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2019-03-01 04:25:19.233 12-74875 0026299638 MSDS COORDINATOR FMP LOCATION 12 1600 E ORANGETHORP FULLERTON, CA 92831-5231 USA MSDS COORDINATOR editTest editi 3M General Offices 3M Center St. Paul, MN 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours) Safety Data Sheet Purchase Order #: Customer Number: Dear Enclosed is the Safety Data Sheet (SDS)* for the product that your company recently purchased from 3M. Please forward the attached document(s) to the individual in your organization responsible for hazard communication. If you are a distributor and resell this product, OSHA and EPA require that you transmit this SDS information to your customers at the time of first shipment or whenever you receive revised SDSs from 3M. 3M SDSs are available over the Internet at www.3m.com/MSDSSearch. You may also order a DVD of 3M SDSs by calling 1-800-364-3577. 3M is committed to meeting our customer requirements. Please contact your 3M customer service or sales representative if you have any questions. If you do not know whom to contact, please call the 3M Product Information Center at 1-800-364-3577. If you are not currently receiving 3M SDSs by e-mail and would like to do so, please contact our eSDS Administrator at This email address is being protected from spambots. You need JavaScript enabled to view it. or by calling 651-736-5875. *An Article Information Sheet (AIS) or Article Information Letter (AIL) may be enclosed in place of an SDS if the product is an article which does not require an SDS under the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. 3M? Weatherstrip Adhesive - Black, P.N. 08011 01/14/19 __________________________________________________________________________________________ Page 1 of 18 Safety Data Sheet Copyright,2019,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 10-2974-3 Version Number: 65.03 Issue Date: 01/14/19 Supercedes Date: 04/02/18 SECTION 1: Identification 1.1. Product identifier 3M? Weatherstrip Adhesive - Black, P.N. 08011 Product Identification Numbers ID Number UPC ID Number UPC 41-0003-7953-1 41-3701-2176-0 60-4550-4404-4 60-4550-5761-6 00051135080115 60-9800-2703-5 00-51135-08011-5 62-4799-2609-9 00-51135-08011-5 7010362993 1.2. Recommended use and restrictions on use Recommended use Automotive, Trim Adhesive 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Liquid: Category 2. Serious Eye Damage/Irritation: Category 2B. Reproductive Toxicity: Category 1B. Carcinogenicity: Category 2. Specific Target Organ Toxicity (single exposure): Category 3. 3M? Weatherstrip Adhesive - Black, P.N. 08011 01/14/19 __________________________________________________________________________________________ Page 2 of 18 Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word Danger Symbols Flame | Exclamation mark | Health Hazard | Pictograms Hazard Statements Highly flammable liquid and vapor. Causes eye irritation. May cause drowsiness or dizziness. May damage fertility or the unborn child. Suspected of causing cancer. Causes damage to organs through prolonged or repeated exposure: nervous system | respiratory system | sensory organs | Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF exposed or concerned: Get medical advice/attention. 3M? Weatherstrip Adhesive - Black, P.N. 08011 01/14/19 __________________________________________________________________________________________ Page 3 of 18 In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. Storage: Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 3% of the mixture consists of ingredients of unknown acute oral toxicity. 3% of the mixture consists of ingredients of unknown acute dermal toxicity. 14% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Hexane 110-54-3 7 - 30 Trade Secret * Heptane 142-82-5 < 15 Trade Secret * Methylcyclopentane 96-37-7 < 15 Trade Secret * 2-Methylpentane 107-83-5 5 - 10 Trade Secret * 3-Methylpentane 96-14-0 5 - 10 Trade Secret * Talc 14807-96-6 5 - 10 Trade Secret * Naphtha, Light Steam-Cracked Arom., Piperylene Conc., Polymd. 68478-07-9 3 - 7 Trade Secret * Polyisoprene 9003-31-0 3 - 7 Trade Secret * Styrene-Butadiene Polymer 9003-55-8 3 - 7 Trade Secret * Toluene 108-88-3 3 - 7 Trade Secret * 2,3-Dimethylbutane 79-29-8 1 - 5 Trade Secret * Calcium Zinc Resinate 68334-35-0 1 - 5 Trade Secret * Cyclohexane 110-82-7 1 - 5 Trade Secret * Phenolic Resin NJTS# 04499600-6305P Trade Secret* 1 - 5 Trade Secret * Ethyl Alcohol 64-17-5 < 1 Trade Secret * Benzene, ethenyl-, homopolymer (oligomeric) 9003-53-6 < 0.5 Trade Secret * Carbon Black Trade Secret* < 0.5 Trade Secret * Benzene 71-43-2 < 0.07 Trade Secret * NJTS or NJTSRN: New Jersey Trade Secret Registry Number. *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. 3M? Weatherstrip Adhesive - Black, P.N. 08011 01/14/19 __________________________________________________________________________________________ Page 4 of 18 Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Aldehydes During Combustion Hydrocarbons During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Toxic Vapor, Gas, Particulate During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking 3M? Weatherstrip Adhesive - Black, P.N. 08011 01/14/19 __________________________________________________________________________________________ Page 5 of 18 tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. Use personal protective equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation during transfer. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments 2-Methylpentane 107-83-5 ACGIH TWA:500 ppm;STEL:1000 ppm Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human carcin Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm Hexane 110-54-3 ACGIH TWA:50 ppm SKIN Hexane 110-54-3 OSHA TWA:1800 mg/m3(500 ppm) Cyclohexane 110-82-7 ACGIH TWA:100 ppm Cyclohexane 110-82-7 OSHA TWA:1050 mg/m3(300 ppm) Heptane 142-82-5 ACGIH TWA:400 ppm;STEL:500 ppm Heptane 142-82-5 OSHA TWA:2000 mg/m3(500 ppm) DUST, INERT OR NUISANCE 14807-96-6 OSHA TWA(as total dust):15 mg/m3;TWA(as total dust):50 millions of particles/cu. ft.(15 mg/m3);TWA(respirable fraction):15 millions of particles/cu. ft.(5 mg/m3);TWA(respirable fraction):5 mg/m3 Talc 14807-96-6 ACGIH TWA(respirable fraction):2 mg/m3 A4: Not class. as human carcin Talc 14807-96-6 OSHA TWA:2 mg/m3 Ethyl Alcohol 64-17-5 ACGIH STEL:1000 ppm A3: Confirmed animal carcin. 3M? Weatherstrip Adhesive - Black, P.N. 08011 01/14/19 __________________________________________________________________________________________ Page 6 of 18 Ethyl Alcohol 64-17-5 OSHA TWA:1900 mg/m3(1000 ppm) Benzene 71-43-2 ACGIH TWA:0.5 ppm;STEL:2.5 ppm SKIN, A1: Confirmed human carcin. Benzene 71-43-2 OSHA TWA:1 ppm;TWA:10 ppm;STEL:5 ppm;CEIL:25 ppm 29 CFR 1910.1028 2,3-Dimethylbutane 79-29-8 ACGIH TWA:500 ppm;STEL:1000 ppm 3-Methylpentane 96-14-0 ACGIH TWA:500 ppm;STEL:1000 ppm Carbon Black Trade Secret ACGIH TWA(inhalable fraction):3 mg/m3 A3: Confirmed animal carcin. Carbon Black Trade Secret OSHA TWA:3.5 mg/m3 ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 3M? Weatherstrip Adhesive - Black, P.N. 08011 01/14/19 __________________________________________________________________________________________ Page 7 of 18 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Medium paste Odor, Color, Grade: Black; Mild odor Odor threshold No Data Available pH No Data Available Melting point No Data Available Boiling Point 148.0 - 189.0 ?F Flash Point -6.0 ?F [Test Method:Tagliabue Closed Cup] Evaporation rate 2.5 [Ref Std:ETHER=1] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) 1.0 % volume Flammable Limits(UEL) 7.0 % volume Vapor Pressure 120.0 mmHg [@ 68 ?F] Vapor Density 3.00 [Ref Std:AIR=1] Density 0.820 g/ml Specific Gravity 0.820 [Ref Std:WATER=1] Solubility in Water Slight (less than 10%) Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity 7,500 - 18,000 centipoise Hazardous Air Pollutants 30.3 % weight [Test Method:Calculated] Hazardous Air Pollutants 1.36 lb HAPS/lb solids [Test Method:Calculated] Volatile Organic Compounds 63.7 % weight [Test Method:calculated per CARB title 2] Volatile Organic Compounds 522 g/l [Test Method:calculated SCAQMD rule 443.1] Percent volatile 63.8 % weight VOC Less H2O & Exempt Solvents 523 g/l [Test Method:calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material is considered to be non reactive under normal use conditions. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat 10.5. Incompatible materials Strong acids Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. 3M? Weatherstrip Adhesive - Black, P.N. 08011 01/14/19 __________________________________________________________________________________________ Page 8 of 18 SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause target organ effects: Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests. Prolonged or repeated exposure by ingestion may cause: Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Peripheral Neuropathy: Signs/symptoms may include tingling or numbness of the extremities, incoordination, weakness of the hands and feet, tremors and muscle atrophy. Olfactory Effects: Signs/symptoms may include decreased ability to detect odors and/or complete loss of smell. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. 3M? Weatherstrip Adhesive - Black, P.N. 08011 01/14/19 __________________________________________________________________________________________ Page 9 of 18 Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation Generic: CAS NO S14807966D 14807-96-6 Grp. 2B: Possible human carc. International Agency for Research on Cancer Benzene 71-43-2 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Benzene 71-43-2 Known human carcinogen National Toxicology Program Carcinogens Benzene 71-43-2 Cancer hazard OSHA Carcinogens Carbon Black Trade Secret Grp. 2B: Possible human carc. International Agency for Research on Cancer Additional Information: This product contains ethanol. Alcoholic beverages and ethanol in alcoholic beverages have been classified by the International Agency for Research on Cancer as carcinogenic to humans. There are also data associating human consumption of alcoholic beverages with developmental toxicity and liver toxicity. Exposure to ethanol during the foreseeable use of this product is not expected to cause cancer, developmental toxicity, or liver toxicity. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE >50 mg/l Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Hexane Dermal Rabbit LD50 > 2,000 mg/kg Hexane Inhalation- Vapor (4 hours) Rat LC50 170 mg/l Hexane Ingestion Rat LD50 > 28,700 mg/kg Heptane Dermal Rabbit LD50 3,000 mg/kg Heptane Inhalation- Vapor (4 hours) Rat LC50 103 mg/l Heptane Ingestion Rat LD50 > 15,000 mg/kg Methylcyclopentane Dermal LD50 estimated to be > 5,000 mg/kg Methylcyclopentane Ingestion Rat LD50 > 5,000 mg/kg 2-Methylpentane Dermal LD50 estimated to be > 5,000 mg/kg 2-Methylpentane Inhalation- Vapor LC50 estimated to be > 50 mg/l 2-Methylpentane Ingestion LD50 estimated to be > 5,000 mg/kg 3-Methylpentane Dermal LD50 estimated to be > 5,000 mg/kg 3-Methylpentane Inhalation- Vapor LC50 estimated to be > 50 mg/l 3-Methylpentane Ingestion LD50 estimated to be > 5,000 mg/kg Toluene Dermal Rat LD50 12,000 mg/kg Toluene Inhalation- Vapor (4 hours) Rat LC50 30 mg/l Toluene Ingestion Rat LD50 5,550 mg/kg Talc Dermal LD50 estimated to be > 5,000 mg/kg Talc Ingestion LD50 estimated to be > 5,000 mg/kg Polyisoprene Dermal LD50 estimated to be > 5,000 mg/kg Polyisoprene Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg Naphtha, Light Steam-Cracked Arom., Piperylene Conc., Dermal Rabbit LD50 > 3,160 mg/kg 3M? Weatherstrip Adhesive - Black, P.N. 08011 01/14/19 __________________________________________________________________________________________ Page 10 of 18 Polymd. Naphtha, Light Steam-Cracked Arom., Piperylene Conc., Polymd. Ingestion Rat LD50 > 5,000 mg/kg Styrene-Butadiene Polymer Dermal Rabbit LD50 > 2,000 mg/kg Styrene-Butadiene Polymer Ingestion Rat LD50 > 5,000 mg/kg Phenolic Resin NJTS# 04499600-6305P Dermal LD50 estimated to be 2,000 - 5,000 