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MG-14_Marine_Grease_SDS.pdf
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Date of issue/Date of revision : 12/3/2018 Date of previous issue : 4/30/2018 Version : 2 1/10 FVP MARINE GREASE SAFETY DATA SHEET GHS product identifier Synonyms PART# : Marine Grease : Lubricating grease; Material Code: 665523341 : FVPMG-14 MSDS # : 665523341 Supplier's details : Factory Motor Parts 1380 Corporate Center Curve, Suite 200 Eagan, MN 55121 866-387-3343 Emergency telephone number (with hours of operation) : INFOTRAC 1-800-535-5053 24 hr. Emergency OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the substance or mixture : AQUATIC HAZARD (LONG-TERM) - Category 4 GHS label elements Signal word : Warning Hazard statements : May cause long lasting harmful effects to aquatic life. Injection of pressurized hydrocarbons can cause severe permanent tissue damage. Initial symptoms may be minor. Precautionary statements Prevention : Avoid release to the environment. Response : Not applicable. Storage : Not applicable. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified : Injection of petroleum hydrocarbons requires immediate medical attention. Substance/mixture Other means of identification : Mixture : Lubricating grease; CITGO? Material Code: 6655233 CAS number/other identifiers CAS number : Not applicable. Ingredient name % CAS number Distillates (petroleum), hydrotreated heavy naphthenic calcium(2+) 12-hydroxyoctadecanoate ?75 - ?90 ?10 64742-52-5 3159-62-4 * = Various ** = Mixture *** = Proprietary Any concentration shown as a range is to protect confidentiality or is due to process variation. Section 1. Identification Section 2. Hazards identification Section 3. Composition/information on ingredients Date of issue/Date of revision : 12/3/2018 Date of previous issue : 4/30/2018 Version : 2 2/10 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Description of necessary first aid measures Eye contact Inhalation Skin contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs. : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : No known significant effects or critical hazards. Inhalation : No known significant effects or critical hazards. Skin contact : Injection of pressurized hydrocarbons can cause severe permanent tissue damage. Initial symptoms may be minor. Ingestion : No known significant effects or critical hazards. Over-exposure signs/symptoms Eye contact : No specific data. Inhalation Skin contact Ingestion : No specific data. : No specific data. : No specific data. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : In the event of injection in underlying tissue, immediate treatment should include extensive incision, debridement and saline irrigation. Inadequate treatment can result in ischemia and gangrene. Early symptoms may be minimal. Specific treatments : Treat symptomatically and supportively. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. See toxicological information (Section 11) FVP Marine Grease Section 3. Composition/information on ingredients Section 4. First aid measures Date of issue/Date of revision : 12/3/2018 Date of previous issue : 4/30/2018 Version : 2 3/10 Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Use an extinguishing agent suitable for the surrounding fire. : None known. Specific hazards arising from the chemical Hazardous thermal decomposition products : This material may cause long lasting harmful effects to aquatic life. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. : Decomposition products may include the following materials: carbon dioxide carbon monoxide sulfur oxides metal oxide/oxides Special protective actions for fire-fighters Special protective equipment for fire-fighters : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Personal precautions, protective equipment and emergency procedures For non-emergency personnel : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Methods and materials for containment and cleaning up Small spill : Large spill : Move containers from spill area. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid release to the environment. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Section 5. Fire-fighting measures FVP Marine Grease Section 6. Accidental release measures Section 7. Handling and storage Date of issue/Date of revision : 12/3/2018 Date of previous issue : 4/30/2018 Version : 2 4/10 FVP Marine Grease Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities : Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. : Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. Bulk Storage Conditions: Do not apply heat or flame to stockpiled material. Rotate stock to reduce the potential for hot spots. Do not store with oxidizers. Minimize dust creation by keeping material moist and/or covered. Control parameters Occupational exposure limits Distillates (petroleum), hydrotreated heavy naphthenic ACGIH TLV (United States, 3/2017). TWA: 5 mg/m? 8 hours. Form: Inhalable fraction NIOSH REL (United States, 10/2016). TWA: 5 mg/m? 10 hours. Form: Mist STEL: 10 mg/m? 15 minutes. Form: Mist OSHA PEL (United States, 6/2016). TWA: 5 mg/m? 8 hours. calcium(2+) 12-hydroxyoctadecanoate ACGIH TLV (United States). TWA: 10 mg/m? 8 hours. Appropriate engineering controls Environmental exposure controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, vapor controls, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection Skin protection Hand protection : Safety glasses equipped with side shields are recommended as minimum protection in industrial settings. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If inhalation hazards exist, a full-face respirator may be required instead. : Chemical-resistant gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. Section 8. Exposure controls/personal protection Date of issue/Date of revision : 12/3/2018 Date of previous issue : 4/30/2018 Version : 2 5/10 FVP Marine Grease Section 8. Exposure controls/personal protection Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Avoid inhalation of gases, vapors, mists or dusts. Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Appearance Physical state Color Odor pH : Solid. [Smooth texture] : Green. : Mild petroleum odor : Not available. Boiling point : Not available. Flash point Evaporation rate : Open cup: >150?C (>302?F) [Estimated] : <1 (n-butyl acetate. = 1) Lower and upper explosive (flammable) limits : Lower: 1% Upper: 7% Vapor pressure Vapor density Relative density Density lbs/gal : <0.0013 kPa (<0.01 mm Hg) [room temperature] : >1 [Air = 1] : 0.92 : Estimated 7.67 lbs/gal Density gm/cm3 : Not available. Gravity, ?API : Estimated 22 @ 60 F Solubility : Insoluble in the following materials: cold water and hot water. Flow time (ISO 2431) : Not available. NLGI Grade : 2 Reactivity : Not expected to be Explosive, Self-Reactive, Self-Heating, or an Organic Peroxide under US GHS Definition(s). Chemical stability : The product is stable. Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Conditions to avoid : No specific data. Incompatible materials : No specific data. Hazardous decomposition products : Under normal conditions of storage and use, hazardous decomposition products should not be produced. Section 9. Physical and chemical properties Section 10. Stability and reactivity Date of issue/Date of revision : 12/3/2018 Date of previous issue : 4/30/2018 Version : 2 6/10 FVP Marine Grease Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure Distillates (petroleum), LD50 Oral Rat >5000 mg/kg - hydrotreated heavy naphthenic LD50 Oral Rat >5000 mg/kg - Conclusion/Summary : Distillates (petroleum), hydrotreated heavy naphthenic: Mineral oil mists derived from highly refined oils are reported to have low acute and sub-acute toxicities in animals. Effects from single and short-term repeated exposures to high concentrations of mineral oil mists well above applicable workplace exposure levels include lung inflammatory reaction, lipoid granuloma formation and lipoid pneumonia. In acute and sub-acute studies involving exposures to lower concentrations of mineral oil mists at or near current work place exposure levels produced no significant toxicological effects. Irritation/Corrosion Not available. Skin Eyes Respiratory Sensitization Not available. : No additional information. : No additional information. : No additional information. Skin Respiratory Mutagenicity Not available. : No additional information. : No additional information. Conclusion/Summary : No additional information. Carcinogenicity Not available. Conclusion/Summary : No additional information. Reproductive toxicity Not available. Conclusion/Summary : Teratogenicity Not available. No additional information. Conclusion/Summary : No additional information. Specific target organ toxicity (single exposure) Not available. Specific target organ toxicity (repeated exposure) Not available. Aspiration hazard Not available. Information on the likely routes of exposure Potential acute health effects : Routes of entry anticipated: Dermal. Date of issue/Date of revision : 12/3/2018 Date of previous issue : 4/30/2018 Version : 2 7/10 FVP Marine Grease Eye contact : No known significant effects or critical hazards. Date of issue/Date of revision : 12/3/2018 Date of previous issue : 4/30/2018 Version : 2 8/10 FVP Marine Grease Inhalation : No known significant effects or critical hazards. Skin contact : Injection of pressurized hydrocarbons can cause severe permanent tissue damage. Initial symptoms may be minor. Ingestion : No known significant effects or critical hazards. Symptoms related to the physical, chemical and toxicological characteristics Eye contact : No specific data. Inhalation Skin contact Ingestion : No specific data. : No specific data. : No specific data. Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate effects : Not available. Potential delayed effects : Not available. Long term exposure Potential immediate effects : Not available. Potential delayed effects : Not available. Potential chronic health effects Not available. General : Carcinogenicity : Mutagenicity : Teratogenicity : No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Toxicity Not available. Conclusion/Summary : Not available. Persistence and degradability Conclusion/Summary : Not available. Product/ingredient name Aquatic half-life Photolysis Biodegradability Distillates (petroleum), hydrotreated heavy naphthenic - - Inherent Bioaccumulative potential Product/ingredient name LogPow BCF Potential Section 12. Ecological information Date of issue/Date of revision : 12/3/2018 Date of previous issue : 4/30/2018 Version : 2 9/10 FVP Marine Grease Distillates (petroleum), hydrotreated heavy naphthenic >6 - high Date of issue/Date of revision : 12/3/2018 Date of previous issue : 4/30/2018 Version : 2 10/10 FVP Marine Grease Section 12. Ecological information Mobility in soil Soil/water partition coefficient (KOC) : Not available. Other adverse effects : No known significant effects or critical hazards. Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. DOT Classification IMDG IATA UN number Not regulated. Not available. Not available. UN proper shipping name - Not available. Not available. Transport hazard class(es) - Not available. Not available. Packing group - - - Environmental hazards No. No. No. Special precautions for user Transport in bulk according to Annex II of MARPOL and the IBC Code : Transport within user?s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. U.S. Federal regulations : United States inventory (TSCA 8b): All components are listed or exempted. Clean Water Act (CWA) 307: tris(dipentyldithiocarbamato-S,S')antimony; Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts; ethylbenzene Clean Water Act (CWA) 311: xylene; ethylbenzene Section 13. Disposal considerations Section 14. Transport information Section 15. Regulatory information Date of issue/Date of revision : 12/3/2018 Date of previous issue : 4/30/2018 Version : 2 11/10 FVP Marine Grease Section 15. Regulatory information This material is classified as an oil under Section 311 of the Clean Water Act (CWA) and the Oil Pollution Act of 1990 (OPA). Discharges or spills which produce a visible sheen on waters of the United States, their adjoining shorelines, or into conduits leading to surface waters must be reported to the EPA's National Response Center at (800) 424-8802. SARA 302/304 Composition/information on ingredients SARA 304 RQ : Not applicable. SARA 311/312 Classification : Not applicable. Composition/information on ingredients No products were found. State regulations Massachusetts : None of the components are listed. New York : None of the components are listed. New Jersey : None of the components are listed. Pennsylvania : None of the components are listed. California Prop. 65 Clear and Reasonable Warnings (2018) WARNING: This product can expose you to Ethylbenzene, which is known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov. Ingredient name % Cancer Reproductive No significant risk level Maximum acceptable dosage level ethylbenzene <0.01 Yes. No. Yes. - International regulations Inventory list United States : All components are listed or exempted. Australia : Not determined. Canada : All components are listed or exempted. China : All components are listed or exempted. Europe : All components are listed or exempted. Japan : Japan inventory (ENCS): Not determined. Japan inventory (ISHL): Not determined. Malaysia : Not determined. New Zealand : All components are listed or exempted. Philippines : All components are listed or exempted. Republic of Korea : All components are listed or exempted. Taiwan : Not determined. Thailand : Not determined. Turkey : Not determined. Viet Nam : Not determined. Date of issue/Date of revision : 12/3/2018 Date of previous issue : 4/30/2018 Version : 2 12/10 FVP Marine Grease Section 16. Other information National Fire Protection Association (U.S.A.) Health 1 Flammability 1 0 Instability/Reactivity Special Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ?1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ?2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Procedure used to derive the classification Classification Justification AQUATIC HAZARD (LONG-TERM) - Category 4 Calculation method History Date of printing Date of issue/Date of revision Date of previous issue Version : 12/3/2018 : 12/3/2018 : 4/30/2018 : 2 Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations References : Not available. Indicates information that has changed from previously issued version. Notice to reader THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED REGARDING ITS CORRECTNESS OR ACCURACY. SOME INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE SUBSTANCE ITSELF. THIS SDS WAS PREPARED AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A COMPONENT IN ANOTHER PRODUCT, THIS SDS INFORMATION MAY NOT BE APPLICABLE. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION OR PRODUCTS FOR THEIR PARTICULAR PURPOSE OR APPLICATION. THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND/OR DISPOSAL OF THE PRODUCT ARE BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR ANY LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT.