Page 1 of 8 Safety Data Sheet Section 1: Identification Product Identifier Ice melting agent Product Name Trade Name: SPLASH Premium Ice Melt -15?F PN (Part number): 10# Shaker Bag-139100, 12# Jug-136012, 20# Bag-136020, 50# Bag-136050 Relevant identified uses of the substance or mixture and uses advised against -Anti-icing and De-icing Details of the supplier of the safety data sheet Manufacturer SPLASH Products 51 E. Maryland Ave. St. Paul, MN 55117 Phone: (651) 489-8211 Emergency telephone number 1-800-535-5053 Section 2: Hazard(s) Identification OSHA/HCS status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the substance or mixture Skin corrosion/irritation, Irritant Category 2 Serious Eye Damage/Eye Irritation, Irritant Category 2A GHS label elements Hazard pictograms Signal word-WARNING Calcium chloride Hazard statements Causes serious eye irritation Causes skin irritation Precautionary statements Page 2 of 8 Prevention Wear protective gloves/protective clothing/eye protection/face protection. Take off contaminated clothing and wash before use Keep away from oxidizing materials and strong acids Response IF SWALLOWED: Single dose oral toxicity is believed to be low. Small amounts swallowed incidental to normal handling procedures are not likely to cause injury. Ingestion may cause gastrointestinal irritation or ulceration. IF ON SKIN (or hair): Short single exposure is not likely to cause significant skin irritation. Prolonged or repeated exposure may cause skin irritation, even a burn. May cause more severe response if confined to skin or skin in abraded (scratched or cut). Material may be handled at elevated temperatures; contact with heated material may cause thermal burns. A single prolonged exposure is not likely to result in the material being absorbed through the skin in harmful amounts. Not classified as corrosive with TDG Act and Regulations. IF IN EYES: Material may be handled at elevated temperatures; contact with heated material may cause thermal burns. May cause severe irritation with corneal injury. Effects may be slow to heal. IF INHALED: Vapors are unlikely due to physical properties. Mists may cause irritation to upper respiratory tract. IF EXPOSED or CONCERNED: Immediately call a POISON CENTER or a doctor/physician. Storage No special storage conditions required. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified Product is stable. Section 3: Composition/Information on Ingredients Substance/mixture: Mixture Chemical name: Calcium Chloride Other means of identification: No CAS number/other identifiers Ingredient name % CAS number Calcium Chloride 20-10 1043-52-4 Sodium Chloride 90-80 7647-14-5 Section 4: First Aid Measurements Description of necessary first aid measures Eye contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 30 minutes. Cold water may be used. Get medical attention immediately. Inhalation: Bring accident victims out into the fresh air. Call a physician immediately in severe cases or if recovery is not rapid. Skin contact: After contact with skin, wash immediately with plenty of water. Remove contaminated clothing and wash before reuse. Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Give large amounts of water or milk if available. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband. Page 3 of 8 Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact Can cause irritation to eyes and mucous membranes. Inhalation Vapors are unlikely due to physical properties. Mists may cause irritation to upper respiratory tract. Skin contact Irritation, itching, dermatitis. Ingestion Irritation to mucous membranes. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Exposure may aggravate acute or chronic asthma, emphysema and bronchitis. Specific treatments N/A Protection of first-aiders N/A See toxicological information (Section 11) Section 5: Fire Fighting Measures Extinguishing media Suitable extinguishing media This material does not burn. If exposed to fire from another source, use suitable extinguishing agent for that fire. Unsuitable extinguishing media None known Specific hazards arising from the chemical None known Hazardous thermal decomposition products/Products of combustion Not applicable Special protective actions for fire fighters Do not release runoff from fire control methods to sewers or waterways. Special protective equipment for fire-fighters In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Section 6: Accidental Release Measures Personal