SAFETY DATA SHEET GOJO? NATURAL* ORANGE? Pumice Hand Cleaner Version 1.0 SDS Number: 400000005275 Revision Date: 10/19/2016 1 / 12 SECTION 1. IDENTIFICATION Product name : GOJO? NATURAL* ORANGE? Pumice Hand Cleaner Manufacturer or supplier's details Company name of supplier : GOJO Industries, Inc. Address : One GOJO Plaza, Suite 500 Akron, Ohio 44311 Telephone : 1 (330) 255-6000 Emergency telephone number : 1-800-424-9300 CHEMTREC Recommended use of the chemical and restrictions on use Recommended use : Skin-care Restrictions on use : This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifi- cally defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this mate- rial is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet. SECTION 2. HAZARDS IDENTIFICATION GHS Classification Not a hazardous substance or mixture. GHS label elements Not a hazardous substance or mixture. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components Chemical name CAS-No. Concentration (%) Petroleum Distillates 64742-47-8 >= 5 - < 10 Limonene 5989-27-5 >= 0.1 - < 1 SAFETY DATA SHEET GOJO? NATURAL* ORANGE? Pumice Hand Cleaner Version 1.0 SDS Number: 400000005275 Revision Date: 10/19/2016 2 / 12 SECTION 4. FIRST AID MEASURES General advice : In the case of accident or if you feel unwell, seek medical ad- vice immediately. When symptoms persist or in all cases of doubt seek medical advice. If inhaled : If inhaled, remove to fresh air. If symptoms persist, call a physician. In case of skin contact : Wash with water and soap as a precaution. Get medical attention if irritation develops and persists. In case of eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn. Seek medical advice. If swallowed : If swallowed, DO NOT induce vomiting. Rinse mouth with water. Obtain medical attention. Most important symptoms and effects, both acute and delayed : None known. Protection of first-aiders : First Aid responders should pay attention to self-protection and use the recommended protective clothing SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or car- bon dioxide. Unsuitable extinguishing media : None known. Hazardous combustion prod- ucts : Carbon oxides Specific extinguishing meth- ods : Use extinguishing measures that are appropriate to local cir- cumstances and the surrounding environment. Use water spray to cool unopened containers. Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. SAFETY DATA SHEET GOJO? NATURAL* ORANGE? Pumice Hand Cleaner Version 1.0 SDS Number: 400000005275 Revision Date: 10/19/2016 3 / 12 SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protec- tive equipment and emer- gency procedures : Use personal protective equipment. Ensure adequate ventilation. Evacuate personnel to safe areas. Material can create slippery conditions. Environmental precautions : Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for containment and cleaning up : Keep in suitable, closed containers for disposal. Clean contaminated floors and objects thoroughly while ob- serving environmental regulations. SECTION 7. HANDLING AND STORAGE Advice on safe handling : For personal protection see section 8. Do not swallow. Avoid contact with eyes. Keep container closed when not in use. Conditions for safe storage : Keep in properly labelled containers. Keep container tightly closed in a dry and well-ventilated place. Store in accordance with the particular national regulations. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parame- ters / Permissible concentration Basis Petroleum Distillates 64742-47-8 TWA (Mist) 5 mg/m3 OSHA Z-1 TWA 200 mg/m3 (as total hydro- carbon vapor) ACGIH TWA (Mist) 5 mg/m3 NIOSH REL ST (Mist) 10 mg/m3 NIOSH REL Limonene 5989-27-5 TWA 20 ppm ACGIH Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally re- quired. Eye protection : No special protective equipment required. Wear face-shield and protective suit for abnormal processing SAFETY DATA SHEET GOJO? NATURAL* ORANGE? Pumice Hand Cleaner Version 1.0 SDS Number: 400000005275 Revision Date: 10/19/2016 4 / 12 problems. Skin and body protection : No special protective equipment required. Protective measures : Choose body protection in relation to its type, to the concen- tration and amount of dangerous substances, and to the spe- cific work-place. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Colour : grey, opaque Odour : citrus Odour Threshold : No data available pH : 6.0 - 8.0, (20 ?C) Solidification / Setting point : 11.4 ?C Initial boiling point and boiling range : 98.00 ?C Flash point : > 100 ?C Evaporation rate : No data available Upper explosion limit : No data available Lower explosion limit : No data available Vapour pressure : No data available Relative vapour density : No data available Density : 1.0328 g/cm3 Solubility(ies) Water solubility : soluble Partition coefficient: n- octanol/water : Not applicable Auto-ignition temperature : No data available Thermal decomposition : The substance or mixture is not classified self-reactive. Viscosity Viscosity, kinematic : 10000 - 50000 mm2/s (20 ?C) SAFETY DATA SHEET GOJO? NATURAL* ORANGE? Pumice Hand Cleaner Version 1.0 SDS Number: 400000005275 Revision Date: 10/19/2016 5 / 12 Explosive properties : Not explosive Oxidizing properties : The substance or mixture is not classified as oxidizing. SECTION 10. STABILITY AND REACTIVITY Reactivity : Not classified as a reactivity hazard. Chemical stability : Stable under normal conditions. Possibility of hazardous reac- tions : No dangerous reaction known under conditions of normal use. Incompatible materials : Oxidizing agents Hazardous decomposition products : No hazardous decomposition products are known. SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Eye contact Skin contact Acute toxicity Not classified based on available information. Components: Petroleum Distillates: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): > 5.3 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhala- tion toxicity Remarks: Based on data from similar materials Acute dermal toxicity : LD50 (Rabbit): > 3,160 mg/kg Assessment: The substance or mixture has no acute dermal toxicity Limonene: Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg Assessment: The substance or mixture has no acute oral tox- icity Remarks: Based on data from similar materials Skin corrosion/irritation Not classified based on available information. SAFETY DATA SHEET GOJO? NATURAL* ORANGE? Pumice Hand Cleaner Version 1.0 SDS Number: 400000005275 Revision Date: 10/19/2016 6 / 12 Components: Petroleum Distillates: Assessment: Repeated exposure may cause skin dryness or cracking. Limonene: Species: Rabbit Result: Skin irritation Serious eye damage/eye irritation Not classified based on available information. Components: Petroleum Distillates: Species: Rabbit Result: No eye irritation Limonene: Species: Rabbit Result: No eye irritation Respiratory or skin sensitisation Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information. Product: Assessment: Does not cause skin sensitisation. Components: Petroleum Distillates: Test Type: Maximisation Test (GPMT) Exposure routes: Skin contact Species: Guinea pig Result: negative Remarks: Based on data from similar materials Limonene: Test Type: Local lymph node assay (LLNA) Exposure routes: Skin contact Species: Mouse Result: positive Assessment: Probability or evidence of skin sensitisation in humans Germ cell mutagenicity Not classified based on available information. Components: Petroleum Distillates: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative Genotoxicity in vivo : Test Type: Chromosomal aberration Test species: Rat Application Route: Intraperitoneal injection SAFETY DATA SHEET GOJO? NATURAL* ORANGE? Pumice Hand Cleaner Version 1.0 SDS Number: 400000005275 Revision Date: 10/19/2016 7 / 12 Result: negative Remarks: Based on data from similar materials Limonene: Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test Result: negative Genotoxicity in vivo : Test Type: Transgenic rodent somatic cell gene mutation as- say Test species: Rat Application Route: Ingestion Result: negative Carcinogenicity Not classified based on available information. Components: Limonene: Species: Mouse Application Route: Ingestion Exposure time: 103 weeks Result: negative IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. Components: Petroleum Distillates: Effects on fertility : Test Type: One-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative Remarks: Based on data from similar materials Effects on foetal develop- ment : Test Type: Embryo-foetal development Species: Rat Application Route: Ingestion Result: negative STOT - single exposure Not classified based on available information. SAFETY DATA SHEET GOJO? NATURAL* ORANGE? Pumice Hand Cleaner Version 1.0 SDS Number: 400000005275 Revision Date: 10/19/2016 8 / 12 STOT - repeated exposure Not classified based on available information. Repeated dose toxicity Components: Petroleum Distillates: Species: Rat NOAEL: > 10.4 mg/l Application Route: inhalation (vapour) Exposure time: 90 d Remarks: Based on data from similar materials Limonene: Species: Rat NOAEL: 600 mg/kg Application Route: Ingestion Exposure time: 13 w Aspiration toxicity Not classified based on available information. Components: Petroleum Distillates: The substance or mixture is known to cause human aspiration toxicity hazards or has to be re- garded as if it causes a human aspiration toxicity hazard. Limonene: The substance or mixture is known to cause human aspiration toxicity hazards or has to be re- garded as if it causes a human aspiration toxicity hazard. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Components: Petroleum Distillates: Toxicity to fish : LL50 (Danio rerio (zebra fish)): > 250 mg/l Exposure time: 96 h Test substance: Water Accommodated Fraction Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EL50 (Acartia tonsa): > 3,193 mg/l Exposure time: 48 h Test substance: Water Accommodated Fraction Toxicity to algae : EL50 (Skeletonema costatum (marine diatom)): > 3,200 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction NOELR (Skeletonema costatum (marine diatom)): 993 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction SAFETY DATA SHEET GOJO? NATURAL* ORANGE? Pumice Hand Cleaner Version 1.0 SDS Number: 400000005275 Revision Date: 10/19/2016 9 / 12 Toxicity to daphnia and other aquatic invertebrates (Chron- ic toxicity) : NOELR (Ceriodaphnia Dubia (water flea)): > 70 mg/l Exposure time: 8 d Test substance: Water Accommodated Fraction Toxicity to bacteria : EC50: > 100 mg/l Exposure time: 3 h Limonene: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 0.72 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 0.36 mg/l Exposure time: 48 h Toxicity to algae : ErC50 (Desmodesmus subspicatus (green algae)): 150 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction Remarks: Based on data from similar materials M-Factor (Acute aquatic tox- icity) : 1 Persistence and degradability Components: Petroleum Distillates: Biodegradability : Result: Readily biodegradable. Biodegradation: 82 % Exposure time: 24 d Method: OECD Test Guideline 301F Limonene: Biodegradability : Result: Readily biodegradable. Biodegradation: 80 % Exposure time: 28 d Remarks: Based on data from similar materials Bioaccumulative potential Components: Limonene: Partition coefficient: n- octanol/water : log Pow: 4.38 Mobility in soil No data available Other adverse effects No data available Product: Regulation 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks This product neither contains, nor was manufactured with a SAFETY DATA SHEET GOJO? NATURAL* ORANGE? Pumice Hand Cleaner Version 1.0 SDS Number: 400000005275 Revision Date: 10/19/2016 10 / 12 Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with local regulations. Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste han- dling site for recycling or disposal. SECTION 14. TRANSPORT INFORMATION International Regulation IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good National Regulations 49 CFR Not regulated as a dangerous good SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : No SARA Hazards SARA 302 : No chemicals in this material are subject to the reporting re- quirements of SARA Title III, Section 302. SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Clean Air Act This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489). SAFETY DATA SHEET GOJO? NATURAL* ORANGE? Pumice Hand Cleaner Version 1.0 SDS Number: 400000005275 Revision Date: 10/19/2016 11 / 12 This product does not contain any VOC exemptions listed under the U.S. Clean Air Act Section 450. Clean Water Act This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 US State Regulations Massachusetts Right To Know Petroleum Distillates 64742-47-8 5 - 10 % Pennsylvania Right To Know Water (Aqua) 7732-18-5 70 - 90 % Pumice 1332-09-8 5 - 10 % Petroleum Distillates 64742-47-8 5 - 10 % New Jersey Right To Know Water (Aqua) 7732-18-5 70 - 90 % Pumice 1332-09-8 5 - 10 % Petroleum Distillates 64742-47-8 5 - 10 % California Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other re- productive harm. The components of this product are reported in the following inventories: TSCA : On TSCA Inventory CH INV : On the inventory, or in compliance with the inventory AICS : On the inventory, or in compliance with the inventory DSL : All components of this product are on the Canadian DSL. PICCS : On the inventory, or in compliance with the inventory ENCS : On the inventory, or in compliance with the inventory IECSC : On the inventory, or in compliance with the inventory ISHL : On the inventory, or in compliance with the inventory NZIoC : On the inventory, or in compliance with the inventory KECI : On the inventory, or in compliance with the inventory Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA) SAFETY DATA SHEET GOJO? NATURAL* ORANGE? Pumice Hand Cleaner Version 1.0 SDS Number: 400000005275 Revision Date: 10/19/2016 12 / 12 SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: Revision Date : 10/19/2016 The information provided in this Safety Data Sheet is correct to the best of our knowledge, in- formation and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Flammability H ea lth Instability 0 1 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 0 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic