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2018-12-27 21:30:02.643 7-62373 0026299440 MSDS COORDINATOR FACTORY MOTOR PARTS 5328 W ROOSEVELT ST PHOENIX, AZ 85043-2713 USA MSDS COORDINATOR editTest editi 3M General Offices 3M Center St. Paul, MN 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours) Safety Data Sheet Purchase Order #: Customer Number: Dear Enclosed is the Safety Data Sheet (SDS)* for the product that your company recently purchased from 3M. Please forward the attached document(s) to the individual in your organization responsible for hazard communication. If you are a distributor and resell this product, OSHA and EPA require that you transmit this SDS information to your customers at the time of first shipment or whenever you receive revised SDSs from 3M. 3M SDSs are available over the Internet at www.3m.com/MSDSSearch. You may also order a DVD of 3M SDSs by calling 1-800-364-3577. 3M is committed to meeting our customer requirements. Please contact your 3M customer service or sales representative if you have any questions. If you do not know whom to contact, please call the 3M Product Information Center at 1-800-364-3577. If you are not currently receiving 3M SDSs by e-mail and would like to do so, please contact our eSDS Administrator at This email address is being protected from spambots. You need JavaScript enabled to view it. or by calling 651-736-5875. *An Article Information Sheet (AIS) or Article Information Letter (AIL) may be enclosed in place of an SDS if the product is an article which does not require an SDS under the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. 3M? High Power Brake Cleaner, 08880 10/22/18 __________________________________________________________________________________________ Page 1 of 15 Safety Data Sheet Copyright,2018,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 36-1997-0 Version Number: 2.00 Issue Date: 10/22/18 Supercedes Date: 09/20/16 SECTION 1: Identification 1.1. Product identifier 3M? High Power Brake Cleaner, 08880 Product Identification Numbers 60-4550-8946-0, 60-4550-9100-3 7100136846, 7100150166 1.2. Recommended use and restrictions on use Recommended use Automotive, Brake Cleaner 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Aerosol: Category 1. Gas Under Pressure: Liquefied gas. Acute Toxicity (oral): Category 4. Serious Eye Damage/Irritation: Category 2B. Aspiration Hazard: Category 1. Reproductive Toxicity: Category 2. Carcinogenicity: Category 2. Specific Target Organ Toxicity (single exposure): Category 1. Specific Target Organ Toxicity (single exposure): Category 3. 3M? High Power Brake Cleaner, 08880 10/22/18 __________________________________________________________________________________________ Page 2 of 15 Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word Danger Symbols Flame | Gas cylinder | Exclamation mark | Health Hazard | Pictograms Hazard Statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Harmful if swallowed. Causes eye irritation. May be fatal if swallowed and enters airways. May cause drowsiness or dizziness. Suspected of damaging fertility or the unborn child. Suspected of causing cancer. Causes damage to organs: sensory organs | Causes damage to organs through prolonged or repeated exposure: nervous system | sensory organs | Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 3M? High Power Brake Cleaner, 08880 10/22/18 __________________________________________________________________________________________ Page 3 of 15 If eye irritation persists: Get medical advice/attention. Rinse mouth. Do NOT induce vomiting. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Specific treatment (see Notes to Physician on this label). Call a POISON CENTER or doctor/physician if you feel unwell. Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: This product contains methanol. If there is a reasonable suspicion of methanol poisoning, intravenous (IV) administration with either fomepizole (preferred) or ethanol (if fomepizole is unavailable) should be considered as part of the medical management. 7% of the mixture consists of ingredients of unknown acute oral toxicity. 8% of the mixture consists of ingredients of unknown acute dermal toxicity. 8% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt 2-Methylhexane 591-76-4 10 - 30 Trade Secret * 3-Methylhexane 589-34-4 10 - 30 Trade Secret * Xylene 1330-20-7 10 - 30 Trade Secret * Ethylbenzene 100-41-4 1 - 10 Trade Secret * Methyl Alcohol 67-56-1 5 - 10 Trade Secret * 2,3-Dimethylpentane 565-59-3 3 - 7 Trade Secret * Carbon Dioxide 124-38-9 1 - 5 Trade Secret * trans-1,3-Dimethylcyclopentane 1759-58-6 1 - 5 Trade Secret * Heptane 142-82-5 0.5 - 2.5 Trade Secret * 3,3-Dimethylpentane 562-49-2 0.5 - 1.5 Trade Secret * 3-Ethylpentane 617-78-7 0.5 - 1.5 Trade Secret * Dimethylcyclopentane 2532-58-3 0.5 - 1.5 Trade Secret * trans-1,2-Dimethylcyclopentane 822-50-4 0.5 - 1.5 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Wash with soap and water. If signs/symptoms develop, get medical attention. 3M? High Power Brake Cleaner, 08880 10/22/18 __________________________________________________________________________________________ Page 4 of 15 Eye Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing. Immediately get medical attention. If Swallowed: Do not induce vomiting. Get immediate medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required This product contains methanol. If there is a reasonable suspicion of methanol poisoning, intravenous (IV) administration with either fomepizole (preferred) or ethanol (if fomepizole is unavailable) should be considered as part of the medical management. SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Toxic Vapor, Gas, Particulate During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material 3M? High Power Brake Cleaner, 08880 10/22/18 __________________________________________________________________________________________ Page 5 of 15 as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Ethylbenzene 100-41-4 ACGIH TWA:20 ppm A3: Confirmed animal carcin. Ethylbenzene 100-41-4 OSHA TWA:435 mg/m3(100 ppm) Carbon Dioxide 124-38-9 ACGIH TWA:5000 ppm;STEL:30000 ppm Carbon Dioxide 124-38-9 OSHA TWA:9000 mg/m3(5000 ppm) Xylene 1330-20-7 ACGIH TWA:100 ppm;STEL:150 ppm A4: Not class. as human carcin Xylene 1330-20-7 OSHA TWA:435 mg/m3(100 ppm) Heptane 142-82-5 ACGIH TWA:400 ppm;STEL:500 ppm Heptane 142-82-5 OSHA TWA:2000 mg/m3(500 ppm) Heptane, all isomers 562-49-2 ACGIH TWA:400 ppm;STEL:500 ppm 2,3-Dimethylpentane 565-59-3 ACGIH TWA:400 ppm;STEL:500 ppm 3-Methylhexane 589-34-4 ACGIH TWA:400 ppm;STEL:500 ppm 2-Methylhexane 591-76-4 ACGIH TWA:400 ppm;STEL:500 ppm Heptane, all isomers 617-78-7 ACGIH TWA:400 ppm;STEL:500 ppm Methyl Alcohol 67-56-1 ACGIH TWA:200 ppm;STEL:250 ppm SKIN Methyl Alcohol 67-56-1 OSHA TWA:260 mg/m3(200 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 3M? High Power Brake Cleaner, 08880 10/22/18 __________________________________________________________________________________________ Page 6 of 15 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Fluoroelastomer Polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Aerosol Odor, Color, Grade: Clear colorless; Solvent odor Odor threshold No Data Available pH Not Applicable Melting point No Data Available Boiling Point No Data Available Flash Point >=15 ?F Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure 40 psi [@ 70 ?F] Vapor Density >=1.0 [Ref Std:AIR=1] Density 6.5 lb/gal Specific Gravity 0.78 [Ref Std:WATER=1] Solubility in Water Nil Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity No Data Available 3M? High Power Brake Cleaner, 08880 10/22/18 __________________________________________________________________________________________ Page 7 of 15 Hazardous Air Pollutants 39.3 % weight [Test Method:Calculated] Volatile Organic Compounds 749 g/l [Test Method:calculated SCAQMD rule 443.1] Volatile Organic Compounds 96 % weight [Test Method:calculated per CARB title 2] Percent volatile 96 % weight VOC Less H2O & Exempt Solvents 749 g/l [Test Method:calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat Sparks and/or flames 10.5. Incompatible materials Strong acids Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: May be harmful if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). 3M? High Power Brake Cleaner, 08880 10/22/18 __________________________________________________________________________________________ Page 8 of 15 Skin Contact: May be harmful in contact with skin. Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. May cause additional health effects (see below). Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: Harmful if swallowed. Chemical (Aspiration) Pneumonitis: Signs/symptoms may include coughing, gasping, choking, burning of the mouth, difficulty breathing, bluish colored skin (cyanosis), and may be fatal. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. May cause blindness. Prolonged or repeated exposure may cause target organ effects: Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation Ethylbenzene 100-41-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE2,000 - 5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE20 - 50 mg/l Overall product Ingestion No data available; calculated ATE300 - 2,000 mg/kg 3-Methylhexane Dermal Rabbit LD50 3,000 mg/kg 3-Methylhexane Inhalation- Vapor (4 hours) Rat LC50 > 80 mg/l 3-Methylhexane Ingestion Rat LD50 17,000 mg/kg Xylene Dermal Rabbit LD50 > 4,200 mg/kg 3M? High Power Brake Cleaner, 08880 10/22/18 __________________________________________________________________________________________ Page 9 of 15 Xylene Inhalation- Vapor (4 hours) Rat LC50 29 mg/l Xylene Ingestion Rat LD50 3,523 mg/kg 2-Methylhexane Dermal Rabbit LD50 3,000 mg/kg 2-Methylhexane Inhalation- Vapor (4 hours) Rat LC50 > 80 mg/l 2-Methylhexane Ingestion Rat LD50 17,000 mg/kg Methyl Alcohol Dermal LD50 estimated to be 1,000 - 2,000 mg/kg Methyl Alcohol Inhalation- Vapor LC50 estimated to be 10 - 20 mg/l Methyl Alcohol Ingestion LD50 estimated to be 50 - 300 mg/kg Ethylbenzene Dermal Rabbit LD50 15,433 mg/kg Ethylbenzene Inhalation- Vapor (4 hours) Rat LC50 17.4 mg/l Ethylbenzene Ingestion Rat LD50 4,769 mg/kg 2,3-Dimethylpentane Dermal Rabbit LD50 > 2,000 mg/kg 2,3-Dimethylpentane Inhalation- Vapor (4 hours) Rat LC50 > 73.5 mg/l 2,3-Dimethylpentane Ingestion Rat LD50 > 5,000 mg/kg Carbon Dioxide Inhalation- Gas (4 hours) Rat LC50 > 53,000 ppm Heptane Dermal Rabbit LD50 3,000 mg/kg Heptane Inhalation- Vapor (4 hours) Rat LC50 103 mg/l Heptane Ingestion Rat LD50 > 15,000 mg/kg 3,3-Dimethylpentane Dermal Rabbit LD50 > 2,000 mg/kg 3,3-Dimethylpentane Inhalation- Vapor (4 hours) Rat LC50 > 73.5 mg/l 3,3-Dimethylpentane Ingestion Rat LD50 > 5,000 mg/kg Dimethylcyclopentane Ingestion LD50 estimated to be 300 - 2,000 mg/kg 3-Ethylpentane Dermal estimated to be > 5,000 mg/kg 3-Ethylpentane Inhalation- Dust/Mist estimated to be > 12.5 mg/l 3-Ethylpentane Inhalation- Vapor estimated to be > 50 mg/l 3-Ethylpentane Ingestion estimated to be > 5,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value 3-Methylhexane Rabbit Minimal irritation Xylene Rabbit Mild irritant 2-Methylhexane Rabbit Minimal irritation Methyl Alcohol Rabbit Mild irritant Ethylbenzene Rabbit Mild irritant 2,3-Dimethylpentane Rabbit Mild irritant Heptane Human Mild irritant 3,3-Dimethylpentane Rabbit Mild irritant Serious Eye Damage/Irritation Name Species Value 3-Methylhexane Rabbit No significant irritation Xylene Rabbit Mild irritant 2-Methylhexane Rabbit No significant irritation 3M? High Power Brake Cleaner, 08880 10/22/18 __________________________________________________________________________________________ Page 10 of 15 Methyl Alcohol Rabbit Moderate irritant Ethylbenzene Rabbit Moderate irritant 2,3-Dimethylpentane Rabbit Mild irritant Heptane Professio nal judgeme nt Moderate irritant 3,3-Dimethylpentane Rabbit Mild irritant Skin Sensitization Name Species Value Methyl Alcohol Guinea pig Not classified Ethylbenzene Human Not classified Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Xylene In Vitro Not mutagenic Xylene In vivo Not mutagenic Methyl Alcohol In Vitro Some positive data exist, but the data are not sufficient for classification Methyl Alcohol In vivo Some positive data exist, but the data are not sufficient for classification Ethylbenzene In vivo Not mutagenic Ethylbenzene In Vitro Some positive data exist, but the data are not sufficient for classification Heptane In Vitro Not mutagenic Carcinogenicity Name Route Species Value Xylene Dermal Rat Not carcinogenic Xylene Ingestion Multiple animal species Not carcinogenic Xylene Inhalation Human Some positive data exist, but the data are not sufficient for classification Methyl Alcohol Inhalation Multiple animal species Not carcinogenic Ethylbenzene Inhalation Multiple animal species Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Xylene Inhalation Not classified for female reproduction Human NOAEL Not available occupational exposure Xylene Ingestion Not classified for development Mouse NOAEL Not available during organogenesi s Xylene Inhalation Not classified for development Multiple animal species NOAEL Not available during gestation Methyl Alcohol Ingestion Not classified for male reproduction Rat NOAEL 1,600 mg/kg/day 21 days Methyl Alcohol Ingestion Toxic to development Mouse LOAEL 4,000 during 3M? High Power Brake Cleaner, 08880 10/22/18 __________________________________________________________________________________________ Page 11 of 15 mg/kg/day organogenesi s Methyl Alcohol Inhalation Toxic to development Mouse NOAEL 1.3 mg/l during organogenesi s Ethylbenzene Inhalation Not classified for development Rat NOAEL 4.3 mg/l premating & during gestation Carbon Dioxide Inhalation Not classified for male reproduction Mouse LOAEL 350,000 ppm not available Carbon Dioxide Inhalation Not classified for development Rat LOAEL 60,000 ppm 24 hours Lactation Name Route Species Value Xylene Ingestion Mouse Not classified for effects on or via lactation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration 3-Methylhexane Inhalation central nervous system depression May cause drowsiness or dizziness Rat NOAEL 4 mg/l 4 hours 3-Methylhexane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Not available NOAEL Not available not available 3-Methylhexane Ingestion central nervous system depression May cause drowsiness or dizziness Not available NOAEL Not available Xylene Inhalation auditory system Causes damage to organs Rat LOAEL 6.3 mg/l 8 hours Xylene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Xylene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Xylene Inhalation eyes Not classified Rat NOAEL 3.5 mg/l not available Xylene Inhalation liver Not classified Multiple animal species NOAEL Not available Xylene Ingestion central nervous system depression May cause drowsiness or dizziness Multiple animal species NOAEL Not available Xylene Ingestion eyes Not classified Rat NOAEL 250 mg/kg not applicable 2-Methylhexane Inhalation central nervous system depression May cause drowsiness or dizziness Rat NOAEL 4 mg/l 4 hours 2-Methylhexane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Not available NOAEL Not available not available 2-Methylhexane Ingestion central nervous system depression May cause drowsiness or dizziness Not available NOAEL Not available Methyl Alcohol Inhalation blindness Causes damage to organs Human NOAEL Not available occupational exposure Methyl Alcohol Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available not available Methyl Alcohol Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Rat NOAEL Not available 6 hours Methyl Alcohol Ingestion blindness Causes damage to organs Human NOAEL Not available poisoning and/or abuse Methyl Alcohol Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse 3M? High Power Brake Cleaner, 08880 10/22/18 __________________________________________________________________________________________ Page 12 of 15 Ethylbenzene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Ethylbenzene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human and animal NOAEL Not available Ethylbenzene Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available 2,3-Dimethylpentane Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Heptane Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Heptane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Heptane Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available 3,3-Dimethylpentane Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Xylene Inhalation nervous system Causes damage to organs through prolonged or repeated exposure Rat LOAEL 0.4 mg/l 4 weeks Xylene Inhalation auditory system May cause damage to organs though prolonged or repeated exposure Rat LOAEL 7.8 mg/l 5 days Xylene Inhalation liver Not classified Multiple animal species NOAEL Not available Xylene Inhalation heart | endocrine system | gastrointestinal tract | hematopoietic system | muscles | kidney and/or bladder | respiratory system Not classified Multiple animal species NOAEL 3.5 mg/l 13 weeks Xylene Ingestion auditory system Not classified Rat NOAEL 900 mg/kg/day 2 weeks Xylene Ingestion kidney and/or bladder Not classified Rat NOAEL 1,500 mg/kg/day 90 days Xylene Ingestion liver Not classified Multiple animal species NOAEL Not available Xylene Ingestion heart | skin | endocrine system | bone, teeth, nails, and/or hair | hematopoietic system | immune system | nervous system | respiratory system Not classified Mouse NOAEL 1,000 mg/kg/day 103 weeks Methyl Alcohol Inhalation liver Not classified Rat NOAEL 6.55 mg/l 4 weeks Methyl Alcohol Inhalation respiratory system Not classified Rat NOAEL 13.1 mg/l 6 weeks Methyl Alcohol Ingestion liver | nervous system Not classified Rat NOAEL 2,500 mg/kg/day 90 days Ethylbenzene Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 2 years 3M? High Power Brake Cleaner, 08880 10/22/18 __________________________________________________________________________________________ Page 13 of 15 Ethylbenzene Inhalation liver Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 1.1 mg/l 103 weeks Ethylbenzene Inhalation hematopoietic system Not classified Rat NOAEL 3.4 mg/l 28 days Ethylbenzene Inhalation auditory system Not classified Rat NOAEL 2.4 mg/l 5 days Ethylbenzene Inhalation endocrine system Not classified Mouse NOAEL 3.3 mg/l 103 weeks Ethylbenzene Inhalation gastrointestinal tract Not classified Rat NOAEL 3.3 mg/l 2 years Ethylbenzene Inhalation bone, teeth, nails, and/or hair | muscles Not classified Multiple animal species NOAEL 4.2 mg/l 90 days Ethylbenzene Inhalation heart | immune system | respiratory system Not classified Multiple animal species NOAEL 3.3 mg/l 2 years Ethylbenzene Ingestion liver | kidney and/or bladder Not classified Rat NOAEL 680 mg/kg/day 6 months Carbon Dioxide Inhalation heart | bone, teeth, nails, and/or hair | liver | nervous system | kidney and/or bladder | respiratory system Not classified Rat LOAEL 60,000 ppm 166 days Heptane Inhalation liver | nervous system | kidney and/or bladder Not classified Rat NOAEL 12 mg/l 26 weeks Aspiration Hazard Name Value 3-Methylhexane Aspiration hazard Xylene Aspiration hazard 2-Methylhexane Aspiration hazard Ethylbenzene Aspiration hazard 2,3-Dimethylpentane Aspiration hazard Heptane Aspiration hazard 3,3-Dimethylpentane Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable 3M? High Power Brake Cleaner, 08880 10/22/18 __________________________________________________________________________________________ Page 14 of 15 regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. EPCRA 311/312 Hazard Classifications: Physical Hazards Flammable (gases, aerosols, liquids, or solids) Gas under pressure Health Hazards Acute toxicity Aspiration Hazard Carcinogenicity Reproductive toxicity Serious eye damage or eye irritation Specific target organ toxicity (single or repeated exposure) Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Methyl Alcohol 67-56-1 Trade Secret 5 - 10 Ethylbenzene 100-41-4 Trade Secret 1 - 10 Xylene 1330-20-7 Trade Secret 10 - 30 Xylene (Benzene, dimethyl-) 1330-20-7 10 - 30 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Listing ETHYLBENZENE 100-41-4 Carcinogen METHANOL 67-56-1 Developmental Toxin 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. All required components of this product are listed on the active portion of the TSCA Inventory. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. 3M? High Power Brake Cleaner, 08880 10/22/18 __________________________________________________________________________________________ Page 15 of 15 This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 4 Instability: 0 Special Hazards: None Aerosol Storage Code: 3 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 36-1997-0 Version Number: 2.00 Issue Date: 10/22/18 Supercedes Date: 09/20/16 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from3M 3M USA SDSs are available at www.3M.com