Marvel Mystery Oil Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. Date of issue: 06/19/2014 Revision date: 06/19/2014 Version: 1.0 06/19/2014 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : Marvel Mystery Oil Product code : MM13R 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Oil and Fuel Additive. 1.3. Details of the supplier of the safety data sheet Turtle Wax, Inc. C/O Marvel Oil Company 625 Willowbrook Centre Parkway Willowbrook, IL 60527 T 1 (630) 455-3862 1.4. Emergency telephone number Emergency number : CHEMTREC: 1 (800) 424-9300 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Flammable Liquid 3 Skin Irritation 2 Reproductive Toxicity 2 Aspiration Toxicity 1 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS02 GHS07 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : Flammable liquid and vapor. Causes skin irritation. Suspected of damaging fertility or the unborn child. May be fatal if swallowed and enters airways. Precautionary statements (GHS-US) : Keep away from heat/sparks/open flames/hot surfaces ? No smoking. Keep container tightly closed. Ground/Bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves/protective clothing/eye protection/face protection. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wash hands thoroughly after handling. If exposed or concerned: Get medical advice/attention. If on skin (or hair): Take off immediately all contaminated clothing and wash it before reuse. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. If swallowed: Immediately call a poison center or doctor. Do NOT induce vomiting. Store in a well-ventilated place. Keep cool. Dispose of contents and container in accordance with all local, regional, national and international regulations. 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) 25 % of the mixture consists of ingredient(s) of unknown acute toxicity. Marvel Mystery Oil Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/19/2014 EN (English) 2/7 SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % GHS-US classification Distillates, petroleum, hydrotreated heavy naphthenic (CAS No) 64742-52-5 60 - 100 Asp. Tox. 1 Stoddard solvent (CAS No) 8052-41-3 10 - 30 Flam. Liq. 3 Skin Irrit. 2 Asp. Tox. 1 Tricresyl phosphate (CAS No) 1330-78-5 0.1 - 1 Repr. 2 o-Dichlorobenzene (CAS No) 95-50-1 0.1 - 1 Flam. Liq. 4 Acute Tox. 4 (Oral) Acute Tox. 3 (Inhalation) Skin Irrit. 2 Eye Irrit. 2A STOT SE 3 p-Dichlorobenzene (CAS No) 106-46-7 < 0.1 Flam. Liq. 4 Eye Irrit. 2A Carc. 2 * The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of ?1910.1200. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. First-aid measures after skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician if irritation develops and persists. First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water. Remove contact lenses, if worn. If irritation persists, get medical attention. First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Never give anything by mouth to an unconscious person. Immediately call a POISON CENTER or doctor/physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : May cause respiratory tract irritation. Vapours may cause drowsiness and dizziness. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms/injuries after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. 4.3. Indication of any immediate medical attention and special treatment needed Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible). SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Dry chemical, foam, carbon dioxide. Unsuitable extinguishing media : None known. 5.2. Special hazards arising from the substance or mixture Fire hazard : Flammable liquid and vapour. Products of combustion may include, and are not limited to: oxides of carbon, hydrocarbons. 5.3. Advice for firefighters Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). Cool closed containers exposed to fire with water. Marvel Mystery Oil Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/19/2014 EN (English) 3/7 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Eliminate sources of ignition. 6.2. Methods and material for containment and cleaning up For containment : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Methods for cleaning up : Scoop up material and place in a disposal container. Vapours may be heavier than air and may travel along the ground to a distant ignition source and flash back. . Provide ventilation. 6.3. Reference to other sections See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Keep away from sources of ignition. - No smoking. Take precautionary measures against static discharge. Avoid contact with skin and eyes. Avoid breathing vapour or mist. Do not swallow. Handle and open container with care. When using do not eat, drink or smoke. Use only non- sparking tools. Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Storage conditions : Keep out of the reach of children. Keep container tightly closed. Keep in a cool, well-ventilated place. Keep from freezing. Do not store at temperatures above 49 ?C / 120 ?F. 7.3. Specific end use(s) Not available. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Distillates, petroleum, hydrotreated heavy naphthenic (64742-52-5) USA ACGIH ACGIH TWA Not applicable USA OSHA OSHA PEL (TWA) Not applicable Stoddard solvent (8052-41-3) USA ACGIH ACGIH TWA (ppm) 100 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 2900 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 500 ppm Tricresyl phosphate (1330-78-5) USA ACGIH ACGIH TWA Not applicable USA OSHA OSHA PEL (TWA) Not applicable o-Dichlorobenzene (95-50-1) USA ACGIH ACGIH TWA (ppm) 25 ppm USA ACGIH ACGIH STEL (ppm) 50 ppm USA OSHA OSHA PEL (Ceiling) (mg/m?) 300 mg/m? USA OSHA OSHA PEL (Ceiling) (ppm) 50 ppm p-Dichlorobenzene (106-46-7) USA ACGIH ACGIH TWA (ppm) 10 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 450 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 75 ppm Marvel Mystery Oil Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/19/2014 EN (English) 4/7 8.2. Exposure controls Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. Ensure that eyewash stations and safety showers are close to the workstation location. Hand protection : Wear chemically resistant protective gloves. Eye protection : Safety glasses or goggles are recommended when using product. Skin and body protection : Wear suitable protective clothing. Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Environmental exposure controls : Maintain levels below Community environmental protection thresholds. Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking. Handle according to established industrial hygiene and safety practices. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid. Appearance : Thin. Colour : Dark red. Odour : Oil of Wintergreen. Odour threshold : No data available. pH : No applicable. Relative evaporation rate (butylacetate=1) : No data available. Melting point : No data available. Freezing point : No data available. Boiling point : No data available. Flash point : 53 ?C (128 ?F) TCC Self ignition temperature : No data available. Decomposition temperature : No data available. Flammability (solid, gas) : Flammable. Vapour pressure : No data available. Relative vapour density at 20 ?C : No data available. Relative density : 0.876 @ 15.6 ?C (60 ?F) Solubility : No data available. Log Pow : No data available. Log Kow : No data available. Viscosity, kinematic : 2.0 - 3.0 cSt Viscosity, dynamic : No data available. Explosive properties : No data available. Oxidising properties : No data available. Explosive limits : No data available. 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reaction known under conditions of normal use. 10.2. Chemical stability Stable under normal storage conditions. May form flammable/explosive vapour-air mixture. 10.3. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. 10.4. Conditions to avoid Heat. Incompatible materials. Sources of ignition. Marvel Mystery Oil Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/19/2014 EN (English) 5/7 10.5. Incompatible materials Strong oxidizers. 10.6. Hazardous decomposition products May include, and are not limited to: oxides of carbon, hydrocarbons. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified. Marvel Mystery Oil LD50 oral rat > 2000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat > 20 mg/l/4h Distillates, petroleum, hydrotreated heavy naphthenic (64742-52-5) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 5000 mg/kg LC50 inhalation rat > 5.0 mg/l/4h Tricresyl phosphate (1330-78-5) LD50 oral rat 3 g/kg o-Dichlorobenzene (95-50-1) LD50 oral rat 500 mg/kg LD50 dermal rabbit > 10 g/kg LC50 inhalation rat 8.15 mg/l/4h p-Dichlorobenzene (106-46-7) LD50 oral rat > 2000 mg/kg LD50 dermal rabbit > 2 g/kg Skin corrosion/irritation : Causes skin irritation. Serious eye damage/irritation : Based on available data, the classification criteria are not met. Respiratory or skin sensitisation : Based on available data, the classification criteria are not met. Germ cell mutagenicity : Based on available data, the classification criteria are not met. Carcinogenicity : Based on available data, the classification criteria are not met. o-Dichlorobenzene (95-50-1) IARC group 3 - Not classifiable p-Dichlorobenzene (106-46-7) IARC group 2B - Possibly carcinogenic to humans National Toxicity Program (NTP) Status 1 - Evidence of Carcinogenicity, 3 - Reasonably anticipated to be Human Carcinogen Reproductive toxicity : Suspected of damaging fertility or the unborn child. Specific target organ toxicity (single exposure) : Based on available data, the classification criteria are not met. Specific target organ toxicity (repeated exposure) : Based on available data, the classification criteria are not met. Aspiration hazard : May be fatal if swallowed and enters airways. Symptoms/injuries after inhalation : May cause respiratory tract irritation. Vapours may cause drowsiness and dizziness. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms/injuries after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. Marvel Mystery Oil Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/19/2014 EN (English) 6/7 SECTION 12: Ecological information 12.1. Toxicity Ecology - general : May cause long-term adverse effects in the aquatic environment. 12.2. Persistence and degradability Marvel Mystery Oil Persistence and degradability Not established. 12.3. Bioaccumulative potential Marvel Mystery Oil Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Effect on ozone layer : No additional information available Effect on the global warming : No known ecological damage caused by this product. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : This material must be disposed of in accordance with all local, state, provincial, and federal regulations. The generation of waste should be avoided or minimized wherever possible. Additional information : Handle empty containers with care because residual vapours are flammable. SECTION 14: Transport information In accordance with DOT 14.1. UN number UN-No.(DOT) : 1268 14.2. UN proper shipping name DOT Proper Shipping Name : Petroleum distillates, n.o.s. Department of Transportation (DOT) Hazard Classes : 3 Hazard labels (DOT) : Packing group (DOT) : III 14.3. Additional information Other information : No supplementary information available. Special transport precautions : Do not handle until all safety precautions have been read and understood. SECTION 15: Regulatory information 15.1. US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory o-Dichlorobenzene (95-50-1) Listed on SARA Section 313 (Specific toxic chemical listings) EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA. SARA Section 313 - Emission Reporting 1.0 % p-Dichlorobenzene (106-46-7) Listed on SARA Section 313 (Specific toxic chemical listings) EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA. SARA Section 313 - Emission Reporting 0.1 % Marvel Mystery Oil Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/19/2014 EN (English) 7/7 15.2. US State regulations Marvel Mystery Oil State or local regulations This product contains a chemical known to the State of California to cause cancer. SECTION 16: Other information Indication of changes : None. Date of issue : 06/19/2014 Other information : None. NFPA health hazard : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. NFPA fire hazard : 2 - Must be moderately heated or exposed to relatively high temperature before ignition can occur. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product