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2019-02-08 21:44:08.467 7-63133 0026299440 MSDS COORDINATOR FACTORY MOTOR PARTS 5328 W ROOSEVELT ST PHOENIX, AZ 85043-2713 USA MSDS COORDINATOR editTest editi 3M General Offices 3M Center St. Paul, MN 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours) Safety Data Sheet Purchase Order #: Customer Number: Dear Enclosed is the Safety Data Sheet (SDS)* for the product that your company recently purchased from 3M. Please forward the attached document(s) to the individual in your organization responsible for hazard communication. If you are a distributor and resell this product, OSHA and EPA require that you transmit this SDS information to your customers at the time of first shipment or whenever you receive revised SDSs from 3M. 3M SDSs are available over the Internet at www.3m.com/MSDSSearch. You may also order a DVD of 3M SDSs by calling 1-800-364-3577. 3M is committed to meeting our customer requirements. Please contact your 3M customer service or sales representative if you have any questions. If you do not know whom to contact, please call the 3M Product Information Center at 1-800-364-3577. If you are not currently receiving 3M SDSs by e-mail and would like to do so, please contact our eSDS Administrator at This email address is being protected from spambots. You need JavaScript enabled to view it. or by calling 651-736-5875. *An Article Information Sheet (AIS) or Article Information Letter (AIL) may be enclosed in place of an SDS if the product is an article which does not require an SDS under the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. 3M? Undercoating, PN 08881 12/13/18 __________________________________________________________________________________________ Page 1 of 15 Safety Data Sheet Copyright,2018,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 19-8684-3 Version Number: 5.01 Issue Date: 12/13/18 Supercedes Date: 05/21/18 SECTION 1: Identification 1.1. Product identifier 3M? Undercoating, PN 08881 Product Identification Numbers ID Number UPC ID Number UPC 60-4400-9649-7 7000044939 1.2. Recommended use and restrictions on use Recommended use Coating, Undercoating for automobiles. 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Aerosol: Category 1. Gas Under Pressure: Liquefied gas. Serious Eye Damage/Irritation: Category 2B. Skin Corrosion/Irritation: Category 2. Reproductive Toxicity: Category 1B. Carcinogenicity: Category 1A. Specific Target Organ Toxicity (single exposure): Category 1. 3M? Undercoating, PN 08881 12/13/18 __________________________________________________________________________________________ Page 2 of 15 Specific Target Organ Toxicity (single exposure): Category 3. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word Danger Symbols Flame | Gas cylinder | Exclamation mark | Health Hazard | Pictograms Hazard Statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes eye irritation. Causes skin irritation. May cause drowsiness or dizziness. May damage fertility or the unborn child. May cause cancer. Causes damage to organs: cardiovascular system | Causes damage to organs through prolonged or repeated exposure: nervous system | sensory organs | Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. 3M? Undercoating, PN 08881 12/13/18 __________________________________________________________________________________________ Page 3 of 15 IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. IF exposed or concerned: Get medical advice/attention. Specific treatment (see Notes to Physician on this label). Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. 15% of the mixture consists of ingredients of unknown acute dermal toxicity. 60% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Asphalt 8052-42-4 15 - 40 Trade Secret * Calcium Carbonate 471-34-1 15 - 40 Trade Secret * Toluene 108-88-3 10 - 30 Trade Secret * Propane 74-98-6 7 - 13 Trade Secret * Medium Aliphatic Solvent Naphtha 64742-88-7 5 - 10 Trade Secret * Butane 106-97-8 3 - 7 Trade Secret * Aluminatesilicate 1327-36-2 1 - 5 Trade Secret * Methyl Alcohol 67-56-1 0.1 - 1 Trade Secret * Quartz Silica 14808-60-7 0.1 - 1 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. Get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you are concerned, get medical advice. 3M? Undercoating, PN 08881 12/13/18 __________________________________________________________________________________________ Page 4 of 15 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Hydrocarbons During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Hydrogen Sulfide During Combustion Oxides of Sulfur During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Contain spill. Cover spill area with a fire-extinguishing foam designed for use on solvents, such as alcohols and acetone, that can dissolve in water. An AR - AFFF type foam is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 3M? Undercoating, PN 08881 12/13/18 __________________________________________________________________________________________ Page 5 of 15 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Butane 106-97-8 ACGIH STEL:1000 ppm Natural gas 106-97-8 ACGIH Limit value not established: simple asphyxiant Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human carcin Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm Aluminum, insoluble compounds 1327-36-2 ACGIH TWA(respirable fraction):1 mg/m3 A4: Not class. as human carcin Quartz Silica 14808-60-7 ACGIH TWA(respirable fraction):0.025 mg/m3 A2: Suspected human carcin. Quartz Silica 14808-60-7 OSHA TWA Table Z- 1(respirable):0.05 mg/m3;TWA Table Z- 3(respirable):0.1 mg/m3 Limestone 471-34-1 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Methyl Alcohol 67-56-1 ACGIH TWA:200 ppm;STEL:250 ppm SKIN Methyl Alcohol 67-56-1 OSHA TWA:260 mg/m3(200 ppm) Propane 74-98-6 ACGIH Limit value not established: simple asphyxiant Propane 74-98-6 OSHA TWA:1800 mg/m3(1000 ppm) Asphalt 8052-42-4 ACGIH TWA(as benzene solubles, inhalable fraction):0.5 mg/m3 A4: Not class. as human carcin ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Provide ventilated enclosure for heat curing. Curing enclosures must be exhausted to outdoors or to a suitable emission control device. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below 3M? Undercoating, PN 08881 12/13/18 __________________________________________________________________________________________ Page 6 of 15 relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Full Face Shield Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Fluoroelastomer Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece supplied-air respirator For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Aerosol Odor, Color, Grade: Thick black solution with a solvent odor. Odor threshold No Data Available pH Not Applicable Melting point No Data Available Boiling Point No Data Available Flash Point -20 ?F Evaporation rate >= 1 [Ref Std:ETHER=1] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) 1.0 % Flammable Limits(UEL) 9.5 % Vapor Pressure No Data Available Vapor Density >= 1 [Ref Std:AIR=1] Density 1.1 g/ml Specific Gravity 1.1 [Ref Std:WATER=1] Solubility In Water Not Applicable Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity No Data Available Average particle size No Data Available 3M? Undercoating, PN 08881 12/13/18 __________________________________________________________________________________________ Page 7 of 15 Hazardous Air Pollutants 0.29 lb HAPS/lb solids [Test Method:Calculated] Volatile Organic Compounds 39.1 % weight [Test Method:calculated per CARB title 2] Volatile Organic Compounds 430 g/l [Test Method:calculated SCAQMD rule 443.1] Percent volatile 61.0 % VOC Less H2O & Exempt Solvents 430 g/l [Test Method:calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material is considered to be non reactive under normal use conditions. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid None known. 10.5. Incompatible materials None known. 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: May be harmful if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. 3M? Undercoating, PN 08881 12/13/18 __________________________________________________________________________________________ Page 8 of 15 May cause additional health effects (see below). Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Single exposure, above recommended guidelines, may cause: Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal. Prolonged or repeated exposure may cause target organ effects: Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Olfactory Effects: Signs/symptoms may include decreased ability to detect odors and/or complete loss of smell. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation SILICA, CRYS AIRRESP 14808-60-7 Known human carcinogen National Toxicology Program Carcinogens Asphalt 8052-42-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Quartz Silica 14808-60-7 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE20 - 50 mg/l Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Asphalt Dermal Rabbit LD50 > 2,000 mg/kg Asphalt Ingestion Rat LD50 > 5,000 mg/kg Calcium Carbonate Dermal Rat LD50 > 2,000 mg/kg Calcium Carbonate Inhalation- Dust/Mist (4 hours) Rat LC50 3 mg/l 3M? Undercoating, PN 08881 12/13/18 __________________________________________________________________________________________ Page 9 of 15 Calcium Carbonate Ingestion Rat LD50 6,450 mg/kg Toluene Dermal Rat LD50 12,000 mg/kg Toluene Inhalation- Vapor (4 hours) Rat LC50 30 mg/l Toluene Ingestion Rat LD50 5,550 mg/kg Propane Inhalation- Gas (4 hours) Rat LC50 > 200,000 ppm Medium Aliphatic Solvent Naphtha Inhalation- Vapor LC50 estimated to be 20 - 50 mg/l Medium Aliphatic Solvent Naphtha Dermal Rabbit LD50 > 3,000 mg/kg Medium Aliphatic Solvent Naphtha Ingestion Rat LD50 > 5,000 mg/kg Butane Inhalation- Gas (4 hours) Rat LC50 277,000 ppm Aluminatesilicate Dermal LD50 estimated to be > 5,000 mg/kg Aluminatesilicate Ingestion LD50 estimated to be > 5,000 mg/kg Methyl Alcohol Dermal LD50 estimated to be 1,000 - 2,000 mg/kg Methyl Alcohol Inhalation- Vapor LC50 estimated to be 10 - 20 mg/l Methyl Alcohol Ingestion LD50 estimated to be 50 - 300 mg/kg Quartz Silica Dermal LD50 estimated to be > 5,000 mg/kg Quartz Silica Ingestion LD50 estimated to be > 5,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Asphalt Human Minimal irritation Calcium Carbonate Rabbit No significant irritation Toluene Rabbit Irritant Propane Rabbit Minimal irritation Medium Aliphatic Solvent Naphtha Rabbit Irritant Butane Professio nal judgeme nt No significant irritation Methyl Alcohol Rabbit Mild irritant Quartz Silica Professio nal judgeme nt No significant irritation Serious Eye Damage/Irritation Name Species Value Asphalt Human Mild irritant Calcium Carbonate Rabbit No significant irritation Toluene Rabbit Moderate irritant Propane Rabbit Mild irritant Medium Aliphatic Solvent Naphtha Rabbit No significant irritation Butane Rabbit No significant irritation Methyl Alcohol Rabbit Moderate irritant Skin Sensitization Name Species Value Toluene Guinea pig Not classified Medium Aliphatic Solvent Naphtha Guinea pig Not classified Methyl Alcohol Guinea Not classified 3M? Undercoating, PN 08881 12/13/18 __________________________________________________________________________________________ Page 10 of 15 pig Photosensitization Name Species Value Asphalt Human Not sensitizing Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Asphalt In vivo Not mutagenic Asphalt In Vitro Some positive data exist, but the data are not sufficient for classification Toluene In Vitro Not mutagenic Toluene In vivo Not mutagenic Propane In Vitro Not mutagenic Medium Aliphatic Solvent Naphtha In vivo Not mutagenic Medium Aliphatic Solvent Naphtha In Vitro Some positive data exist, but the data are not sufficient for classification Butane In Vitro Not mutagenic Methyl Alcohol In Vitro Some positive data exist, but the data are not sufficient for classification Methyl Alcohol In vivo Some positive data exist, but the data are not sufficient for classification Quartz Silica In Vitro Some positive data exist, but the data are not sufficient for classification Quartz Silica In vivo Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Asphalt Not Specified Human and animal Some positive data exist, but the data are not sufficient for classification Toluene Dermal Mouse Some positive data exist, but the data are not sufficient for classification Toluene Ingestion Rat Some positive data exist, but the data are not sufficient for classification Toluene Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Medium Aliphatic Solvent Naphtha Dermal Mouse Some positive data exist, but the data are not sufficient for classification Medium Aliphatic Solvent Naphtha Inhalation Human and animal Some positive data exist, but the data are not sufficient for classification Methyl Alcohol Inhalation Multiple animal species Not carcinogenic Quartz Silica Inhalation Human and animal Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Calcium Carbonate Ingestion Not classified for development Rat NOAEL 625 mg/kg/day premating & during gestation 3M? Undercoating, PN 08881 12/13/18 __________________________________________________________________________________________ Page 11 of 15 Toluene Inhalation Not classified for female reproduction Human NOAEL Not available occupational exposure Toluene Inhalation Not classified for male reproduction Rat NOAEL 2.3 mg/l 1 generation Toluene Ingestion Toxic to development Rat LOAEL 520 mg/kg/day during gestation Toluene Inhalation Toxic to development Human NOAEL Not available poisoning and/or abuse Medium Aliphatic Solvent Naphtha Inhalation Not classified for development Rat NOAEL 2.4 mg/l during organogenesi s Methyl Alcohol Ingestion Not classified for male reproduction Rat NOAEL 1,600 mg/kg/day 21 days Methyl Alcohol Ingestion Toxic to development Mouse LOAEL 4,000 mg/kg/day during organogenesi s Methyl Alcohol Inhalation Toxic to development Mouse NOAEL 1.3 mg/l during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Calcium Carbonate Inhalation respiratory system Not classified Rat NOAEL 0.812 mg/l 90 minutes Toluene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Toluene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Toluene Inhalation immune system Not classified Mouse NOAEL 0.004 mg/l 3 hours Toluene Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Propane Inhalation cardiac sensitization Causes damage to organs Human NOAEL Not available Propane Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Propane Inhalation respiratory irritation Not classified Human NOAEL Not available Medium Aliphatic Solvent Naphtha Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Medium Aliphatic Solvent Naphtha Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Medium Aliphatic Solvent Naphtha Inhalation nervous system Not classified Dog NOAEL 6.5 mg/l 4 hours Medium Aliphatic Solvent Naphtha Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Butane Inhalation cardiac sensitization Causes damage to organs Human NOAEL Not available Butane Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Butane Inhalation heart Not classified Dog NOAEL 5,000 ppm 25 minutes Butane Inhalation respiratory irritation Not classified Rabbit NOAEL Not available Methyl Alcohol Inhalation blindness Causes damage to organs Human NOAEL Not available occupational exposure Methyl Alcohol Inhalation central nervous May cause drowsiness or Human NOAEL Not not available 3M? Undercoating, PN 08881 12/13/18 __________________________________________________________________________________________ Page 12 of 15 system depression dizziness available Methyl Alcohol Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Rat NOAEL Not available 6 hours Methyl Alcohol Ingestion blindness Causes damage to organs Human NOAEL Not available poisoning and/or abuse Methyl Alcohol Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Asphalt Inhalation respiratory system Not classified Human NOAEL Not available occupational exposure Calcium Carbonate Inhalation respiratory system Not classified Human NOAEL Not available occupational exposure Toluene Inhalation auditory system | nervous system | eyes | olfactory system Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Toluene Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 2.3 mg/l 15 months Toluene Inhalation heart | liver | kidney and/or bladder Not classified Rat NOAEL 11.3 mg/l 15 weeks Toluene Inhalation endocrine system Not classified Rat NOAEL 1.1 mg/l 4 weeks Toluene Inhalation immune system Not classified Mouse NOAEL Not available 20 days Toluene Inhalation bone, teeth, nails, and/or hair Not classified Mouse NOAEL 1.1 mg/l 8 weeks Toluene Inhalation hematopoietic system | vascular system Not classified Human NOAEL Not available occupational exposure Toluene Inhalation gastrointestinal tract Not classified Multiple animal species NOAEL 11.3 mg/l 15 weeks Toluene Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 625 mg/kg/day 13 weeks Toluene Ingestion heart Not classified Rat NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion liver | kidney and/or bladder Not classified Multiple animal species NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion hematopoietic system Not classified Mouse NOAEL 600 mg/kg/day 14 days Toluene Ingestion endocrine system Not classified Mouse NOAEL 105 mg/kg/day 28 days Toluene Ingestion immune system Not classified Mouse NOAEL 105 mg/kg/day 4 weeks Medium Aliphatic Solvent Naphtha Inhalation nervous system Not classified Rat LOAEL 4.6 mg/l 6 months Medium Aliphatic Solvent Naphtha Inhalation kidney and/or bladder Not classified Rat LOAEL 1.9 mg/l 13 weeks Medium Aliphatic Solvent Naphtha Inhalation respiratory system Not classified Multiple animal species NOAEL 0.6 mg/l 90 days Medium Aliphatic Solvent Naphtha Inhalation bone, teeth, nails, and/or hair | blood | liver | muscles Not classified Rat NOAEL 5.6 mg/l 12 weeks Medium Aliphatic Solvent Naphtha Inhalation heart Not classified Multiple animal species NOAEL 1.3 mg/l 90 days Butane Inhalation kidney and/or bladder | blood Not classified Rat NOAEL 4,489 ppm 90 days 3M? Undercoating, PN 08881 12/13/18 __________________________________________________________________________________________ Page 13 of 15 Methyl Alcohol Inhalation liver Not classified Rat NOAEL 6.55 mg/l 4 weeks Methyl Alcohol Inhalation respiratory system Not classified Rat NOAEL 13.1 mg/l 6 weeks Methyl Alcohol Ingestion liver | nervous system Not classified Rat NOAEL 2,500 mg/kg/day 90 days Quartz Silica Inhalation silicosis Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Aspiration Hazard Name Value Toluene Aspiration hazard Medium Aliphatic Solvent Naphtha Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. If no other disposal options are available, waste product that has been completely cured or polymerized may be placed in a landfill properly designed for industrial waste. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. EPCRA 311/312 Hazard Classifications: Physical Hazards Flammable (gases, aerosols, liquids, or solids) 3M? Undercoating, PN 08881 12/13/18 __________________________________________________________________________________________ Page 14 of 15 Gas under pressure Health Hazards Carcinogenicity Reproductive toxicity Serious eye damage or eye irritation Skin Corrosion or Irritation Specific target organ toxicity (single or repeated exposure) Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Toluene 108-88-3 Trade Secret 10 - 30 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Listing BITUMENS, EXTRACTS OF STEAM-REFINED AND AIR REFINED None Carcinogen SILICA, CRYSTALLINE (AIRBORNE PARTICLES OF RESPIRABLE SIZE) None Carcinogen TOLUENE 108-88-3 Developmental Toxin METHANOL 67-56-1 Developmental Toxin 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. All required components of this product are listed on the active portion of the TSCA Inventory. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 4 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 19-8684-3 Version Number: 5.01 Issue Date: 12/13/18 Supercedes Date: 05/21/18 3M? Undercoating, PN 08881 12/13/18 __________________________________________________________________________________________ Page 15 of 15 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from3M 3M USA SDSs are available at www.3M.com