Date of issue/Date of revision : 11/11/2014. Date of previous issue : No previous validation. Version : 1 1/10 FVP GENERAL PURPOSE GREASE SAFETY DATA SHEET GHS product identifier Synonyms PART # : FVP General Purpose Grease : Material Code: 665408419 : FVPMPG-14 MSDS # : 665408419 Supplier's details : Factory Motor Parts 1380 Corporate Center Curve, Suite 200 Eagan, MN 55121 866-387-3343 Emergency telephone number : INFOTRAC 1-800-535-5053 24 hr. Emergency OSHA/HCS status : While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available for employees and other users of this product. Classification of the substance or mixture : Not classified. GHS label elements Signal word : Warning Hazard statements : Injection under the skin can cause severe injury. Most damage occurs in the first few hours. Initial symptoms may be minimal. Precautionary statements General : Avoid contact with eyes, skin and clothing. May be harmful if swallowed. IF IN EYES: Rinse cautiously with water for several minutes. IF SWALLOWED: Do NOT induce vomiting. After handling, always wash hands thoroughly with soap and water. If you feel unwell, seek medical attention and show the label when possible. Keep out of reach of children. Prevention : Not applicable. Response : Not applicable. Storage : Store in a dry place and/or in closed container. Store in accordance with all local, regional, national and international regulations. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified : Injection of petroleum hydrocarbons requires immediate medical attention Substance/mixture Other means of identification : Mixture : Grease ; CITGO? Material Code: 665408419 Section 1. Identification Section 2. Hazards identification Section 3. Composition/information on ingredients Date of issue/Date of revision : 11/11/2014. Date of previous issue : No previous validation. Version : 1 2/10 CAS number/other identifiers CAS number : Not applicable. Date of issue/Date of revision : 11/11/2014. Date of previous issue : No previous validation. Version : 1 3/10 FVP General Purpose Grease Section 3. Composition/information on ingredients Ingredient name % CAS number Distillates (petroleum), hydrotreated heavy naphthenic 0 - 95 calcium carbonate 1 - 5 Polymers 1 - 5 64742-52-5 471-34-1 Proprietary * = Various ** = Mixture *** = Proprietary Any concentration shown as a range is to protect confidentiality or is due to process variation. Occupational exposure limits, if available, are listed in Section 8. Description of necessary first aid measures Eye contact Inhalation Skin contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur. : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Ingestion : Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur. Most important symptoms/effects, acute Potential acute health effects Eye contact : No known significant effects or critical hazards. Inhalation : No known significant effects or critical hazards. Skin contact : Injection of pressurized hydrocarbons can cause severe permanent tissue damage. Initial symptoms may be minor. Ingestion : No known significant effects or critical hazards. Over-exposure signs/symptoms Eye contact : No specific data. Inhalation Skin contact Ingestion : No specific data. : No specific data. : No specific data. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : Treat symptomatically and supportively. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. See toxicological information (Section 11) Specific hazards arising from the chemical Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Section 4. First aid measures Section 5. Fire-fighting measures Date of issue/Date of revision : 11/11/2014. Date of previous issue : No previous validation. Version : 1 4/10 : No specific fire or explosion hazard. : Use an extinguishing agent suitable for the surrounding fire. : None known. Date of issue/Date of revision : 11/11/2014. Date of previous issue : No previous validation. Version : 1 5/10 Hazardous thermal decomposition products : Decomposition products may include the following materials: carbon dioxide carbon monoxide sulfur oxides phosphorus oxides metal oxide/oxides Special protective actions for fire-fighters Special protective equipment for fire-fighters : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Personal precautions, protective equipment and emergency procedures For non-emergency personnel : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and cleaning up Small spill : Large spill : Move containers from spill area. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Precautions for safe handling Protective measures : Advice on general : occupational hygiene Conditions for safe storage, : including any incompatibilities Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Bulk Storage Conditions: Do not apply heat or flame to stockpiled material. Rotate stock to reduce the potential for hot spots. Do not store with oxidizers. Minimize dust creation by keeping material moist and/or covered. FVP General Purpose Grease Section 5. Fire-fighting measures Section 6. Accidental release measures Section 7. Handling and storage Date of issue/Date of revision : 11/11/2014. Date of previous issue : No previous validation. Version : 1 6/10 Control parameters Occupational exposure limits Ingredient name Exposure limits calcium carbonate OSHA PEL (United States, 2/2013). TWA: 5 mg/m? 8 hours. Form: Respirable fraction TWA: 15 mg/m? 8 hours. Form: Total dust Appropriate engineering controls Environmental exposure controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, vapor controls, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection Skin protection Hand protection Body protection : Safety glasses equipped with side shields are recommended as minimum protection in industrial settings. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: Safety glasses with side shields. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If inhalation hazards exist, a full-face respirator may be required instead. : Chemical-resistant gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Physical state Color Odor pH : Solid. [Paste.] : Dark amber to black : Petroleum. : Not available. Boiling point : Not available. Flash point Evaporation rate : Open cup: >150?C (>302?F) [Estimated] : <1 (n-butyl acetate. = 1) Lower and upper explosive (flammable) limits : Lower: 1% Upper: 7% Vapor pressure Vapor density Relative density Section 8. Exposure controls/personal protection FVP General Purpose Grease Section 9. Physical and chemical properties Date of issue/Date of revision : 11/11/2014. Date of previous issue : No previous validation. Version : 1 7/10 : <0.0013 kPa (<0.01 mm Hg) [room temperature] : >10 [Air = 1] : 0.97 Date of issue/Date of revision : 11/11/2014. Date of previous issue : No previous validation. Version : 1 8/10 Density lbs/gal Gravity, ?API : Estimated 8.09 lbs/gal : Estimated 14 @ 60 F Solubility NLGI Grade : Insoluble in the following materials: cold water and hot water. : 2 Reactivity : Not expected to be Explosive, Self-Reactive, Self-Heating, or an Organic Peroxide under US GHS Definition(s). Chemical stability : The product is stable. Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Conditions to avoid : No specific data. Incompatible materials : No specific data. Hazardous decomposition products : Under normal conditions of storage and use, hazardous decomposition products should not be produced. Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure calcium carbonate LD50 Oral Rat 6450 mg/kg - Polymers LD50 Dermal Rabbit >2000 mg/kg - LD50 Oral Rat >5000 mg/kg - Conclusion/Summary : Distillates (petroleum), hydrotreated heavy naphthenic: Mineral oil mists derived from highly refined oils are reported to have low acute and sub-acute toxicities in animals. Effects from single and short-term repeated exposures to high concentrations of mineral oil mists well above applicable workplace exposure levels include lung inflammatory reaction, lipoid granuloma formation and lipoid pneumonia. In acute and sub-acute studies involving exposures to lower concentrations of mineral oil mists at or near current work place exposure levels produced no significant toxicological effects. 1-Decene homopolymer, hydrogenated: Practically non-irritating to eyes. Practically non-irritating to the skin. Distillates (petroleum), hydrotreated heavy paraffinic: Mineral oil mists derived from highly refined oils are reported to have low acute and sub-acute toxicities in animals. Effects from single and short-term repeated exposures to high concentrations of mineral oil mists well above applicable workplace exposure levels include lung inflammatory reaction, lipoid granuloma formation and lipoid pneumonia. In acute and sub-acute studies involving exposures to lower concentrations of mineral oil mists at or near current work place exposure levels produced no significant toxicological effects. Poly alpha olefins: Potential mild skin irritant from repeated or prolonged exposures. molybdenum disulphide: In general, insoluble compounds of molybdenum, such as molybdenum disulfide, exhibit a low order of toxicity. Molybdenum disulfide dust can cause eye, skin and respiratory tract irritation due to frictional action. Other effects of molybdenum disulfide dusts and mists are similar to those of nuisance particulates. In acute ingestion studies with rats and guinea pigs, no fatalities were reported when doses of molybdenum disulfide as high as 6.0 grams per kilogram of body weight. In a FVP General Purpose Grease Section 9. Physical and chemical properties Section 10. Stability and reactivity Section 11. Toxicological information Date of issue/Date of revision : 11/11/2014. Date of previous issue : No previous validation. Version : 1 9/10 subchronic oral study, no signs of toxicity appeared in rats receiving molybdenum disulfide at 10 to 500 milligrams of molybdenum disulfide per animal per day. In an experimental study, guinea pigs were exposed to an average concentration of 286 Date of issue/Date of revision : 11/11/2014. Date of previous issue : No previous validation. Version : 1 10/10 milligrams of molybdenum disulfide dust per cubic meter for one hour per day, five days per week for five weeks. Of the 25 animals studied, one animal died within three days; the appearance of the other animals was normal. Natural graphite: Laboratory studies have associated graphite with mild pulmonary fibrotic reactions when administered to rats by intratracheal injection. Numerous epidemiological studies performed in the mining, milling and carbon electrode manufacturing industries have associated a form of pneumoconiosis with overexposure to both synthetic and natural graphite. These data are not expected to be relevant to graphic used in a grease or oil matrix. Irritation/Corrosion Product/ingredient name Result Species Score Exposure Observation calcium carbonate Polymers Skin - Moderate irritant Eyes - Mild irritant Respiratory - Irritant Respiratory - Mild irritant Rabbit Rabbit Rabbit Human - - - - 24 hours 500 milligrams - - - - - - - Skin Eyes Respiratory Sensitization Skin Respiratory Mutagenicity : No additional information. : No additional information. : No additional information. : No additional information. : No additional information. Conclusion/Summary : No additional information. Carcinogenicity Conclusion/Summary : No additional information. Reproductive toxicity Conclusion/Summary : No additional information. Teratogenicity Conclusion/Summary : No additional information. Specific target organ toxicity (single exposure) Not available. Specific target organ toxicity (repeated exposure) Not available. Aspiration hazard Not available. Information on the likely routes of exposure Potential acute health effects : Routes of entry anticipated: Dermal. Eye contact : No known significant effects or critical hazards. Inhalation : No known significant effects or critical hazards. Skin contact : Injection of pressurized hydrocarbons can cause severe permanent tissue damage. Initial symptoms may be minor. Ingestion : No known significant effects or critical hazards. Symptoms related to the physical, chemical and toxicological characteristics Eye contact : No specific data. FVP General Purpose Grease Section 11. Toxicological information Date of issue/Date of revision : 11/11/2014. Date of previous issue : No previous validation. Version : 1 11/10 Inhalation : No specific data. Date of issue/Date of revision : 11/11/2014. Date of previous issue : No previous validation. Version : 1 12/10 Skin contact Ingestion : No specific data. : No specific data. Potential chronic health effects General : Carcinogenicity : Mutagenicity : Teratogenicity : No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Toxicity Product/ingredient name Result Species Exposure calcium carbonate Acute LC50 56000 ppm Fresh water Chronic NOEC 61 mg/g Fresh water Fish - Gambusia affinis - Adult Fish - Oncorhynchus mykiss - Juvenile (Fledgling, Hatchling, Weanling) 96 hours 28 days Conclusion/Summary : Not available. Persistence and degradability Conclusion/Summary : Not available. Bioaccumulative potential Not available. Mobility in soil Soil/water partition coefficient (KOC) : Not available. Other adverse effects : No known significant effects or critical hazards. Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. FVP General Purpose Grease Section 11. Toxicological information Section 13. Disposal considerations Section 12. Ecological information Date of issue/Date of revision : 11/11/2014. Date of previous issue : No previous validation. Version : 1 13/10 FVP General Purpose Grease Section 14. Transport information DOT Classification IMDG IATA UN number Not regulated. Not available. Not available. UN proper shipping name - Not available. Not available. Transport hazard class(es) - Not available. Not available. Packing group - - - Environmental hazards No. No. No. Additional information - - - Oil: The product(s) represented by this MSDS is (are) regulated as ?oil? under 49 CFR Part 130. Shipments by rail or highway in packaging having a capacity of 3500 gallons or more or in a quantity greater 42,000 gallons are subject to these requirements. In addition, mixtures containing 10% or more of this product may be subject to these requirements. Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code : Transport within user?s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. U.S. Federal regulations : United States inventory (TSCA 8b): All components are listed or exempted. Clean Water Act (CWA) 307: Antimony & Antimony Compounds; Naphthenic acids, zinc salts; zinc neodecanoate Clean Water Act (CWA) 311: xylene; maleic anhydride This material is classified as an oil under Section 311 of the Clean Water Act (CWA) and the Oil Pollution Act of 1990 (OPA). Discharges or spills which produce a visible sheen on waters of the United States, their adjoining shorelines, or into conduits leading to surface waters must be reported to the EPA's National Response Center at (800) 424-8802. SARA 302/304 Composition/information on ingredients SARA 304 RQ : Not applicable. SARA 311/312 Classification : Not applicable. Composition/information on ingredients Section 15. Regulatory information Date of issue/Date of revision : 11/11/2014. Date of previous issue : No previous validation. Version : 1 14/10 FVP General Purpose Grease Section 15. Regulatory information Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard calcium carbonate <5 Polymers <5 No. No. No. No. No. No. Yes. Yes. No. No. State regulations Massachusetts : The following components are listed: molybdenum disulphide; molybdenum disulphide New York : The following components are listed: Butene, homopolymer (products derived from either/or But-1-ene/But-2-ene) New Jersey : The following components are listed: Petroleum Oil (Grease) Pennsylvania : The following components are listed: Butene, homopolymer (products derived from either/or But-1-ene/But-2-ene) California Prop. 65 WARNING: This product contains less than 0.1% of a chemical known to the State of California to cause cancer. Ingredient name % Cancer Reproductive No significant risk level Maximum acceptable dosage level cumene <0.001 Yes. No. No. No. International regulations International lists : Australia inventory (AICS): At least one component is not listed. China inventory (IECSC): At least one component is not listed. Japan inventory: At least one component is not listed. Korea inventory: At least one component is not listed. Malaysia Inventory (EHS Register): Not determined. New Zealand Inventory of Chemicals (NZIoC): At least one component is not listed. Philippines inventory (PICCS): At least one component is not listed. Taiwan inventory (CSNN): Not determined. Canada inventory : All components are listed or exempted. EU Inventory : At least one component is not listed. WHMIS (Canada) : Class D-2B: Material causing other toxic effects (Toxic). National Fire Protection Association (U.S.A.) Health 1 Flammability 1 0 Instability/Reactivity Special Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ?1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ?2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. History Date of issue/Date of revision : 11/11/2014. Section 16. Other information Date of issue/Date of revision : 11/11/2014. Date of previous issue : No previous validation. Version : 1 15/10 Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations Notice to reader THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED REGARDING ITS CORRECTNESS OR ACCURACY. SOME INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE SUBSTANCE ITSELF. THIS SDS WAS PREPARED AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A COMPONENT IN ANOTHER PRODUCT, THIS SDS INFORMATION MAY NOT BE APPLICABLE. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION OR PRODUCTS FOR THEIR PARTICULAR PURPOSE OR APPLICATION. THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND/OR DISPOSAL OF THE PRODUCT ARE BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR ANY LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT. FVP General Purpose Grease Section 16. Other information