precautions, protective equipment and emergency procedures For non-emergency personnel Isolate area. Avoid contact with eye and skin. May be a slipping hazard. Stop leak if it can be done safely. Wash exposed body areas thoroughly after handling. Use appropriate safety equipment. Environmental precautions Methods and materials for containment and cleaning up: For small spills: Losses incidental to correct applications of this product in its intended uses are not expected to be harmful to the environment. Page 4 of 8 For large spills: Avoid contamination of drinking water, natural water, ground water or any waterway. Losses incidental to correct applications of this product in its intended uses are not expected to be harmful to the environment. Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Wear complete and proper personal protective equipment following the recommendation of Section 8 at a minimum. Dike with suitable absorbent material like granulated clay. Gather and store in a sealed container pending a waste disposal evaluation. Section 7: Handling and Storage Precautions for safe handling Protective measures, advice on general occupational hygiene and conditions for safe storage, including any incompatibilities: Product shipped/handled hot can cause thermal burns. Selection of specific items such as gloves, boots, apron, or other will depend on each operation. If hands are cut or scratched, use gloves impervious to this material for brief exposures. Use gloves with insulation for thermal protection when needed. Atmospheric levels should be maintained below the exposure guideline. When respiratory protection is required for certain operations, use an approved air-purifying respirator. In misty atmospheres, use an approved mist respirator. Section 8: Exposure Controls/Personal Protection Control parameters Occupational exposure limits Ingredient name Exposure limits Calcium Chloride ACGIH OSHA (TWA) (STEL) (TWA) (STEL) 10 mg/m3 10 mg/m3 10 mg/m3 N/A Appropriate engineering controls and Environmental exposure controls A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Individual protection measures Hygiene measures None Eye/face protection: Use chemical safety goggles. Skin protection Hand protection and Body protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Other skin protection Wash hands and other exposed areas with mild soap and water before eating or drinking. Respiratory protection: No respiratory protection required under normal circumstances. Respirator Type(s) (NIOSH Approved): If the exposure limit is exceeded and engineering controls are not feasible, a half face piece particulate respirator (NIOSH type N95 or better filters) may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full face piece particulate respirator (NIOSH type N100 filter) may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids, Glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full face piece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in Oxygen- deficient atmospheres. Section 9: Physical and Chemical Properties Appearance Physical state: Blue colored crystalline solids Page 5 of 8 Odor: None Odor threshold: Not determined pH: (5% in water) 6-9 Specific Gravity: 1.988 Melting point: Not determined Boiling point: Not determined Flash point: Not applicable Evaporation rate (BuAc=1): Not determined Flammability (solid, gas): No Lower and upper explosive (flammable) limits: LEL: Not applicable, UEL: Not applicable Vapor pressure: 1.0 mm Hg at 865oC Vapor density (Air=1): Not applicable Solubility: Soluble in water Partition coefficient: n-octanol/water: Not Established Auto-ignition temperature: Not Applicable Decomposition temperature: Not Established Viscosity: Not determined VOC%: 0 Section 10: Stability and Reactivity Reactivity Stable under recommended storage conditions. Chemical stability Stable under recommended storage conditions. Hygroscopic Possibility of hazardous reactions Will not occur. Conditions to avoid Mildly corrosive to metals in the presence of moisture Incompatible materials Hot nitric acid Hazardous decomposition products None Section 11: Toxicological Information Information on toxicological effects Acute toxicity Product/ingredient name Test Results Calcium Chloride Acute toxicity, oral (male rat) LD50 = 1000 mg/kg Acute toxicity, dermal (rabbit) LD50 = >5000 mg/kg Summary Comments: Sensitization Product/ingredient name Test Results Basis Calcium Chloride No evidence of sensitization effect