SAFETY DATA SHEET GOJO? Cherry Gel Pumice Hand Cleaner Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36926-00002 Date of last issue: 12/15/2014 Date of first issue: 12/15/2014 1 / 14 SECTION 1. IDENTIFICATION Product name : GOJO? Cherry Gel Pumice Hand Cleaner Manufacturer or supplier's details Company name of supplier : GOJO Industries, Inc. Address : One GOJO Plaza, Suite 500 Akron OH 44311 Telephone : 1 (330) 255-6000 Emergency telephone : 1-800-424-9300 CHEMTREC Recommended use of the chemical and restrictions on use Recommended use : Skin-care Restrictions on use : This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet. SECTION 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids : Category 4 Serious eye damage : Category 1 GHS Label element Hazard pictograms : Signal Word : Danger Hazard Statements : H227 Combustible liquid. H318 Causes serious eye damage. SAFETY DATA SHEET GOJO? Cherry Gel Pumice Hand Cleaner Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36926-00002 Date of last issue: 12/15/2014 Date of first issue: 12/15/2014 2 / 14 Precautionary Statements : Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P280 Wear protective gloves/ eye protection/ face protection. Response: P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Other hazards Repeated exposure may cause skin dryness or cracking. Vapors may form explosive mixture with air. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous ingredients Chemical Name CAS-No. Concentration (%) Distillates (petroleum), hydrotreated light 64742-47-8 >= 20 - < 30 Ethoxylated branched C11-14, C13-rich alcohols 78330-21-9 >= 5 - < 10 SECTION 4. FIRST AID MEASURES General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice. If inhaled : If inhaled, remove to fresh air. Get medical attention if symptoms occur. In case of skin contact : Wash with water and soap as a precaution. Get medical attention if symptoms occur. In case of eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn. Get medical attention immediately. If swallowed : If swallowed, DO NOT induce vomiting. Get medical attention if symptoms occur. Rinse mouth thoroughly with water. Most important symptoms and effects, both acute and : Prolonged or repeated contact may dry skin and cause irritation. SAFETY DATA SHEET GOJO? Cherry Gel Pumice Hand Cleaner Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36926-00002 Date of last issue: 12/15/2014 Date of first issue: 12/15/2014 3 / 14 delayed Causes serious eye damage. Protection of first-aiders : First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists. Notes to physician : Treat symptomatically and supportively. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Water spray Alcohol-resistant foam Dry chemical Carbon dioxide (CO2) Unsuitable extinguishing media : High volume water jet Specific hazards during fire fighting : Do not use a solid water stream as it may scatter and spread fire. Flash back possible over considerable distance. Vapors may form explosive mixtures with air. Exposure to combustion products may be a hazard to health. Hazardous combustion prod- ucts : Carbon oxides Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area. Special protective equipment for fire-fighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Remove all sources of ignition. Use personal protective equipment. Follow safe handling advice and personal protective equipment recommendations. Environmental precautions : Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for : Non-sparking tools should be used. SAFETY DATA SHEET GOJO? Cherry Gel Pumice Hand Cleaner Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36926-00002 Date of last issue: 12/15/2014 Date of first issue: 12/15/2014 4 / 14 containment and cleaning up Soak up with inert absorbent material. Suppress (knock down) gases/vapors/mists with a water spray jet. For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements. SECTION 7. HANDLING AND STORAGE Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. Local/Total ventilation : Use with local exhaust ventilation. Use only in an area equipped with explosion proof exhaust ventilation. Advice on safe handling : Do not get on skin or clothing. Avoid inhalation of vapor or mist. Do not swallow. Do not get in eyes. Handle in accordance with good industrial hygiene and safety practice. Keep container tightly closed. Keep away from heat and sources of ignition. Take precautionary measures against static discharges. Take care to prevent spills, waste and minimize release to the environment. Conditions for safe storage : Keep in properly labeled containers. Keep tightly closed. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from heat and sources of ignition. Materials to avoid : Do not store with the following product types: Strong oxidizing agents Explosives Gases SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Ingredients CAS-No. Value type Control Basis SAFETY DATA SHEET GOJO? Cherry Gel Pumice Hand Cleaner Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36926-00002 Date of last issue: 12/15/2014 Date of first issue: 12/15/2014 5 / 14 (Form of exposure) parameters / Permissible concentration Distillates (petroleum), hydrotreated light 64742-47-8 TWA (Mist) 5 mg/m3 OSHA Z-1 TWA (Mist) 5 mg/m3 NIOSH REL ST (Mist) 10 mg/m3 NIOSH REL Hazardous components without workplace control parameters Ingredients CAS-No. Ethoxylated branched C11-14, C13-rich alcohols 78330-21-9 Engineering measures : Ensure adequate ventilation, especially in confined areas. Minimize workplace exposure concentrations. Use only in an area equipped with explosion proof exhaust ventilation. Dust formation may be relevant in the processing of this product. In addition to substance-specific OELs, general limitations of concentrations of particulates in the air at workplaces have to be considered in workplace risk assessment. Relevant limits include: OSHA PEL for Particulates Not Otherwise Regulated of 15 mg/m3 - total dust, 5 mg/m3 - respirable fraction; and ACGIH TWA for Particles (insoluble or poorly soluble) Not Otherwise Specified of 3 mg/m3 - respirable particles, 10 mg/m3 - inhalable particles. Personal protective equipment Respiratory protection : General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection. Hand protection Material : Impervious gloves Material : Flame retardant gloves Remarks : Choose gloves to protect hands against chemicals depending on the concentration specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday. SAFETY DATA SHEET GOJO? Cherry Gel Pumice Hand Cleaner Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36926-00002 Date of last issue: 12/15/2014 Date of first issue: 12/15/2014 6 / 14 Eye protection : Wear the following personal protective equipment: Chemical resistant goggles must be worn. If splashes are likely to occur, wear: Face-shield Skin and body protection : Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Wear the following personal protective equipment: Flame retardant antistatic protective clothing. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc). Hygiene measures : Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : gel Color : red, translucent Odor : fruity Odor Threshold : No data available pH : 6.5 - 8.0 Melting point/freezing point : No data available Initial boiling point and boiling range : No data available Flash point : 93 ?C Evaporation rate : No data available Flammability (solid, gas) : Not applicable Upper explosion limit : No data available Lower explosion limit : No data available Vapor pressure : No data available Relative vapor density : No data available Density : 1 g/cm3 Solubility(ies) SAFETY DATA SHEET GOJO? Cherry Gel Pumice Hand Cleaner Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36926-00002 Date of last issue: 12/15/2014 Date of first issue: 12/15/2014 7 / 14 Water solubility : soluble Partition coefficient: n- octanol/water : Not applicable Autoignition temperature : No data available Decomposition temperature : The substance or mixture is not classified self-reactive. Viscosity Viscosity, kinematic : 5,000 - 75,000 mm2/s (20 ?C) Explosive properties : Not explosive Oxidizing properties : The substance or mixture is not classified as oxidizing. SECTION 10. STABILITY AND REACTIVITY Reactivity : Not classified as a reactivity hazard. Chemical stability : Stable under normal conditions. Possibility of hazardous reac- tions : Combustible liquid. Vapors may form explosive mixture with air. Can react with strong oxidizing agents. Conditions to avoid : Heat, flames and sparks. Incompatible materials : Oxidizing agents Hazardous decomposition products : No hazardous decomposition products are known. SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Skin contact Ingestion Eye contact Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Ingredients: Distillates (petroleum), hydrotreated light: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): > 5.3 mg/l SAFETY DATA SHEET GOJO? Cherry Gel Pumice Hand Cleaner Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36926-00002 Date of last issue: 12/15/2014 Date of first issue: 12/15/2014 8 / 14 Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity Remarks: Based on data from similar materials Acute dermal toxicity : LD50 (Rabbit): > 3,160 mg/kg Assessment: The substance or mixture has no acute dermal toxicity Ethoxylated branched C11-14, C13-rich alcohols: Acute oral toxicity : Acute toxicity estimate: 500 mg/kg Method: Expert judgment Skin corrosion/irritation Not classified based on available information. Product: Result: No skin irritation Ingredients: Distillates (petroleum), hydrotreated light: Assessment: Repeated exposure may cause skin dryness or cracking. Ethoxylated branched C11-14, C13-rich alcohols: Species: Rabbit Result: No skin irritation Remarks: Based on data from similar materials Serious eye damage/eye irritation Causes serious eye damage. Ingredients: Distillates (petroleum), hydrotreated light: Species: Rabbit Result: No eye irritation Ethoxylated branched C11-14, C13-rich alcohols: Result: Irreversible effects on the eye Remarks: Based on data from similar materials Respiratory or skin sensitization Skin sensitization: Not classified based on available information. Respiratory sensitization: Not classified based on available information. Product: Assessment: Does not cause skin sensitization. Ingredients: Distillates (petroleum), hydrotreated light: Test Type: Maximization Test (GPMT) Routes of exposure: Skin contact SAFETY DATA SHEET GOJO? Cherry Gel Pumice Hand Cleaner Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36926-00002 Date of last issue: 12/15/2014 Date of first issue: 12/15/2014 9 / 14 Species: Guinea pig Result: negative Remarks: Based on data from similar materials Ethoxylated branched C11-14, C13-rich alcohols: Test Type: Human repeat insult patch test (HRIPT) Routes of exposure: Skin contact Result: negative Remarks: Based on data from similar materials Germ cell mutagenicity Not classified based on available information. Ingredients: Distillates (petroleum), hydrotreated light: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative Genotoxicity in vivo : Test Type: Chromosomal aberration Species: Rat Application Route: Intraperitoneal injection Result: negative Remarks: Based on data from similar materials Carcinogenicity Not classified based on available information. IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by OSHA. NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. Ingredients: Distillates (petroleum), hydrotreated light: Effects on fertility : Test Type: One-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative Remarks: Based on data from similar materials Effects on fetal development : Test Type: Embryo-fetal development Species: Rat Application Route: Ingestion Result: negative SAFETY DATA SHEET GOJO? Cherry Gel Pumice Hand Cleaner Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36926-00002 Date of last issue: 12/15/2014 Date of first issue: 12/15/2014 10 / 14 STOT-single exposure Not classified based on available information. STOT-repeated exposure Not classified based on available information. Repeated dose toxicity Ingredients: Distillates (petroleum), hydrotreated light: Species: Rat NOAEL: > 10.4 mg/l Application Route: inhalation (vapor) Exposure time: 90 d Remarks: Based on data from similar materials Aspiration toxicity Not classified based on available information. Product: No aspiration toxicity classification Ingredients: Distillates (petroleum), hydrotreated light: The substance or mixture is known to cause human aspiration toxicity hazards or has to be regarded as if it causes a human aspiration toxicity hazard. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Ingredients: Distillates (petroleum), hydrotreated light: Toxicity to fish : LL50 (Danio rerio (zebra fish)): > 250 mg/l Exposure time: 96 h Test substance: Water Accommodated Fraction Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EL50 (Acartia tonsa): > 3,193 mg/l Exposure time: 48 h Test substance: Water Accommodated Fraction Toxicity to algae : EL50 (Skeletonema costatum (marine diatom)): > 3,200 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction NOELR (Skeletonema costatum (marine diatom)): 993 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction Toxicity to daphnia and other : NOELR (Ceriodaphnia dubia (water flea)): > 70 mg/l SAFETY DATA SHEET GOJO? Cherry Gel Pumice Hand Cleaner Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36926-00002 Date of last issue: 12/15/2014 Date of first issue: 12/15/2014 11 / 14 aquatic invertebrates (Chronic toxicity) Exposure time: 8 d Test substance: Water Accommodated Fraction Toxicity to bacteria : EC50: > 100 mg/l Exposure time: 3 h Ethoxylated branched C11-14, C13-rich alcohols: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 5.6 mg/l Exposure time: 96 h Remarks: Based on data from similar materials Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 1 - 10 mg/l Exposure time: 48 h Remarks: Based on data from similar materials Toxicity to algae : EC50: > 1 - 10 mg/l Exposure time: 96 h Remarks: Based on data from similar materials Toxicity to fish (Chronic toxicity) : NOEC (Lepomis macrochirus (Bluegill sunfish)): > 0.33 mg/l Exposure time: 30 d Remarks: Based on data from similar materials Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): 0.77 mg/l Exposure time: 21 d Remarks: Based on data from similar materials Persistence and degradability Ingredients: Distillates (petroleum), hydrotreated light: Biodegradability : Result: Readily biodegradable. Biodegradation: 82 % Exposure time: 24 d Method: OECD Test Guideline 301F Ethoxylated branched C11-14, C13-rich alcohols: Biodegradability : Result: Readily biodegradable. Biodegradation: 95 % Exposure time: 28 d Method: OECD Test Guideline 301F Remarks: Based on data from similar materials Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available SAFETY DATA SHEET GOJO? Cherry Gel Pumice Hand Cleaner Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36926-00002 Date of last issue: 12/15/2014 Date of first issue: 12/15/2014 12 / 14 SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with local regulations. Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not burn, or use a cutting torch on, the empty drum. SECTION 14. TRANSPORT INFORMATION International Regulation UNRTDG Not regulated as a dangerous good IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. Domestic regulation 49 CFR UN/ID/NA number : NA 1993 Proper shipping name : COMBUSTIBLE LIQUID, N.O.S. (Fragrance - Cherry Bomb) Class : CBL Packing group : III Labels : None ERG Code : 128 Marine pollutant : no Remarks : Above applies only to containers over 119 gallons or 450 liters. Not regulated if shipped in packages less than or equal to 119 gallons (450 liters). SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity Ingredients CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Sodium hydroxide 1310-73-2 1000 * *: Calculated RQ exceeds reasonably attainable upper limit. SAFETY DATA SHEET GOJO? Cherry Gel Pumice Hand Cleaner Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36926-00002 Date of last issue: 12/15/2014 Date of first issue: 12/15/2014 13 / 14 SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Fire Hazard Acute Health Hazard SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. US State Regulations Pennsylvania Right To Know Water 7732-18-5 30 - 50 % Distillates (petroleum), hydrotreated light 64742-47-8 20 - 30 % Oleic acid 112-80-1 10 - 20 % Ethoxylated branched C11-14, C13-rich alcohols 78330-21-9 5 - 10 % Pumice 1332-09-8 5 - 10 % 2-Phenoxyethanol 122-99-6 0.1 - 1 % Sodium hydroxide 1310-73-2 0.1 - 1 % New Jersey Right To Know Water 7732-18-5 30 - 50 % Distillates (petroleum), hydrotreated light 64742-47-8 20 - 30 % Oleic acid 112-80-1 10 - 20 % Ethoxylated branched C11-14, C13-rich alcohols 78330-21-9 5 - 10 % Pumice 1332-09-8 5 - 10 % California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. The ingredients of this product are reported in the following inventories: AICS : All ingredients listed or exempt. Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), NECSI (Taiwan), TSCA (USA) SAFETY DATA SHEET GOJO? Cherry Gel Pumice Hand Cleaner Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36926-00002 Date of last issue: 12/15/2014 Date of first issue: 12/15/2014 14 / 14 SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: Full text of other abbreviations NIOSH REL : USA. NIOSH Recommended Exposure Limits OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim- its for Air Contaminants NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour workday during a 40-hour workweek NIOSH REL / ST : STEL - 15-minute TWA exposure that should not be exceeded at any time during a workday OSHA Z-1 / TWA : 8-hour time weighted average Sources of key data used to compile the Material Safety Data Sheet : Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agen- cy, http://echa.europa.eu/ Revision Date : 02/10/2015 The information provided in this Safety Data Sheet is correct to the best of our knowledge, in- formation and belief at the date of its publication. The information is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information pro- vided relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, un- less specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, in- cluding an assessment of the appropriateness of the SDS material in the user?s end product, if applicable. US / Z8 Flammability H e a lt h In s ta b ility 3 2 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 2 0 3 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic