FVP Instant Hand Cleaner 16 oz Spray Safety Data Sheet Issue Date: 23-Mar-2020 Revision Date: 24-Mar-2020 Version 1 _____________________________________________________________________________________________ Page 1 / 8 1. IDENTIFICATION Product identifier Product Name Other means of identification SDS # UN/ID No Instant Hand Cleaner 16 oz. Spray SPLASH-030 UN1170 Recommended use of the chemical and restrictions on use Recommended Use Hand cleanser. Details of the supplier of the safety data sheet Manufacturer Address FVP 1380 Corporate Center Curve, Suite 200 Eagan, MN 55121 Phone: 866-387-3343 Emergency telephone number Emergency Telephone INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America) 2. HAZARDS IDENTIFICATION Appearance Clear, water-white liquid Physical state Liquid Odor Lemon Classification Serious eye damage/eye irritation Category 2 Flammable liquids Category 2 Signal Word Danger Hazard statements Causes serious eye irritation Highly flammable liquid and vapor Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear eye/face protection Keep away from heat/sparks/open flames/hot surfaces. ? No smoking Keep container tightly closed SPLASH-030 - Sprayable Waterless Hand Cleaner Revision Date: 24-Mar-2020 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 2 / 8 Ground/bond container and receiving equipment Use explosion-proof equipment Use only non-sparking tools Take precautionary measures against static discharge Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention In case of fire: Use CO2, dry chemical, or foam for extinction Precautionary Statements - Storage Store in a well-ventilated place. Keep cool Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical name CAS No Weight-% Ethyl Alcohol 64-17-5 >60 Proprietary humectant Proprietary <1 Proprietary fragrance Proprietary <0.1 Proprietary fragrance Proprietary <0.1 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret. Any chemicals not listed in section 3 are not hazardous or are below reportable limits.** 4. FIRST AID MEASURES Description of first aid measures Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If eye irritation persists: Get medical advice/attention. Skin Contact None under normal use conditions. Inhalation None under normal use conditions. Ingestion Give large quantities of water. Do NOT induce vomiting. Get medical attention. Most important symptoms and effects, both acute and delayed Symptoms Can cause eye irritation. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Water. Foam. Carbon dioxide (CO2). Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Flammable. SPLASH-030 - Sprayable Waterless Hand Cleaner Revision Date: 24-Mar-2020 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 3 / 8 Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. Environmental precautions Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Clean-Up Flood area with water and then mop up. Dispose of in accordance with federal, state and local regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Wash face, hands and any exposed skin thoroughly after handling. Wear eye/face protection. Do not destroy or deface the label. Keep away from heat/sparks/open flames/hot surfaces. ? No smoking. Use spark-proof tools and explosion-proof equipment. Ground/bond container and receiving equipment. Take precautionary measures against static discharges. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Store containers upright. Incompatible Materials None known based on information supplied. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical name ACGIH TLV OSHA PEL NIOSH IDLH Ethyl Alcohol 64-17-5 STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3 Proprietary humectant - TWA: 15 mg/m3 mist, total particulate TWA: 5 mg/m3 mist, respirable fraction (vacated) TWA: 10 mg/m3 mist, total particulate (vacated) TWA: 5 mg/m3 mist, respirable fraction - Proprietary fragrance TWA: 100 ppm TWA: 100 ppm TWA: 300 mg/m3 (vacated) TWA: 100 ppm (vacated) TWA: 300 mg/m3 (vacated) STEL: 150 ppm (vacated) STEL: 450 mg/m3 IDLH: 1600 ppm TWA: 100 ppm TWA: 300 mg/m3 STEL: 150 ppm STEL: 450 mg/m3 Proprietary fragrance TWA: 5 ppm inhalable fraction and vapor S* - - SPLASH-030 - Sprayable Waterless Hand Cleaner Revision Date: 24-Mar-2020 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 4 / 8 Appropriate engineering controls Engineering Controls None under normal use conditions. Individual protection measures, such as personal protective equipment Eye/Face Protection Refer to 29 CFR 1910.133 for eye and face protection regulations. Skin and Body Protection No protective equipment is needed under normal use conditions. Respiratory Protection No protective equipment is needed under normal use conditions. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Clear, water-white liquid Odor Lemon Color Clear, water-white Odor Threshold Not determined Property Values Remarks ? Method pH Not determined Melting point / freezing point Not available Boiling point / boiling range Not determined Flash point 22?C / 72?F Evaporation Rate Not determined Flammability (Solid, Gas) n/a-liquid Flammability Limit in Air Upper flammability or explosive limits Not determined Lower flammability or explosive limits Not determined Vapor Pressure Not available Vapor Density Not determined Relative Density 0.8935 @ 60?F (ASTM D 1298) Water Solubility Completely soluble Solubility in other solvents Not determined Partition Coefficient Not determined Autoignition temperature Not determined Decomposition temperature Not determined Kinematic viscosity Not determined Dynamic Viscosity Not determined Explosive Properties Not determined Oxidizing Properties Not determined 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions SPLASH-030 - Sprayable Waterless Hand Cleaner Revision Date: 24-Mar-2020 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 5 / 8 None under normal processing. Conditions to Avoid Heat, flames and sparks. Incompatible materials None known based on information supplied. Hazardous decomposition products None known based on information supplied. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact Causes serious eye irritation. Skin Contact Not expected to be a skin irritant during prescribed use. Inhalation Under normal conditions of intended use, this material is not expected to be an inhalation hazard. Ingestion Do not taste or swallow. Component Information Chemical name Oral LD50 Dermal LD50 Inhalation LC50 Ethyl Alcohol 64-17-5 = 7060 mg/kg ( Rat ) - = 124.7 mg/L ( Rat ) 4 h Proprietary humectant = 12600 mg/kg ( Rat ) > 10 g/kg ( Rabbit ) > 570 mg/m3 ( Rat ) 1 h Proprietary fragrance = 2200 mg/kg ( Rat ) > 2 g/kg ( Rabbit ) > 10000 ppm ( Rat ) 4 h Proprietary fragrance = 4960 mg/kg ( Rat ) = 2250 mg/kg ( Rabbit ) - Symptoms related to the physical, chemical and toxicological characteristics Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity Ethanol has been shown to be carcinogenic in long-term studies only when consumed as an alcoholic beverage. Chemical name ACGIH IARC NTP OSHA Ethyl Alcohol 64-17-5 A3 Group 1 Known X Legend ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Numerical measures of toxicity The following values are calculated based on chapter 3.1 of the GHS document . Oral LD50 10,631.00 mg/kg SPLASH-030 - Sprayable Waterless Hand Cleaner Revision Date: 24-Mar-2020 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 6 / 8 ATEmix (inhalation-dust/mist) 191.80 mg/L ATEmix (inhalation-vapor) 191.80 mg/L 12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Chemical name Algae/aquatic plants Fish Crustacea Ethyl Alcohol 64-17-5 13400 - 15100: 96 h Pimephales promelas mg/L LC50 flow-through 12.0 - 16.0: 96 h Oncorhynchus mykiss mL/L LC50 static 100: 96 h Pimephales promelas mg/L LC50 static 10800: 24 h Daphnia magna mg/L EC50 2: 48 h Daphnia magna mg/L EC50 Static 9268 - 14221: 48 h Daphnia magna mg/L LC50 Proprietary humectant 51 - 57: 96 h Oncorhynchus mykiss mL/L LC50 static 500: 24 h Daphnia magna mg/L EC50 Proprietary fragrance 1000: 72 h Desmodesmus subspicatus mg/L EC50 6130 - 6700: 96 h Pimephales promelas mg/L LC50 flow-through 4607 - 6577: 48 h Daphnia magna mg/L EC50 Static 933: 48 h Daphnia magna mg/L EC50 Proprietary fragrance 19: 96 h Desmodesmus subspicatus mg/L EC50 16: 72 h Desmodesmus subspicatus mg/L EC50 4.6 - 10: 96 h Leuciscus idus mg/L LC50 static 7: 48 h Daphnia magna mg/L EC50 Persistence/Degradability Not determined. Bioaccumulation There is no data for this product. Mobility Chemical name Partition coefficient Ethyl Alcohol 64-17-5 -0.32 Proprietary humectant -1.76 Proprietary fragrance 0.35 Proprietary fragrance 2.76 Other Adverse Effects Not determined 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. California Hazardous Waste Status Chemical name California Hazardous Waste Status Ethyl Alcohol 64-17-5 Toxic Ignitable SPLASH-030 - Sprayable Waterless Hand Cleaner Revision Date: 24-Mar-2020 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 7 / 8 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT This product is packaged in 4oz., 16oz. 32oz., and 1-gallon bottles. By ground transportation, the limited quantity exception may be used for the 4oz., 16oz., and 32oz. bottles. UN/ID No UN1170 Proper Shipping Name Ethanol solution Hazard class 3 Packing Group II IATA UN number UN1170 Proper Shipping Name Ethanol solution Transport hazard class(es) 3 Packing Group II IMDG UN number UN1170 Proper Shipping Name Ethanol solution Transport hazard class(es) 3 Packing Group II 15. REGULATORY INFORMATION International Inventories Chemical name TSCA TSCA Inventory Status DSL/NDSL EINECS/ELI NCS ENCS IECSC KECL PICCS AICS Ethyl Alcohol X ACTIVE X X X X X X X Proprietary humectant X ACTIVE X X X X X X X Proprietary fragrance X ACTIVE X X X X X X X Proprietary fragrance X ACTIVE X X X X X X X Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SPLASH-030 - Sprayable Waterless Hand Cleaner Revision Date: 24-Mar-2020 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 8 / 8 Chemical name CAS No Weight-% SARA 313 - Threshold Values % Proprietary fragrance - <0.1 1.0 US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals. Chemical name California Proposition 65 Ethyl Alcohol - 64-17-5 Carcinogen Developmental U.S. State Right-to-Know Regulations Chemical name New Jersey Massachusetts Pennsylvania Ethyl Alcohol 64-17-5 X X X Proprietary humectant X X X Proprietary fragrance X X X 16. OTHER INFORMATION NFPA Health Hazards Not determined Flammability Not determined Instability Not determined Special Hazards Not determined HMIS Health Hazards 0 Flammability 3 Physical hazards 0 Personal Protection Not determined Issue Date: 23-Mar-2020 Revision Date: 24-Mar-2020 Revision Note: New product Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet