Oil Enhancer Safety Data Sheet According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015 Date of issue: 03/08/2017 Revision date: 03/01/2019 Version: 2.2 SECTION 1: Identification 1.1. Identification Product name : Oil Enhancer Product code : 203000, 203000C, 203100, 203100C 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Motor oil additive 1.3. Details of the supplier of the safety data sheet Manufacturer R.B. Howes & Co., Inc. 3511 North Ohio Street Wichita, KS 67219 - USA T 401-294-5500, 1-800 GET HOWES (438-4693) 1.4. Emergency telephone number Emergency number : CHEMTREC 1 (800) 424-9300 / 703-527-3887 SECTION 2: Hazard identification 2.1. Classification of the substance or mixture GHS classification Eye Irrit. 2A 2.2. Label elements GHS labelling Hazard pictograms (GHS) : GHS07 Signal word (GHS) : Warning Hazard statements (GHS) : Causes serious eye irritation Precautionary statements (GHS) : Wash hands thoroughly after handling. Wear face protection, eye protection. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity Not applicable SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and isopropyl) esters, zinc salts (n? CAS.) 84605-29-8 < 2 *Chemical name, CAS number and/or exact concentration have been withheld as a trade secret SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. First-aid measures after skin contact : If skin irritation occurs: Wash skin with plenty of water. Obtain medical attention if irritation persists. 03/01/2019 EN (English) Page 1 Oil Enhancer Safety Data Sheet According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015 First-aid measures after eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid measures after ingestion : Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Get medical advice/attention if you feel unwell. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects after inhalation : May cause irritation to the respiratory tract. Symptoms/effects after skin contact : May cause skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin. Symptoms/effects after eye contact : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Symptoms/effects after ingestion : May be harmful if swallowed. May cause gastrointestinal irritation, nausea, vomiting and diarrhea. 4.3. Indication of any immediate medical attention and special treatment needed Symptoms may be delayed. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). SECTION 5: Fire-fighting measures 5.1. Extinguishing media Suitable extinguishing media : Carbon dioxide. Foam. Dry powder. Unsuitable extinguishing media : Do not use water. Water may cause frothing. 5.2. Special hazards arising from the substance or mixture Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon. Oxides of nitrogen. Oxides of zinc. Hydrocarbons. Hydrogen sulfide. Mercaptans. Sulfides. Toxic fumes. Reactivity : No dangerous reactions known under normal conditions of use. 5.3. Advice for firefighters Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. 6.1.1. For non-emergency personnel No additional information available 6.1.2. For emergency responders No additional information available 6.2. Environmental precautions Prevent entry to sewers and public waters. 6.3. Methods and material for containment and cleaning up For containment : Absorb and/or contain spill with inert material (sand, vermiculite or other appropriate material), then place in suitable container. Do not flush into surface water or sewer system. Wear recommended personal protective equipment. Methods for cleaning up : Sweep or shovel spills into appropriate container for disposal. 6.4. Reference to other sections For further information refer to section 8: "Exposure controls/personal protection" SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Avoid contact with skin and eyes. Avoid breathing vapour or mist. Do not swallow. Handle and open container with care. When using do not eat, drink or smoke. Hygiene measures : Wash contaminated clothing before reuse. Always wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep out of the reach of children. Keep container tightly closed. Store in a dry, cool area. 03/01/2019 EN (English) 2/5 Oil Enhancer Safety Data Sheet According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015 SECTION 8: Exposure controls/personal protection 8.1. Control parameters Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and isopropyl) esters, zinc salts (84605-29-8) Not applicable 8.2. Exposure controls Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. Ensure good ventilation of the work station. Hand protection : Wear suitable gloves. Eye protection : Wear eye/face protection. Skin and body protection : Wear suitable protective clothing. Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Environmental exposure controls : Avoid release to the environment. Other information : Handle in accordance with good industrial hygiene and safety procedures. Do not eat, drink or smoke when using this product. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Liquid Colour : Amber Odour : Petroleum-like odor Odour threshold : No data available pH : No data available Melting point : No data available Freezing point : No data available Boiling point : No data available Flash point : > 188 ?C (> 370 ?F) Relative evaporation rate (butylacetate=1) : No data available Flammability (solid, gas) : No data available Vapour pressure : No data available Relative vapour density at 20 ?C : Heavier than air Relative density : No data available Specific gravity / density : No data available Solubility : Water: insoluble in water Partition coefficient n-octanol/water : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive limits : No data available Explosive properties : No data available Oxidising properties : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reactions known under normal conditions of use. 10.2. Chemical stability Stable under normal conditions. 03/01/2019 EN (English) 3/5 Oil Enhancer Safety Data Sheet According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015 10.3. Possibility of hazardous reactions No dangerous reactions known under normal conditions of use. 10.4. Conditions to avoid Heat. Incompatible materials. 10.5. Incompatible materials Strong oxidizing agents. 10.6. Hazardous decomposition products May include, and are not limited to: oxides of carbon. Oxides of nitrogen. Oxides of zinc. Hydrocarbons. Hydrogen sulfide. Mercaptans. Sulfides. Toxic fumes. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity (oral) : Not classified. Acute toxicity (dermal) : Not classified. Acute toxicity (inhalation) : Not classified. Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and isopropyl) esters, zinc salts (84605-29-8) LD50 oral rat 3200 mg/kg LD50 dermal rabbit > 2000 mg/kg ATE CA (oral) 3200 mg/kg bodyweight Skin corrosion/irritation : Not classified. Serious eye damage/irritation : Not classified. Respiratory or skin sensitisation : Not classified. Germ cell mutagenicity : Not classified. Carcinogenicity : Not classified. Reproductive toxicity : Not classified. STOT-single exposure : Not classified. STOT-repeated exposure : Not classified. Aspiration hazard : Not classified. SECTION 12: Ecological information 12.1. Toxicity Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and isopropyl) esters, zinc salts (84605-29-8) LC50 fish 1 10 - 100 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) EC50 Daphnia 1 0.1 - 1 mg/l (Exposure time: 48 h - Species: Daphnia magna) LC50 fish 2 38 mg/l (Exposure time: 96 h - Species: Pimephales promelas) 12.2. Persistence and degradability No additional information available 12.3. Bioaccumulative potential No additional information available 12.4. Mobility in soil No additional information available 12.5. Other adverse effects No additional information available SECTION 13: Disposal considerations 13.1. Waste treatment methods No additional information available 03/01/2019 EN (English) 4/5 Oil Enhancer Safety Data Sheet According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015 SECTION 14: Transport information Department of Transportation (DOT) and Transportation of Dangerous Goods (TDG) In accordance with DOT/TDG Not regulated Transport by sea This product is currently not packaged to comply with IMDG regulations. It is not intended to be shipped by sea. Transport by air This product is currently not packaged to comply with IATA regulations. It is not intended to be shipped by air. SECTION 15: Regulatory information 15.1. US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory. All components of this product are listed, or excluded from listing, on the Canadian DSL (Domestic Substances List) and NDSL (Non-Domestic Substances List) inventories. 15.2. International regulations No additional information available 15.3. US State regulations California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm SECTION 16: Other information Revision date : 03/01/2019 Other information : None. Prepared by : Nexreg Compliance Inc. www.Nexreg.com NFPA health hazard : 1 NFPA fire hazard : 1 NFPA reactivity : 0 SDS HazCom 2012 - WHMIS 2015 (NexReg) - Section 15 Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user?s responsibility to satisfy oneself as to the suitability and completeness of this information for the user?s own particular use. 03/01/2019 EN (English) 5/5 SECTION 1: Identification 1.1. Identification 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet 1.4. Emergency telephone number 2.1. Classification of the substance or mixture GHS classification 2.2. Label elements GHS labelling 2.3. Other hazards 2.4. Unknown acute toxicity 3.1. Substances 3.2. Mixtures SECTION 4: First aid measures 4.1. Description of first aid measures 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Fire-fighting measures 5.1. Extinguishing media 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel 6.2. Environmental precautions 6.3. Methods and material for containment and cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities SECTION 8: Exposure controls/personal protection 8.1. Control parameters SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties SECTION 10: Stability and reactivity 10.1. Reactivity 10.2. Chemical stability 10.3. Possibility of hazardous reactions 10.4. Conditions to avoid 10.5. Incompatible materials SECTION 11: Toxicological information 11.1. Information on toxicological effects SECTION 12: Ecological information 12.1. Toxicity 12.2. Persistence and degradability 12.3. Bioaccumulative potential 12.4. Mobility in soil SECTION 13: Disposal considerations 13.1. Waste treatment methods SECTION 14: Transport information SECTION 15: Regulatory information 15.1. US Federal regulations 15.2. International regulations 15.3. US State regulations