Mystik Bar and Chain Lubricant Lubricating oil Technical Contact: (800) 248-4684 Medical Emergency: (832) 486-4700 CHEMTREC Emergency: (800) 424-9300 (United States Only) SAFETY DATA SHEET GHS product identifier Synonyms Emergency telephone number (with hours of operation) Section 1. Identification : : : Supplier's details : CITGO Petroleum Corporation P.O. Box 4689 Houston, TX 77210 Mystik Bar and Chain Lubricant 663605002:Code This email address is being protected from spambots. You need JavaScript enabled to view it. Section 2. Hazards identification Not classified.Classification of the substance or mixture : Signal word : No signal word. Hazard statements : No known significant effects or critical hazards. Precautionary statements Prevention : Not applicable. Response : Not applicable. Storage : Store in a dry place and/or in closed container. Store in accordance with all local, regional, national and international regulations. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. GHS label elements General : Avoid contact with eyes, skin and clothing. Thoroughly wash exposed areas and clothing with soap and water. IF IN EYES: Rinse cautiously with water for several minutes. IF SWALLOWED: Do not induce vomiting. If you feel unwell, seek medical attention and show the label when possible. Keep out of reach of children. OSHA/HCS status : While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available for employees and other users of this product. Hazards not otherwise classified : None known. Section 3. Composition/information on ingredients Distillates, petroleum, hydrotreated, light naphthenic ?50 - ?75 64742-53-6 Ingredient name CAS number% Other means of identification : Lubricating oil CAS number : Not applicable. Substance/mixture CAS number/other identifiers : Mixture Date of issue/Date of revision : 9/27/2019 Date of previous issue : 4/26/2018 Version : 3 1/10 Mystik Bar and Chain Lubricant Section 3. Composition/information on ingredients There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to process variation. * = Various ** = Mixture *** = Proprietary Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Description of necessary first aid measures Specific treatments : Treat symptomatically and supportively. Most important symptoms/effects, acute and delayed Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards.:Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : No specific data. Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide In a fire or if heated, a pressure increase will occur and the container may burst. Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Date of issue/Date of revision : 9/27/2019 Date of previous issue : 4/26/2018 Version : 3 2/10 Mystik Bar and Chain Lubricant Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : Protective measures Put on appropriate personal protective equipment (see Section 8).: Precautions for safe handling Bulk Storage Conditions: Maintain all storage tanks in accordance with applicable regulations. Use necessary controls to monitor tank inventories. Inspect all storage tanks on a periodic basis. Test tanks and associated piping for tightness. Maintain the automatic leak detection devices to assure proper working condition. Date of issue/Date of revision : 9/27/2019 Date of previous issue : 4/26/2018 Version : 3 3/10 Mystik Bar and Chain Lubricant Section 8. Exposure controls/personal protection Hand protection Avoid inhalation of gases, vapors, mists or dusts. Use a properly fitted, air-purifying or supplied-air respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Safety glasses equipped with side shields are recommended as minimum protection in industrial settings. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If inhalation hazards exist, a full-face respirator may be required instead. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, vapor controls, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Control parameters Individual protection measures Occupational exposure limits Skin protection Other skin protection : Avoid skin contact with liquid. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Leather boots are not protective for liquid contact. Distillates, petroleum, hydrotreated, light naphthenic ACGIH TLV (United States, 3/2018). TWA: 5 mg/m? 8 hours. Form: Inhalable fraction NIOSH REL (United States, 10/2016). TWA: 5 mg/m? 10 hours. Form: Mist STEL: 10 mg/m? 15 minutes. Form: Mist OSHA PEL (United States, 5/2018). TWA: 5 mg/m? 8 hours. Section 9. Physical and chemical properties Physical state Liquid. Petroleum.Odor pH Dark.Color Evaporation rate <1 (n-butyl acetate. = 1) Flash point Closed cup: >177?C (>350.6?F) [Pensky-Martens.] Not available. : : : : : : Appearance Boiling point : Not available. Date of issue/Date of revision : 9/27/2019 Date of previous issue : 4/26/2018 Version : 3 4/10 Mystik Bar and Chain Lubricant Section 9. Physical and chemical properties Vapor pressure Relative density Vapor density Solubility 0.89 >1 [Air = 1] <0.013 kPa (<0.1 mm Hg) [room temperature] Insoluble in the following materials: cold water. Viscosity Kinematic (room temperature): Not applicable. Kinematic (40?C (104?F)): 0.68 cm2/s (68 cSt) : : : : : Lower and upper explosive (flammable) limits : Lower: 1% Upper: 7% Density lbs/gal Gravity, ?API : : Estimated 27 @ 60 F Estimated 7.42 lbs/gal Viscosity SUS : Estimated 315 SUS @104 F Flow time (ISO 2431) : Not available. Density gm/cm3 : Not available. Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : Not expected to be Explosive, Self-Reactive, Self-Heating, or an Organic Peroxide under US GHS Definition(s). Section 11. Toxicological information Acute toxicity Distillates, petroleum, hydrotreated, light naphthenic LD50 Oral Rat >5000 mg/kg - Product/ingredient name Result Species Dose Exposure Irritation/Corrosion Information on toxicological effects Conclusion/Summary : Distillates (petroleum), hydrotreated light naphthenic: INHALATION (LC50) Acute: 9.6 mg/L (Female Rat). INHALATION (LC50) Acute: 10.5 mg/L (Male Rat). DRAIZE EYE Acute: Non-irritating (Rabbit). DRAIZE DERMAL Acute: Mild skin irritant (Rabbit). BUEHLER DERMAL Acute: Non-sensitizing (Guinea Pig). 