Summary Comments: Page 6 of 8 Carcinogenicity Product/ingredient name Test Results Basis Calcium Chloride No known carcinogenic effects Summary Comments: Specific target organ toxicity (single exposure) Product/ingredient name Test Results Basis Calcium Chloride STOT-one-time exposure-oral No information available STOT-one-time exposure-dermal No information available STOT-one-time exposure-inhalation No information available Summary Comments: Specific target organ toxicity (repeated exposure) Product/ingredient name Test Results Basis Calcium Chloride No information available Summary Comments: Aspiration hazard Product/ingredient name Test Results Basis Calcium Chloride No information available Summary Comments: Information on the likely routes of exposure Ingesting may irritate the gastrointestinal tract. Potential acute health effects Eye contact: Irritating to the eyes. Inhalation: No information available. Skin contact: Contact of skin can produce mild dermatitis in humans. Ingestion: Tests involving acute exposure of rats, mice, and rabbits have demonstrated calcium chloride to have low acute toxicity from oral exposure. Symptoms related to the physical, chemical and toxicological characteristics Eye contact: Eye irritation. Inhalation: No information available. Skin contact: Skin irritation. Ingestion: May irritate the gastrointestinal tract, cause nausea, and vomiting. Potential chronic health effects (Calcium Chloride) Carcinogenicity: No known carcinogens. Mutagenicity: No data available. Teratogenicity: No data available. Developmental effects: No data available. Fertility effects: No data available. Numerical measures of toxicity Acute toxicity estimates 0% of the mixture consists of ingredients of known toxicity. Section 12: Ecological Information Page 7 of 8 Toxicity Acute Fish toxicity: (Calcium Chloride) LC50 ? Lepomis macrochirus (Bluegill) ? 10,650 mg/l - 96 h Acute toxicity for daphnia: (Calcium Chloride) EC50 - Daphnia magna (Water flea) ? 2,400 mg/l - 48 h Acute toxicity for algae: (Calcium Chloride) EC50 - Scenedesmus capricornutum (fresh water algae) ? No information available Acute bacterial toxicity: (Calcium Chloride) No data available. Ecotoxicology Assessment: (Calcium Chloride) Material is expected to be slightly toxic to aquatic life. Persistence and degradability Biodegradability: (Calcium Chloride) Product is not biodegradable Stability in water: (Calcium Chloride) No data available Photodegradation: (Calcium Chloride) No data available Volatility (Henry's Law constant): (Calcium Chloride) No data available Bioaccumulative potential Bioaccumulation: (Calcium Chloride) Does not bioaccumulate Mobility in soil: (Calcium Chloride) Distribution among environmental compartments: Does not bioaccumulate Other adverse effects: No information available Section 13: Disposal Considerations Disposal methods Dispose in accordance with applicable international, national and local laws, ordinances and statutes. Section 14: Transport Information UN Number: Not regulated UN Proper Shipping Name: CALCIUM CHLORIDE Transport hazard Class(es): N/A Packing Group: N/A Land Transport ADR/RID and GGVS/GGVE (Cross Border / Domestic) Transport Hazard Class(es): Not Regulated Maritime Transport IMDG/GGVSea Transport Hazard Class(es): Not Regulated Marine Pollutant: No Page 8 of 8 Air Transport ICAO-TI and IATA-DGR Transport Hazard Class(es): Not regulated Section 15: Regulatory Information Chemical Inventory Status-Part 1 Ingredient (CAS#) TSCA EC Japan Australia Calcium Chloride (10043-52-4) Yes Yes Yes Yes Chemical Inventory Status-Part 2 Ingredient (CAS#) Korea Canada Canada Philippines DSL NDSL Calcium Chloride (10043-52-4) Yes Yes No Yes Federal, State & International Regulations-Part 1 SARA 302 SARA 313 Ingredient (CAS#) RQ TPQ List Chemical Category Calcium Chloride (10043-52-4) No No No No Federal, State & International Regulations-Part 2 RCRA TSCA Ingredient (CAS#) CERCLA 261.33 8(d) Calcium Chloride (10043-52-4) No No No Chemical Weapons Convention: No TSCA 12b: No CDTA: No SARA 311/312: Acute: Yes, Chronic: No, Fire: No, Pressure: No, Reactivity: No Mixture/Solid Australian Hazchem Code: None allocated Poison Schedule: No information found Section 16: Other Information History Date of issue: 11/06/19 Version: 5a Revised Sections(s): Added part numbers Prepared by: Andrew Gioino, SPLASH PRODUCTS Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of the suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.