Version: 1.0 Revision Date: 10/23/2019 SDS_US - RE1000040592 1/21 SAFETY DATA SHEET 1. Identification Product identifier: Penray Penetrating Gel Lubricant with PTFE #4716 Other means of identification SDS number: RE1000040592 Recommended restrictions Product Use: Lubricant Restrictions on use: Not known. Manufacturer/Importer/Distributor Information Manufacturer Company Name: The Penray Companies, Inc. Address: 440 Denniston Ct. Wheeling, IL 60090 Telephone: (800) 373-6729 Fax: Emergency telephone number: 1-800-424-9300 2. Hazard(s) identification Hazard Classification Physical Hazards Flammable aerosol Category 1 Health Hazards Serious Eye Damage/Eye Irritation Category 2A Specific Target Organ Toxicity - Single Exposure Category 31. Specific Target Organ Toxicity - Repeated Exposure Category 2 Aspiration Hazard Category 1 Target Organs 1. Narcotic effect. Environmental Hazards Acute hazards to the aquatic environment Category 3 Hazard Symbol: Label Elements Version: 1.0 Revision Date: 10/23/2019 SDS_US - RE1000040592 2/21 Signal Word: Danger Hazard Statement: Extremely flammable aerosol. Causes serious eye irritation. May cause drowsiness or dizziness. May cause damage to organs through prolonged or repeated exposure. May be fatal if swallowed and enters airways. Harmful to aquatic life. Precautionary Statements Prevention: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Use only outdoors or in a well-ventilated area. Do not breathe dust/fume/gas/mist/vapors/spray. Avoid release to the environment. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF SWALLOWED: Immediately call a POISON CENTER/doctor Do NOT induce vomiting. Call a POISON CENTER/doctor if you feel unwell. Storage: Protect from sunlight. Do not expose to temperatures exceeding 50?C/122?F. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Hazard(s) not otherwise classified (HNOC): None. 3. Composition/information on ingredients Version: 1.0 Revision Date: 10/23/2019 SDS_US - RE1000040592 3/21 Mixtures Chemical Identity CAS number Content in percent (%)* 2-Propanone 67-64-1 20 - <50% Petrolatum 8009-03-8 10 - <20% Distillates (petroleum), hydrotreated light 64742-47-8 10 - <20% Acetic acid, methyl ester 79-20-9 10 - <20% Naphtha (petroleum), hydrotreated light 64742-49-0 5 - <10% Carbon dioxide 124-38-9 1 - <5% Heptane 142-82-5 1 - <5% Cyclohexane, methyl- 108-87-2 0.1 - <1% Methanol 67-56-1 0.1 - <1% * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First-aid measures Ingestion: Call a physician or poison control center immediately. Rinse mouth. Never give liquid to an unconscious person. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Inhalation: Move to fresh air. Skin Contact: Wash skin thoroughly with soap and water. If skin irritation occurs: Get medical advice/attention. Eye contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Get medical attention. Most important symptoms/effects, acute and delayed Symptoms: No data available. Hazards: No data available. Indication of immediate medical attention and special treatment needed Treatment: No data available. 5. Fire-fighting measures General Fire Hazards: Use water spray to keep fire-exposed containers cool. Fight fire from a protected location. Move containers from fire area if you can do so without risk. Suitable (and unsuitable) extinguishing media Suitable extinguishing media: Use fire-extinguishing media appropriate for surrounding materials. Unsuitable extinguishing media: Do not use water jet as an extinguisher, as this will spread the fire. Version: 1.0 Revision Date: 10/23/2019 SDS_US - RE1000040592 4/21 Specific hazards arising from the chemical: Vapors may travel considerable distance to a source of ignition and flash back. Special protective equipment and precautions for firefighters Special fire fighting procedures: No data available. Special protective equipment for fire-fighters: Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures: Ventilate closed spaces before entering them. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Keep upwind. Methods and material for containment and cleaning up: Absorb spill with vermiculite or other inert material, then place in a container for chemical waste. Dike far ahead of larger spill for later recovery and disposal. Notification Procedures: Dike for later disposal. Prevent entry into waterways, sewer, basements or confined areas. Stop the flow of material, if this is without risk. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. Environmental Precautions: Do not contaminate water sources or sewer. Prevent further leakage or spillage if safe to do so. Avoid release to the environment. 7. Handling and storage Precautions for safe handling: Avoid contact with eyes. Wash hands thoroughly after handling. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Conditions for safe storage, including any incompatibilities: Store locked up. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50?C. Do not pierce or burn, even after use. Aerosol Level 2 8. Exposure controls/personal protection Control Parameters Occupational Exposure Limits Chemical Identity Type Exposure Limit Values Source 2-Propanone STEL 1,000 ppm 2,400 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) PEL 1,000 ppm 2,400 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) TWA 250 ppm US. ACGIH Threshold Limit Values (03 2015) TWA 750 ppm 1,800 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) STEL 500 ppm US. ACGIH Threshold Limit Values (03 2015) REL 250 ppm 590 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) Petrolatum - Inhalable TWA 5 mg/m3 US. ACGIH Threshold Limit Values (01 2010) Version: 1.0 Revision Date: 10/23/2019 SDS_US - RE1000040592 5/21 fraction. Petrolatum - Mist. REL 5 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) STEL 10 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) TWA 5 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) Distillates (petroleum), hydrotreated light REL 100 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) Distillates (petroleum), hydrotreated light - Non- aerosol. - as total hydrocarbon vapor TWA 200 mg/m3 US. ACGIH Threshold Limit Values (2008) TWA 200 mg/m3 US. ACGIH Threshold Limit Values (2008) Acetic acid, methyl ester REL 200 ppm 610 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) STEL 250 ppm 760 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) PEL 200 ppm 610 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) STEL 250 ppm US. ACGIH Threshold Limit Values (2008) TWA 200 ppm 610 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) STEL 250 ppm 760 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) TWA 200 ppm US. ACGIH Threshold Limit Values (2008) Naphtha (petroleum), hydrotreated light PEL 100 ppm 400 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (03 2016) REL 100 ppm 400 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2010) TWA 100 ppm 400 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) Carbon dioxide TWA 5,000 ppm US. ACGIH Threshold Limit Values (2008) STEL 30,000 ppm US. ACGIH Threshold Limit Values (2008) STEL 30,000 ppm 54,000 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) REL 5,000 ppm 9,000 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) PEL 5,000 ppm 9,000 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) TWA 10,000 ppm 18,000 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) STEL 30,000 ppm 54,000 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) Heptane TWA 400 ppm 1,600 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) REL 85 ppm 350 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) PEL 500 ppm 2,000 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) STEL 500 ppm 2,000 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) TWA 400 ppm US. ACGIH Threshold Limit Values (02 2012) STEL 500 ppm US. ACGIH Threshold Limit Values (02 2012) Ceil_Time 440 ppm 1,800 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) Cyclohexane, methyl- PEL 500 ppm 2,000 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) TWA 400 ppm 1,600 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) TWA 400 ppm US. ACGIH Threshold Limit Values (2008) REL 400 ppm 1,600 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) Methanol REL 200 ppm 260 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) PEL 200 ppm 260 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) Version: 1.0 Revision Date: 10/23/2019 SDS_US - RE1000040592 6/21 TWA 200 ppm 260 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) STEL 250 ppm 325 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) TWA 200 ppm US. ACGIH Threshold Limit Values (2008) STEL 250 ppm US. ACGIH Threshold Limit Values (2008) STEL 250 ppm 325 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) Benzene, methyl- STEL 150 ppm 560 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) REL 100 ppm 375 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) TWA 100 ppm 375 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) Ceiling 300 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02 2006) TWA 20 ppm US. ACGIH Threshold Limit Values (2008) TWA 200 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02 2006) MAX. CONC 500 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02 2006) STEL 150 ppm 560 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) Hexane TWA 50 ppm 180 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) PEL 500 ppm 1,800 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) REL 50 ppm 180 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) TWA 50 ppm US. ACGIH Threshold Limit Values (2008) Cyclohexane TWA 100 ppm US. ACGIH Threshold Limit Values (2008) TWA 300 ppm 1,050 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) REL 300 ppm 1,050 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) PEL 300 ppm 1,050 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) Benzene, ethyl- STEL 125 ppm 545 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) REL 100 ppm 435 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) PEL 100 ppm 435 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) STEL 125 ppm 545 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) TWA 100 ppm 435 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) TWA 20 ppm US. ACGIH Threshold Limit Values (12 2010) Benzene REL 0.1 ppm US. NIOSH: Pocket Guide to Chemical Hazards (2005) TWA 1 ppm US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) Ceiling 25 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02 2006) TWA 0.5 ppm US. ACGIH Threshold Limit Values (2008) STEL 2.5 ppm US. ACGIH Threshold Limit Values (2008) STEL 5 ppm US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) (02 2006) OSHA_AC T 0.5 ppm US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) (02 2006) TWA 10 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02 2006) MAX. CONC 50 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02 2006) STEL 5 ppm US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) TWA 1 ppm US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) (02 2006) Version: 1.0 Revision Date: 10/23/2019 SDS_US - RE1000040592 7/21 STEL 1 ppm US. NIOSH: Pocket Guide to Chemical Hazards (2005) Biological Limit Values Chemical Identity Exposure Limit Values Source 2-Propanone (acetone: Sampling time: End of shift.) 25 mg/l (Urine) ACGIH BEL (03 2015) Methanol (methanol: Sampling time: End of shift.) 15 mg/l (Urine) ACGIH BEL (03 2013) Benzene, methyl- (toluene: Sampling time: End of shift.) 0.03 mg/l (Urine) ACGIH BEL (03 2013) Benzene, methyl- (o-Cresol, with hydrolysis: Sampling time: End of shift.) 0.3 mg/g (Creatinine in urine) ACGIH BEL (03 2013) Benzene, methyl- (toluene: Sampling time: Prior to last shift of work week.) 0.02 mg/l (Blood) ACGIH BEL (03 2013) Hexane (2,5-Hexanedion, without hydrolysis: Sampling time: End of shift.) 0.5 mg/l (Urine) ACGIH BEL (03 2018) Benzene, ethyl- (Sum of mandelic acid and phenylglyoxylic acid: Sampling time: End of shift.) 0.15 g/g (Creatinine in urine) ACGIH BEL (02 2014) Benzene (S- Phenylmercapturic acid: Sampling time: End of shift.) 25 ?g/g (Creatinine in urine) ACGIH BEL (03 2013) Benzene (t,t-Muconic acid: Sampling time: End of shift.) 500 ?g/g (Creatinine in urine) ACGIH BEL (03 2013) Appropriate Engineering Controls No data available. Individual protection measures, such as personal protective equipment General information: Provide easy access to water supply and eye wash facilities. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye/face protection: Wear safety glasses with side shields (or goggles). Skin Protection Hand Protection: No data available. Other: Wear suitable protective clothing. Respiratory Protection: In case of inadequate ventilation use suitable respirator. Seek advice from local supervisor. Hygiene measures: Observe good industrial hygiene practices. Avoid contact with eyes. When using do not smoke. 9. Physical and chemical properties Version: 1.0 Revision Date: 10/23/2019 SDS_US - RE1000040592 8/21 Appearance Physical state: liquid Form: Spray Aerosol Color: No data available. Odor: No data available. Odor threshold: No data available. pH: No data available. Melting point/freezing point: No data available. Initial boiling point and boiling range: No data available. Flash Point: No data available. Evaporation rate: No data available. Flammability (solid, gas): No data available. Upper/lower limit on flammability or explosive limits Flammability limit - upper (%): No data available. Flammability limit - lower (%): No data available. Explosive limit - upper (%): No data available. Explosive limit - lower (%): No data available. Vapor pressure: No data available. Vapor density: No data available. Density: No data available. Relative density: No data available. Solubility(ies) Solubility in water: No data available. Solubility (other): No data available. Partition coefficient (n-octanol/water): No data available. Auto-ignition temperature: No data available. Decomposition temperature: No data available. Viscosity: No data available. 10. Stability and reactivity Reactivity: No data available. Chemical Stability: Material is stable under normal conditions. Possibility of hazardous reactions: No data available. Conditions to avoid: Avoid heat or contamination. Incompatible Materials: No data available. Hazardous Decomposition Products: No data available. 11. Toxicological information Version: 1.0 Revision Date: 10/23/2019 SDS_US - RE1000040592 9/21 Information on likely routes of exposure Inhalation: No data available. Skin Contact: No data available. Eye contact: No data available. Ingestion: No data available. Symptoms related to the physical, chemical and toxicological characteristics Inhalation: No data available. Skin Contact: No data available. Eye contact: No data available. Ingestion: No data available. Information on toxicological effects Acute toxicity (list all possible routes of exposure) Oral Product: Not classified for acute toxicity based on available data. Specified substance(s): 2-Propanone LD 50 (Rat): 5,800 mg/kg Petrolatum LD 50 (Rat): > 5,000 mg/kg LD 50 (Rat): > 5,000 mg/kg LD 50 (Rat): > 5,000 mg/kg LD 50 (Rat): > 5,000 mg/kg Distillates (petroleum), hydrotreated light LD 50 (Rat): > 5,000 mg/kg Acetic acid, methyl ester LD 50 (Rat): 6,482 mg/kg Naphtha (petroleum), hydrotreated light LD 50 (Rat): > 5,000 mg/kg Heptane LD 50 (Rat): > 5,000 mg/kg Cyclohexane, methyl- LD Lo (Rabbit): 4,000 - 4,500 mg/kg Methanol ATE: 100 mg/kg LD 50 (Rat): > 1,187 - 2,769 mg/kg Dermal Product: ATEmix: 361,663.65 mg/kg Version: 1.0 Revision Date: 10/23/2019 SDS_US - RE1000040592 10/21 Inhalation Product: ATEmix: 280.29 mg/l Repeated dose toxicity Product: No data available. Specified substance(s): 2-Propanone NOAEL (Rat(Male), Oral, 13 Weeks): 10,000 ppm(m) Oral Experimental result, Key study Petrolatum LOAEL (Rat(Male), Oral, 13 Weeks): 125 mg/kg Oral Read-across from supporting substance (structural analogue or surrogate), Key study NOAEL (Rat(Female, Male), Oral, 2 yr): 5,000 mg/kg Oral Experimental result, Key study NOAEL (Rat(Female, Male), Oral, 2 yr): > 5,700 mg/kg Oral Read-across from supporting substance (structural analogue or surrogate), Supporting study NOAEL (Rat(Female, Male), Oral, 90 d): 1.5 mg/kg Oral Read-across from supporting substance (structural analogue or surrogate), Key study NOAEL (Rat(Female, Male), Oral, 90 d): 1,500 mg/kg Oral Read-across from supporting substance (structural analogue or surrogate), Key study Distillates (petroleum), hydrotreated light NOAEL (Rat(Female, Male), Inhalation): >= 24 mg/m3 Inhalation Experimental result, Key study NOAEL (Rat(Female), Oral, 70 - 147 d): 750 mg/kg Oral Experimental result, Key study Acetic acid, methyl ester NOAEL (Rat(Female, Male), Inhalation, 28 d): 350 ppm(m) Inhalation Experimental result, Key study LOAEL (Rat(Female, Male), Inhalation, 28 d): 2,000 ppm(m) Inhalation Experimental result, Key study Naphtha (petroleum), hydrotreated light LOAEL (Rat(Female, Male), Oral, 13 Weeks): 1,250 mg/kg Oral Read- across based on grouping of substances (category approach), Key study NOAEL (Rat(Female, Male), Dermal, 28 d): > 375 mg/kg Dermal Experimental result, Supporting study NOAEL (Rat(Female, Male), Inhalation): 10,000 mg/m3 Inhalation Experimental result, Key study Heptane NOAEL (Rat(Male), Inhalation): 12,470 mg/m3 Inhalation Experimental result, Key study Cyclohexane, methyl- LOAEL (Rat(Female, Male), Oral, 28 d): 1,000 mg/kg Oral Experimental result, Key study NOAEL (Rat(Female, Male), Oral, 28 d): 250 mg/kg Oral Experimental result, Key study NOAEL (Rat(Female, Male), Inhalation): 1,600 mg/m3 Inhalation Experimental result, Key study Methanol LOAEL (Rat(Male), Inhalation, 1 - 6 Weeks): 13.3 mg/l Inhalation Experimental result, Supporting study Skin Corrosion/Irritation Product: No data available. Specified substance(s): Version: 1.0 Revision Date: 10/23/2019 SDS_US - RE1000040592 11/21 2-Propanone in vivo (Rabbit): Not irritant Experimental result, Supporting study Petrolatum in vivo (Rabbit): Not irritant Read-across from supporting substance (structural analogue or surrogate), Key study in vivo (Rabbit): Not irritant Read-across from supporting substance (structural analogue or surrogate), Key study Distillates (petroleum), hydrotreated light in vivo (Rabbit): Not irritant Experimental result, Key study Acetic acid, methyl ester in vivo (Rabbit): Not irritant Experimental result, Key study Heptane in vivo (Rabbit): Irritating Read-across based on grouping of substances (category approach), Key study Methanol in vivo (Rabbit): Not irritant Experimental result, Key study Serious Eye Damage/Eye Irritation Product: No data available. Specified substance(s): 2-Propanone Irritating. Rabbit, 24 hrs: Minimum grade of severe eye irritant Petrolatum Rabbit, 24 - 72 hrs: Not irritating Rabbit, 24 - 72 hrs: Not irritating Rabbit, 24 - 72 hrs: Not irritating Distillates (petroleum), hydrotreated light Rabbit, 24 - 72 hrs: Not irritating Acetic acid, methyl ester Rabbit: Irritating Naphtha (petroleum), hydrotreated light Rabbit, 24 - 72 hrs: Not irritating Heptane Rabbit, 24 - 72 hrs: Not irritating Cyclohexane, methyl- Rabbit, 0.5 - 168 hrs: Not irritating Respiratory or Skin Sensitization Product: No data available. Version: 1.0 Revision Date: 10/23/2019 SDS_US - RE1000040592 12/21 Specified substance(s): 2-Propanone Skin sensitization:, in vivo (Guinea pig): Non sensitising Petrolatum Skin sensitization:, in vivo (Guinea pig): Non sensitising Skin sensitization:, in vivo (Guinea pig): Non sensitising Distillates (petroleum), hydrotreated light Skin sensitization:, in vivo (Guinea pig): Non sensitising Naphtha (petroleum), hydrotreated light Skin sensitization:, in vivo (Guinea pig): Non sensitising Heptane Skin sensitization:, in vivo (Guinea pig): Non sensitising Cyclohexane, methyl- Skin sensitization:, in vivo (Guinea pig): Non sensitising Methanol Skin sensitization:, in vivo (Guinea pig): Non sensitising Carcinogenicity Product: No data available. Specified substance(s): Cyclohexane, methyl- May cause cancer. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: No carcinogenic components identified US. National Toxicology Program (NTP) Report on Carcinogens: No carcinogenic components identified US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): No carcinogenic components identified Germ Cell Mutagenicity In vitro Product: No data available. In vivo Product: No data available. Reproductive toxicity Product: No data available. Specific Target Organ Toxicity - Single Exposure Product: No data available. Specified substance(s): 2-Propanone Inhalation - vapor: Narcotic effect. - Category 3 with narcotic effects. Heptane Narcotic effect. - Category 3 with narcotic effects. Cyclohexane, methyl- Inhalation - vapor: Narcotic effect. - Category 3 with narcotic effects. Methanol Causes damage to organs. Specific Target Organ Toxicity - Repeated Exposure Product: No data available. Specified substance(s): Cyclohexane, methyl- Category 1 Target Organs Specific Target Organ Toxicity - Single Exposure: Narcotic effect. Aspiration Hazard Version: 1.0 Revision Date: 10/23/2019 SDS_US - RE1000040592 13/21 Product: No data available. Specified substance(s): Distillates (petroleum), hydrotreated light May be fatal if swallowed and enters airways. Naphtha (petroleum), hydrotreated light May be fatal if swallowed and enters airways. Heptane May be fatal if swallowed and enters airways. Cyclohexane, methyl- May be fatal if swallowed and enters airways. Other effects: No data available. 12. Ecological information Ecotoxicity: Acute hazards to the aquatic environment: Fish Product: No data available. Specified substance(s): 2-Propanone LC 50 (Oncorhynchus mykiss, 96 h): 5,540 mg/l Experimental result, Key study Petrolatum LL 50 (Pimephales promelas, 96 h): > 100 mg/l Read-across from supporting substance (structural analogue or surrogate), Key study NOAEL (Pimephales promelas, 96 h): >= 100 mg/l Read-across from supporting substance (structural analogue or surrogate), Key study LL 50 (Oncorhynchus mykiss, 96 h): > 1,000 mg/l QSAR QSAR, Supporting study Acetic acid, methyl ester LC 50 (Fathead minnow (Pimephales promelas), 96 h): 295 - 348 mg/l Mortality LC 50 (Danio rerio, 48 h): 250 - 350 mg/l Experimental result, Key study Naphtha (petroleum), hydrotreated light LC 50 (96 h): 8.41 mg/l Experimental result, Key study Heptane LC 50 (Mozambique tilapia (Tilapia mossambica), 96 h): 375 mg/l Mortality Cyclohexane, methyl- LC 50 (Oryzias latipes, 96 h): 2.07 mg/l Experimental result, Key study Methanol EC 50 (Lepomis macrochirus, 96 h): 12,700 mg/l Experimental result, Key study Aquatic Invertebrates Product: No data available. Specified substance(s): 2-Propanone LC 50 (Daphnia pulex, 48 h): 8,800 mg/l Experimental result, Key study Petrolatum NOAEL (Daphnia magna, 48 h): >= 10,000 mg/l Read-across from supporting substance (structural analogue or surrogate), Key study LL 50 (Gammarus pulex, 96 h): > 10,000 mg/l Read-across from supporting Version: 1.0 Revision Date: 10/23/2019 SDS_US - RE1000040592 14/21 substance (structural analogue or surrogate), Key study EC 50 (Daphnia magna, 48 h): > 10,000 mg/l Read-across from supporting substance (structural analogue or surrogate), Key study LL 50 (Daphnia magna, 48 h): > 1,000 mg/l QSAR QSAR, Supporting study LL 50 (Gammarus pulex, 24 h): > 10,000 mg/l Read-across from supporting substance (structural analogue or surrogate), Key study Acetic acid, methyl ester EC 50 (Daphnia magna, 48 h): 1,026.7 mg/l Experimental result, Key study Naphtha (petroleum), hydrotreated light EC 50 (Daphnia magna, 48 h): 4.5 mg/l Experimental result, Key study Heptane EC 50 (Daphnia magna, 48 h): 1.5 mg/l Experimental result, Key study Cyclohexane, methyl- EC 50 (Daphnia magna, 48 h): 0.326 mg/l Experimental result, Key study ED 0 (Daphnia magna, 48 h): 0.037 mg/l Experimental result, Key study Methanol EC 50 (Daphnia magna, 96 h): 18,260 mg/l Experimental result, Key study Chronic hazards to the aquatic environment: Fish Product: No data available. Specified substance(s): Petrolatum NOAEL (Oncorhynchus mykiss): >= 1,000 mg/l QSAR QSAR, Supporting study LL 50 (Oncorhynchus mykiss): > 1,000 mg/l QSAR QSAR, Supporting study Distillates (petroleum), hydrotreated light NOAEL (Oncorhynchus mykiss): 0.098 mg/l QSAR QSAR, Key study Naphtha (petroleum), hydrotreated light EC 50 (Daphnia magna): 10 mg/l Other, Key study NOAEL (Daphnia magna): 2.6 mg/l Other, Key study Heptane NOAEL (Oncorhynchus mykiss): 1.284 mg/l QSAR QSAR, Key study Methanol EC 50 (Oryzias latipes): 9,164 mg/l Experimental result, Supporting study Aquatic Invertebrates Product: No data available. Specified substance(s): 2-Propanone LOAEL (Daphnia magna): 2,212 mg/l Experimental result, Key study NOAEL (Daphnia magna): 2,212 mg/l Experimental result, Key study Petrolatum NOAEL (Daphnia magna): 10 mg/l Read-across from supporting substance (structural analogue or surrogate), Key study NOAEL (Daphnia magna): >= 1,000 mg/l QSAR QSAR, Supporting study Naphtha (petroleum), hydrotreated light EC 50 (Daphnia magna): 10 mg/l Experimental result, Key study NOAEL (Daphnia magna): 2.6 mg/l Experimental result, Key study Heptane NOAEL (Daphnia magna): 0.17 mg/l Read-across based on grouping of substances (category approach), Key study EC 50 (Daphnia magna): 0.23 mg/l Read-across based on grouping of substances (category approach), Key study Version: 1.0 Revision Date: 10/23/2019 SDS_US - RE1000040592 15/21 Methanol NOAEL (Daphnia magna): 122 mg/l Experimental result, Supporting study Toxicity to Aquatic Plants Product: No data available. Persistence