28-Day DERMAL Sub-Chronic: Mild to moderate skin irritant (Rabbit & Rat). A life-time dermal application of severely hydrotreated light naphthenic oils produced skin masses on mice which correlated with the skin irritation response levels of the test animals. Additional studies attribute these masses to a weak promotional activity. These studies indicate that light naphthenic oils are not mutagenic, tumor initiators nor complete chemical carcinogens. These materials have not been determined to be carcinogenic by IARC, NTP or OSHA. Date of issue/Date of revision : 9/27/2019 Date of previous issue : 4/26/2018 Version : 3 5/10 Mystik Bar and Chain Lubricant Section 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Distillates, petroleum, hydrotreated, light naphthenic Skin - Moderate irritant Rabbit - 24 hours 0.5 Mililiters - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Information on the likely routes of exposure Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards.:Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : No specific data. Delayed and immediate effects and also chronic effects from short and long term exposure Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Not available. Not available. Aspiration hazard Name Result Distillates, petroleum, hydrotreated, light naphthenic ASPIRATION HAZARD - Category 1 : Routes of entry anticipated: Dermal. Potential acute health effects Conclusion/Summary : No additional information. No additional information. Conclusion/Summary : No additional information. Conclusion/Summary : Conclusion/Summary : No additional information. Skin Respiratory : : No additional information. No additional information. Skin Eyes Respiratory : : : No additional information. No additional information. No additional information. Date of issue/Date of revision : 9/27/2019 Date of previous issue : 4/26/2018 Version : 3 6/10 Mystik Bar and Chain Lubricant Section 11. Toxicological information Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Not available. No known significant effects or critical hazards.General : No known significant effects or critical hazards.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Potential chronic health effects Section 12. Ecological information Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Not available. Toxicity Not available. Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Conclusion/Summary : Not available. Conclusion/Summary : Not available. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Date of issue/Date of revision : 9/27/2019 Date of previous issue : 4/26/2018 Version : 3 7/10 Mystik Bar and Chain Lubricant Section 14. Transport information Special precautions for user Transport in bulk according to Annex II of MARPOL and the IBC Code Transport within user?s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. : - - - - Not regulated. - - Not regulated. DOT Classification IATA UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards No. No. IMDG Not regulated. - - - No. Section 15. Regulatory information U.S. Federal regulations The following components are listed: PolymerMassachusetts : : New York : None of the components are listed. New Jersey : The following components are listed: Polymer Pennsylvania : The following components are listed: Polymer State regulations SARA 302/304 SARA 304 RQ : Not applicable. Composition/information on ingredients SARA 311/312 Classification : Not applicable. Clean Water Act (CWA) 307: naphthalene; ethylbenzene; toluene; benzene Clean Water Act (CWA) 311: naphthalene; ethylbenzene; toluene; benzene United States inventory (TSCA 8b): All components are listed or exempted. This material is classified as an oil under Section 311 of the Clean Water Act (CWA) and the Oil Pollution Act of 1990 (OPA). Discharges or spills which produce a visible sheen on waters of the United States, their adjoining shorelines, or into conduits leading to surface waters must be reported to the EPA's National Response Center at (800) 424-8802. California Prop. 65 Clear and Reasonable Warnings (2018) Distillates, petroleum, hydrotreated, light naphthenic ?50 - ?75 ASPIRATION HAZARD - Category 1 Name % Classification Composition/information on ingredients Date of issue/Date of revision : 9/27/2019 Date of previous issue : 4/26/2018 Version : 3 8/10 Mystik Bar and Chain Lubricant Section 15. Regulatory information International regulations Inventory list Australia : Not determined. Canada : All components are listed or exempted. China : Not determined. Europe : Not determined. Japan : Japan inventory (ENCS): Not determined. Japan inventory (ISHL): Not determined. Republic of Korea : Not determined. Malaysia : Not determined. New Zealand : Not determined. Philippines : Not determined. Taiwan : Not determined. Turkey : Not determined. United States : All components are listed or exempted. Thailand : Not determined. Viet Nam : Not determined. toluene trace No. Yes. - Yes. benzene trace Yes. Yes. Yes. Yes. ethylbenzene trace Yes. No. Yes. - naphthalene trace Yes. No. Yes. - Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level % WARNING: This product can expose you to Benzene, which is known to the State of California to cause cancer and birth defects or other reproductive harm. This product can expose you to chemicals including Ethylbenzene, Naphthalene, which are known to the State of California to cause cancer, and Toluene, which is known to the State of California to cause birth defects or other reproductive harm. For more information go to www.P65Warnings.ca. gov. Section 16. Other information 9/27/2019 History Date of printing : Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ?1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ?2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Procedure used to derive the classification Classification Justification Not classified. 0 1 1 National Fire Protection Association (U.S.A.) Health Special Instability/Reactivity Flammability Date of issue/Date of revision : 9/27/2019 Date of previous issue : 4/26/2018 Version : 3 9/10 Mystik Bar and Chain Lubricant Section 16. Other information Date of issue/Date of revision Version Notice to reader Date of previous issue : : : Indicates information that has changed from previously issued version. References : Not available. Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 9/27/2019 4/26/2018 3 THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED REGARDING ITS CORRECTNESS OR ACCURACY. SOME INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE SUBSTANCE ITSELF. THIS SDS WAS PREPARED AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A COMPONENT IN ANOTHER PRODUCT, THIS SDS INFORMATION MAY NOT BE APPLICABLE. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION OR PRODUCTS FOR THEIR PARTICULAR PURPOSE OR APPLICATION. THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND/OR DISPOSAL OF THE PRODUCT ARE BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR ANY LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT. Mystik is a registered trademark of CITGO Petroleum Corporation Date of issue/Date of revision : 9/27/2019 Date of previous issue : 4/26/2018 Version : 3 10/10