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2019-02-08 21:44:08.467 12-74527 0026299638 MSDS COORDINATOR FMP LOCATION 12 1600 E ORANGETHORP FULLERTON, CA 92831-5231 USA MSDS COORDINATOR editTest editi 3M General Offices 3M Center St. Paul, MN 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours) Safety Data Sheet Purchase Order #: Customer Number: Dear Enclosed is the Safety Data Sheet (SDS)* for the product that your company recently purchased from 3M. Please forward the attached document(s) to the individual in your organization responsible for hazard communication. If you are a distributor and resell this product, OSHA and EPA require that you transmit this SDS information to your customers at the time of first shipment or whenever you receive revised SDSs from 3M. 3M SDSs are available over the Internet at www.3m.com/MSDSSearch. You may also order a DVD of 3M SDSs by calling 1-800-364-3577. 3M is committed to meeting our customer requirements. Please contact your 3M customer service or sales representative if you have any questions. If you do not know whom to contact, please call the 3M Product Information Center at 1-800-364-3577. If you are not currently receiving 3M SDSs by e-mail and would like to do so, please contact our eSDS Administrator at This email address is being protected from spambots. You need JavaScript enabled to view it. or by calling 651-736-5875. *An Article Information Sheet (AIS) or Article Information Letter (AIL) may be enclosed in place of an SDS if the product is an article which does not require an SDS under the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. 3M? Yellow Super Weatherstrip and Gasket Adhesive, 08001, 08002 01/18/19 __________________________________________________________________________________________ Page 1 of 19 Safety Data Sheet Copyright,2019,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 10-9110-7 Version Number: 54.04 Issue Date: 01/18/19 Supercedes Date: 01/18/19 SECTION 1: Identification 1.1. Product identifier 3M? Yellow Super Weatherstrip and Gasket Adhesive, 08001, 08002 Product Identification Numbers ID Number UPC ID Number UPC LB-K100-0312-3 LB-K100-0312-4 41-0003-7950-7 60-4550-2994-6 60-4550-2995-3 60-4550-5559-4 00051135080016 60-4550-5568-5 00051135080023 60-9800-2407-3 00-51135-08001-6 60-9800-3334-8 00-51135-08001-6 60-9800-3470-0 00-51135-08012-2 62-2140-0609-0 00-51135-08002-3 62-2140-2609-8 00-51135-08001-6 7000000456, 7000000456, 7010294865 1.2. Recommended use and restrictions on use Recommended use Adhesive, Adhesive for Gaskets, Rubber Weatherstripping 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Liquid: Category 2. Serious Eye Damage/Irritation: Category 2A. 3M? Yellow Super Weatherstrip and Gasket Adhesive, 08001, 08002 01/18/19 __________________________________________________________________________________________ Page 2 of 19 Skin Sensitizer: Category 1A. Reproductive Toxicity: Category 1B. Carcinogenicity: Category 2. Specific Target Organ Toxicity (single exposure): Category 3. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word Danger Symbols Flame | Exclamation mark | Health Hazard | Pictograms Hazard Statements Highly flammable liquid and vapor. Causes serious eye irritation. May cause an allergic skin reaction. May cause drowsiness or dizziness. May damage fertility or the unborn child. Suspected of causing cancer. Causes damage to organs through prolonged or repeated exposure: nervous system | sensory organs | Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. 3M? Yellow Super Weatherstrip and Gasket Adhesive, 08001, 08002 01/18/19 __________________________________________________________________________________________ Page 3 of 19 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF exposed or concerned: Get medical advice/attention. In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. Storage: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 13% of the mixture consists of ingredients of unknown acute oral toxicity. 13% of the mixture consists of ingredients of unknown acute dermal toxicity. 22% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Hexane 110-54-3 7 - 30 Trade Secret * Methyl Ethyl Ketone 78-93-3 10 - 30 Trade Secret * Polychloroprene 9010-98-4 10 - 30 Trade Secret * Formaldehyde, Polymer With 4-(1,1- Dimethylethyl)Phenol, Magnesium Oxide Complex Trade Secret* 10 - 20 Trade Secret * Phenolic Resin Trade Secret* 10 - 15 Trade Secret * Heptane 142-82-5 1 - 10 Trade Secret * Methylcyclopentane 96-37-7 1 - 10 Trade Secret * Toluene 108-88-3 < 10 Trade Secret * 2-Methylpentane 107-83-5 3 - 7 Trade Secret * 3-Methylpentane 96-14-0 3 - 7 Trade Secret * Cyclohexane 110-82-7 < 5 Trade Secret * Magnesium Oxide 1309-48-4 1 - 5 Trade Secret * Zinc Oxide 1314-13-2 < 3 Trade Secret * Styrenated Phenol 61788-44-1 0.1 - 1 Trade Secret * Ethylbenzene 100-41-4 0.01 - 0.42 Trade Secret * Benzene 71-43-2 < 0.05 Trade Secret * Formaldehyde 50-00-0 < 0.05 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: 3M? Yellow Super Weatherstrip and Gasket Adhesive, 08001, 08002 01/18/19 __________________________________________________________________________________________ Page 4 of 19 Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Toxic Vapor, Gas, Particulate During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially 3M? Yellow Super Weatherstrip and Gasket Adhesive, 08001, 08002 01/18/19 __________________________________________________________________________________________ Page 5 of 19 available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. Use personal protective equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation during transfer. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Ethylbenzene 100-41-4 ACGIH TWA:20 ppm A3: Confirmed animal carcin. Ethylbenzene 100-41-4 OSHA TWA:435 mg/m3(100 ppm) 2-Methylpentane 107-83-5 ACGIH TWA:500 ppm;STEL:1000 ppm Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human carcin Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm Hexane 110-54-3 ACGIH TWA:50 ppm SKIN Hexane 110-54-3 OSHA TWA:1800 mg/m3(500 ppm) Cyclohexane 110-82-7 ACGIH TWA:100 ppm Cyclohexane 110-82-7 OSHA TWA:1050 mg/m3(300 ppm) DUST, INERT OR NUISANCE 1309-48-4 OSHA TWA(as total dust):15 mg/m3;TWA(as total dust):50 millions of particles/cu. ft.(15 mg/m3);TWA(respirable fraction):15 millions of particles/cu. ft.(5 mg/m3);TWA(respirable fraction):5 mg/m3 Magnesium Oxide 1309-48-4 ACGIH TWA(inhalable fraction):10 A4: Not class. as human 3M? Yellow Super Weatherstrip and Gasket Adhesive, 08001, 08002 01/18/19 __________________________________________________________________________________________ Page 6 of 19 mg/m3 carcin Magnesium Oxide 1309-48-4 OSHA TWA(as total particulates):15 mg/m3 Zinc Oxide 1314-13-2 ACGIH TWA(respirable fraction):2 mg/m3;STEL(respirable fraction):10 mg/m3 Zinc Oxide 1314-13-2 OSHA TWA(as fume):5 mg/m3;TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Heptane 142-82-5 ACGIH TWA:400 ppm;STEL:500 ppm Heptane 142-82-5 OSHA TWA:2000 mg/m3(500 ppm) Formaldehyde 50-00-0 ACGIH TWA:0.1 ppm;STEL:0.3 ppm A1: Confirmed human carcin., Dermal/Respiratory Sensitizer Formaldehyde 50-00-0 OSHA TWA:0.75 ppm;STEL:2 ppm 29 CFR 1910.1048 Benzene 71-43-2 ACGIH TWA:0.5 ppm;STEL:2.5 ppm SKIN, A1: Confirmed human carcin. Benzene 71-43-2 OSHA TWA:1 ppm;TWA:10 ppm;STEL:5 ppm;CEIL:25 ppm 29 CFR 1910.1028 Methyl Ethyl Ketone 78-93-3 ACGIH TWA:200 ppm;STEL:300 ppm Methyl Ethyl Ketone 78-93-3 OSHA TWA:590 mg/m3(200 ppm) 3-Methylpentane 96-14-0 ACGIH TWA:500 ppm;STEL:1000 ppm ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate 3M? Yellow Super Weatherstrip and Gasket Adhesive, 08001, 08002 01/18/19 __________________________________________________________________________________________ Page 7 of 19 If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Viscous Liquid Odor, Color, Grade: Yellow; Sweet petroleum odor Odor threshold No Data Available pH Not Applicable Melting point No Data Available Boiling Point 148.00 - 189.00 ?F [Details:Petroleum Distillate] Flash Point -6.00 ?F [Test Method:Tagliabue Closed Cup] [Details:Petroleum Distillate] Evaporation rate >=2.5 Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure <=27 psia [@ 131 ?F] Vapor Density 3.0 Density 0.88 g/ml Specific Gravity 0.88 [Ref Std:WATER=1] Solubility in Water Slight (less than 10%) Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity 4,000 - 6,800 centistoke [@ 73.4 ?F ] Hazardous Air Pollutants 0.58 lb HAPS/lb solids [Test Method:Calculated] Volatile Organic Compounds 559 g/l [Test Method:calculated SCAQMD rule 443.1] Volatile Organic Compounds 63.4 % weight [Test Method:calculated per CARB title 2] Percent volatile 64.1 % weight VOC Less H2O & Exempt Solvents 560 g/l [Test Method:calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 3M? Yellow Super Weatherstrip and Gasket Adhesive, 08001, 08002 01/18/19 __________________________________________________________________________________________ Page 8 of 19 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Sparks and/or flames Heat 10.5. Incompatible materials Strong acids 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. 3M? Yellow Super Weatherstrip and Gasket Adhesive, 08001, 08002 01/18/19 __________________________________________________________________________________________ Page 9 of 19 Prolonged or repeated exposure may cause target organ effects: Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Peripheral Neuropathy: Signs/symptoms may include tingling or numbness of the extremities, incoordination, weakness of the hands and feet, tremors and muscle atrophy. Olfactory Effects: Signs/symptoms may include decreased ability to detect odors and/or complete loss of smell. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation Benzene 71-43-2 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Benzene 71-43-2 Known human carcinogen National Toxicology Program Carcinogens Benzene 71-43-2 Cancer hazard OSHA Carcinogens Ethylbenzene 100-41-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Formaldehyde 50-00-0 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Formaldehyde 50-00-0 Known human carcinogen National Toxicology Program Carcinogens Formaldehyde 50-00-0 Cancer hazard OSHA Carcinogens Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE >50 mg/l Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Methyl Ethyl Ketone Dermal Rabbit LD50 > 8,050 mg/kg Methyl Ethyl Ketone Inhalation- Vapor (4 hours) Rat LC50 34.5 mg/l Methyl Ethyl Ketone Ingestion Rat LD50 2,737 mg/kg Hexane Dermal Rabbit LD50 > 2,000 mg/kg Hexane Inhalation- Vapor (4 hours) Rat LC50 170 mg/l Hexane Ingestion Rat LD50 > 28,700 mg/kg Formaldehyde, Polymer With 4-(1,1-Dimethylethyl)Phenol, Magnesium Oxide Complex Dermal LD50 estimated to be 2,000 - 5,000 mg/kg Formaldehyde, Polymer With 4-(1,1-Dimethylethyl)Phenol, Magnesium Oxide Complex Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg Polychloroprene Dermal LD50 estimated to be > 5,000 mg/kg Polychloroprene Ingestion Rat LD50 > 20,000 mg/kg Heptane Dermal Rabbit LD50 3,000 mg/kg Heptane Inhalation- Vapor (4 hours) Rat LC50 103 mg/l Heptane Ingestion Rat LD50 > 15,000 mg/kg 3M? Yellow Super Weatherstrip and Gasket Adhesive, 08001, 08002 01/18/19 __________________________________________________________________________________________ Page 10 of 19 Methylcyclopentane Dermal LD50 estimated to be > 5,000 mg/kg Methylcyclopentane Ingestion Rat LD50 > 5,000 mg/kg Toluene Dermal Rat LD50 12,000 mg/kg Toluene Inhalation- Vapor (4 hours) Rat LC50 30 mg/l Toluene Ingestion Rat LD50 5,550 mg/kg 2-Methylpentane Dermal LD50 estimated to be > 5,000 mg/kg 2-Methylpentane Inhalation- Vapor LC50 estimated to be > 50 mg/l 2-Methylpentane Ingestion LD50 estimated to be > 5,000 mg/kg 3-Methylpentane Dermal LD50 estimated to be > 5,000 mg/kg 3-Methylpentane Inhalation- Vapor LC50 estimated to be > 50 mg/l 3-Methylpentane Ingestion LD50 estimated to be > 5,000 mg/kg Magnesium Oxide Dermal Professio nal judgeme nt LD50 estimated to be 2,000 - 5,000 mg/kg Magnesium Oxide Ingestion Rat LD50 3,870 mg/kg Cyclohexane Dermal Rat LD50 > 2,000 mg/kg Cyclohexane Inhalation- Vapor (4 hours) Rat LC50 > 32.9 mg/l Cyclohexane Ingestion Rat LD50 6,200 mg/kg Zinc Oxide Dermal LD50 estimated to be > 5,000 mg/kg Zinc Oxide Inhalation- Dust/Mist (4 hours) Rat LC50 > 5.7 mg/l Zinc Oxide Ingestion Rat LD50 > 5,000 mg/kg Ethylbenzene Dermal Rabbit LD50 15,433 mg/kg Ethylbenzene Inhalation- Vapor (4 hours) Rat LC50 17.4 mg/l Ethylbenzene Ingestion Rat LD50 4,769 mg/kg Styrenated Phenol Dermal Rabbit LD50 > 5,010 mg/kg Styrenated Phenol Ingestion Rat LD50 3,550 mg/kg Formaldehyde Dermal Rabbit LD50 270 mg/kg Formaldehyde Inhalation- Gas (4 hours) Rat LC50 470 ppm Formaldehyde Ingestion Rat LD50 800 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Methyl Ethyl Ketone Rabbit Minimal irritation Hexane Human and animal Mild irritant Polychloroprene Human No significant irritation Heptane Human Mild irritant Methylcyclopentane similar compoun ds Minimal irritation Toluene Rabbit Irritant 2-Methylpentane Professio nal judgeme nt Mild irritant 3-Methylpentane Professio nal judgeme Mild irritant 3M? Yellow Super Weatherstrip and Gasket Adhesive, 08001, 08002 01/18/19 __________________________________________________________________________________________ Page 11 of 19 nt Magnesium Oxide Professio nal judgeme nt No significant irritation Cyclohexane Rabbit Mild irritant Zinc Oxide Human and animal No significant irritation Ethylbenzene Rabbit Mild irritant Formaldehyde official classifica tion Corrosive Serious Eye Damage/Irritation Name Species Value Methyl Ethyl Ketone Rabbit Severe irritant Hexane Rabbit Mild irritant Polychloroprene Professio nal judgeme nt No significant irritation Heptane Professio nal judgeme nt Moderate irritant Methylcyclopentane similar compoun ds Mild irritant Toluene Rabbit Moderate irritant 2-Methylpentane Professio nal judgeme nt Moderate irritant 3-Methylpentane Professio nal judgeme nt Moderate irritant Cyclohexane Rabbit Mild irritant Zinc Oxide Rabbit Mild irritant Ethylbenzene Rabbit Moderate irritant Formaldehyde official classifica tion Corrosive Skin Sensitization Name Species Value Hexane Human Not classified Toluene Guinea pig Not classified Zinc Oxide Guinea pig Not classified Ethylbenzene Human Not classified Formaldehyde Guinea pig Sensitizing Respiratory Sensitization Name Species Value Formaldehyde Human Some positive data exist, but the data are not sufficient for classification Germ Cell Mutagenicity 3M? Yellow Super Weatherstrip and Gasket Adhesive, 08001, 08002 01/18/19 __________________________________________________________________________________________ Page 12 of 19 Name Route Value Methyl Ethyl Ketone In Vitro Not mutagenic Hexane In Vitro Not mutagenic Hexane In vivo Not mutagenic Heptane In Vitro Not mutagenic Toluene In Vitro Not mutagenic Toluene In vivo Not mutagenic Magnesium Oxide In Vitro Not mutagenic Cyclohexane In Vitro Not mutagenic Cyclohexane In vivo Some positive data exist, but the data are not sufficient for classification Zinc Oxide In Vitro Some positive data exist, but the data are not sufficient for classification Zinc Oxide In vivo Some positive data exist, but the data are not sufficient for classification Ethylbenzene In vivo Not mutagenic Ethylbenzene In Vitro Some positive data exist, but the data are not sufficient for classification Formaldehyde In Vitro Some positive data exist, but the data are not sufficient for classification Formaldehyde In vivo Mutagenic Carcinogenicity Name Route Species Value Methyl Ethyl Ketone Inhalation Human Not carcinogenic Hexane Dermal Mouse Not carcinogenic Hexane Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Toluene Dermal Mouse Some positive data exist, but the data are not sufficient for classification Toluene Ingestion Rat Some positive data exist, but the data are not sufficient for classification Toluene Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Magnesium Oxide Not Specified Human and animal Some positive data exist, but the data are not sufficient for classification Ethylbenzene Inhalation Multiple animal species Carcinogenic Formaldehyde Not Specified Human and animal Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Methyl Ethyl Ketone Inhalation Not classified for development Rat LOAEL 8.8 mg/l during gestation Hexane Ingestion Not classified for development Mouse NOAEL 2,200 mg/kg/day during organogenesi s Hexane Inhalation Not classified for development Rat NOAEL 0.7 mg/l during gestation Hexane Ingestion Toxic to male reproduction Rat NOAEL 1,140 mg/kg/day 90 days Hexane Inhalation Toxic to male reproduction Rat LOAEL 3.52 mg/l 28 days Toluene Inhalation Not classified for female reproduction Human NOAEL Not available occupational exposure Toluene Inhalation Not classified for male reproduction Rat NOAEL 2.3 mg/l 1 generation 3M? Yellow Super Weatherstrip and Gasket Adhesive, 08001, 08002 01/18/19 __________________________________________________________________________________________ Page 13 of 19 Toluene Ingestion Toxic to development Rat LOAEL 520 mg/kg/day during gestation Toluene Inhalation Toxic to development Human NOAEL Not available poisoning and/or abuse Cyclohexane Inhalation Not classified for female reproduction Rat NOAEL 24 mg/l 2 generation Cyclohexane Inhalation Not classified for male reproduction Rat NOAEL 24 mg/l 2 generation Cyclohexane Inhalation Not classified for development Rat NOAEL 6.9 mg/l 2 generation Zinc Oxide Ingestion Not classified for reproduction and/or development Multiple animal species NOAEL 125 mg/kg/day premating & during gestation Ethylbenzene Inhalation Not classified for development Rat NOAEL 4.3 mg/l premating & during gestation Formaldehyde Ingestion Not classified for male reproduction Rat NOAEL 100 mg/kg not applicable Formaldehyde Inhalation Not classified for development Rat NOAEL 10 ppm during gestation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Methyl Ethyl Ketone Inhalation central nervous system depression May cause drowsiness or dizziness official classifica tion NOAEL Not available Methyl Ethyl Ketone Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Methyl Ethyl Ketone Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Methyl Ethyl Ketone Ingestion liver Not classified Rat NOAEL Not available not applicable Methyl Ethyl Ketone Ingestion kidney and/or bladder Not classified Rat LOAEL 1,080 mg/kg not applicable Hexane Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available not available Hexane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Rabbit NOAEL Not available 8 hours Hexane Inhalation respiratory system Not classified Rat NOAEL 24.6 mg/l 8 hours Heptane Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Heptane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Heptane Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Methylcyclopentane Inhalation central nervous system depression May cause drowsiness or dizziness similar compoun ds NOAEL Not available Methylcyclopentane Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Toluene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Toluene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available 3M? Yellow Super Weatherstrip and Gasket Adhesive, 08001, 08002 01/18/19 __________________________________________________________________________________________ Page 14 of 19 Toluene Inhalation immune system Not classified Mouse NOAEL 0.004 mg/l 3 hours Toluene Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse 2-Methylpentane Inhalation central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available 2-Methylpentane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available 2-Methylpentane Inhalation cardiac sensitization Not classified Dog NOAEL Not available 2-Methylpentane Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available 3-Methylpentane Inhalation central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available 3-Methylpentane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available 3-Methylpentane Inhalation cardiac sensitization Not classified Dog NOAEL Not available 3-Methylpentane Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Magnesium Oxide Inhalation respiratory system Not classified Human NOAEL Not available Cyclohexane Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Cyclohexane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human and animal NOAEL Not available Cyclohexane Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Ethylbenzene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Ethylbenzene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human and animal NOAEL Not available Ethylbenzene Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Formaldehyde Inhalation respiratory system Causes damage to organs Rat LOAEL 128 ppm 6 hours Formaldehyde Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Methyl Ethyl Ketone Dermal nervous system Not classified Guinea pig NOAEL Not available 31 weeks Methyl Ethyl Ketone Inhalation liver | kidney and/or bladder | heart | endocrine system | gastrointestinal tract | bone, teeth, nails, Not classified Rat NOAEL 14.7 mg/l 90 days 3M? Yellow Super Weatherstrip and Gasket Adhesive, 08001, 08002 01/18/19 __________________________________________________________________________________________ Page 15 of 19 and/or hair | hematopoietic system | immune system | muscles Methyl Ethyl Ketone Ingestion liver Not classified Rat NOAEL Not available 7 days Methyl Ethyl Ketone Ingestion nervous system Not classified Rat NOAEL 173 mg/kg/day 90 days Hexane Inhalation peripheral nervous system Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Hexane Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Mouse LOAEL 1.76 mg/l 13 weeks Hexane Inhalation liver Not classified Rat NOAEL Not available 6 months Hexane Inhalation kidney and/or bladder Not classified Rat LOAEL 1.76 mg/l 6 months Hexane Inhalation hematopoietic system Not classified Mouse NOAEL 35.2 mg/l 13 weeks Hexane Inhalation auditory system | immune system | eyes Not classified Human NOAEL Not available occupational exposure Hexane Inhalation heart | skin | endocrine system Not classified Rat NOAEL 1.76 mg/l 6 months Hexane Ingestion peripheral nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,140 mg/kg/day 90 days Hexane Ingestion endocrine system | hematopoietic system | liver | immune system | kidney and/or bladder Not classified Rat NOAEL Not available 13 weeks Heptane Inhalation liver | nervous system | kidney and/or bladder Not classified Rat NOAEL 12 mg/l 26 weeks Toluene Inhalation auditory system | nervous system | eyes | olfactory system Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Toluene Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 2.3 mg/l 15 months Toluene Inhalation heart | liver | kidney and/or bladder Not classified Rat NOAEL 11.3 mg/l 15 weeks Toluene Inhalation endocrine system Not classified Rat NOAEL 1.1 mg/l 4 weeks Toluene Inhalation immune system Not classified Mouse NOAEL Not available 20 days Toluene Inhalation bone, teeth, nails, and/or hair Not classified Mouse NOAEL 1.1 mg/l 8 weeks Toluene Inhalation hematopoietic system | vascular system Not classified Human NOAEL Not available occupational exposure Toluene Inhalation gastrointestinal tract Not classified Multiple animal species NOAEL 11.3 mg/l 15 weeks Toluene Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 625 mg/kg/day 13 weeks Toluene Ingestion heart Not classified Rat NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion liver | kidney and/or bladder Not classified Multiple animal species NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion hematopoietic Not classified Mouse NOAEL 600 14 days 3M? Yellow Super Weatherstrip and Gasket Adhesive, 08001, 08002 01/18/19 __________________________________________________________________________________________ Page 16 of 19 system mg/kg/day Toluene Ingestion endocrine system Not classified Mouse NOAEL 105 mg/kg/day 28 days Toluene Ingestion immune system Not classified Mouse NOAEL 105 mg/kg/day 4 weeks 2-Methylpentane Inhalation peripheral nervous system Not classified Rat NOAEL 5.3 mg/l 14 weeks 2-Methylpentane Ingestion peripheral nervous system Not classified Rat NOAEL Not available 8 weeks 2-Methylpentane Ingestion kidney and/or bladder Not classified Rat LOAEL 2,000 mg/kg 28 days 3-Methylpentane Inhalation peripheral nervous system Not classified Rat NOAEL 5.3 mg/l 14 weeks 3-Methylpentane Ingestion peripheral nervous system Not classified Rat NOAEL Not available 8 weeks 3-Methylpentane Ingestion kidney and/or bladder Not classified Rat LOAEL 2,000 mg/kg 28 days Cyclohexane Inhalation liver Not classified Rat NOAEL 24 mg/l 90 days Cyclohexane Inhalation auditory system Not classified Rat NOAEL 1.7 mg/l 90 days Cyclohexane Inhalation kidney and/or bladder Not classified Rabbit NOAEL 2.7 mg/l 10 weeks Cyclohexane Inhalation hematopoietic system Not classified Mouse NOAEL 24 mg/l 14 weeks Cyclohexane Inhalation peripheral nervous system Not classified Rat NOAEL 8.6 mg/l 30 weeks Zinc Oxide Ingestion nervous system Not classified Rat NOAEL 600 mg/kg/day 10 days Zinc Oxide Ingestion endocrine system | hematopoietic system | kidney and/or bladder Not classified Other NOAEL 500 mg/kg/day 6 months Ethylbenzene Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 2 years Ethylbenzene Inhalation liver Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 1.1 mg/l 103 weeks Ethylbenzene Inhalation hematopoietic system Not classified Rat NOAEL 3.4 mg/l 28 days Ethylbenzene Inhalation auditory system Not classified Rat NOAEL 2.4 mg/l 5 days Ethylbenzene Inhalation endocrine system Not classified Mouse NOAEL 3.3 mg/l 103 weeks Ethylbenzene Inhalation gastrointestinal tract Not classified Rat NOAEL 3.3 mg/l 2 years Ethylbenzene Inhalation bone, teeth, nails, and/or hair | muscles Not classified Multiple animal species NOAEL 4.2 mg/l 90 days Ethylbenzene Inhalation heart | immune system | respiratory system Not classified Multiple animal species NOAEL 3.3 mg/l 2 years Ethylbenzene Ingestion liver | kidney and/or bladder Not classified Rat NOAEL 680 mg/kg/day 6 months Formaldehyde Dermal respiratory system Not classified Mouse NOAEL 80 mg/kg/day 60 weeks Formaldehyde Inhalation respiratory system Causes damage to organs through prolonged or repeated exposure Rat NOAEL 0.3 ppm 28 months Formaldehyde Inhalation liver Not classified Rat NOAEL 20 ppm 13 weeks Formaldehyde Inhalation hematopoietic system Not classified Mouse NOAEL 15 ppm 3 weeks Formaldehyde Inhalation nervous system Not classified Mouse NOAEL 10 ppm 13 weeks Formaldehyde Inhalation endocrine system | immune system | Not classified Rat NOAEL 15 ppm 28 months 3M? Yellow Super Weatherstrip and Gasket Adhesive, 08001, 08002 01/18/19 __________________________________________________________________________________________ Page 17 of 19 muscles | kidney and/or bladder Formaldehyde Inhalation gastrointestinal tract Not classified Rat NOAEL 15 ppm 2 years Formaldehyde Inhalation eyes | vascular system Not classified Rat NOAEL 14.3 ppm 2 years Formaldehyde Inhalation heart Not classified Mouse NOAEL 14.3 ppm 2 years Formaldehyde Ingestion liver Not classified Rat NOAEL 300 mg/kg/day 2 years Formaldehyde Ingestion immune system Not classified Rat NOAEL 20 mg/kg/day 4 weeks Formaldehyde Ingestion kidney and/or bladder Not classified Rat NOAEL 15 mg/kg/day 24 months Formaldehyde Ingestion nervous system Not classified Rat NOAEL 109 mg/kg/day 2 years Formaldehyde Ingestion heart | endocrine system | hematopoietic system | respiratory system | vascular system Not classified Rat NOAEL 300 mg/kg/day 2 years Formaldehyde Ingestion skin | muscles | eyes Not classified Rat NOAEL 109 mg/kg/day 2 years Aspiration Hazard Name Value Hexane Aspiration hazard Heptane Aspiration hazard Methylcyclopentane Aspiration hazard Toluene Aspiration hazard 2-Methylpentane Aspiration hazard 3-Methylpentane Aspiration hazard Cyclohexane Aspiration hazard Ethylbenzene Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. 3M? Yellow Super Weatherstrip and Gasket Adhesive, 08001, 08002 01/18/19 __________________________________________________________________________________________ Page 18 of 19 SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. EPCRA 311/312 Hazard Classifications: Physical Hazards Flammable (gases, aerosols, liquids, or solids) Health Hazards Carcinogenicity Reproductive toxicity Respiratory or Skin Sensitization Serious eye damage or eye irritation Specific target organ toxicity (single or repeated exposure) Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Toluene 108-88-3 Trade Secret < 10 Cyclohexane 110-82-7 Trade Secret < 5 Hexane 110-54-3 Trade Secret 7 - 30 Hexane (Hexane) 110-54-3 7 - 30 Zinc Oxide (ZINC COMPOUNDS) 1314-13-2 < 3 Ethylbenzene 100-41-4 Trade Secret 0.01 - 0.42 Benzene 71-43-2 Trade Secret < 0.05 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Listing LEAD None Female reproductive toxin LEAD None Male reproductive toxin LEAD COMPOUNDS None Carcinogen LEAD None Developmental Toxin CADMIUM None Male reproductive toxin CADMIUM AND CADMIUM COMPOUNDS None Carcinogen CADMIUM None Developmental Toxin ETHYLBENZENE 100-41-4 Carcinogen TOLUENE 108-88-3 Developmental Toxin N-HEXANE 110-54-3 Male reproductive toxin 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. All required components of this product are listed on the active portion of the TSCA Inventory. 3M? Yellow Super Weatherstrip and Gasket Adhesive, 08001, 08002 01/18/19 __________________________________________________________________________________________ Page 19 of 19 Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 3 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 10-9110-7 Version Number: 54.04 Issue Date: 01/18/19 Supercedes Date: 01/18/19 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from3M 3M USA SDSs are available at www.3M.com