Control No. Date First May 16, 2008 Date Final January 1, 2021 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION A. PRODUCT NAME : Lead-acid Battery B. RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE : Lead-acid Batteries for automotive C. MANUFACTURER/SUPPLIER/DISTRIBUTOR INFORMATION MANUFACTURER : Sebang Global Battery CO.,Ltd. Sonjae-ro 287beon-gil, Gwangsan-Gu, Gwangju, KOREA TEL: +82-62-601-6128 FAX: +82-62-951-4126 2. HAZARDS IDENTIFICATION A. HAZARD CLASSIFICATION PHYSICAL HAZARDS : Not Classified. HEALTH HAZARDS : Acute toxicity Category 4 (inhalation) : Skin corrosion/irritation Category 1 : Serious eye damage/eye irritation Category 1 : Carcinogenicity Category 1B : Germ cell mutagenicity Category 2 : Specific target organ toxicity ? single exposure Category 1 : Specific target organ toxicity ? repeated exposure Category 1 ENVIRONMENTAL HAZARDS : Not Classified. B. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS PICTOGRAMS : SIGNAL WORD : DANGER. HAZARD STATEMENTS H332 H314 H318 H350 H341 H370 Harmful if inhaled. May cause cancer (inhalation). Specific target organ toxicity ? single exposure; Respiratory tract irritation Causes serious eye damage. Suspected of causing genetic defects. Causes severe skin burns and eye damage. Material Safety Data sheet (MSDS) 10??? ? 1??? Control No. Date First May 16, 2008 Date Final January 1, 2021 Material Safety Data sheet (MSDS) H372 PRECAUTIONARY STATEMENTS : [Prevention] P261 P271 P260 P264 P280 P201 P202 P281 P270 [Response] P304 + P340 P312 P301+P330+P331 P303 + P361 + P353 P363 P310 P321 P305 + P351 + P338 P308 + P313 P307+P311 P314 [Storage] P405 [Disposal] P501 C. NFPA/HMIS Rating : 3. COMPOSITION / INFORMATION ON INGREDIENTS Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Do not eat, drink or smoke when using this product. Immediately call a POISON CENTER or doctor/physician. IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Specific treatment (see ... on this label). Wash hands thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Use only outdoors or in a wellventilated area. Do not breathe dust/fume/gas/mist/vapours/spray. Causes damage to organs (Hematopoietic system, kidney, central nervous system, peripheral nervous system, cardiovascular system, immune system, respiratory). Wash contaminated clothing before reuse. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION (e.g. Dust explosion hazards) IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Health=3, Flammability=0, Instability=1 (0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Dispose of contents/container in accordance with local/regional/national regulations. Store locked up. Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF exposed or concerned: Get medical advice/attention. IF exposed: Call a POISON CENTER or doctor/physician. Get medical advice/attention if you feel unwell. 10??? ? 2??? Control No. Date First May 16, 2008 Date Final January 1, 2021 Material Safety Data sheet (MSDS) Content (%) 52 - 59 0.5 - 0.7 30 - 38 6 - 9 1 - 2 4. FIRST AID MEASURES A. EYE CONTACT : B. SKIN CONTACT : C. INHALATION : D. INGESTION : E. MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE OR DELAYED EYES : SKIN : INHALATION : INGESTION : F. INDICATION OF IMMEDIATE MEDICAL ATTENTION AND NOTES FOR PHYSICIAN * Lead may causes toxic to blood, kidneys, central nervous system (CNS). Repeated or prolonged exposure to lead can produce target organs damage. If a battery ruptures, move to fresh air in case of accidental inhalation of mist. If breathing has stopped, perform artificial respiration. If breathing is difficult, give oxygen. GET MEDICAL ATTENTION AS SOON AS POSSIBLE. If solutions of a battery chemicals have been swallowed and the person is conscious, give one glass of water. Vomiting may occur spontaneously, but Do NOT induce vomiting. Never give anything by mouth to an unconscious person. GET MEDICAL ATTENTION IMMEDIATELY. Antimony 7440-36-0 Sulfuric acid / Oil of vitriol 7664-93-9 Polypropylene / PP Resin 9003-07-0 Separator Not available If a battery ruptures, do not rub or scratch exposed eye. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. GET MEDICAL ATTENTION IMMEDIATELY. If a battery ruptures, do not rub or scratch exposed skin. If liquid get on the skin, immediately flush the contaminated skin with water for at least 15 minutes. If liquid penetrate through the clothing, immediately remove the clothing and shoes under a safety shower and continue to wash the skin for at least 15 minutes. GET MEDICAL ATTENTION IMMEDIATELY. Not a likely route of exposure. If a battery ruptures, direct contact with the liquid or exposure to vapors or mists may cause tearing, redness, swelling, corneal damage and irreversible eye damage. Splashes in the eyes will cause severe burns. * European Inventory of Existing Commercial Chemical Substances (EINECS). Not a likely route of exposure. Causes serious burns of the mouth or perforation of the esophagus or stomach. May be fatal if swallowed. Not a likely route of exposure. If a battery ruptures, may be harmful or fatal if inhaled in a confined area. May cause severe irritation and burns of the nose, throat and respiratory tract. Not a likely route of exposure. Direct contact with internal components of a battery can be severely irritating to the skin and may result in redness, swelling, burns and severe skin damage. Skin contact may aggravate an existing dermatitis condition. CAS No. or IDChemical name / Synonym Lead 7439-92-1 10??? ? 3??? Control No. Date First May 16, 2008 Date Final January 1, 2021 Material Safety Data sheet (MSDS) : 5. FIRE FIGHTING MEASURES A. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA : B. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL : C. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE FIGHTERS : D. FIRE AND EXPLOSION HAZARD : 6. ACCIDENTAL RELEASE MEASURES A. NECESSARY MEASURES AND PROTECTIVE GEAR TO PROTECT HUMANS : B. NECESSARY MEASURES TO PROTECT ENVIRONMENT : C. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP : 7. HANDLING AND STORAGE A. PRECAUTIONS FOR SAFE HANDLING : Not flammable. Battery may rupture due to pressure buildup when exposed to excessive heat and may be result in the release of corrosive materials. Protect from physical damage. SMALL SPILLS: Collect all released material in a plastic lined metal container. If necessary neutralize the residue with a dilute solution of sodium carbonate. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by building a dike. Absorb with dry earth, sand or other non-combustible material. Neutralize the residue with a dilute solution of sodium carbonate. Dispose of all contaminated materials in accordance with current local regulations. Notify authorities and appropriate federal, state, and local agencies. Prevent the product from spreading into the environment. Avoid direct discharge into drains. If a battery ruptures, avoid contact with skin, eyes and clothing. Do not touch spilled material. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Lead, lead compounds and sulfuric acid fume may be released during a fire involving the product. Use extinguishing media appropriate for surrounding fire. If a battery ruptures, use dry chemical, soda ash, lime, sand or carbon dioxide. Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition. 10??? ? 4??? Control No. Date First May 16, 2008 Date Final January 1, 2021 Material Safety Data sheet (MSDS) B. CONDITIONS FOR SAFE STORAGE (INCLUDING ANY INCOMPATIBILITIES) : 8. EXPOSURE CONTROLS/PERSONAL PROTECTION A. OCCUPATIONAL EXPOSURE LIMIT(S), BIOLOGICAL EXPOSURE STANDARD OSHA-PEL ACGIH-TLV B. : C. INDIVIDUAL PROTECTION MEASURES Respiratory protection : Eye protection : Hand protection : Body protection : 9. PHYSICAL AND CHEMICAL PROPERTIES A. APPEARANCE (PHYSICAL STATE, COLOUR etc.) : Off-white cloudy liquid with solid object. B. Odour : Characteristics. C. ODOR THRESHOLD : Not available. D. pH : pH < 1 (Sulfuric acid) E. MELTING POINT/FREEZING POINT : F. INITIAL BOILING POINT AND BOILING RANGE : G. FLASH POINT : Non-flammable. H. EVAPORATION RATE : Not available. I. FLAMMABILITY (SOLID, GAS) : Not applicable. J. UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS : Non-flammable. K. VAPOR PRESSURE : 0.05 mg/m3 (Lead), 1 mg/m3 (Sulfuric acid), 0.5 mg/m3 (Antimony) Use local exhaust ventilation if necessary to control airborne mist and vapor. TWA 0.05 mg/m3 (Lead), TWA 0.2 mg/m3 (Sulfuric acid) TWA 0.5 mg/m3(Antimony) APPROPRIATE ENGINEERING CONTROLS Use good work and personal hygiene practices to avoid exposure. Consider the provision in the work area of a safety shower and eyewash. Always wash thoroughly after handling chemicals. Not available. Not available. Wear safety glasses with side shields (or goggles). Not available. Avoid contact with eyes. Store in a cool, dry, ventilated area away from sources of heat, moisture, incompatibilities, and direct sunlight. Have emergency equipment (for fires, spills, leaks, etc.) readily available. If significant mists or aerosols are generated an approved respirator is recommended. If respiratory protection is required, institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection. Wear chemical resistant gloves. Gloves should be replaced immediately if signs of degradation are observed. 10??? ? 5??? Control No. Date First May 16, 2008 Date Final January 1, 2021 Material Safety Data sheet (MSDS) L. SOLUBILITY : Soluble in water. M. VAPOR DENSITY : N. SPECIFIC GRAVITY : O. PARTITION COEFFICIENT OF n-OCTANOL/WATER: Not available. P. AUTO-IGNITION TEMPERATURE : Not applicable. Q. DECOMPOSITION TEMPERATURE : Not available. R. VISCOSITY : S. MOLECULAR WEIGHT : Mixture. Note: These physical properties are typical values for this product. A. APPEARANCE (PHYSICAL STATE, COLOUR etc.) : Bluish white, silvery gray. B. Odour : None. C. ODOR THRESHOLD : Not available. D. pH : Not applicable. E. MELTING POINT/FREEZING POINT : F. INITIAL BOILING POINT AND BOILING RANGE : G. FLASH POINT : Non-flammable. H. EVAPORATION RATE : Not applicable. I. FLAMMABILITY (SOLID, GAS) : Not applicable. J. UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS : Non-flammable. K. VAPOR PRESSURE : L. SOLUBILITY : Insoluble in water. M. VAPOR DENSITY : N. SPECIFIC GRAVITY : O. PARTITION COEFFICIENT OF n-OCTANOL/WATER: Not applicable. P. AUTO-IGNITION TEMPERATURE : Not applicable. Q. DECOMPOSITION TEMPERATURE : Not applicable. R. VISCOSITY : S. MOLECULAR WEIGHT : 207.2 Note: These physical properties are typical values for Lead(Pb). 10. STABILITY AND REACTIVITY A. CHEMICAL STABILITY: B. POSSIBILITY OF HAZARDOUS REACTIONS : C. CONDITIONS TO AVOID (STATIC DISCHARGE, SHOCK, VIBRATION etc.): : Not available. Not available. Overcharging. Sources of ignition. Mechanical impact. Contact with incompatible chemicals. Stable at normal temperatures and storage conditions. Hazardous polymerization will not occur. Not available. 11.34 g/cm3 Not applicable. 327.5? 1740? (1013 hPa) 1.33 hPa (973?) Not applicable. 10??? ? 6??? Control No. Date First May 16, 2008 Date Final January 1, 2021 Material Safety Data sheet (MSDS) D. SUBSTANCES TO AVOID : If a battery ruptures, avoid contact with organic materials and alkaline materials. E. HAZARDOUS DECOMPOSITION PRODUCTS : 11. TOXICOLOGICAL INFORMATION A. Information on the likely routes of exposure Inhalation : Ingestion : Eye/Skin Eye : Skin : B. Delayed and immediate effects and also chronic effects from short and long term exposure Acute toxicity (possible route of exposure) : Oral (LD50) : Rat Skin (LD50) : Not available. Inhalation (LC50) : Rat Skin corrosion/irritation : cat 1 Serious eye damage/irritation : cat 1 Respiratory sensitization : Not available. Skin sensitization : Carcinogenicity : Germ cell mutagenicity : cat 2 Reproductive toxicity : STOST-single exposure : cat 1 : STOST-repeated exposure : cat 1 : Aspiration hazard : C. Numeric measure of toxicity (such as acute toxicity estimates) - ATEmix Oral (LD50) : Rat Lead, Lead compounds and sulfuric acid fumes may be released during a fire involving the product. Serious burns. ACGIH Group A2, IARC Group 1 (Mist containing sulfuric acid) * Note: Sulfuric acid mist is not expected under normal use of the product. ACGIH Group A3, IARC Group 2B (Lead), IARC Group 3 (Polypropylene) Not available. Tearing, redness, swelling, corneal damage, irreversible eye damage and severe burns. Redness, swelling, burns and severe skin damage. cat 1B 0.347 mg/L(4hr) (dust//mist) > 5,000 mg/kg Not available. Corrosive. severe irritation and burns. Respiratory. 2140 mg/kg (Sulfuric acid), 7000 mg/kg (Antimony) Hematopoietic system, kidney, central nervous system, peripheral nervous system, cardiovascular system, immune system, respiratory. Not available. 10??? ? 7??? Control No. Date First May 16, 2008 Date Final January 1, 2021 Material Safety Data sheet (MSDS) Skin (LD50) : Not available. Inhalation (LC50) : Rat 12. ECOLOGICAL INFORMATION A. Aquatic/terrestrial ecology toxicity Fish (LC50) : Not available. Daphnia (EC50) : Not available. Algae (EC50) : B. Persistence and degradability Persistence : Degradability : C. Bioaccumulative potential : D. Mobility in soil : E. Other hazardous effects : Not available. 13. DISPOSAL CONSIDERATIONS A. DISPOSAL METHODS : B. : 14. TRANSPORT INFORMATION A. UN NUMBER : UN 2794 B. UN PROPER SHIPPING NAME C. TRANSPORT HAZARD CLASS(ES) : 8 D. PACKING GROUP (IF APPLICABLE) : None. E. MARINE POLLUTANT SUBSTANCES (APPLICABLE/NOT APPLICABLE) BATTERIES, WET, FILLED WITH ACID, electric storage. Not available. 2.51 mg/L(4hr) (dust//mist) PRECAUTIONS (INCLUDING DISPOSAL OF CONTAMINATED CONTAINER OR PACKAGE) Since emptied containers retain product residue, follow label warnings even after container is emptied. Not available. Not available. Not available. Not available. The information in this section is for reference only and should not take the place of a shipping paper (BL). Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of transportation. Dispose of in accordance with local, state, and federal regulations. Hazardous wastes must be transported by a licensed hazardous waste transporter and disposed of or treated in a properly licensed hazardous waste treatment, storage, disposal or recycling facility. Consult local, state, and federal regulations for specific requirements. 10??? ? 8??? Control No. Date First May 16, 2008 Date Final January 1, 2021 Material Safety Data sheet (MSDS) : Not Applicable. F. SPECIAL PRECAUTIONS FOR USER : Not available. 15. REGULATORY INFORMATION ? INVENTORIES EINECS/EU : TSCA/US : ENCS/JAPAN : AICS/AUSTRALIA : DSL/CANADA : IECSC/CHINA : PICCS/PHILIPPINES : KECI/S.KOREA : ? International Environmental Agreement PIC : Not listed. POPs : Not listed. Ozone depletion : Not listed. EU. Directive 67/548/EEC on the classification, packaging, and labelling of dangerous substances, Annex I Classification : Risk Phrases : Safety Phrases : ? U.S. Federal, Heanth and Environment) and U.S. Federal, Right-To-Know CERCLA Section 103 (40 CFR 302.4) : EPCRA (SARA Title III) Section 302 (EHS -TPQ) : EPCRA (SARA Title III) Section 304 (EHS - Reporting Quantities) : EPCRA (SARA Title III) Section 313 - Toxic chemical release reporting : OSHA Specifically Regulated Substances (29 CFR 1910.1001-.1052) : ? 10lb (4.535 kg) (Lead), 1000 lb (453.599 kg) (Sulfuric acid) 1000 lb (453.599 kg) (Sulfuric acid) 1000 lb (453.599 kg) (Sulfuric acid) WHMIS Ingredient Disclosure List : Regulated. Sulfuric acid (acid aerosols including mists, vapors, gas, fog, and other airborne forms of any particle size) Not applicable. NOTE: The regulatory information given above only indicates the principal regulations specifically applicable to the product described in the Safety Data Sheet. The user's attention is drawn to the possible existence of additional provisions which complete these regulations. Refer to all applicable national, international and local regulations or provisions. Listed (EINECS No. 231-100-4(Lead), 231-639-5(Sulfuric acid)) Listed. Listed (ENCS No. 1-527(Lead), 1-430(Sulfuric acid)) Listed. Listed. Listed. Listed. CANADA REGULATORY INFORMATION S1/2, S26, S30, S45 R35 C; R35 Listed (KE-21887(Lead), KE-32570(Sulfuric acid)) 10??? ? 9??? Control No. Date First May 16, 2008 Date Final January 1, 2021 Material Safety Data sheet (MSDS) 16. OTHER INFORMATION A. SOURCE OF DATA : B. THE DATE OF PREPARATION OF THE MSDS : May 16, 2008 C. THE DATE OF PREPARATION OF THE LATEST REVISION : January 1, 2021 D. OTHER INFORMATION: EC-ECB, International Uniform Chemical Information Database (IUCLID) Support on preparation of the GHS-MSDS: RGB Chemicals Co.,Ltd. +82-2-597-0645 National Institute of Technology and Evaluatio -NITE (Japan). The above information is believed to be correct but does not propose to be all inclusive and shall be used only as a guide. Sebang Global Battery CO.,Ltd. shall not be held liable for any damage resulting from handling or from contact with the above product. Each individual should make a determination as to the suitability of the information for their particular purpose(s). Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. NFPA 704 Standard System for the Identification of the Hazards of Materials for Emergency Response. 3E Company/Ariel WebInsight DB. International Chemical Safety Cards(ICSC)(http://www.nihs.go.jp/ICSC) Hazardous Substances Data Bank (HSDB) Registry of Toxic Effects of Chemical Substances (RTECS) Guideline for Globally Harmonized System of Classification and Labelling of Chemicals (GHS). 10??? ? 10???