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2019-02-08 21:44:08.467 12-74527 0026299638 MSDS COORDINATOR FMP LOCATION 12 1600 E ORANGETHORP FULLERTON, CA 92831-5231 USA MSDS COORDINATOR editTest editi 3M General Offices 3M Center St. Paul, MN 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours) Safety Data Sheet Purchase Order #: Customer Number: Dear Enclosed is the Safety Data Sheet (SDS)* for the product that your company recently purchased from 3M. Please forward the attached document(s) to the individual in your organization responsible for hazard communication. If you are a distributor and resell this product, OSHA and EPA require that you transmit this SDS information to your customers at the time of first shipment or whenever you receive revised SDSs from 3M. 3M SDSs are available over the Internet at www.3m.com/MSDSSearch. You may also order a DVD of 3M SDSs by calling 1-800-364-3577. 3M is committed to meeting our customer requirements. Please contact your 3M customer service or sales representative if you have any questions. If you do not know whom to contact, please call the 3M Product Information Center at 1-800-364-3577. If you are not currently receiving 3M SDSs by e-mail and would like to do so, please contact our eSDS Administrator at This email address is being protected from spambots. You need JavaScript enabled to view it. or by calling 651-736-5875. *An Article Information Sheet (AIS) or Article Information Letter (AIL) may be enclosed in place of an SDS if the product is an article which does not require an SDS under the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. 3M? Fast 'N Firm? Seam Sealer, 08505 12/27/17 __________________________________________________________________________________________ Page 1 of 17 Safety Data Sheet Copyright,2017,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 27-9977-3 Version Number: 3.01 Issue Date: 12/27/17 Supercedes Date: 03/26/15 SECTION 1: Identification 1.1. Product identifier 3M? Fast 'N Firm? Seam Sealer, 08505 Product Identification Numbers 60-4550-5202-1 1.2. Recommended use and restrictions on use Recommended use Automotive, A tan heavy bodied seam sealer Heavy bodied sealer for sealing interior and exterior joints. Quick skinning, fast curing, flexible sealer. High solids and low shrinkage. Ideal seam sealer where time and speed are important. Paintable in 45 min. 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Solid: Category 1. Serious Eye Damage/Irritation: Category 2B. Skin Corrosion/Irritation: Category 2. Reproductive Toxicity: Category 1B. Carcinogenicity: Category 2. Specific Target Organ Toxicity (single exposure): Category 1. Specific Target Organ Toxicity (single exposure): Category 3. Specific Target Organ Toxicity (repeated exposure): Category 1. 3M? Fast 'N Firm? Seam Sealer, 08505 12/27/17 __________________________________________________________________________________________ Page 2 of 17 2.2. Label elements Signal word Danger Symbols Flame | Exclamation mark | Health Hazard | Pictograms Hazard Statements Flammable solid. Causes eye irritation. Causes skin irritation. May cause drowsiness or dizziness. May damage fertility or the unborn child. Suspected of causing cancer. Causes damage to organs: sensory organs | Causes damage to organs through prolonged or repeated exposure: nervous system | sensory organs | Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. 3M? Fast 'N Firm? Seam Sealer, 08505 12/27/17 __________________________________________________________________________________________ Page 3 of 17 Call a POISON CENTER or doctor/physician if you feel unwell. Storage: Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 59% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Toluene 108-88-3 15 - 40 Trade Secret * Hydrocarbons, C6-20, Polymers, Hydrogenated 69430-35-9 10 - 30 Trade Secret * Styrene/Alpha-Methylstyrene Copolymer 9011-11-4 10 - 30 Trade Secret * Hydrogenated Styrene-Butadiene Polymer 66070-58-4 7 - 13 Trade Secret * White Mineral Oil (Petroleum) 8042-47-5 7 - 13 Trade Secret * Synthetic Amorphous Silica, Fumed, Crystalline Free 112945-52-5 3 - 7 Trade Secret * Xylene 1330-20-7 1 - 5 Trade Secret * M-Xylene 108-38-3 < 1.5 Trade Secret * Rutile Titanium Dioxide 1317-80-2 0.5 - 1.5 Trade Secret * Ethylbenzene 100-41-4 < 1 Trade Secret * Benzene 71-43-2 < 0.05 Trade Secret * Cumene 98-82-8 < 0.05 Trade Secret * Naphthalene 91-20-3 0.0001782 0.0003564 *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing. Immediately get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required 3M? Fast 'N Firm? Seam Sealer, 08505 12/27/17 __________________________________________________________________________________________ Page 4 of 17 Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. Use personal protective equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation during transfer. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed to prevent loss of stabilizing materials. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 3M? Fast 'N Firm? Seam Sealer, 08505 12/27/17 __________________________________________________________________________________________ Page 5 of 17 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Ethylbenzene 100-41-4 ACGIH TWA:20 ppm A3: Confirmed animal carcin. Ethylbenzene 100-41-4 OSHA TWA:435 mg/m3(100 ppm) Benzene, dimethyl- 108-38-3 OSHA TWA:435 mg/m3(100 ppm) M-Xylene 108-38-3 ACGIH TWA:100 ppm;STEL:150 ppm A4: Not class. as human carcin Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human carcin Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm SILICA, AMORPHOUS 112945-52- 5 OSHA TWA concentration:0.8 mg/m3;TWA:20 millions of particles/cu. ft. Titanium oxide (TiO2) 1317-80-2 ACGIH TWA:10 mg/m3 A4: Not class. as human carcin Titanium oxide (TiO2) 1317-80-2 OSHA TWA(as total dust):15 mg/m3 Xylene 1330-20-7 ACGIH TWA:100 ppm;STEL:150 ppm A4: Not class. as human carcin Xylene 1330-20-7 OSHA TWA:435 mg/m3(100 ppm) Benzene 71-43-2 ACGIH TWA:0.5 ppm;STEL:2.5 ppm SKIN, A1: Confirmed human carcin. Benzene 71-43-2 OSHA TWA:1 ppm;TWA:10 ppm;STEL:5 ppm;CEIL:25 ppm 29 CFR 1910.1028 MINERAL OILS, HIGHLY- REFINED OILS 8042-47-5 ACGIH TWA(inhalable fraction):5 mg/m3 A4: Not class. as human carcin Paraffin oil 8042-47-5 OSHA TWA(as mist):5 mg/m3 Naphthalene 91-20-3 ACGIH TWA:10 ppm A3: Confirmed animal carcin., SKIN Naphthalene 91-20-3 OSHA TWA:50 mg/m3(10 ppm) Cumene 98-82-8 ACGIH TWA:50 ppm Cumene 98-82-8 OSHA TWA:245 mg/m3(50 ppm) SKIN ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Provide ventilated enclosure for heat curing. Curing enclosures must be exhausted to outdoors or to a suitable emission control device. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment. 8.2.2. Personal protective equipment (PPE) 3M? Fast 'N Firm? Seam Sealer, 08505 12/27/17 __________________________________________________________________________________________ Page 6 of 17 Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Solid Specific Physical Form: Paste Odor, Color, Grade: Viscous Paste Tan Colored Sweet Odor. Odor threshold No Data Available pH Not Applicable Melting point No Data Available Boiling Point 232.00 ?F [Details:CONDITIONS: (toluene)] Flash Point 28 ?F [Test Method:Pensky-Martens Closed Cup] Evaporation rate 4.5 [Ref Std:ETHER=1] Flammability (solid, gas) Flammable Solid: Category 1. Flammable Limits(LEL) 1.27 % volume Flammable Limits(UEL) 7.00 % volume Vapor Pressure 25.1900 mmHg [Details:CONDITIONS: @ 68F] Vapor Density 3.14 [Ref Std:AIR=1] Density 0.940 g/ml Specific Gravity 0.940 [Ref Std:WATER=1] Solubility in Water Nil Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity Approximately 600,000 centipoise Hazardous Air Pollutants 41.528 % weight [Test Method:Calculated] Hazardous Air Pollutants 0.88 lb HAPS/lb solids [Test Method:Calculated] Molecular weight No Data Available Volatile Organic Compounds 41.6 % weight [Test Method:calculated per CARB title 2] Volatile Organic Compounds 391 g/l [Test Method:calculated SCAQMD rule 443.1] Percent volatile 41.6 % weight VOC Less H2O & Exempt Solvents 391 g/l [Test Method:calculated SCAQMD rule 443.1] 3M? Fast 'N Firm? Seam Sealer, 08505 12/27/17 __________________________________________________________________________________________ Page 7 of 17 Solids Content 47.157 % weight SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Sparks and/or flames Heat 10.5. Incompatible materials Strong acids 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: May be harmful if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. 3M? Fast 'N Firm? Seam Sealer, 08505 12/27/17 __________________________________________________________________________________________ Page 8 of 17 Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause target organ effects: Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Olfactory Effects: Signs/symptoms may include decreased ability to detect odors and/or complete loss of smell. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation Benzene 71-43-2 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Benzene 71-43-2 Known human carcinogen National Toxicology Program Carcinogens Benzene 71-43-2 Cancer hazard OSHA Carcinogens Cumene 98-82-8 Grp. 2B: Possible human carc. International Agency for Research on Cancer Cumene 98-82-8 Anticipated human carcinogen National Toxicology Program Carcinogens Ethylbenzene 100-41-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Naphthalene 91-20-3 Grp. 2B: Possible human carc. International Agency for Research on Cancer Naphthalene 91-20-3 Anticipated human carcinogen National Toxicology Program Carcinogens Rutile Titanium Dioxide 1317-80-2 Grp. 2B: Possible human carc. International Agency for Research on Cancer Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE20 - 50 mg/l Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Toluene Dermal Rat LD50 12,000 mg/kg Toluene Inhalation- Vapor (4 hours) Rat LC50 30 mg/l Toluene Ingestion Rat LD50 5,550 mg/kg Styrene/Alpha-Methylstyrene Copolymer Dermal LD50 estimated to be > 5,000 mg/kg Styrene/Alpha-Methylstyrene Copolymer Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg 3M? Fast 'N Firm? Seam Sealer, 08505 12/27/17 __________________________________________________________________________________________ Page 9 of 17 Hydrocarbons, C6-20, Polymers, Hydrogenated Dermal Rat LD50 > 2,000 mg/kg Hydrocarbons, C6-20, Polymers, Hydrogenated Ingestion Rat LD50 > 5,000 mg/kg White Mineral Oil (Petroleum) Dermal Rabbit LD50 > 2,000 mg/kg White Mineral Oil (Petroleum) Ingestion Rat LD50 > 5,000 mg/kg Hydrogenated Styrene-Butadiene Polymer Dermal LD50 estimated to be > 5,000 mg/kg Hydrogenated Styrene-Butadiene Polymer Ingestion LD50 estimated to be > 5,000 mg/kg Synthetic Amorphous Silica, Fumed, Crystalline Free Dermal Rabbit LD50 > 5,000 mg/kg Synthetic Amorphous Silica, Fumed, Crystalline Free Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l Synthetic Amorphous Silica, Fumed, Crystalline Free Ingestion Rat LD50 > 5,110 mg/kg Xylene Dermal Rabbit LD50 > 4,200 mg/kg Xylene Inhalation- Vapor (4 hours) Rat LC50 29 mg/l Xylene Ingestion Rat LD50 3,523 mg/kg M-Xylene Dermal Rabbit LD50 > 4,200 mg/kg M-Xylene Inhalation- Vapor (4 hours) Rat LC50 29 mg/l M-Xylene Ingestion Rat LD50 3,523 mg/kg Rutile Titanium Dioxide Dermal Rabbit LD50 > 10,000 mg/kg Rutile Titanium Dioxide Inhalation- Dust/Mist (4 hours) Rat LC50 > 6.82 mg/l Rutile Titanium Dioxide Ingestion Rat LD50 > 10,000 mg/kg Ethylbenzene Dermal Rabbit LD50 15,433 mg/kg Ethylbenzene Inhalation- Vapor (4 hours) Rat LC50 17.4 mg/l Ethylbenzene Ingestion Rat LD50 4,769 mg/kg Cumene Dermal Rabbit LD50 > 3,160 mg/kg Cumene Inhalation- Vapor (4 hours) Rat LC50 39.4 mg/l Cumene Ingestion Rat LD50 1,400 mg/kg Naphthalene Dermal Human LD50 estimated to be 2,000 - 5,000 mg/kg Naphthalene Inhalation- Vapor Human LC50 estimated to be 20 - 50 mg/l Naphthalene Ingestion Human LD50 estimated to be 300 - 2,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Toluene Rabbit Irritant White Mineral Oil (Petroleum) Rabbit No significant irritation Synthetic Amorphous Silica, Fumed, Crystalline Free Rabbit No significant irritation Xylene Rabbit Mild irritant M-Xylene Rabbit Mild irritant Rutile Titanium Dioxide Rabbit No significant irritation Ethylbenzene Rabbit Mild irritant Cumene Rabbit Minimal irritation Naphthalene Rabbit Minimal irritation Serious Eye Damage/Irritation Name Species Value Toluene Rabbit Moderate irritant White Mineral Oil (Petroleum) Rabbit Mild irritant Synthetic Amorphous Silica, Fumed, Crystalline Free Rabbit No significant irritation Xylene Rabbit Mild irritant M-Xylene Rabbit Mild irritant 3M? Fast 'N Firm? Seam Sealer, 08505 12/27/17 __________________________________________________________________________________________ Page 10 of 17 Rutile Titanium Dioxide Rabbit No significant irritation Ethylbenzene Rabbit Moderate irritant Cumene Rabbit Mild irritant Naphthalene Rabbit No significant irritation Skin Sensitization Name Species Value Toluene Guinea pig Not classified White Mineral Oil (Petroleum) Guinea pig Not classified Synthetic Amorphous Silica, Fumed, Crystalline Free Human and animal Not classified Rutile Titanium Dioxide Human and animal Not classified Ethylbenzene Human Not classified Cumene Guinea pig Not classified Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Toluene In Vitro Not mutagenic Toluene In vivo Not mutagenic White Mineral Oil (Petroleum) In Vitro Not mutagenic Synthetic Amorphous Silica, Fumed, Crystalline Free In Vitro Not mutagenic Xylene In Vitro Not mutagenic Xylene In vivo Not mutagenic M-Xylene In Vitro Not mutagenic M-Xylene In vivo Not mutagenic Rutile Titanium Dioxide In Vitro Not mutagenic Rutile Titanium Dioxide In vivo Not mutagenic Ethylbenzene In vivo Not mutagenic Ethylbenzene In Vitro Some positive data exist, but the data are not sufficient for classification Cumene In Vitro Not mutagenic Cumene In vivo Not mutagenic Carcinogenicity Name Route Species Value Toluene Dermal Mouse Some positive data exist, but the data are not sufficient for classification Toluene Ingestion Rat Some positive data exist, but the data are not sufficient for classification Toluene Inhalation Mouse Some positive data exist, but the data are not sufficient for classification White Mineral Oil (Petroleum) Dermal Mouse Not carcinogenic White Mineral Oil (Petroleum) Inhalation Multiple animal species Not carcinogenic Synthetic Amorphous Silica, Fumed, Crystalline Free Not Specified Mouse Some positive data exist, but the data are not sufficient for classification Xylene Dermal Rat Not carcinogenic Xylene Ingestion Multiple animal species Not carcinogenic Xylene Inhalation Human Some positive data exist, but the data are not sufficient for classification M-Xylene Dermal Rat Not carcinogenic 3M? 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Seam Sealer, 08505 12/27/17 __________________________________________________________________________________________ Page 11 of 17 M-Xylene Ingestion Multiple animal species Not carcinogenic M-Xylene Inhalation Human Some positive data exist, but the data are not sufficient for classification Rutile Titanium Dioxide Ingestion Multiple animal species Not carcinogenic Rutile Titanium Dioxide Inhalation Rat Carcinogenic Ethylbenzene Inhalation Multiple animal species Carcinogenic Cumene Inhalation Multiple animal species Carcinogenic Naphthalene Inhalation Multiple animal species Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Toluene Inhalation Not classified for female reproduction Human NOAEL Not available occupational exposure Toluene Inhalation Not classified for male reproduction Rat NOAEL 2.3 mg/l 1 generation Toluene Ingestion Toxic to development Rat LOAEL 520 mg/kg/day during gestation Toluene Inhalation Toxic to development Human NOAEL Not available poisoning and/or abuse White Mineral Oil (Petroleum) Ingestion Not classified for female reproduction Rat NOAEL 4,350 mg/kg/day 13 weeks White Mineral Oil (Petroleum) Ingestion Not classified for male reproduction Rat NOAEL 4,350 mg/kg/day 13 weeks White Mineral Oil (Petroleum) Ingestion Not classified for development Rat NOAEL 4,350 mg/kg/day during gestation Synthetic Amorphous Silica, Fumed, Crystalline Free Ingestion Not classified for female reproduction Rat NOAEL 509 mg/kg/day 1 generation Synthetic Amorphous Silica, Fumed, Crystalline Free Ingestion Not classified for male reproduction Rat NOAEL 497 mg/kg/day 1 generation Synthetic Amorphous Silica, Fumed, Crystalline Free Ingestion Not classified for development Rat NOAEL 1,350 mg/kg/day during organogenesi s Xylene Inhalation Not classified for female reproduction Human NOAEL Not available occupational exposure Xylene Ingestion Not classified for development Mouse NOAEL Not available during organogenesi s Xylene Inhalation Not classified for development Multiple animal species NOAEL Not available during gestation M-Xylene Inhalation Not classified for female reproduction Human NOAEL Not available occupational exposure M-Xylene Ingestion Not classified for development Mouse NOAEL Not available during organogenesi s M-Xylene Inhalation Not classified for development Multiple animal species NOAEL Not available during gestation Ethylbenzene Inhalation Not classified for development Rat NOAEL 4.3 mg/l premating & during gestation Cumene Inhalation Not classified for development Rabbit NOAEL 11.3 mg/l during organogenesi 3M? 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Seam Sealer, 08505 12/27/17 __________________________________________________________________________________________ Page 12 of 17 s Lactation Name Route Species Value Xylene Ingestion Mouse Not classified for effects on or via lactation M-Xylene Ingestion Mouse Not classified for effects on or via lactation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Toluene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Toluene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Toluene Inhalation immune system Not classified Mouse NOAEL 0.004 mg/l 3 hours Toluene Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Xylene Inhalation auditory system Causes damage to organs Rat LOAEL 6.3 mg/l 8 hours Xylene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Xylene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Xylene Inhalation eyes Not classified Rat NOAEL 3.5 mg/l not available Xylene Inhalation liver Not classified Multiple animal species NOAEL Not available Xylene Ingestion central nervous system depression May cause drowsiness or dizziness Multiple animal species NOAEL Not available Xylene Ingestion eyes Not classified Rat NOAEL 250 mg/kg not applicable M-Xylene Inhalation auditory system Causes damage to organs Rat LOAEL 6.3 mg/l 8 hours M-Xylene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available M-Xylene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available M-Xylene Inhalation eyes Not classified Rat NOAEL 3.5 mg/l not available M-Xylene Inhalation liver Not classified Multiple animal species NOAEL Not available M-Xylene Ingestion central nervous system depression May cause drowsiness or dizziness Multiple animal species NOAEL Not available M-Xylene Ingestion eyes Not classified Rat NOAEL 250 mg/kg not applicable Ethylbenzene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Ethylbenzene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human and animal NOAEL Not available Ethylbenzene Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available 3M? 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Seam Sealer, 08505 12/27/17 __________________________________________________________________________________________ Page 13 of 17 Cumene Inhalation central nervous system depression May cause drowsiness or dizziness Multiple animal species NOAEL Not available not available Cumene Inhalation respiratory irritation May cause respiratory irritation Human LOAEL 0.2 mg/l occupational exposure Cumene Ingestion central nervous system depression May cause drowsiness or dizziness Multiple animal species NOAEL Not available not available Naphthalene Ingestion blood Causes damage to organs Human NOAEL Not available poisoning and/or abuse Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Toluene Inhalation auditory system | nervous system | eyes | olfactory system Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Toluene Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 2.3 mg/l 15 months Toluene Inhalation heart | liver | kidney and/or bladder Not classified Rat NOAEL 11.3 mg/l 15 weeks Toluene Inhalation endocrine system Not classified Rat NOAEL 1.1 mg/l 4 weeks Toluene Inhalation immune system Not classified Mouse NOAEL Not available 20 days Toluene Inhalation bone, teeth, nails, and/or hair Not classified Mouse NOAEL 1.1 mg/l 8 weeks Toluene Inhalation hematopoietic system | vascular system Not classified Human NOAEL Not available occupational exposure Toluene Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 625 mg/kg/day 13 weeks Toluene Ingestion heart Not classified Rat NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion liver | kidney and/or bladder Not classified Multiple animal species NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion hematopoietic system Not classified Mouse NOAEL 600 mg/kg/day 14 days Toluene Ingestion endocrine system Not classified Mouse NOAEL 105 mg/kg/day 28 days Toluene Ingestion immune system Not classified Mouse NOAEL 105 mg/kg/day 4 weeks White Mineral Oil (Petroleum) Ingestion hematopoietic system Not classified Rat NOAEL 1,381 mg/kg/day 90 days White Mineral Oil (Petroleum) Ingestion liver | immune system Not classified Rat NOAEL 1,336 mg/kg/day 90 days Synthetic Amorphous Silica, Fumed, Crystalline Free Inhalation respiratory system | silicosis Not classified Human NOAEL Not available occupational exposure Xylene Inhalation nervous system Causes damage to organs through prolonged or repeated exposure Rat LOAEL 0.4 mg/l 4 weeks Xylene Inhalation auditory system May cause damage to organs though prolonged or repeated exposure Rat LOAEL 7.8 mg/l 5 days Xylene Inhalation liver Not classified Multiple animal species NOAEL Not available Xylene Inhalation heart | endocrine system | hematopoietic Not classified Multiple animal species NOAEL 3.5 mg/l 13 weeks 3M? 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Seam Sealer, 08505 12/27/17 __________________________________________________________________________________________ Page 14 of 17 system | muscles | kidney and/or bladder | respiratory system Xylene Ingestion auditory system Not classified Rat NOAEL 900 mg/kg/day 2 weeks Xylene Ingestion kidney and/or bladder Not classified Rat NOAEL 1,500 mg/kg/day 90 days Xylene Ingestion liver Not classified Multiple animal species NOAEL Not available Xylene Ingestion heart | skin | endocrine system | bone, teeth, nails, and/or hair | hematopoietic system | immune system | nervous system | respiratory system Not classified Mouse NOAEL 1,000 mg/kg/day 103 weeks M-Xylene Inhalation nervous system Causes damage to organs through prolonged or repeated exposure Rat LOAEL 0.4 mg/l 4 weeks M-Xylene Inhalation auditory system May cause damage to organs though prolonged or repeated exposure Rat LOAEL 7.8 mg/l 5 days M-Xylene Inhalation liver Not classified Multiple animal species NOAEL Not available M-Xylene Inhalation heart | endocrine system | hematopoietic system | muscles | kidney and/or bladder | respiratory system Not classified Multiple animal species NOAEL 3.5 mg/l 13 weeks M-Xylene Ingestion auditory system Not classified Rat NOAEL 900 mg/kg/day 2 weeks M-Xylene Ingestion kidney and/or bladder Not classified Rat NOAEL 1,500 mg/kg/day 90 days M-Xylene Ingestion liver Not classified Multiple animal species NOAEL Not available M-Xylene Ingestion heart | skin | endocrine system | bone, teeth, nails, and/or hair | hematopoietic system | immune system | nervous system | respiratory system Not classified Mouse NOAEL 1,000 mg/kg/day 103 weeks Rutile Titanium Dioxide Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 0.01 mg/l 2 years Rutile Titanium Dioxide Inhalation pulmonary fibrosis Not classified Human NOAEL Not available occupational exposure Ethylbenzene Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 2 years Ethylbenzene Inhalation liver Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 1.1 mg/l 103 weeks Ethylbenzene Inhalation hematopoietic system Not classified Rat NOAEL 3.4 mg/l 28 days Ethylbenzene Inhalation auditory system Not classified Rat NOAEL 2.4 mg/l 5 days 3M? 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Seam Sealer, 08505 12/27/17 __________________________________________________________________________________________ Page 15 of 17 Ethylbenzene Inhalation endocrine system Not classified Mouse NOAEL 3.3 mg/l 103 weeks Ethylbenzene Inhalation bone, teeth, nails, and/or hair | muscles Not classified Multiple animal species NOAEL 4.2 mg/l 90 days Ethylbenzene Inhalation heart | immune system | respiratory system Not classified Multiple animal species NOAEL 3.3 mg/l 2 years Ethylbenzene Ingestion liver | kidney and/or bladder Not classified Rat NOAEL 680 mg/kg/day 6 months Cumene Inhalation auditory system | endocrine system | hematopoietic system | liver | nervous system | eyes Not classified Rat NOAEL 59 mg/l 13 weeks Cumene Inhalation kidney and/or bladder Not classified Rat NOAEL 4.9 mg/l 13 weeks Cumene Inhalation respiratory system Not classified Rat NOAEL 59 mg/l 13 weeks Cumene Ingestion kidney and/or bladder | heart | endocrine system | hematopoietic system | liver | respiratory system Not classified Rat NOAEL 769 mg/kg/day 6 months Naphthalene Dermal blood Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Naphthalene Dermal eyes Not classified Human NOAEL Not available occupational exposure Naphthalene Inhalation respiratory system Causes damage to organs through prolonged or repeated exposure Rat LOAEL 0.01 mg/l 13 weeks Naphthalene Inhalation blood Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Naphthalene Inhalation eyes Not classified Human NOAEL Not available occupational exposure Naphthalene Ingestion blood Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Naphthalene Ingestion eyes May cause damage to organs though prolonged or repeated exposure Rabbit LOAEL 500 mg/kg/day 15 days Aspiration Hazard Name Value Toluene Aspiration hazard White Mineral Oil (Petroleum) Aspiration hazard Xylene Aspiration hazard M-Xylene Aspiration hazard Ethylbenzene Aspiration hazard Cumene Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material 3M? Fast 'N Firm? Seam Sealer, 08505 12/27/17 __________________________________________________________________________________________ Page 16 of 17 and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. EPCRA 311/312 Hazard Classifications: Physical Hazards Flammable (gases, aerosols, liquids, or solids) Health Hazards Carcinogenicity Reproductive toxicity Serious eye damage or eye irritation Skin Corrosion or Irritation Specific target organ toxicity (single or repeated exposure) Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Toluene 108-88-3 Trade Secret 15 - 40 Xylene 1330-20-7 Trade Secret 1 - 5 Xylene (Benzene, dimethyl-) 1330-20-7 1 - 5 M-Xylene 108-38-3 Trade Secret < 1.5 M-Xylene (Benzene, 1,3-dimethyl-) 108-38-3 < 1.5 M-Xylene (Benzene, dimethyl-) 108-38-3 < 1.5 Ethylbenzene 100-41-4 Trade Secret < 1 Benzene 71-43-2 Trade Secret < 0.05 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Classification Titanium oxide (TiO2) None Carcinogen 3M? Fast 'N Firm? Seam Sealer, 08505 12/27/17 __________________________________________________________________________________________ Page 17 of 17 Ethylbenzene 100-41-4 Carcinogen Toluene 108-88-3 Developmental Toxin Benzene 71-43-2 Male reproductive toxin Benzene 71-43-2 Carcinogen Benzene 71-43-2 Developmental Toxin Cumene 98-82-8 Carcinogen WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. WARNING: This product contains a chemical known to the State of California to cause cancer. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 3 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 27-9977-3 Version Number: 3.01 Issue Date: 12/27/17 Supercedes Date: 03/26/15 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from3M 3M USA SDSs are available at www.3M.com