mg/kg Phenolic Resin NJTS# 04499600-6305P Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg Cyclohexane Dermal Rat LD50 > 2,000 mg/kg Cyclohexane Inhalation- Vapor (4 hours) Rat LC50 > 32.9 mg/l Cyclohexane Ingestion Rat LD50 6,200 mg/kg 2,3-Dimethylbutane Dermal LD50 estimated to be > 5,000 mg/kg 2,3-Dimethylbutane Inhalation- Vapor LC50 estimated to be > 50 mg/l 2,3-Dimethylbutane Ingestion LD50 estimated to be > 5,000 mg/kg Ethyl Alcohol Dermal Rabbit LD50 > 15,800 mg/kg Ethyl Alcohol Inhalation- Vapor (4 hours) Rat LC50 124.7 mg/l Ethyl Alcohol Ingestion Rat LD50 17,800 mg/kg Carbon Black Dermal Rabbit LD50 > 3,000 mg/kg Carbon Black Ingestion Rat LD50 > 8,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Hexane Human and animal Mild irritant Heptane Human Mild irritant Methylcyclopentane similar compoun ds Minimal irritation 2-Methylpentane Professio nal judgeme nt Mild irritant 3-Methylpentane Professio nal judgeme nt Mild irritant Toluene Rabbit Irritant Talc Rabbit No significant irritation Naphtha, Light Steam-Cracked Arom., Piperylene Conc., Polymd. similar compoun ds No significant irritation Polyisoprene Professio nal judgeme nt No significant irritation Styrene-Butadiene Polymer Professio nal judgeme nt No significant irritation Cyclohexane Rabbit Mild irritant 2,3-Dimethylbutane Professio nal judgeme nt Mild irritant Ethyl Alcohol Rabbit No significant irritation Carbon Black Rabbit No significant irritation 3M? Weatherstrip Adhesive - Black, P.N. 08011 01/14/19 __________________________________________________________________________________________ Page 11 of 18 Serious Eye Damage/Irritation Name Species Value Hexane Rabbit Mild irritant Heptane Professio nal judgeme nt Moderate irritant Methylcyclopentane similar compoun ds Mild irritant 2-Methylpentane Professio nal judgeme nt Moderate irritant 3-Methylpentane Professio nal judgeme nt Moderate irritant Toluene Rabbit Moderate irritant Talc Rabbit No significant irritation Naphtha, Light Steam-Cracked Arom., Piperylene Conc., Polymd. similar compoun ds Mild irritant Polyisoprene Professio nal judgeme nt No significant irritation Cyclohexane Rabbit Mild irritant 2,3-Dimethylbutane Professio nal judgeme nt Moderate irritant Ethyl Alcohol Rabbit Severe irritant Carbon Black Rabbit No significant irritation Skin Sensitization Name Species Value Hexane Human Not classified Toluene Guinea pig Not classified Polyisoprene Human Not classified Ethyl Alcohol Human Not classified Respiratory Sensitization Name Species Value Talc Human Not classified Germ Cell Mutagenicity Name Route Value Hexane In Vitro Not mutagenic Hexane In vivo Not mutagenic Heptane In Vitro Not mutagenic Toluene In Vitro Not mutagenic Toluene In vivo Not mutagenic Talc In Vitro Not mutagenic Talc In vivo Not mutagenic Cyclohexane In Vitro Not mutagenic Cyclohexane In vivo Some positive data exist, but the data are not sufficient for classification Ethyl Alcohol In Vitro Some positive data exist, but the data are not sufficient for classification 3M? Weatherstrip Adhesive - Black, P.N. 08011 01/14/19 __________________________________________________________________________________________ Page 12 of 18 Ethyl Alcohol In vivo Some positive data exist, but the data are not sufficient for classification Carbon Black In Vitro Not mutagenic Carbon Black In vivo Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Hexane Dermal Mouse Not carcinogenic Hexane Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Toluene Dermal Mouse Some positive data exist, but the data are not sufficient for classification Toluene Ingestion Rat Some positive data exist, but the data are not sufficient for classification Toluene Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Talc Inhalation Rat Some positive data exist, but the data are not sufficient for classification Ethyl Alcohol Ingestion Multiple animal species Some positive data exist, but the data are not sufficient for classification Carbon Black Dermal Mouse Not carcinogenic Carbon Black Ingestion Mouse Not carcinogenic Carbon Black Inhalation Rat Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Hexane Ingestion Not classified for development Mouse NOAEL 2,200 mg/kg/day during organogenesi s Hexane Inhalation Not classified for development Rat NOAEL 0.7 mg/l during gestation Hexane Ingestion Toxic to male reproduction Rat NOAEL 1,140 mg/kg/day 90 days Hexane Inhalation Toxic to male reproduction Rat LOAEL 3.52 mg/l 28 days Toluene Inhalation Not classified for female reproduction Human NOAEL Not available occupational exposure Toluene Inhalation Not classified for male reproduction Rat NOAEL 2.3 mg/l 1 generation Toluene Ingestion Toxic to development Rat LOAEL 520 mg/kg/day during gestation Toluene Inhalation Toxic to development Human NOAEL Not available poisoning and/or abuse Talc Ingestion Not classified for development Rat NOAEL 1,600 mg/kg during organogenesi s Cyclohexane Inhalation Not classified for female reproduction Rat NOAEL 24 mg/l 2 generation Cyclohexane Inhalation Not classified for male reproduction Rat NOAEL 24 mg/l 2 generation Cyclohexane Inhalation Not classified for development Rat NOAEL 6.9 mg/l 2 generation Ethyl Alcohol Inhalation Not classified for development Rat NOAEL 38 mg/l during gestation Ethyl Alcohol Ingestion Not classified for development Rat NOAEL 5,200 mg/kg/day premating & during gestation Benzene, ethenyl-, homopolymer (oligomeric) Ingestion Toxic to female reproduction Rat NOAEL 5 mg/kg/day premating into lactation 3M? Weatherstrip Adhesive - Black, P.N. 08011 01/14/19 __________________________________________________________________________________________ Page 13 of 18 Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Hexane Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available not available Hexane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Rabbit NOAEL Not available 8 hours Hexane Inhalation respiratory system Not classified Rat NOAEL 24.6 mg/l 8 hours Heptane Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Heptane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Heptane Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Methylcyclopentane Inhalation central nervous system depression May cause drowsiness or dizziness similar compoun ds NOAEL Not available Methylcyclopentane Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available 2-Methylpentane Inhalation central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available 2-Methylpentane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available 2-Methylpentane Inhalation cardiac sensitization Not classified Dog NOAEL Not available 2-Methylpentane Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available 3-Methylpentane Inhalation central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available 3-Methylpentane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available 3-Methylpentane Inhalation cardiac sensitization Not classified Dog NOAEL Not available 3-Methylpentane Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Toluene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Toluene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Toluene Inhalation immune system Not classified Mouse NOAEL 0.004 mg/l 3 hours Toluene Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Cyclohexane Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Cyclohexane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human and animal NOAEL Not available 3M? Weatherstrip Adhesive - Black, P.N. 08011 01/14/19 __________________________________________________________________________________________ Page 14 of 18 Cyclohexane Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available 2,3-Dimethylbutane Inhalation central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available 2,3-Dimethylbutane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available 2,3-Dimethylbutane Inhalation cardiac sensitization Not classified Dog NOAEL Not available 2,3-Dimethylbutane Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Ethyl Alcohol Inhalation central nervous system depression