. Keep container tightly closed. No release into water. Use explosion-proof equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing vapors, mist, or spray. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves, eye protection, and face protection. Response: If on skin (or hair): Take off immediately all contaminated clothing. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. Call a poison control center or physician if you feel unwell. If skin irritation or rash occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing. In case of fire: Use foam, dry chemical or carbon dioxide to extinguish. Storage: Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up. IDH number: 1533652 Product name: LOCTITE 5113 THREAD SEALANT known as LOCTITE? THREAD SEALANT WITH P Page 2 of 6 Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* 2-Propanol 67-63-0 30 - 60 Talc 14807-96-6 10 - 30 Glyceridic oil Proprietary 10 - 30 Butyral resin Proprietary 10 - 30 Titanium dioxide 13463-67-7 1 - 5 Ethene, tetrafluoro-, homopolymer 9002-84-0 1 - 5 Quartz (SiO2) 14808-60-7 0.1 - 1 * Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and footwear. Wash clothing before reuse. Get medical attention. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Ingestion: Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention. Symptoms: See Section 11. 5. FIRE FIGHTING MEASURES Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide. Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Unusual fire or explosion hazards: Uncontrolled polymerization may occur at high temperatures resulting in explosions or rupture of storage containers. In case of fire, keep containers cool with water spray. Hazardous combustion products: Oxides of carbon. Toxic fluorides. Irritating vapors. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Do not allow product to enter sewer or waterways. IDH number: 1533652 Product name: LOCTITE 5113 THREAD SEALANT known as LOCTITE? THREAD SEALANT WITH P Page 3 of 6 Clean-up methods: Remove all sources of ignition. Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective equipment during clean- up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Scrape up as much material as possible. Store in a partly filled, closed container until disposal. Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up. 7. HANDLING AND STORAGE Handling: Use only with adequate ventilation. Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Refer to Section 8. Storage: Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use. For information on product shelf life contact Henkel Customer Service at (800) 243-4874. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER 2-Propanol 200 ppm TWA 400 ppm STEL 400 ppm (980 mg/m3) PEL None None Talc 2 mg/m3 TWA Respirable fraction. 20 MPPCF TWA 2.4 MPPCF TWA Respirable. 0.1 mg/m3 TWA Respirable. 0.3 mg/m3 TWA Total dust. None 50 ppm Glyceridic oil None None None None Butyral resin None None None None Titanium dioxide 10 mg/m3 TWA 15 mg/m3 PEL Total dust. None None Ethene, tetrafluoro-, homopolymer None None None 10 mg/m3 TWA Total dust. 5 mg/m3 TWA Respirable fraction. Quartz (SiO2) 0.025 mg/m3 TWA Respirable fraction. 2.4 MPPCF TWA Respirable. 0.1 mg/m3 TWA Respirable. 0.3 mg/m3 TWA Total dust. None None Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Safety showers and eye wash stations should be available. Skin protection: Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to prevent skin contact. Neoprene gloves. IDH number: 1533652 Product name: LOCTITE 5113 THREAD SEALANT known as LOCTITE? THREAD SEALANT WITH P Page 4 of 6 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Paste Color: White Odor: Alcoholic Odor threshold: Not available. pH: Not applicable Vapor pressure: 33 mm hg (20 ?C (68?F)) Boiling point/range: 82 ?C (179.6 ?F) Melting point/ range: Not determined Specific gravity: 1.12 at 25 ?C (77?F) Vapor density: 2.07 Flash point: 23 ?C (73.4 ?F) Tagliabue closed cup Flammable/Explosive limits - lower: 2.3 % Flammable/Explosive limits - upper: 12.7 % Autoignition temperature: 398.3 ?C (748.94 ?F) Estimated Evaporation rate: 7.7 (Ether = 1) Solubility in water: Partially soluble Partition coefficient (n-octanol/water): Not determined VOC content: 35.98 %; 343.43 g/l Viscosity: Not available. Decomposition temperature: Not available. 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions of storage and use. Hazardous reactions: None under normal processing. Hazardous decomposition products: Toxic fluorides. Oxides of carbon. Irritating vapors. Incompatible materials: Oxidizing agents. Acids. Aldehydes. Amines. Reactivity: Not available. Conditions to avoid: Heat, flames, sparks and other sources of ignition. Store away from incompatible materials. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion IDH number: 1533652 Product name: LOCTITE 5113 THREAD SEALANT known as LOCTITE? THREAD SEALANT WITH P Page 5 of 6 Potential Health Effects/Symptoms Inhalation: Inhalation of vapors or mists of the product may be irritating to the respiratory system. May cause dizziness, incoordination, headache, nausea, and vomiting. Skin contact: Causes skin irritation. May cause allergic skin reaction. Eye contact: Causes serious eye irritation. Ingestion: Ingestion can cause gastrointestinal irritation, nausea, vomiting and diarrhea. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects 2-Propanol Oral LD50 (RAT) = 5,045 mg/kg Oral LD50 (RABBIT) = 6,410 mg/kg Oral LD50 (RAT) = 4.7 g/kg Oral LD50 (RABBIT) = 8.0 g/kg Oral LD50 (RABBIT) = 5.03 g/kg Dermal LD50 (RABBIT) = 12,800 mg/kg Allergen, Blood, Brain, Central nervous system, Irritant, Kidney, Liver, Spleen Talc None Irritant, Lung, Some evidence of carcinogenicity Glyceridic oil None Irritant Butyral resin None No Records Titanium dioxide None Irritant, Respiratory, Some evidence of carcinogenicity Ethene, tetrafluoro-, homopolymer None No Target Organs Quartz (SiO2) None Immune system, Lung, Some evidence of carcinogenicity Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) 2-Propanol No No No Talc No Group 2B No Glyceridic oil No No No Butyral resin No No No Titanium dioxide No Group 2B No Ethene, tetrafluoro-, homopolymer No No No Quartz (SiO2) Known To Be Human Carcinogen. Group 1 No 12. ECOLOGICAL INFORMATION Ecological information: Not available. 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal. Hazardous waste number: D001: Ignitable. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Resin solution Hazard class or division: 3 Identification number: UN 1866 Packing group: III IDH number: 1533652 Product name: LOCTITE 5113 THREAD SEALANT known as LOCTITE? THREAD SEALANT WITH P Page 6 of 6 International Air Transportation (ICAO/IATA) Proper shipping name: Resin solution Hazard class or division: 3 Identification number: UN 1866 Packing group: III Exceptions: Consumer Commodity, ID 8000, Class 9, (Not more than 500 ml) Water Transportation (IMO/IMDG) Proper shipping name: RESIN SOLUTION Hazard class or division: 3 Identification number: UN 1866 Packing group: III 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 (b) Export Notification: Ethene, tetrafluoro-, homopolymer (CAS# 9002-84-0). CERCLA/SARA Section 302 EHS: None above reporting de minimis CERCLA/SARA Section 311/312: Immediate Health, Delayed Health, Fire CERCLA/SARA Section 313: None above reporting de minimis CERCLA Reportable quantity: 2-Propanol (CAS# 67-63-0) 100 lbs. (45.4 kg) California Proposition 65: This product contains a chemical known in the State of California to cause cancer. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format. Prepared by: Sheila Gines, Regulatory Affairs Specialist Issue date: 08/06/2014 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (?Henkel?) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user?s responsibility to determine the suitability of Henkel?s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel?s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel?s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits.