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8154J_Alkeline_AA_Battery.pdf
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Spectrum Brands, Inc. Rayovac Division 3001 Deming Way Middleton, WI 53562-1431 Phone: (608) 275-3340 Fax: (608) 275-4577 http://www.rayovac.com The Safety Data Sheet is supplied as a service to you. For other related information, please visit: http://www.rayovac.com NA = Not Applicable Safety Data Sheet Information (800) 237-7000 Page 1 of 4 SAFETY DATA SHEET 1. IDENTIFICATION PRODUCT NAME: Alkaline Battery Mercury Free SIZES: All sizes EMERGENCY HOTLINE: 800-424-9300 (24 hr, Chemtrec) EDITION DATE: 07/01/2017 2. HAZARD IDENTIFICATION We would like to inform our customers that these batteries are exempt articles and are not subject to the 29 CFR 1910.1200 OSHA requirements, Canadian WHMIS requirements or GHS requirements. Emergency Overview OSHA Hazards-not applicable Target Organs-not applicable GHS Classification-not applicable GHS Label Elements, including precautionary Statement-not applicable Pictogram-not applicable Signal words-not applicable Hazard statements-not applicable Precautionary statements-not applicable 3. COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENT NAME CAS # % TLV*/**TWA Manganese Dioxide 1313-13-9 32-38 C5.0 mg/m3 Steel 7439-89-6 19-23 --- Zinc 7440-66-6 11-16 5 mg/m3 (as ZnO Fume) Potassium Hydroxide 1310-58-3 5-9 Solution Not Listed Graphite 7782-42-5 3-5 15 mppcf Barium Sulfate 7727-43-7 <5 15 mg/m3 Water, paper, plastic, other --- Balance --- *Source: OSHA 29 CFR 1910.1000 Table Z-1, 2 or 3 11-01-2012 NA = Not Applicable Safety Data Sheet Information (800) 237-7000 Page 2 of 4 4. FIRST AID INFORMATION THRESHOLD LIMIT VALUE (TLV) AND SOURCE: NA EFFECTS OF OVEREXPOSURE: None in normal use EMERGENCY FIRST AID PROCEDURES: Skin and Eyes: Do not pick up a shorting battery as it may cause a burn. Get immediate medical attention when eyes may have been exposed to battery contents from a ruptured battery. Wash skin with soap and water. Swallowing: If you or your doctor suspects that a battery has been ingested-for assistance in the US call the NATIONAL BATTERY INGESTION HOTLINE any time at (202) 625-3333: in Canada call 416-813- 5900. For more information, please visit: http://www.nema.org/Policy/Environmental-Stewardship/Documents/batteryingest.pdf 5. FIRE FIGHTING MEASURES FLASH POINT: NA LOWER (LEL): NA FLAMMABLE LIMITS IN AIR (%): NA UPPER (UEL): NA EXTINGUISHING MEDIA: Use water, foam, or dry powder as appropriate. AUTO-IGNITION: NA SPECIAL FIRE FIGHTING PROCEDURES: As with any fire, wear self-contained breathing apparatus to avoid inhalation of hazardous decomposition products (See section 2). SPECIAL FIRE OR EXPLOSION HAZARDS: DO NOT RECHARGE. As a typical sealed battery they may rupture when exposed to excessive heat; this could result in the release of flammable or corrosive materials. 6. ACCIDENTAL RELEASE MEASURES TO CONTAIN AND CLEAN UP LEAKS OR SPILLS: In the event of a battery rupture, prevent skin contact and collect all released material in a plastic lined metal container. REPORTING PROCEDURE: Report all spills in accordance with Federal, State and Local reporting requirements. NA = Not Applicable Safety Data Sheet Information (800) 237-7000 Page 3 of 4 7. HANDLING AND STORAGE Store batteries in a dry place. Storing unpackaged cells together with other combustible materials could result in cell shorting and heat build-up. Do not recharge. Do not puncture or abuse. 8. EXPOSURE CONTROL/PERSONAL PROTECTION RESPIRATORY PROTECTION (SPECIFY TYPE): NA VENTILATION: Local Exhaust: NA Mechanical (General): NA Special: NA Other: NA PROTECTIVE GLOVES: NA EYE PROTECTION: NA OTHER PROTECTIVE CLOTHING: NA 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point @ 760 mm Hg (?C): NA Percent Volatile by Volume (%): NA Vapor Pressure (mm Hg @ 25?C): NA Evaporation Rate (Butyl Acetate = 1): NA Vapor Density (Air = 1): NA Physical State: NA Density (grams/cc): NA Solubility in Water (% by Weight): NA pH: NA Appearance and Odor: Geometric solid object 10. STABILITY AND REACTIVITY STABLE OR UNSTABLE: Stable INCOMPATIBILITY (MATERIALS TO AVOID): NA HAZARDOUS DECOMPOSITION PRODUCTS: NA DECOMPOSITION TEMPERATURE (0?F): NA HAZARDOUS POLYMERIZATION: Will Not Occur CONDITIONS TO AVOID: Avoid electrical shorting, puncturing or deforming 11. TOXICOLOGICAL INFORMATION INGREDIENT NAME CAS # % TLV*/**TWA Manganese Dioxide 1313-13-9 32-38 C5.0 mg/m3 Steel 7439-89-6 19-23 --- Zinc 7440-66-6 11-16 5 mg/m3 (as ZnO Fume) Potassium Hydroxide 1310-58-3 5-9 Solution Not Listed Graphite 7782-42-5 3-5 15 mppcf Barium Sulfate 7727-43-7 <5 15 mg/m3 Water, paper, plastic, other --- Balance --- *Source: OSHA 29 CFR 1910.1000 Table Z-1, 2 or 3 11-01-2012 NA = Not Applicable Safety Data Sheet Information (800) 237-7000 Page 4 of 4 12. ECOLOGICAL INFORMATION Consumers should dispose of discharged batteries through waste disposal services or legitimate collection outlets. Those collecting batteries should follow state and federal regulations. Partially discharged damaged batteries can overheat and cause fires in the presence of other combustible materials. 13. DISPOSAL CONSIDERATIONS Always comply with Federal, state or local requirements. All Rayovac Alkaline batteries have been tested per Federal hazardous waste testing requirements (TCLP). The TCLP tests show Rayovac alkaline batteries are not hazardous waste. http://www.nema.org/Policy/Environmental- Stewardship/Documents/Companies%20Claiming%20to%20Recycle.MARCH2005.pdf 14. TRANSPORTATION INFORMATION TRANSPORTATION-SHIPPING: Alkaline Batteries are considered dry-cell batteries and they are non- dangerous goods for transportation. These batteries must be packed in a way to prevent short circuits or generation of a dangerous quantity of heat. USDOT ? See Special Provision 130. IMO/Ocean ? Not Listed. ICAO/IATA ? See Special Provision A123. This special provision also states to put the words ?not restricted? and ?special provision A123? on the air waybill when an air waybill is issued. 15. REGULATORY INFORMATION SARA 313: Notification is not required because these products are article(s) that do not release a covered toxic chemical under the normal conditions of storage, use, or handling. 16. OTHER INFORMATION The information and recommendations set forth are made in good faith and are believed to be accurate at the date of preparation. Spectrum Brands Inc. (Rayovac) makes no warranty expressed or implied.