and Degradability Biodegradation Product: No data available. Specified substance(s): 2-Propanone 90.9 % (28 d) Detected in water. Experimental result, Key study Petrolatum 31 % (28 d) Detected in water. Read-across from supporting substance (structural analogue or surrogate), Supporting study Distillates (petroleum), hydrotreated light 61 % Detected in water. Experimental result, Supporting study Acetic acid, methyl ester 70 % Detected in water. Experimental result, Key study Naphtha (petroleum), hydrotreated light 90.35 % (28 d) Detected in water. Experimental result, Supporting study Heptane 70 % Detected in water. Experimental result, Key study Cyclohexane, methyl- > 0 % (28 d) Detected in water. Experimental result, Weight of Evidence study > 0 % (28 d) Detected in water. Experimental result, Weight of Evidence study Methanol 97 % Detected in water. Experimental result, Key study BOD/COD Ratio Product: No data available. Bioaccumulative potential Bioconcentration Factor (BCF) Product: No data available. Specified substance(s): 2-Propanone Haddock, adult, Bioconcentration Factor (BCF): 0.69 Aquatic sediment Experimental result, Not specified Naphtha (petroleum), hydrotreated light Bioconcentration Factor (BCF): 10 - 2,500 Aquatic sediment Estimated by calculation, Key study Heptane Bioconcentration Factor (BCF): 552 Aquatic sediment Estimated by calculation, Key study Cyclohexane, methyl- Cyprinus carpio, Bioconcentration Factor (BCF): > 95 - < 321 Aquatic sediment Experimental result, Key study Methanol Leuciscus idus, Bioconcentration Factor (BCF): < 10 Aquatic sediment Experimental result, Supporting study Version: 1.0 Revision Date: 10/23/2019 SDS_US - RE1000040592 16/21 Partition Coefficient n-octanol / water (log Kow) Product: No data available. Specified substance(s): Naphtha (petroleum), hydrotreated light Log Kow: > 2.4 - < 5.7 23 ?C Yes Experimental result, Key study Log Kow: 2.2 - 5.2 23 ?C Yes Experimental result, Key study Log Kow: 2.2 - 6.1 23 ?C Yes Experimental result, Key study Mobility in soil: No data available. Known or predicted distribution to environmental compartments 2-Propanone No data available. Petrolatum No data available. Distillates (petroleum), hydrotreated light No data available. Acetic acid, methyl ester No data available. Naphtha (petroleum), hydrotreated light No data available. Carbon dioxide No data available. Heptane No data available. Cyclohexane, methyl- No data available. Methanol No data available. Other adverse effects: Harmful to aquatic organisms. 13. Disposal considerations Disposal instructions: Discharge, treatment, or disposal may be subject to national, state, or local laws. Contaminated Packaging: No data available. 14. Transport information DOT UN Number: UN 1950 UN Proper Shipping Name: Aerosols, flammable Transport Hazard Class(es) Class: 2.1 Label(s): ? Packing Group: II Marine Pollutant: No Environmental Hazards: No Marine Pollutant No Version: 1.0 Revision Date: 10/23/2019 SDS_US - RE1000040592 17/21 Special precautions for user: Not regulated. IMDG UN Number: UN 1950 UN Proper Shipping Name: Aerosols, flammable Transport Hazard Class(es) Class: 2 Label(s): ? EmS No.: Packing Group: ? Environmental Hazards: No Marine Pollutant No Special precautions for user: Not regulated. IATA UN Number: UN 1950 Proper Shipping Name: Aerosols, flammable Transport Hazard Class(es): Class: 2.1 Label(s): ? Packing Group: ? Environmental Hazards: No Marine Pollutant No Special precautions for user: Not regulated. 15. Regulatory information US Federal Regulations Restrictions on use: Not known. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Chemical Identity OSHA hazard(s) Benzene Flammability Cancer Aspiration Eye Blood Skin respiratory tract irritation Central nervous system Version: 1.0 Revision Date: 10/23/2019 SDS_US - RE1000040592 18/21 CERCLA Hazardous Substance List (40 CFR 302.4): Chemical Identity Reportable quantity 2-Propanone lbs. 5000 Acetic acid, methyl ester lbs. 100 Heptane lbs. 100 Cyclohexane, methyl- lbs. 100 Methanol lbs. 5000 Benzene, methyl- lbs. 1000 Hexane lbs. 5000 Cyclohexane lbs. 1000 Benzene, ethyl- lbs. 1000 Benzene lbs. 10 Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Fire Hazard Immediate (Acute) Health Hazards Delayed (Chronic) Health Hazard Flammable aerosol Serious Eye Damage/Eye Irritation Specific Target Organ Toxicity - Single Exposure Specific Target Organ Toxicity - Repeated Exposure Aspiration Hazard SARA 302 Extremely Hazardous Substance Chemical Identity Reportable quantity Threshold Planning Quantity 2-Propanone Distillates (petroleum), hydrotreated light Acetic acid, methyl ester Hexane SARA 304 Emergency Release Notification Chemical Identity Reportable quantity 2-Propanone lbs. 5000 Distillates (petroleum), hydrotreated light Acetic acid, methyl ester lbs. 100 Heptane lbs. 100 Cyclohexane, methyl- lbs. 100 Methanol lbs. 5000 Benzene, methyl- lbs. 1000 Hexane lbs. 5000 Cyclohexane lbs. 1000 Benzene, ethyl- lbs. 1000 Benzene lbs. 10 Version: 1.0 Revision Date: 10/23/2019 SDS_US - RE1000040592 19/21 SARA 311/312 Hazardous Chemical Chemical Identity Threshold Planning Quantity 2-Propanone 10000 lbs Petrolatum 10000 lbs Distillates (petroleum), hydrotreated light 10000 lbs Acetic acid, methyl ester 10000 lbs Naphtha (petroleum), hydrotreated light 10000 lbs Carbon dioxide 10000 lbs Heptane 10000 lbs Cyclohexane, methyl- 10000 lbs Methanol 10000 lbs Benzene, methyl- 10000 lbs Hexane 10000 lbs Cyclohexane 10000 lbs Benzene, ethyl- 10000 lbs Benzene 10000 lbs SARA 313 (TRI Reporting) None present or none present in regulated quantities. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3) US State Regulations US. California Proposition 65 This product contains chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm. Methanol Developmental toxin. 03 2012 Benzene, methyl- Developmental toxin. 03 2008 Hexane Male reproductive toxin. 12 2017 Benzene, ethyl- Carcinogenic. 05 2011 Benzene Developmental toxin. 03 2008 Benzene Carcinogenic. 05 2011 Benzene Male reproductive toxin. 03 2008 US. New Jersey Worker and Community Right-to-Know Act Chemical Identity 2-Propanone Petrolatum Distillates (petroleum), hydrotreated light Acetic acid, methyl ester Naphtha (petroleum), hydrotreated light Carbon dioxide Heptane US. Massachusetts RTK - Substance List No ingredient regulated by MA Right-to-Know Law present. Version: 1.0 Revision Date: 10/23/2019 SDS_US - RE1000040592 20/21 US. Pennsylvania RTK - Hazardous Substances Chemical Identity 2-Propanone Petrolatum Distillates (petroleum), hydrotreated light Acetic acid, methyl ester Naphtha (petroleum), hydrotreated light Carbon dioxide Heptane US. Rhode Island RTK No ingredient regulated by RI Right-to-Know Law present. International regulations Montreal protocol 2-Propanone Distillates (petroleum), hydrotreated light Acetic acid, methyl ester Stockholm convention 2-Propanone - - Distillates (petroleum), hydrotreated light - - Acetic acid, methyl ester - - Rotterdam convention 2-Propanone - - Distillates (petroleum), hydrotreated light - - Acetic acid, methyl ester - - Kyoto protocol Version: 1.0 Revision Date: 10/23/2019 SDS_US - RE1000040592 21/21 Inventory Status: Australia AICS: On or in compliance with the inventory Canada DSL Inventory List: On or in compliance with the inventory EINECS, ELINCS or NLP: Not in compliance with the inventory. Japan (ENCS) List: Not in compliance with the inventory. China Inv. Existing Chemical Substances: Not in compliance with the inventory. Korea Existing Chemicals Inv. (KECI): Not in compliance with the inventory. Canada NDSL Inventory: Not in compliance with the inventory. Philippines PICCS: On or in compliance with the inventory US TSCA Inventory: On or in compliance with the inventory New Zealand Inventory of Chemicals: On or in compliance with the inventory Japan ISHL Listing: Not in compliance with the inventory. Japan Pharmacopoeia Listing: Not in compliance with the inventory. Mexico INSQ: Not in compliance with the inventory. Ontario Inventory: Not in compliance with the inventory. Taiwan Chemical Substance Inventory: On or in compliance with the inventory 16.Other information, including date of preparation or last revision Issue Date: 10/23/2019 Revision Information: No data available. Version #: 1.0 Further Information: No data available. Disclaimer: This information is provided without warranty. The information is believed to be correct. This information should be used to make an independent determination of the methods to safeguard workers and the environment.