SAFETY DATA SHEET GOJO? Lemon Hand Cleaner Version 1.0 Revision Date: 02/12/2015 MSDS Number: 57077-00001 Date of last issue: - Date of first issue: 02/12/2015 1 / 20 SECTION 1. IDENTIFICATION Product name : GOJO? Lemon Hand Cleaner Manufacturer or supplier's details Company name of supplier : GOJO Industries, Inc. Address : One GOJO Plaza, Suite 500 Akron OH 44311 Telephone : 1 (330) 255-6000 Emergency telephone : 1-800-424-9300 CHEMTREC Recommended use of the chemical and restrictions on use Recommended use : Skin-care Restrictions on use : This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet. SECTION 2. HAZARDS IDENTIFICATION GHS Classification Serious eye damage : Category 1 GHS Label element Hazard pictograms : Signal Word : Danger Hazard Statements : H318 Causes serious eye damage. Precautionary Statements : Prevention: P280 Wear eye protection/ face protection. Response: SAFETY DATA SHEET GOJO? Lemon Hand Cleaner Version 1.0 Revision Date: 02/12/2015 MSDS Number: 57077-00001 Date of last issue: - Date of first issue: 02/12/2015 2 / 20 P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Other hazards Repeated exposure may cause skin dryness or cracking. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous ingredients Chemical Name CAS-No. Concentration (%) Distillates (petroleum), hydrotreated light 64742-47-8 >= 30 - < 50 White mineral oil (petroleum) 8042-47-5 >= 10 - < 20 Ethoxylated branched C11-14, C13-rich alcohols 78330-21-9 >= 1 - < 5 Propylene glycol 57-55-6 >= 1 - < 5 Petrolatum 8009-03-8 >= 1 - < 5 Sodium Hydroxymethylglycinate 70161-44-3 >= 0.1 - < 1 SECTION 4. FIRST AID MEASURES General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice. If inhaled : If inhaled, remove to fresh air. Get medical attention if symptoms occur. In case of skin contact : Wash with water and soap as a precaution. Get medical attention if symptoms occur. In case of eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn. Get medical attention immediately. If swallowed : If swallowed, DO NOT induce vomiting. Get medical attention if symptoms occur. Rinse mouth thoroughly with water. Most important symptoms and effects, both acute and delayed : Prolonged or repeated contact may dry skin and cause irritation. Causes serious eye damage. Protection of first-aiders : First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists. Notes to physician : Treat symptomatically and supportively. SAFETY DATA SHEET GOJO? Lemon Hand Cleaner Version 1.0 Revision Date: 02/12/2015 MSDS Number: 57077-00001 Date of last issue: - Date of first issue: 02/12/2015 3 / 20 SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Water spray Alcohol-resistant foam Dry chemical Carbon dioxide (CO2) Unsuitable extinguishing media : None known. Specific hazards during fire fighting : Exposure to combustion products may be a hazard to health. Hazardous combustion prod- ucts : Carbon oxides Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area. Special protective equipment for fire-fighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Follow safe handling advice and personal protective equipment recommendations. Environmental precautions : Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for containment and cleaning up : Soak up with inert absorbent material. For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding SAFETY DATA SHEET GOJO? Lemon Hand Cleaner Version 1.0 Revision Date: 02/12/2015 MSDS Number: 57077-00001 Date of last issue: - Date of first issue: 02/12/2015 4 / 20 certain local or national requirements. SECTION 7. HANDLING AND STORAGE Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. Local/Total ventilation : Use only with adequate ventilation. Advice on safe handling : Do not get on skin or clothing. Avoid inhalation of vapor or mist. Do not swallow. Do not get in eyes. Handle in accordance with good industrial hygiene and safety practice. Keep container tightly closed. Take care to prevent spills, waste and minimize release to the environment. Conditions for safe storage : Keep in properly labeled containers. Keep tightly closed. Store in accordance with the particular national regulations. Materials to avoid : Do not store with the following product types: Strong oxidizing agents SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Ingredients CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis Distillates (petroleum), hydrotreated light 64742-47-8 TWA (Mist) 5 mg/m3 OSHA Z-1 TWA (Mist) 5 mg/m3 NIOSH REL ST (Mist) 10 mg/m3 NIOSH REL White mineral oil (petroleum) 8042-47-5 TWA (Mist) 5 mg/m3 OSHA Z-1 TWA (Inhal- able fraction) 5 mg/m3 ACGIH TWA (Mist) 5 mg/m3 NIOSH REL ST (Mist) 10 mg/m3 NIOSH REL Propylene glycol 57-55-6 TWA 10 mg/m3 US WEEL Petrolatum 8009-03-8 TWA (Mist) 5 mg/m3 OSHA Z-1 TWA (Inhal- able fraction) 5 mg/m3 ACGIH TWA (Mist) 5 mg/m3 NIOSH REL ST (Mist) 10 mg/m3 NIOSH REL Hazardous components without workplace control parameters Ingredients CAS-No. SAFETY DATA SHEET GOJO? Lemon Hand Cleaner Version 1.0 Revision Date: 02/12/2015 MSDS Number: 57077-00001 Date of last issue: - Date of first issue: 02/12/2015 5 / 20 Ethoxylated branched C11-14, C13-rich alcohols 78330-21-9 Sodium Hydroxymethylglycinate 70161-44-3 Engineering measures : Ensure adequate ventilation, especially in confined areas. Minimize workplace exposure concentrations. Personal protective equipment Respiratory protection : General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection. Hand protection Material : Impervious gloves Remarks : Choose gloves to protect hands against chemicals depending on the concentration specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday. Eye protection : Wear the following personal protective equipment: Chemical resistant goggles must be worn. If splashes are likely to occur, wear: Face-shield Skin and body protection : Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc). Hygiene measures : Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : cream SAFETY DATA SHEET GOJO? Lemon Hand Cleaner Version 1.0 Revision Date: 02/12/2015 MSDS Number: 57077-00001 Date of last issue: - Date of first issue: 02/12/2015 6 / 20 Color : opaque, yellow Odor : citrus Odor Threshold : No data available pH : 8.5 Melting point/freezing point : No data available Initial boiling point and boiling range : No data available Flash point : > 100 ?C Evaporation rate : No data available Flammability (solid, gas) : Not applicable Upper explosion limit : No data available Lower explosion limit : No data available Vapor pressure : No data available Relative vapor density : No data available Density : 0.88 g/cm3 Solubility(ies) Water solubility : soluble Partition coefficient: n- octanol/water : Not applicable Autoignition temperature : No data available Decomposition temperature : The substance or mixture is not classified self-reactive. Viscosity Viscosity, kinematic : 25,000 - 50,000 mm2/s (20 ?C) Explosive properties : Not explosive Oxidizing properties : The substance or mixture is not classified as oxidizing. SECTION 10. STABILITY AND REACTIVITY Reactivity : Not classified as a reactivity hazard. Chemical stability : Stable under normal conditions. SAFETY DATA SHEET GOJO? Lemon Hand Cleaner Version 1.0 Revision Date: 02/12/2015 MSDS Number: 57077-00001 Date of last issue: - Date of first issue: 02/12/2015 7 / 20 Possibility of hazardous reac- tions : Can react with strong oxidizing agents. Conditions to avoid : None known. Incompatible materials : Oxidizing agents Hazardous decomposition products : No hazardous decomposition products are known. SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Skin contact Ingestion Eye contact Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Ingredients: Distillates (petroleum), hydrotreated light: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): > 5.3 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity Remarks: Based on data from similar materials Acute dermal toxicity : LD50 (Rabbit): > 3,160 mg/kg Assessment: The substance or mixture has no acute dermal toxicity White mineral oil (petroleum): Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): > 5 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity Ethoxylated branched C11-14, C13-rich alcohols: Acute oral toxicity : Acute toxicity estimate: 500 mg/kg SAFETY DATA SHEET GOJO? Lemon Hand Cleaner Version 1.0 Revision Date: 02/12/2015 MSDS Number: 57077-00001 Date of last issue: - Date of first issue: 02/12/2015 8 / 20 Method: Expert judgment Propylene glycol: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rabbit): > 159 mg/l, > 51091 ppm Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity Petrolatum: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Method: OECD Test Guideline 401 Remarks: Based on data from similar materials Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 402 Assessment: The substance or mixture has no acute dermal toxicity Remarks: Based on data from similar materials Sodium Hydroxymethylglycinate: Acute oral toxicity : LD50 (Rat): 1,050 mg/kg Skin corrosion/irritation Not classified based on available information. Product: Result: No skin irritation Ingredients: Distillates (petroleum), hydrotreated light: Assessment: Repeated exposure may cause skin dryness or cracking. White mineral oil (petroleum): Species: Rabbit Result: No skin irritation Ethoxylated branched C11-14, C13-rich alcohols: Species: Rabbit Result: No skin irritation Remarks: Based on data from similar materials Propylene glycol: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Petrolatum: SAFETY DATA SHEET GOJO? Lemon Hand Cleaner Version 1.0 Revision Date: 02/12/2015 MSDS Number: 57077-00001 Date of last issue: - Date of first issue: 02/12/2015 9 / 20 Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Remarks: Based on data from similar materials Sodium Hydroxymethylglycinate: Species: Rabbit Result: Skin irritation Serious eye damage/eye irritation Causes serious eye damage. Ingredients: Distillates (petroleum), hydrotreated light: Species: Rabbit Result: No eye irritation White mineral oil (petroleum): Species: Rabbit Result: No eye irritation Ethoxylated branched C11-14, C13-rich alcohols: Result: Irreversible effects on the eye Remarks: Based on data from similar materials Propylene glycol: Species: Rabbit Result: No eye irritation Method: OECD Test Guideline 405 Petrolatum: Species: Rabbit Result: No eye irritation Method: OECD Test Guideline 405 Remarks: Based on data from similar materials Sodium Hydroxymethylglycinate: Species: Rabbit Result: Irritation to eyes, reversing within 21 days Respiratory or skin sensitization Skin sensitization: Not classified based on available information. Respiratory sensitization: Not classified based on available information. Product: Assessment: Does not cause skin sensitization. Ingredients: Distillates (petroleum), hydrotreated light: Test Type: Maximization Test (GPMT) Routes of exposure: Skin contact Species: Guinea pig Result: negative SAFETY DATA SHEET GOJO? Lemon Hand Cleaner Version 1.0 Revision Date: 02/12/2015 MSDS Number: 57077-00001 Date of last issue: - Date of first issue: 02/12/2015 10 / 20 Remarks: Based on data from similar materials White mineral oil (petroleum): Test Type: Buehler Test Routes of exposure: Skin contact Species: Guinea pig Result: negative Ethoxylated branched C11-14, C13-rich alcohols: Test Type: Human repeat insult patch test (HRIPT) Routes of exposure: Skin contact Result: negative Remarks: Based on data from similar materials Propylene glycol: Test Type: Maximization Test (GPMT) Routes of exposure: Skin contact Species: Guinea pig Result: negative Petrolatum: Test Type: Buehler Test Routes of exposure: Skin contact Species: Guinea pig Result: negative Remarks: Based on data from similar materials Sodium Hydroxymethylglycinate: Test Type: Maximization Test (GPMT) Routes of exposure: Skin contact Species: Guinea pig Result: positive Assessment: Probability or evidence of skin sensitization in humans Germ cell mutagenicity Not classified based on available information. Ingredients: Distillates (petroleum), hydrotreated light: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative Genotoxicity in vivo : Test Type: Chromosomal aberration Species: Rat Application Route: Intraperitoneal injection Result: negative Remarks: Based on data from similar materials White mineral oil (petroleum): Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test Result: negative Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) SAFETY DATA SHEET GOJO? Lemon Hand Cleaner Version 1.0 Revision Date: 02/12/2015 MSDS Number: 57077-00001 Date of last issue: - Date of first issue: 02/12/2015 11 / 20 Species: Mouse Application Route: Intraperitoneal injection Method: OECD Test Guideline 474 Result: negative Remarks: Based on data from similar materials Propylene glycol: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative Genotoxicity in vivo : Test Type: In vivo micronucleus test Species: Mouse Application Route: Intraperitoneal injection Result: negative Petrolatum: Genotoxicity in vitro : Test Type: Chromosome aberration test in vitro Result: negative Remarks: Based on data from similar materials Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Species: Mouse Application Route: Intraperitoneal injection Method: OECD Test Guideline 474 Result: negative Remarks: Based on data from similar materials Sodium Hydroxymethylglycinate: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative Genotoxicity in vivo : Test Type: Unscheduled DNA synthesis (UDS) test with mammalian liver cells in vivo Species: Rat Result: negative Carcinogenicity Not classified based on available information. Ingredients: White mineral oil (petroleum): Species: Rat Application Route: Ingestion Exposure time: 24 Months Result: negative Propylene glycol: Species: Rat Application Route: Ingestion Exposure time: 2 Years Result: negative Petrolatum: Species: Rat SAFETY DATA SHEET GOJO? Lemon Hand Cleaner Version 1.0 Revision Date: 02/12/2015 MSDS Number: 57077-00001 Date of last issue: - Date of first issue: 02/12/2015 12 / 20 Application Route: Ingestion Exposure time: 2 Years Result: negative IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by OSHA. NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. Ingredients: Distillates (petroleum), hydrotreated light: Effects on fertility : Test Type: One-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative Remarks: Based on data from similar materials Effects on fetal development : Test Type: Embryo-fetal development Species: Rat Application Route: Ingestion Result: negative White mineral oil (petroleum): Effects on fertility : Test Type: One-generation reproduction toxicity study Species: Rat Application Route: Skin contact Result: negative Effects on fetal development : Test Type: Embryo-fetal development Species: Rat Application Route: Ingestion Result: negative Propylene glycol: Effects on fertility : Species: Mouse Application Route: Ingestion Result: negative Effects on fetal development : Test Type: Embryo-fetal development Species: Mouse Application Route: Ingestion Result: negative Petrolatum: Effects on fertility : Test Type: Reproduction/Developmental toxicity screening SAFETY DATA SHEET GOJO? Lemon Hand Cleaner Version 1.0 Revision Date: 02/12/2015 MSDS Number: 57077-00001 Date of last issue: - Date of first issue: 02/12/2015 13 / 20 test Species: Rat Application Route: Ingestion Result: negative Remarks: Based on data from similar materials Effects on fetal development : Test Type: Embryo-fetal development Species: Rat Application Route: Skin contact Result: negative Remarks: Based on data from similar materials Sodium Hydroxymethylglycinate: Effects on fetal development : Species: Rat Application Route: Ingestion Result: negative STOT-single exposure Not classified based on available information. STOT-repeated exposure Not classified based on available information. Repeated dose toxicity Ingredients: Distillates (petroleum), hydrotreated light: Species: Rat NOAEL: > 10.4 mg/l Application Route: inhalation (vapor) Exposure time: 90 d Remarks: Based on data from similar materials White mineral oil (petroleum): Species: Rat LOAEL: 160 mg/kg Application Route: Ingestion Exposure time: 90 d Species: Rat LOAEL: >= 1 mg/l Application Route: inhalation (dust/mist/fume) Exposure time: 4 w Method: OECD Test Guideline 412 Propylene glycol: Species: Rat NOAEL: 1,700 mg/kg Application Route: Ingestion Exposure time: 2 y Petrolatum: Species: Rat NOAEL: 5,000 mg/kg Application Route: Ingestion SAFETY DATA SHEET GOJO? Lemon Hand Cleaner Version 1.0 Revision Date: 02/12/2015 MSDS Number: 57077-00001 Date of last issue: - Date of first issue: 02/12/2015 14 / 20 Exposure time: 2 y Aspiration toxicity Not classified based on available information. Product: No aspiration toxicity classification Ingredients: Distillates (petroleum), hydrotreated light: The substance or mixture is known to cause human aspiration toxicity hazards or has to be regarded as if it causes a human aspiration toxicity hazard. White mineral oil (petroleum): The substance or mixture is known to cause human aspiration toxicity hazards or has to be regarded as if it causes a human aspiration toxicity hazard. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Ingredients: Distillates (petroleum), hydrotreated light: Toxicity to fish : LL50 (Danio rerio (zebra fish)): > 250 mg/l Exposure time: 96 h Test substance: Water Accommodated Fraction Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EL50 (Acartia tonsa): > 3,193 mg/l Exposure time: 48 h Test substance: Water Accommodated Fraction Toxicity to algae : EL50 (Skeletonema costatum (marine diatom)): > 3,200 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction NOELR (Skeletonema costatum (marine diatom)): 993 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOELR (Ceriodaphnia dubia (water flea)): > 70 mg/l Exposure time: 8 d Test substance: Water Accommodated Fraction Toxicity to bacteria : EC50: > 100 mg/l Exposure time: 3 h White mineral oil (petroleum): Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 SAFETY DATA SHEET GOJO? Lemon Hand Cleaner Version 1.0 Revision Date: 02/12/2015 MSDS Number: 57077-00001 Date of last issue: - Date of first issue: 02/12/2015 15 / 20 Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 100 mg/l Exposure time: 48 h Method: OECD Test Guideline 202 Toxicity to algae : NOEC (Pseudokirchneriella subcapitata (green algae)): 100 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Toxicity to fish (Chronic toxicity) : NOEC (Oncorhynchus mykiss (rainbow trout)): 1,000 mg/l Exposure time: 28 d Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): 1,000 mg/l Exposure time: 21 d Ethoxylated branched C11-14, C13-rich alcohols: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 5.6 mg/l Exposure time: 96 h Remarks: Based on data from similar materials Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 1 - 10 mg/l Exposure time: 48 h Remarks: Based on data from similar materials Toxicity to algae : EC50: > 1 - 10 mg/l Exposure time: 96 h Remarks: Based on data from similar materials Toxicity to fish (Chronic toxicity) : NOEC (Lepomis macrochirus (Bluegill sunfish)): > 0.33 mg/l Exposure time: 30 d Remarks: Based on data from similar materials Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): 0.77 mg/l Exposure time: 21 d Remarks: Based on data from similar materials Propylene glycol: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 40,613 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Ceriodaphnia dubia (water flea)): 18,340 mg/l Exposure time: 48 h Toxicity to algae : EC50 (Skeletonema costatum (marine diatom)): 19,000 mg/l Exposure time: 48 h Method: OECD Test Guideline 201 Toxicity to fish (Chronic toxicity) : Chronic Toxicity Value: 2,500 mg/l Exposure time: 30 d Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Ceriodaphnia dubia (water flea)): 29,000 mg/l Exposure time: 7 d SAFETY DATA SHEET GOJO? Lemon Hand Cleaner Version 1.0 Revision Date: 02/12/2015 MSDS Number: 57077-00001 Date of last issue: - Date of first issue: 02/12/2015 16 / 20 Toxicity to bacteria : NOEC (Pseudomonas putida): > 20,000 mg/l Exposure time: 18 h Petrolatum: Toxicity to fish : LL50 (Pimephales promelas (fathead minnow)): > 100 mg/l Exposure time: 96 h Test substance: Water Accommodated Fraction Method: OECD Test Guideline 203 Remarks: Based on data from similar materials Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 10,000 mg/l Exposure time: 48 h Test substance: Water Accommodated Fraction Remarks: Based on data from similar materials Toxicity to algae : NOEL (Pseudokirchneriella subcapitata (green algae)): >= 100 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction Method: OECD Test Guideline 201 Remarks: Based on data from similar materials Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): 10 mg/l Exposure time: 21 d Test substance: Water Accommodated Fraction Remarks: Based on data from similar materials Sodium Hydroxymethylglycinate: Toxicity to fish : LC50: > 10 - 100 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia pulex (Water flea)): > 10 - 100 mg/l Exposure time: 48 h Toxicity to algae : ErC50 (Desmodesmus subspicatus (Scenedesmus subspicatus)): > 10 - 100 mg/l Exposure time: 72 h Toxicity to bacteria : EC50: > 100 mg/l Exposure time: 120 h Persistence and degradability Ingredients: Distillates (petroleum), hydrotreated light: Biodegradability : Result: Readily biodegradable. Biodegradation: 82 % Exposure time: 24 d Method: OECD Test Guideline 301F White mineral oil (petroleum): Biodegradability : Result: Not readily biodegradable. Biodegradation: 31 % Exposure time: 28 d SAFETY DATA SHEET GOJO? Lemon Hand Cleaner Version 1.0 Revision Date: 02/12/2015 MSDS Number: 57077-00001 Date of last issue: - Date of first issue: 02/12/2015 17 / 20 Ethoxylated branched C11-14, C13-rich alcohols: Biodegradability : Result: Readily biodegradable. Biodegradation: 95 % Exposure time: 28 d Method: OECD Test Guideline 301F Remarks: Based on data from similar materials Propylene glycol: Biodegradability : Result: Readily biodegradable. Biodegradation: 98.3 % Exposure time: 28 d Method: OECD Test Guideline 301F Petrolatum: Biodegradability : Result: Not readily biodegradable. Biodegradation: 31 % Exposure time: 28 d Method: OECD Test Guideline 301F Remarks: Based on data from similar materials Sodium Hydroxymethylglycinate: Biodegradability : Result: Readily biodegradable. Bioaccumulative potential Ingredients: Propylene glycol: Partition coefficient: n- octanol/water : log Pow: -1.07 Sodium Hydroxymethylglycinate: Partition coefficient: n- octanol/water : log Pow: < 3 Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with local regulations. Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. SAFETY DATA SHEET GOJO? Lemon Hand Cleaner Version 1.0 Revision Date: 02/12/2015 MSDS Number: 57077-00001 Date of last issue: - Date of first issue: 02/12/2015 18 / 20 SECTION 14. TRANSPORT INFORMATION International Regulation UNRTDG Not regulated as a dangerous good IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. Domestic regulation 49 CFR Not regulated as a dangerous good SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity Ingredients CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Sodium hydroxide 1310-73-2 1000 * *: Calculated RQ exceeds reasonably attainable upper limit. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Acute Health Hazard SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. US State Regulations Pennsylvania Right To Know Distillates (petroleum), hydrotreated light 64742-47-8 30 - 50 % Water 7732-18-5 30 - 50 % White mineral oil (petroleum) 8042-47-5 10 - 20 % Oleic acid 112-80-1 5 - 10 % Ethoxylated branched C11-14, C13-rich alcohols 78330-21-9 1 - 5 % Propylene glycol 57-55-6 1 - 5 % SAFETY DATA SHEET GOJO? Lemon Hand Cleaner Version 1.0 Revision Date: 02/12/2015 MSDS Number: 57077-00001 Date of last issue: - Date of first issue: 02/12/2015 19 / 20 Petrolatum 8009-03-8 1 - 5 % Sodium hydroxide 1310-73-2 0.1 - 1 % New Jersey Right To Know Distillates (petroleum), hydrotreated light 64742-47-8 30 - 50 % Water 7732-18-5 30 - 50 % White mineral oil (petroleum) 8042-47-5 10 - 20 % Oleic acid 112-80-1 5 - 10 % Ethoxylated branched C11-14, C13-rich alcohols 78330-21-9 1 - 5 % Propylene glycol 57-55-6 1 - 5 % California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. The ingredients of this product are reported in the following inventories: REACH : All ingredients (pre-)registered or exempt. TSCA : All chemical substances in this product are either listed on the TSCA Inventory or are in compliance with a TSCA Inventory exemption. DSL : All chemical substances in this product comply with the CEPA 1999 and NSNR and are on or exempt from listing on the Canadian Domestic Substances List (DSL). AICS : All ingredients listed or exempt. Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), NECSI (Taiwan), TSCA (USA) SAFETY DATA SHEET GOJO? Lemon Hand Cleaner Version 1.0 Revision Date: 02/12/2015 MSDS Number: 57077-00001 Date of last issue: - Date of first issue: 02/12/2015 20 / 20 SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) NIOSH REL : USA. NIOSH Recommended Exposure Limits OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim- its for Air Contaminants US WEEL : USA. Workplace Environmental Exposure Levels (WEEL) ACGIH / TWA : 8-hour, time-weighted average NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour workday during a 40-hour workweek NIOSH REL / ST : STEL - 15-minute TWA exposure that should not be exceeded at any time during a workday OSHA Z-1 / TWA : 8-hour time weighted average US WEEL / TWA : 8-hr TWA Sources of key data used to compile the Material Safety Data Sheet : Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agen- cy, http://echa.europa.eu/ Revision Date : 02/12/2015 The information provided in this Safety Data Sheet is correct to the best of our knowledge, in- formation and belief at the date of its publication. The information is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provid- ed relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, un- less specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, in- cluding an assessment of the appropriateness of the SDS material in the user?s end product, if applicable. US / Z8 Flammability H e a lt h In s ta b ility 3 1 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 3 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic