SAFETY DATA SHEET GOJO? MULTI GREEN? Hand Cleaner GOJO? MULTI GREEN? Eco Hand Cleaner Version 1.4 SDS Number: 400000005228 Revision Date: 10/18/2018 1 / 13 SECTION 1. IDENTIFICATION Product name : GOJO? MULTI GREEN? Hand Cleaner GOJO? MULTI GREEN? Eco Hand Cleaner Manufacturer or supplier's details Company name of supplier : GOJO Industries, Inc. Address : One GOJO Plaza, Suite 500 Akron, Ohio 44311 Telephone : 1 (330) 255-6000 Emergency telephone number : CHEMTREC 1-800-424-9300 CHEMTREC +1-703-527-3887: Outside USA & CANADA Recommended use of the chemical and restrictions on use Recommended use : Skin-care Restrictions on use : This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet. SECTION 2. HAZARDS IDENTIFICATION GHS Classification Eye irritation : Category 2B GHS label elements Signal word : Warning Hazard statements : H320 Causes eye irritation. Precautionary statements : Response: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 2 / 13 SAFETY DATA SHEET GOJO? MULTI GREEN? Hand Cleaner GOJO? MULTI GREEN? Eco Hand Cleaner Version 1.4 SDS Number: 400000005228 Revision Date: 10/18/2018 P337 + P313 If eye irritation persists: Get medical advice/ attention. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components: GOJO? MULTI GREEN? Hand Cleaner Chemical name CAS-No. Concentration (%) Laureth-6 68439-50-9 >= 5 - < 10 Limonene 5989-27-5 >= 0.1 - < 1 Hazardous components: GOJO? MULTI GREEN? ECOPREFERRED? Hand Cleaner Chemical name CAS-No. Concentration (%) Laureth-6 68439-50-9 >= 5 - < 10 Limonene 5989-27-5 >= 0.1 - < 1 Sodium Hydroxymethylglycinate 70161-44-3 >= 0.1 - < 1 SECTION 4. FIRST AID MEASURES General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice. If inhaled : If inhaled, remove to fresh air. If symptoms persist, call a physician. In case of skin contact : Wash with water and soap as a precaution. Get medical attention if irritation develops and persists. In case of eye contact : Rinse thoroughly with plenty of water, also under the eyelids. If easy to do, remove contact lens, if worn. Seek medical advice. If swallowed : If swallowed, DO NOT induce vomiting. Rinse mouth with water. Obtain medical attention. Most important symptoms and effects, both acute and delayed : Causes eye irritation. Protection of first-aiders : First Aid responders should pay attention to self-protection and use the recommended protective clothing SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Water spray Alcohol-resistant foam Dry chemical Carbon dioxide (CO2) Unsuitable extinguishing media : None known. 3 / 13 SAFETY DATA SHEET GOJO? MULTI GREEN? Hand Cleaner GOJO? MULTI GREEN? Eco Hand Cleaner Version 1.4 SDS Number: 400000005228 Revision Date: 10/18/2018 Hazardous combustion products : Carbon oxides Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Ensure adequate ventilation. Evacuate personnel to safe areas. Material can create slippery conditions. Environmental precautions : Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for containment and cleaning up : Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. Clean contaminated floors and objects thoroughly while observing environmental regulations. SECTION 7. HANDLING AND STORAGE Advice on safe handling : For personal protection see section 8. Do not swallow. Avoid contact with eyes. Keep container closed when not in use. Conditions for safe storage : Keep in properly labelled containers. Keep containers tightly closed in a cool, well-ventilated place. Store in accordance with the particular national regulations. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of Control parameters / Basis 4 / 13 SAFETY DATA SHEET GOJO? MULTI GREEN? Hand Cleaner GOJO? MULTI GREEN? Eco Hand Cleaner Version 1.4 SDS Number: 400000005228 Revision Date: 10/18/2018 exposure) Permissible concentration Limonene 5989-27-5 TWA 20 ppm ACGIH Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally required. Eye protection : No special measures necessary provided product is used correctly. Wear face-shield and protective suit for abnormal processing problems. Skin and body protection : No special measures necessary provided product is used correctly. Protective measures : Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Colour : green, opaque Odour : citrus Odour Threshold : No data available pH : 6 - 9 Melting point/freezing point : No data available Initial boiling point and boiling range : 98 ?C Flash point : > 100 ?C Evaporation rate : No data available Flammability (solid, gas) : Not applicable Flammability (liquids) : No data available Upper explosion limit : No data available Lower explosion limit : No data available 5 / 13 SAFETY DATA SHEET GOJO? MULTI GREEN? Hand Cleaner GOJO? MULTI GREEN? Eco Hand Cleaner Version 1.4 SDS Number: 400000005228 Revision Date: 10/18/2018 Vapour pressure : No data available Relative vapour density : No data available Density : 1.033 g/cm3 Solubility(ies) Water solubility : soluble Partition coefficient: n- octanol/water : Not applicable Auto-ignition temperature : not determined Thermal decomposition : The substance or mixture is not classified self-reactive. Viscosity Viscosity, kinematic : 25000 - 45000 mm2/s (20 ?C) Explosive properties : Not explosive Oxidizing properties : The substance or mixture is not classified as oxidizing. SECTION 10. STABILITY AND REACTIVITY Reactivity : Not classified as a reactivity hazard. Chemical stability : Stable under normal conditions. Incompatible materials : Strong oxidizing agents Hazardous decomposition products : No hazardous decomposition products are known. SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Eye contact Skin contact Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method Components: Laureth-6: Acute oral toxicity : LD50 (Rat): > 500 - 2,000 mg/kg 6 / 13 SAFETY DATA SHEET GOJO? MULTI GREEN? Hand Cleaner GOJO? MULTI GREEN? Eco Hand Cleaner Version 1.4 SDS Number: 400000005228 Revision Date: 10/18/2018 Remarks: Based on data from similar materials Acute inhalation toxicity : LC50 (Rat): > 1.6 mg/l Exposure time: 4 h Test atmosphere: dust/mist Remarks: Based on data from similar materials Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg Remarks: Based on data from similar materials Limonene: Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg Assessment: The substance or mixture has no acute oral toxicity Remarks: Based on data from similar materials Sodium Hydroxymethylglycinate: Acute oral toxicity : LD50 (Rat): 1,050 mg/kg Skin corrosion/irritation Not classified based on available information. Product: Result: No skin irritation Components: Laureth-6: Species: Rabbit Result: No skin irritation Remarks: Based on data from similar materials Limonene: Species: Rabbit Result: Skin irritation Sodium Hydroxymethylglycinate: Species: Rabbit Result: Skin irritation Serious eye damage/eye irritation Causes eye irritation. Product: Result: Mild eye irritation Components: Laureth-6: Species: Rabbit Result: Irreversible effects on the eye Remarks: Based on data from similar materials 7 / 13 SAFETY DATA SHEET GOJO? MULTI GREEN? Hand Cleaner GOJO? MULTI GREEN? Eco Hand Cleaner Version 1.4 SDS Number: 400000005228 Revision Date: 10/18/2018 Limonene: Species: Rabbit Result: No eye irritation Sodium Hydroxymethylglycinate: Species: Rabbit Result: Irritation to eyes, reversing within 21 days Respiratory or skin sensitisation Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information. Product: Result: Does not cause skin sensitisation. Remarks: Patch test on human volunteers did not demonstrate sensitisation properties. Components: Laureth-6: Test Type: Maximisation Test (GPMT) Exposure routes: Skin contact Species: Guinea pig Method: OECD Test Guideline 406 Result: negative Remarks: Based on data from similar materials Limonene: Test Type: Local lymph node assay (LLNA) Exposure routes: Skin contact Species: Mouse Result: positive Assessment: Probability or evidence of skin sensitisation in humans Sodium Hydroxymethylglycinate: Test Type: Maximisation Test (GPMT) Exposure routes: Skin contact Species: Guinea pig Result: positive Assessment: Probability or evidence of skin sensitisation in humans Germ cell mutagenicity Not classified based on available information. Components: Laureth-6: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 Result: negative Remarks: Based on data from similar materials Limonene: 8 / 13 SAFETY DATA SHEET GOJO? MULTI GREEN? Hand Cleaner GOJO? MULTI GREEN? Eco Hand Cleaner Version 1.4 SDS Number: 400000005228 Revision Date: 10/18/2018 Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test Result: negative Genotoxicity in vivo : Test Type: Transgenic rodent somatic cell gene mutation assay Test species: Rat Application Route: Ingestion Result: negative Sodium Hydroxymethylglycinate: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative Genotoxicity in vivo : Test Type: Unscheduled DNA synthesis (UDS) test with mammali an liver cells in vivo Test species: Rat Result: negative Carcinogenicity Not classified based on available information. Components: Limonene: Species: Mouse Application Route: Ingestion Exposure time: 103 weeks Result: negative IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. Components: Sodium Hydroxymethylglycinate: Effects on foetal development : Species: Rat Application Route: Ingestion Result: negative STOT - single exposure Not classified based on available information. 9 / 13 SAFETY DATA SHEET GOJO? MULTI GREEN? Hand Cleaner GOJO? MULTI GREEN? Eco Hand Cleaner Version 1.4 SDS Number: 400000005228 Revision Date: 10/18/2018 STOT - repeated exposure Not classified based on available information. Repeated dose toxicity Components: Limonene: Species: Rat NOAEL: 600 mg/kg Application Route: Ingestion Exposure time: 13 w Aspiration toxicity Not classified based on available information. Components: Limonene: The substance or mixture is known to cause human aspiration toxicity hazards or has to be regarded as if it causes a human aspiration toxicity hazard. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Components: Laureth-6: Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 1 - 10 mg/l Exposure time: 48 h Remarks: Based on data from similar materials Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): > 0.1 - 1 mg/l Exposure time: 21 d Remarks: Based on data from similar materials Limonene: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 0.72 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 0.36 mg/l Exposure time: 48 h Toxicity to algae : ErC50 (Desmodesmus subspicatus (green algae)): 150 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction Remarks: Based on data from similar materials M-Factor (Acute aquatic toxicity) : 1 Toxicity to fish : LC50 (Danio rerio (zebra fish)): > 1 - 10 mg/l Exposure time: 96 h Remarks: Based on data from similar materials 10 / 13 SAFETY DATA SHEET GOJO? MULTI GREEN? Hand Cleaner GOJO? MULTI GREEN? Eco Hand Cleaner Version 1.4 SDS Number: 400000005228 Revision Date: 10/18/2018 Sodium Hydroxymethylglycinate: Toxicity to fish : LC50: > 10 - 100 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia pulex (Water flea)): > 10 - 100 mg/l Exposure time: 48 h Toxicity to algae : ErC50 (Desmodesmus subspicatus (Scenedesmus subspicatus)): > 10 - 100 mg/l Exposure time: 72 h Toxicity to bacteria : EC50: > 100 mg/l Exposure time: 120 h Persistence and degradability Components: Laureth-6: Biodegradability : Result: rapidly degradable Remarks: Based on data from similar materials Limonene: Biodegradability : Result: Readily biodegradable. Biodegradation: 80 % Exposure time: 28 d Remarks: Based on data from similar materials Sodium Hydroxymethylglycinate: Biodegradability : Result: Readily biodegradable. Bioaccumulative potential Components: Laureth-6: Bioaccumulation : Species: Fish Bioconcentration factor (BCF): < 500 Remarks: Based on data from similar materials Limonene: Partition coefficient: n- octanol/water : log Pow: 4.38 Sodium Hydroxymethylglycinate: Partition coefficient: n- octanol/water : log Pow: < 3 Mobility in soil No data available Other adverse effects No data available Product: Regulation 40 CFR Protection of Environment; Part 82 Protection of 11 / 13 SAFETY DATA SHEET GOJO? MULTI GREEN? Hand Cleaner GOJO? MULTI GREEN? Eco Hand Cleaner Version 1.4 SDS Number: 400000005228 Revision Date: 10/18/2018 Stratospheric Ozone - CAA Section 602 Class I Substances Remarks This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with local regulations. Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. SECTION 14. TRANSPORT INFORMATION International Regulation IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good National Regulations 49 CFR Not regulated as a dangerous good SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Acute Health Hazard SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Clean Air Act This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). 12 / 13 SAFETY DATA SHEET GOJO? MULTI GREEN? Hand Cleaner GOJO? MULTI GREEN? Eco Hand Cleaner Version 1.4 SDS Number: 400000005228 Revision Date: 10/18/2018 This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489). This product does not contain any VOC exemptions listed under the U.S. Clean Air Act Section 450. Clean Water Act This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 California Prop 65 This product does not require a warning label under California Proposition 65. The components of this product are reported in the following inventories: TSCA : On TSCA Inventory CH INV : On the inventory, or in compliance with the inventory AICS : On the inventory, or in compliance with the inventory DSL : On the inventory, or in compliance with the inventory ISHL : On the inventory, or in compliance with the inventory KECI : On the inventory, or in compliance with the inventory PICCS : On the inventory, or in compliance with the inventory ENCS : On the inventory, or in compliance with the inventory IECSC : On the inventory, or in compliance with the inventory NZIoC : On the inventory, or in compliance with the inventory Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA) 13 / 13 SAFETY DATA SHEET GOJO? MULTI GREEN? Hand Cleaner GOJO? MULTI GREEN? Eco Hand Cleaner Instability H ea lth Version 1.4 SDS Number: 400000005228 Revision Date: 10/18/2018 SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: Flammability 1 1 0 Special hazard. HEALTH 1 FLAMMABILITY 1 PHYSICAL HAZARD 0 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Revision Date : 10/18/2018 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. SECTION 1. IDENTIFICATION Other hazards SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS SECTION 10. STABILITY AND REACTIVITY Acute toxicity Product: Limonene: Product: Components: Limonene: Sodium Hydroxymethylglycinate: Serious eye damage/eye irritation Product: Components: Limonene: Sodium Hydroxymethylglycinate: Respiratory or skin sensitisation Product: Components: Limonene: Components: Components: Reproductive toxicity Components: STOT - repeated exposure Repeated dose toxicity Aspiration toxicity Components: SECTION 12. ECOLOGICAL INFORMATION Sodium Hydroxymethylglycinate: Other adverse effects Product: SARA 304 Extremely Hazardous Substances Reportable Quantity Clean Air Act Clean Water Act The components of this product are reported in the following inventories: SECTION 16. OTHER INFORMATION Further information