SDS Repository

sds

Collection
GoJo
Description
 
Tags
Search Tag
Filename
0965_Hand_Cleaner.pdf
Source
 
Full Text
SAFETY DATA SHEET GOJO? ORIGINAL FORMULA? Hand Cleaner Version 1.1 SDS Number: 400000000198 Revision Date: 02/28/2018 1 / 19 SECTION 1. IDENTIFICATION Product name : GOJO? ORIGINAL FORMULA? Hand Cleaner Manufacturer or supplier's details Company name of supplier : GOJO Industries, Inc. Address : One GOJO Plaza, Suite 500 Akron, Ohio 44311 Telephone : 1 (330) 255-6000 Emergency telephone number : CHEMTREC 1-800-424-9300 CHEMTREC +1-703-527-3887: Outside USA & CANADA Recommended use of the chemical and restrictions on use Recommended use : Skin-care Restrictions on use : This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet. SECTION 2. HAZARDS IDENTIFICATION GHS Classification Serious eye damage : Category 1 GHS label elements Hazard pictograms : Signal word : Danger Hazard statements : H318 Causes serious eye damage. SAFETY DATA SHEET GOJO? ORIGINAL FORMULA? Hand Cleaner Version 1.1 SDS Number: 400000000198 Revision Date: 02/28/2018 2 / 19 Precautionary statements : Prevention: P280 Wear eye protection/ face protection. Response: P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components Chemical name CAS-No. Concentration (%) C11-15 Alkane/cycloalkane 64742-47-8 >= 30 - < 50 Mineral Oil (Paraffinum Liquidum) 8042-47-5 >= 10 - < 20 Trideceth-9 24938-91-8 >= 1 - < 5 Propylene Glycol 57-55-6 >= 1 - < 5 Petrolatum 8009-03-8 >= 1 - < 5 Sodium Hydroxymethylglycinate 70161-44-3 >= 0.1 - < 1 Chloroxylenol 88-04-0 >= 0.1 - < 1 SECTION 4. FIRST AID MEASURES General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice. If inhaled : If inhaled, remove to fresh air. If symptoms persist, call a physician. In case of skin contact : Wash with water and soap as a precaution. Get medical attention if irritation develops and persists. In case of eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn. Seek medical advice. If swallowed : If swallowed, DO NOT induce vomiting. Rinse mouth with water. Obtain medical attention. Most important symptoms and effects, both acute and delayed : Causes serious eye damage. Protection of first-aiders : First Aid responders should pay attention to self-protection and use the recommended protective clothing SAFETY DATA SHEET GOJO? ORIGINAL FORMULA? Hand Cleaner Version 1.1 SDS Number: 400000000198 Revision Date: 02/28/2018 3 / 19 SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Water spray Alcohol-resistant foam Dry chemical Carbon dioxide (CO2) Unsuitable extinguishing media : None known. Hazardous combustion products : Carbon oxides Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Ensure adequate ventilation. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Material can create slippery conditions. Environmental precautions : Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for containment and cleaning up : Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Keep in suitable, closed containers for disposal. Clean contaminated floors and objects thoroughly while observing environmental regulations. SECTION 7. HANDLING AND STORAGE Advice on safe handling : For personal protection see section 8. Do not swallow. SAFETY DATA SHEET GOJO? ORIGINAL FORMULA? Hand Cleaner Version 1.1 SDS Number: 400000000198 Revision Date: 02/28/2018 4 / 19 Avoid contact with eyes. Keep container closed when not in use. Conditions for safe storage : Keep in properly labelled containers. Keep container tightly closed in a dry and well-ventilated place. Store in accordance with the particular national regulations. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis C11-15 Alkane/cycloalkane 64742-47-8 TWA (Mist) 5 mg/m3 OSHA Z-1 TWA 200 mg/m3 (as total hydrocarbon vapor) ACGIH TWA (Mist) 5 mg/m3 NIOSH REL ST (Mist) 10 mg/m3 NIOSH REL Mineral Oil (Paraffinum Liquidum) 8042-47-5 TWA (Mist) 5 mg/m3 OSHA Z-1 TWA (Inhalable fraction) 5 mg/m3 ACGIH TWA (Mist) 5 mg/m3 NIOSH REL ST (Mist) 10 mg/m3 NIOSH REL TWA (Mist) 5 mg/m3 OSHA P0 Propylene Glycol 57-55-6 TWA 10 mg/m3 US WEEL Petrolatum 8009-03-8 TWA (Mist) 5 mg/m3 OSHA Z-1 TWA (Inhalable fraction) 5 mg/m3 ACGIH TWA (Mist) 5 mg/m3 NIOSH REL ST (Mist) 10 mg/m3 NIOSH REL TWA (Mist) 5 mg/m3 OSHA P0 Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally required. Hand protection Remarks : No special protective equipment required. Eye protection : Wear face-shield and protective suit for abnormal processing problems. Skin and body protection : No special measures necessary provided product is used correctly. Protective measures : Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to SAFETY DATA SHEET GOJO? ORIGINAL FORMULA? Hand Cleaner Version 1.1 SDS Number: 400000000198 Revision Date: 02/28/2018 5 / 19 the specific work-place. Ensure that eye flushing systems and safety showers are located close to the working place. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Colour : opaque, white, yellow Odour : solvent-like pH : 9.0, (20 ?C) Melting point/freezing point : No data available Initial boiling point and boiling range : 98 ?C Flash point : > 100 ?C Evaporation rate : No data available Flammability (solid, gas) : Not applicable Flammability (liquids) : No data available Upper explosion limit : No data available Lower explosion limit : No data available Vapour pressure : No data available Relative vapour density : No data available Density : 0.883 g/cm3 Solubility(ies) Water solubility : soluble Partition coefficient: n- octanol/water : Not applicable Auto-ignition temperature : No data available Thermal decomposition : The substance or mixture is not classified self-reactive. Viscosity Viscosity, kinematic : > 100000 mm2/s (20 ?C) SAFETY DATA SHEET GOJO? ORIGINAL FORMULA? Hand Cleaner Version 1.1 SDS Number: 400000000198 Revision Date: 02/28/2018 6 / 19 Explosive properties : Not explosive Oxidizing properties : The substance or mixture is not classified as oxidizing. SECTION 10. STABILITY AND REACTIVITY Reactivity : Not classified as a reactivity hazard. Chemical stability : Stable under normal conditions. Conditions to avoid : No data available Incompatible materials : Strong oxidizing agents Hazardous decomposition products : No hazardous decomposition products are known. SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Eye contact Skin contact Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method Components: C11-15 Alkane/cycloalkane: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): > 5.3 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity Remarks: Based on data from similar materials Acute dermal toxicity : LD50 (Rabbit): > 3,160 mg/kg Assessment: The substance or mixture has no acute dermal toxicity Mineral Oil (Paraffinum Liquidum): Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): > 5 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity SAFETY DATA SHEET GOJO? ORIGINAL FORMULA? Hand Cleaner Version 1.1 SDS Number: 400000000198 Revision Date: 02/28/2018 7 / 19 Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity Trideceth-9: Acute oral toxicity : LD50 (Rat): > 500 - < 2,000 mg/kg Propylene Glycol: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rabbit): > 159 mg/l, > 51091 ppm Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity Petrolatum: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Method: OECD Test Guideline 401 Remarks: Based on data from similar materials Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 402 Assessment: The substance or mixture has no acute dermal toxicity Remarks: Based on data from similar materials Sodium Hydroxymethylglycinate: Acute oral toxicity : LD50 (Rat): 1,050 mg/kg Chloroxylenol: Acute oral toxicity : Acute toxicity estimate : 500 mg/kg Method: Expert judgement Remarks: Based on harmonised classification in EU regulati on 1272/2008, Annex VI Acute inhalation toxicity : LC50 (Rat): > 6.29 mg/l Test atmosphere: dust/mist Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg Skin corrosion/irritation Not classified based on available information. Components: C11-15 Alkane/cycloalkane: Assessment: Repeated exposure may cause skin dryness or cracking. Mineral Oil (Paraffinum Liquidum): Species: Rabbit Result: No skin irritation SAFETY DATA SHEET GOJO? ORIGINAL FORMULA? Hand Cleaner Version 1.1 SDS Number: 400000000198 Revision Date: 02/28/2018 8 / 19 Trideceth-9: Species: Rabbit Result: No skin irritation Propylene Glycol: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Petrolatum: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Remarks: Based on data from similar materials Sodium Hydroxymethylglycinate: Species: Rabbit Result: Skin irritation Chloroxylenol: Result: Skin irritation Remarks: Based on harmonised classification in EU regulati on 1272/2008, Annex VI Serious eye damage/eye irritation Causes serious eye damage. Components: C11-15 Alkane/cycloalkane: Species: Rabbit Result: No eye irritation Mineral Oil (Paraffinum Liquidum): Species: Rabbit Result: No eye irritation Trideceth-9: Species: Rabbit Result: Irreversible effects on the eye Propylene Glycol: Species: Rabbit Result: No eye irritation Method: OECD Test Guideline 405 Petrolatum: Species: Rabbit Result: No eye irritation Method: OECD Test Guideline 405 Remarks: Based on data from similar materials Sodium Hydroxymethylglycinate: Species: Rabbit Result: Irritation to eyes, reversing within 21 days Chloroxylenol: SAFETY DATA SHEET GOJO? ORIGINAL FORMULA? Hand Cleaner Version 1.1 SDS Number: 400000000198 Revision Date: 02/28/2018 9 / 19 Result: Irreversible effects on the eye Respiratory or skin sensitisation Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information. Product: Result: Does not cause skin sensitisation. Remarks: Patch test on human volunteers did not demonstrate sensitisation properties. Components: C11-15 Alkane/cycloalkane: Test Type: Maximisation Test (GPMT) Exposure routes: Skin contact Species: Guinea pig Result: negative Remarks: Based on data from similar materials Mineral Oil (Paraffinum Liquidum): Test Type: Buehler Test Exposure routes: Skin contact Species: Guinea pig Result: negative Propylene Glycol: Test Type: Maximisation Test (GPMT) Exposure routes: Skin contact Species: Guinea pig Result: negative Petrolatum: Test Type: Buehler Test Exposure routes: Skin contact Species: Guinea pig Result: negative Remarks: Based on data from similar materials Sodium Hydroxymethylglycinate: Test Type: Maximisation Test (GPMT) Exposure routes: Skin contact Species: Guinea pig Result: positive Assessment: Probability or evidence of skin sensitisation in humans Chloroxylenol: Assessment: Probability or evidence of skin sensitisation in humans Remarks: Based on harmonised classification in EU regulati on 1272/2008, Annex VI Germ cell mutagenicity Not classified based on available information. Components: C11-15 Alkane/cycloalkane: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) SAFETY DATA SHEET GOJO? ORIGINAL FORMULA? Hand Cleaner Version 1.1 SDS Number: 400000000198 Revision Date: 02/28/2018 10 / 19 Result: negative Genotoxicity in vivo : Test Type: Chromosomal aberration Test species: Rat Application Route: Intraperitoneal injection Result: negative Remarks: Based on data from similar materials Mineral Oil (Paraffinum Liquidum): Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test Result: negative Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Test species: Mouse Application Route: Intraperitoneal injection Method: OECD Test Guideline 474 Result: negative Remarks: Based on data from similar materials Propylene Glycol: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative Genotoxicity in vivo : Test Type: In vivo micronucleus test Test species: Mouse Application Route: Intraperitoneal injection Result: negative Petrolatum: Genotoxicity in vitro : Test Type: Chromosome aberration test in vitro Result: negative Remarks: Based on data from similar materials Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Test species: Mouse Application Route: Intraperitoneal injection Method: OECD Test Guideline 474 Result: negative Remarks: Based on data from similar materials Sodium Hydroxymethylglycinate: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative Genotoxicity in vivo : Test Type: Unscheduled DNA synthesis (UDS) test with mammali an liver cells in vivo Test species: Rat Result: negative Chloroxylenol: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative Carcinogenicity SAFETY DATA SHEET GOJO? ORIGINAL FORMULA? Hand Cleaner Version 1.1 SDS Number: 400000000198 Revision Date: 02/28/2018 11 / 19 Not classified based on available information. Components: Mineral Oil (Paraffinum Liquidum): Species: Rat Application Route: Ingestion Exposure time: 24 Months Result: negative Propylene Glycol: Species: Rat Application Route: Ingestion Exposure time: 2 Years Result: negative Petrolatum: Species: Rat Application Route: Ingestion Exposure time: 2 Years Result: negative IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. Components: C11-15 Alkane/cycloalkane: Effects on fertility : Test Type: One-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative Remarks: Based on data from similar materials Effects on foetal development : Test Type: Embryo-foetal development Species: Rat Application Route: Ingestion Result: negative Mineral Oil (Paraffinum Liquidum): Effects on fertility : Test Type: One-generation reproduction toxicity study Species: Rat Application Route: Skin contact Result: negative SAFETY DATA SHEET GOJO? ORIGINAL FORMULA? Hand Cleaner Version 1.1 SDS Number: 400000000198 Revision Date: 02/28/2018 12 / 19 Effects on foetal development : Test Type: Embryo-foetal development Species: Rat Application Route: Ingestion Result: negative Propylene Glycol: Effects on fertility : Species: Mouse Application Route: Ingestion Result: negative Effects on foetal development : Test Type: Embryo-foetal development Species: Mouse Application Route: Ingestion Result: negative Petrolatum: Effects on fertility : Test Type: Reproduction/Developmental toxicity screening tes t Species: Rat Application Route: Ingestion Result: negative Remarks: Based on data from similar materials Effects on foetal development : Test Type: Embryo-foetal development Species: Rat Application Route: Skin contact Result: negative Remarks: Based on data from similar materials Sodium Hydroxymethylglycinate: Effects on foetal development : Species: Rat Application Route: Ingestion Result: negative STOT - single exposure Not classified based on available information. STOT - repeated exposure Not classified based on available information. Repeated dose toxicity Components: C11-15 Alkane/cycloalkane: Species: Rat NOAEL: > 10.4 mg/l Application Route: inhalation (vapour) Exposure time: 90 d Remarks: Based on data from similar materials Mineral Oil (Paraffinum Liquidum): Species: Rat LOAEL: 160 mg/kg Application Route: Ingestion Exposure time: 90 d SAFETY DATA SHEET GOJO? ORIGINAL FORMULA? Hand Cleaner Version 1.1 SDS Number: 400000000198 Revision Date: 02/28/2018 13 / 19 Species: Rat LOAEL: >= 1 mg/l Application Route: inhalation (dust/mist/fume) Exposure time: 4 w Method: OECD Test Guideline 412 Propylene Glycol: Species: Rat NOAEL: 1,700 mg/kg Application Route: Ingestion Exposure time: 2 y Petrolatum: Species: Rat NOAEL: 5,000 mg/kg Application Route: Ingestion Exposure time: 2 y Chloroxylenol: Species: Rabbit LOAEL: 180 mg/kg Application Route: Skin contact Exposure time: 90 d Aspiration toxicity Not classified based on available information. Components: C11-15 Alkane/cycloalkane: The substance or mixture is known to cause human aspiration toxicity hazards or has to be regarded as if it causes a human aspiration toxicity hazard. Mineral Oil (Paraffinum Liquidum): The substance or mixture is known to cause human aspiration toxicity hazards or has to be regarded as if it causes a human aspiration toxicity hazard. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Components: C11-15 Alkane/cycloalkane: Toxicity to fish : LL50 (Danio rerio (zebra fish)): > 250 mg/l Exposure time: 96 h Test substance: Water Accommodated Fraction Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EL50 (Acartia tonsa): > 3,193 mg/l Exposure time: 48 h Test substance: Water Accommodated Fraction Toxicity to algae : EL50 (Skeletonema costatum (marine diatom)): > 3,200 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction SAFETY DATA SHEET GOJO? ORIGINAL FORMULA? Hand Cleaner Version 1.1 SDS Number: 400000000198 Revision Date: 02/28/2018 14 / 19 NOELR (Skeletonema costatum (marine diatom)): 993 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOELR (Ceriodaphnia Dubia (water flea)): > 70 mg/l Exposure time: 8 d Test substance: Water Accommodated Fraction Toxicity to bacteria : EC50: > 100 mg/l Exposure time: 3 h Mineral Oil (Paraffinum Liquidum): Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 100 mg/l Exposure time: 48 h Method: OECD Test Guideline 202 Toxicity to algae : NOEC (Pseudokirchneriella subcapitata (green algae)): 100 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Toxicity to fish (Chronic toxicity) : NOEC (Oncorhynchus mykiss (rainbow trout)): 1,000 mg/l Exposure time: 28 d Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): 1,000 mg/l Exposure time: 21 d Trideceth-9: Toxicity to fish : LC50 (Leuciscus idus (Golden orfe)): > 1 - 10 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50: > 1 - 10 mg/l Exposure time: 48 h Toxicity to algae : EC50: > 1 - 10 mg/l Exposure time: 72 h Propylene Glycol: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 40,613 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Ceriodaphnia Dubia (water flea)): 18,340 mg/l Exposure time: 48 h Toxicity to algae : EC50 (Skeletonema costatum (marine diatom)): 19,000 mg/l Exposure time: 48 h Method: OECD Test Guideline 201 Toxicity to fish (Chronic toxicity) : Chronic Toxicity Value: 2,500 mg/l Exposure time: 30 d SAFETY DATA SHEET GOJO? ORIGINAL FORMULA? Hand Cleaner Version 1.1 SDS Number: 400000000198 Revision Date: 02/28/2018 15 / 19 Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Ceriodaphnia Dubia (water flea)): 29,000 mg/l Exposure time: 7 d Toxicity to bacteria : NOEC (Pseudomonas putida): > 20,000 mg/l Exposure time: 18 h Petrolatum: Toxicity to fish : LL50 (Pimephales promelas (fathead minnow)): > 100 mg/l Exposure time: 96 h Test substance: Water Accommodated Fraction Method: OECD Test Guideline 203 Remarks: Based on data from similar materials Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 10,000 mg/l Exposure time: 48 h Test substance: Water Accommodated Fraction Remarks: Based on data from similar materials Toxicity to algae : NOEL (Pseudokirchneriella subcapitata (green algae)): >= 100 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction Method: OECD Test Guideline 201 Remarks: Based on data from similar materials Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): 10 mg/l Exposure time: 21 d Test substance: Water Accommodated Fraction Remarks: Based on data from similar materials Sodium Hydroxymethylglycinate: Toxicity to fish : LC50: > 10 - 100 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia pulex (Water flea)): > 10 - 100 mg/l Exposure time: 48 h Toxicity to algae : ErC50 (Desmodesmus subspicatus (Scenedesmus subspicatus)): > 10 - 100 mg/l Exposure time: 72 h Toxicity to bacteria : EC50: > 100 mg/l Exposure time: 120 h Chloroxylenol: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 0.76 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 7.7 mg/l Exposure time: 48 h M-Factor (Acute aquatic toxicity) : 1 SAFETY DATA SHEET GOJO? ORIGINAL FORMULA? Hand Cleaner Version 1.1 SDS Number: 400000000198 Revision Date: 02/28/2018 16 / 19 Persistence and degradability Components: C11-15 Alkane/cycloalkane: Biodegradability : Result: Readily biodegradable. Biodegradation: 82 % Exposure time: 24 d Method: OECD Test Guideline 301F Mineral Oil (Paraffinum Liquidum): Biodegradability : Result: Not readily biodegradable. Biodegradation: 31 % Exposure time: 28 d Trideceth-9: Biodegradability : Result: Readily