May cause drowsiness or dizziness Human LOAEL 2.6 mg/l 30 minutes Ethyl Alcohol Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human LOAEL 9.4 mg/l not available Ethyl Alcohol Ingestion central nervous system depression May cause drowsiness or dizziness Multiple animal species NOAEL not available Ethyl Alcohol Ingestion kidney and/or bladder Not classified Dog NOAEL 3,000 mg/kg Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Hexane Inhalation peripheral nervous system Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Hexane Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Mouse LOAEL 1.76 mg/l 13 weeks Hexane Inhalation liver Not classified Rat NOAEL Not available 6 months Hexane Inhalation kidney and/or bladder Not classified Rat LOAEL 1.76 mg/l 6 months Hexane Inhalation hematopoietic system Not classified Mouse NOAEL 35.2 mg/l 13 weeks Hexane Inhalation auditory system | immune system | eyes Not classified Human NOAEL Not available occupational exposure Hexane Inhalation heart | skin | endocrine system Not classified Rat NOAEL 1.76 mg/l 6 months Hexane Ingestion peripheral nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,140 mg/kg/day 90 days Hexane Ingestion endocrine system | hematopoietic system | liver | immune system | kidney and/or bladder Not classified Rat NOAEL Not available 13 weeks Heptane Inhalation liver | nervous system | kidney and/or bladder Not classified Rat NOAEL 12 mg/l 26 weeks 2-Methylpentane Inhalation peripheral nervous system Not classified Rat NOAEL 5.3 mg/l 14 weeks 2-Methylpentane Ingestion peripheral nervous system Not classified Rat NOAEL Not available 8 weeks 2-Methylpentane Ingestion kidney and/or bladder Not classified Rat LOAEL 2,000 mg/kg 28 days 3-Methylpentane Inhalation peripheral nervous system Not classified Rat NOAEL 5.3 mg/l 14 weeks 3M? Weatherstrip Adhesive - Black, P.N. 08011 01/14/19 __________________________________________________________________________________________ Page 15 of 18 3-Methylpentane Ingestion peripheral nervous system Not classified Rat NOAEL Not available 8 weeks 3-Methylpentane Ingestion kidney and/or bladder Not classified Rat LOAEL 2,000 mg/kg 28 days Toluene Inhalation auditory system | nervous system | eyes | olfactory system Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Toluene Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 2.3 mg/l 15 months Toluene Inhalation heart | liver | kidney and/or bladder Not classified Rat NOAEL 11.3 mg/l 15 weeks Toluene Inhalation endocrine system Not classified Rat NOAEL 1.1 mg/l 4 weeks Toluene Inhalation immune system Not classified Mouse NOAEL Not available 20 days Toluene Inhalation bone, teeth, nails, and/or hair Not classified Mouse NOAEL 1.1 mg/l 8 weeks Toluene Inhalation hematopoietic system | vascular system Not classified Human NOAEL Not available occupational exposure Toluene Inhalation gastrointestinal tract Not classified Multiple animal species NOAEL 11.3 mg/l 15 weeks Toluene Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 625 mg/kg/day 13 weeks Toluene Ingestion heart Not classified Rat NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion liver | kidney and/or bladder Not classified Multiple animal species NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion hematopoietic system Not classified Mouse NOAEL 600 mg/kg/day 14 days Toluene Ingestion endocrine system Not classified Mouse NOAEL 105 mg/kg/day 28 days Toluene Ingestion immune system Not classified Mouse NOAEL 105 mg/kg/day 4 weeks Talc Inhalation pneumoconiosis Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Talc Inhalation pulmonary fibrosis | respiratory system Not classified Rat NOAEL 18 mg/m3 113 weeks Cyclohexane Inhalation liver Not classified Rat NOAEL 24 mg/l 90 days Cyclohexane Inhalation auditory system Not classified Rat NOAEL 1.7 mg/l 90 days Cyclohexane Inhalation kidney and/or bladder Not classified Rabbit NOAEL 2.7 mg/l 10 weeks Cyclohexane Inhalation hematopoietic system Not classified Mouse NOAEL 24 mg/l 14 weeks Cyclohexane Inhalation peripheral nervous system Not classified Rat NOAEL 8.6 mg/l 30 weeks 2,3-Dimethylbutane Inhalation peripheral nervous system Not classified Rat NOAEL 5.3 mg/l 14 weeks 2,3-Dimethylbutane Ingestion peripheral nervous system Not classified Rat NOAEL Not available 8 weeks 2,3-Dimethylbutane Ingestion kidney and/or bladder Not classified Rat LOAEL 2,000 mg/kg 28 days Ethyl Alcohol Inhalation liver Some positive data exist, but the data are not sufficient for classification Rabbit LOAEL 124 mg/l 365 days Ethyl Alcohol Inhalation hematopoietic system | immune system Not classified Rat NOAEL 25 mg/l 14 days Ethyl Alcohol Ingestion liver Some positive data exist, but the Rat LOAEL 4 months 3M? Weatherstrip Adhesive - Black, P.N. 08011 01/14/19 __________________________________________________________________________________________ Page 16 of 18 data are not sufficient for classification 8,000 mg/kg/day Ethyl Alcohol Ingestion kidney and/or bladder Not classified Dog NOAEL 3,000 mg/kg/day 7 days Carbon Black Inhalation pneumoconiosis Not classified Human NOAEL Not available occupational exposure Aspiration Hazard Name Value Hexane Aspiration hazard Heptane Aspiration hazard Methylcyclopentane Aspiration hazard 2-Methylpentane Aspiration hazard 3-Methylpentane Aspiration hazard Toluene Aspiration hazard Cyclohexane Aspiration hazard 2,3-Dimethylbutane Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate uncured product in a permitted waste incineration facility. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. EPCRA 311/312 Hazard Classifications: 3M? Weatherstrip Adhesive - Black, P.N. 08011 01/14/19 __________________________________________________________________________________________ Page 17 of 18 Physical Hazards Flammable (gases, aerosols, liquids, or solids) Health Hazards Carcinogenicity Reproductive toxicity Serious eye damage or eye irritation Specific target organ toxicity (single or repeated exposure) Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Toluene 108-88-3 Trade Secret 3 - 7 Calcium Zinc Resinate (ZINC COMPOUNDS) 68334-35-0 1 - 5 Hexane 110-54-3 Trade Secret 7 - 30 Hexane (Hexane) 110-54-3 7 - 30 Cyclohexane 110-82-7 Trade Secret 1 - 5 Benzene 71-43-2 Trade Secret < 0.07 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Listing LEAD None Female reproductive toxin LEAD None Male reproductive toxin LEAD COMPOUNDS None Carcinogen LEAD None Developmental Toxin METHANOL 67-56-1 Developmental Toxin CADMIUM None Male reproductive toxin CADMIUM AND CADMIUM COMPOUNDS None Carcinogen CADMIUM None Developmental Toxin COBALT METAL POWDER None Carcinogen METHYL ISOBUTYL KETONE (MIBK) 108-10-1 Carcinogen METHYL ISOBUTYL KETONE (MIBK) 108-10-1 Developmental Toxin FORMALDEHYDE (GAS) 50-00-0 Carcinogen TOLUENE 108-88-3 Developmental Toxin n-Hexane 110-54-3 Male reproductive toxin CARBON BLACK (AIRBORNE, UNBOUND PARTICLES OF RESPIRABLE SIZE [<= 10 MICROMETERS]) Trade Secret Carcinogen BENZENE 71-43-2 Male reproductive toxin BENZENE 71-43-2 Carcinogen BENZENE 71-43-2 Developmental Toxin 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. All required components of this product are listed on the active portion of the TSCA Inventory. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. 3M? Weatherstrip Adhesive - Black, P.N. 08011 01/14/19 __________________________________________________________________________________________ Page 18 of 18 This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 1 Flammability: 3 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: *3 Flammability: 3 Physical Hazard: 0 Personal Protection: X - See PPE section. Hazardous Material Identification System (HMIS? IV) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS? IV ratings are to be used with a fully implemented HMIS? IV program. HMIS? is a registered mark of the American Coatings Association (ACA). Document Group: 10-2974-3 Version Number: 65.03 Issue Date: 01/14/19 Supercedes Date: 04/02/18 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from3M 3M USA SDSs are available at www.3M.com