biodegradable. Biodegradation: > 60 % Exposure time: 28 d Propylene Glycol: Biodegradability : Result: Readily biodegradable. Biodegradation: 98.3 % Exposure time: 28 d Method: OECD Test Guideline 301F Petrolatum: Biodegradability : Result: Not readily biodegradable. Biodegradation: 31 % Exposure time: 28 d Method: OECD Test Guideline 301F Remarks: Based on data from similar materials Sodium Hydroxymethylglycinate: Biodegradability : Result: Readily biodegradable. Bioaccumulative potential Components: Propylene Glycol: Partition coefficient: n- octanol/water : log Pow: -1.07 Sodium Hydroxymethylglycinate: Partition coefficient: n- octanol/water : log Pow: < 3 Chloroxylenol: Partition coefficient: n- octanol/water : log Pow: 3.27 Mobility in soil No data available Other adverse effects No data available SAFETY DATA SHEET GOJO? ORIGINAL FORMULA? Hand Cleaner Version 1.1 SDS Number: 400000000198 Revision Date: 02/28/2018 17 / 19 Product: Regulation 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with local regulations. Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. SECTION 14. TRANSPORT INFORMATION International Regulation IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good National Regulations 49 CFR Not regulated as a dangerous good SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Sodium Hydroxide 1310-73-2 1000 * *: Calculated RQ exceeds reasonably attainable upper limit. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Acute Health Hazard SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SAFETY DATA SHEET GOJO? ORIGINAL FORMULA? Hand Cleaner Version 1.1 SDS Number: 400000000198 Revision Date: 02/28/2018 18 / 19 SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Clean Air Act This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489): Propylene Glycol 57-55-6 1.7691 % This product does not contain any VOC exemptions listed under the U.S. Clean Air Act Section 450. Clean Water Act This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 US State Regulations Massachusetts Right To Know C11-15 Alkane/cycloalkane 64742-47-8 30 - 50 % Mineral Oil (Paraffinum Liquidum) 8042-47-5 10 - 20 % Petrolatum 8009-03-8 1 - 5 % Sodium Hydroxymethylglycinate 70161-44-3 0.1 - 1 % Pennsylvania Right To Know C11-15 Alkane/cycloalkane 64742-47-8 30 - 50 % Water (Aqua) 7732-18-5 30 - 50 % Mineral Oil (Paraffinum Liquidum) 8042-47-5 10 - 20 % Oleic Acid 112-80-1 5 - 10 % Trideceth-9 24938-91-8 1 - 5 % Propylene Glycol 57-55-6 1 - 5 % Petrolatum 8009-03-8 1 - 5 % Sodium Hydroxide 1310-73-2 0.1 - 1 % Sodium Hydroxymethylglycinate 70161-44-3 0.1 - 1 % New Jersey Right To Know C11-15 Alkane/cycloalkane 64742-47-8 30 - 50 % Water (Aqua) 7732-18-5 30 - 50 % Mineral Oil (Paraffinum Liquidum) 8042-47-5 10 - 20 % Oleic Acid 112-80-1 5 - 10 % Trideceth-9 24938-91-8 1 - 5 % Propylene Glycol 57-55-6 1 - 5 % Sodium Hydroxymethylglycinate 70161-44-3 0.1 - 1 % California Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. The components of this product are reported in the following inventories: TSCA : On TSCA Inventory SAFETY DATA SHEET GOJO? ORIGINAL FORMULA? Hand Cleaner Version 1.1 SDS Number: 400000000198 Revision Date: 02/28/2018 19 / 19 AICS : On the inventory, or in compliance with the inventory DSL : On the inventory, or in compliance with the inventory ENCS : On the inventory, or in compliance with the inventory ISHL : On the inventory, or in compliance with the inventory KECI : On the inventory, or in compliance with the inventory PICCS : On the inventory, or in compliance with the inventory IECSC : On the inventory, or in compliance with the inventory NZIoC : On the inventory, or in compliance with the inventory Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA) SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: Revision Date : 02/28/2018 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Flammability H e a lt h In s ta b ility 3 1 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 3 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic