3M? Foaming Engine Degreaser, 08899 04/09/20 __________________________________________________________________________________________ Page 1 of 17 Safety Data Sheet Copyright,2020, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 25-9904-1 Version Number: 5.03 Issue Date: 04/09/20 Supercedes Date: 09/04/18 SECTION 1: Identification 1.1. Product identifier 3M? Foaming Engine Degreaser, 08899 Product Identification Numbers ID Number UPC ID Number UPC 60-4550-4625-4 60-4550-5415-9 60-4550-6573-4 000511350088999 7000028274, 7100039391 1.2. Recommended use and restrictions on use Recommended use Automotive 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Aerosol: Category 1. Gas Under Pressure: Liquefied gas. Serious Eye Damage/Irritation: Category 2A. Skin Corrosion/Irritation: Category 2. Aspiration Hazard: Category 1. Carcinogenicity: Category 2. 3M? Foaming Engine Degreaser, 08899 04/09/20 __________________________________________________________________________________________ Page 2 of 17 Specific Target Organ Toxicity (single exposure): Category 1. Specific Target Organ Toxicity (single exposure): Category 3. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word Danger Symbols Flame | Gas cylinder | Exclamation mark | Health Hazard | Pictograms Hazard Statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. Causes skin irritation. May be fatal if swallowed and enters airways. May cause drowsiness or dizziness. Suspected of causing cancer. Causes damage to organs: blood or blood-forming organs | cardiovascular system | Causes damage to organs through prolonged or repeated exposure: blood or blood-forming organs | respiratory system | May cause damage to organs through prolonged or repeated exposure: sensory organs | Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. 3M? Foaming Engine Degreaser, 08899 04/09/20 __________________________________________________________________________________________ Page 3 of 17 Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Do NOT induce vomiting. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF exposed or concerned: Get medical advice/attention. Specific treatment (see Notes to Physician on this label). Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. 2% of the mixture consists of ingredients of unknown acute dermal toxicity. 15% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Water 7732-18-5 40 - 70 Trade Secret * 2-Butoxyethanol 111-76-2 7 - 13 Trade Secret * Heavy Aromatic Solvent Naphtha 64742-94-5 5 - 10 Trade Secret * Fatty Acids Trade Secret* 3 - 7 Trade Secret * 1,2,4-Trimethylbenzene 95-63-6 1 - 5 Trade Secret * Butane 106-97-8 1 - 5 Trade Secret * Ethoxylated Lauryl Alcohol 9002-92-0 1 - 5 Trade Secret * Light Aromatic Solvent Naphtha 64742-95-6 1 - 5 Trade Secret * Propane 74-98-6 1 - 5 Trade Secret * Ammonium Hydroxide 1336-21-6 < 3 Trade Secret * Glycol Ethers 25498-49-1 0.5 - 1.5 Trade Secret * Mesitylene 108-67-8 0.5 - 1.5 Trade Secret * Naphthalene 91-20-3 0.5 - 1.5 Trade Secret * Cumene 98-82-8 <= 0.5 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: 3M? Foaming Engine Degreaser, 08899 04/09/20 __________________________________________________________________________________________ Page 4 of 17 Remove person to fresh air. Get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Do not induce vomiting. Get immediate medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material 3M? Foaming Engine Degreaser, 08899 04/09/20 __________________________________________________________________________________________ Page 5 of 17 as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Natural gas 106-97-8 ACGIH Limit value not established: simple asphyxiant Butane 106-97-8 ACGIH STEL:1000 ppm Benzene, trimethyl- 108-67-8 ACGIH TWA:25 ppm 2-Butoxyethanol 111-76-2 OSHA TWA:240 mg/m3(50 ppm) SKIN 2-Butoxyethanol 111-76-2 ACGIH TWA:20 ppm A3: Confirmed animal carcin. AMMONIA RELEASED FROM AMMONIUM HYDROXIDE/AQUEOUS AMMONIA SOLUTIONS 1336-21-6 ACGIH TWA:25 ppm;STEL:35 ppm AMMONIA RELEASED FROM AMMONIUM HYDROXIDE/AQUEOUS AMMONIA SOLUTIONS 1336-21-6 OSHA TWA:35 mg/m3(50 ppm) Propane 74-98-6 ACGIH Limit value not established: simple asphyxiant Propane 74-98-6 OSHA TWA:1800 mg/m3(1000 ppm) Naphthalene 91-20-3 ACGIH TWA:10 ppm A3: Confirmed animal carcin., Danger of cutaneous absorption Naphthalene 91-20-3 OSHA TWA:50 mg/m3(10 ppm) Benzene, trimethyl- 95-63-6 ACGIH TWA:25 ppm Cumene 98-82-8 OSHA TWA:245 mg/m3(50 ppm) SKIN Cumene 98-82-8 ACGIH TWA:50 ppm ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit 3M? Foaming Engine Degreaser, 08899 04/09/20 __________________________________________________________________________________________ Page 6 of 17 CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Full Face Shield Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece supplied-air respirator For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state Color Liquid Colorless Specific Physical Form: Aerosol Odor Ammoniacal Odor threshold No Data Available pH 9.5 Melting point No Data Available Boiling Point <=469 ?F Flash Point < 0 ?F [Test Method:Closed Cup] Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure No Data Available Vapor Density No Data Available Density 0.89 g/cm3 3M? Foaming Engine Degreaser, 08899 04/09/20 __________________________________________________________________________________________ Page 7 of 17 Specific Gravity 0.89 [Ref Std:WATER=1] Solubility In Water No Data Available Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature Not Applicable Viscosity No Data Available Hazardous Air Pollutants 0.179 lb HAPS/lb solids [Test Method:Calculated] Volatile Organic Compounds 34.1 % weight [Test Method:calculated per CARB title 2] Volatile Organic Compounds 312 g/l [Test Method:calculated SCAQMD rule 443.1] VOC Less H2O & Exempt Solvents 598 g/l [Test Method:calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material is considered to be non reactive under normal use conditions. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat 10.5. Incompatible materials None known. 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. 3M? Foaming Engine Degreaser, 08899 04/09/20 __________________________________________________________________________________________ Page 8 of 17 May cause additional health effects (see below). Skin Contact: Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. May cause additional health effects (see below). Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: May be harmful if swallowed. Chemical (Aspiration) Pneumonitis: Signs/symptoms may include coughing, gasping, choking, burning of the mouth, difficulty breathing, bluish colored skin (cyanosis), and may be fatal. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Blood Effects: Signs/symptoms may include generalized weakness and fatigue, skin pallor, changes in blood clotting time, internal bleeding, and/or hemoglobinemia. Single exposure, above recommended guidelines, may cause: Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal. Prolonged or repeated exposure may cause target organ effects: Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Blood Effects: Signs/symptoms may include generalized weakness and fatigue, skin pallor, changes in blood clotting time, internal bleeding, and/or hemoglobinemia. Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation Cumene 98-82-8 Grp. 2B: Possible human carc. International Agency for Research on Cancer Cumene 98-82-8 Anticipated human carcinogen National Toxicology Program Carcinogens Naphthalene 91-20-3 Grp. 2B: Possible human carc. International Agency for Research on Cancer Naphthalene 91-20-3 Anticipated human carcinogen National Toxicology Program Carcinogens Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity 3M? Foaming Engine Degreaser, 08899 04/09/20 __________________________________________________________________________________________ Page 9 of 17 Name Route Species Value Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE >50 mg/l Overall product Ingestion No data available; calculated ATE2,000 - 5,000 mg/kg 2-Butoxyethanol Dermal Guinea pig LD50 > 2,000 mg/kg 2-Butoxyethanol Inhalation- Vapor (4 hours) Guinea pig LC50 > 2.6 mg/l 2-Butoxyethanol Ingestion Guinea pig LD50 1,414 mg/kg Heavy Aromatic Solvent Naphtha Dermal Rabbit LD50 > 2,000 mg/kg Heavy Aromatic Solvent Naphtha Ingestion Rat LD50 > 5,000 mg/kg Propane Inhalation- Gas (4 hours) Rat LC50 > 200,000 ppm Fatty Acids Dermal Guinea pig LD50 > 3,000 mg/kg Fatty Acids Ingestion Rat LD50 57,000 mg/kg 1,2,4-Trimethylbenzene Dermal Rabbit LD50 > 3,160 mg/kg 1,2,4-Trimethylbenzene Inhalation- Vapor (4 hours) Rat LC50 18 mg/l 1,2,4-Trimethylbenzene Ingestion Rat LD50 3,400 mg/kg Butane Inhalation- Gas (4 hours) Rat LC50 277,000 ppm Ethoxylated Lauryl Alcohol Dermal Rat LD50 > 2,000 mg/kg Ethoxylated Lauryl Alcohol Ingestion Rat LD50 1,000 mg/kg Ammonium Hydroxide Ingestion Rat LD50 350 mg/kg Light Aromatic Solvent Naphtha Dermal Rabbit LD50 > 2,000 mg/kg Light Aromatic Solvent Naphtha Inhalation- Vapor (4 hours) Rat LC50 > 5.2 mg/l Light Aromatic Solvent Naphtha Ingestion Rat LD50 > 5,000 mg/kg Mesitylene Dermal Rabbit LD50 > 3,160 mg/kg Mesitylene Inhalation- Vapor (4 hours) Rat LC50 18 mg/l Mesitylene Ingestion Rat LD50 3,400 mg/kg Naphthalene Dermal Human LD50 estimated to be 2,000 - 5,000 mg/kg Naphthalene Inhalation- Vapor Human LC50 estimated to be 20 - 50 mg/l Naphthalene Ingestion Human LD50 estimated to be 300 - 2,000 mg/kg Glycol Ethers Dermal Rabbit LD50 > 19,340 mg/kg Glycol Ethers Inhalation- Dust/Mist Rat LC50 estimated to be 5 - 12.5 mg/l Glycol Ethers Ingestion Rat LD50 3,300 mg/kg Cumene Dermal Rabbit LD50 > 3,160 mg/kg Cumene Inhalation- Vapor (4 hours) Rat LC50 39.4 mg/l Cumene Ingestion Rat LD50 1,400 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value 2-Butoxyethanol Rabbit Irritant Heavy Aromatic Solvent Naphtha Rabbit Irritant Propane Rabbit Minimal irritation Fatty Acids Rabbit Minimal irritation 1,2,4-Trimethylbenzene Rabbit Irritant 3M? Foaming Engine Degreaser, 08899 04/09/20 __________________________________________________________________________________________ Page 10 of 17 Butane Professio nal judgeme nt No significant irritation Ethoxylated Lauryl Alcohol Rabbit No significant irritation Ammonium Hydroxide Rabbit Corrosive Light Aromatic Solvent Naphtha Rabbit Irritant Mesitylene Rabbit Irritant Naphthalene Rabbit Minimal irritation Cumene Rabbit Minimal irritation Serious Eye Damage/Irritation Name Species Value 2-Butoxyethanol Rabbit Severe irritant Heavy Aromatic Solvent Naphtha Rabbit Mild irritant Propane Rabbit Mild irritant Fatty Acids Rabbit Mild irritant 1,2,4-Trimethylbenzene Rabbit Mild irritant Butane Rabbit No significant irritation Ethoxylated Lauryl Alcohol Rabbit Severe irritant Ammonium Hydroxide Rabbit Corrosive Light Aromatic Solvent Naphtha Rabbit Mild irritant Mesitylene Rabbit Mild irritant Naphthalene Rabbit No significant irritation Cumene Rabbit Mild irritant Skin Sensitization Name Species Value 2-Butoxyethanol Guinea pig Not classified Heavy Aromatic Solvent Naphtha Guinea pig Not classified 1,2,4-Trimethylbenzene Guinea pig Not classified Ethoxylated Lauryl Alcohol Human and animal Not classified Light Aromatic Solvent Naphtha Guinea pig Not classified Mesitylene Guinea pig Not classified Cumene Guinea pig Not classified Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value 2-Butoxyethanol In Vitro Some positive data exist, but the data are not sufficient for classification Propane In Vitro Not mutagenic Fatty Acids In Vitro Some positive data exist, but the data are not sufficient for classification 1,2,4-Trimethylbenzene In Vitro Not mutagenic Butane In Vitro Not mutagenic Ethoxylated Lauryl Alcohol In Vitro Not mutagenic Ethoxylated Lauryl Alcohol In vivo Not mutagenic Mesitylene In Vitro Not mutagenic Cumene In Vitro Not mutagenic Cumene In vivo Not mutagenic 3M? Foaming Engine Degreaser, 08899 04/09/20 __________________________________________________________________________________________ Page 11 of 17 Carcinogenicity Name Route Species Value 2-Butoxyethanol Inhalation Multiple animal species Some positive data exist, but the data are not sufficient for classification Heavy Aromatic Solvent Naphtha Dermal Mouse Some positive data exist, but the data are not sufficient for classification Fatty Acids Dermal Mouse Not carcinogenic Fatty Acids Ingestion Rat Not carcinogenic Fatty Acids Not Specified Multiple animal species Not carcinogenic Light Aromatic Solvent Naphtha Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Naphthalene Inhalation Multiple animal species Carcinogenic Cumene Inhalation Multiple animal species Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration 2-Butoxyethanol Dermal Not classified for development Rat NOAEL 1,760 mg/kg/day during gestation 2-Butoxyethanol Ingestion Not classified for development Rat NOAEL 100 mg/kg/day during organogenesi s 2-Butoxyethanol Inhalation Not classified for development Multiple animal species NOAEL 0.48 mg/l during organogenesi s 1,2,4-Trimethylbenzene Inhalation Not classified for female reproduction Rat NOAEL 1.2 mg/l 3 months 1,2,4-Trimethylbenzene Inhalation Not classified for male reproduction Rat NOAEL 1.2 mg/l 3 months 1,2,4-Trimethylbenzene Inhalation Not classified for development Rat NOAEL 1.5 mg/l during gestation Light Aromatic Solvent Naphtha Inhalation Not classified for female reproduction Rat NOAEL 1,500 ppm 2 generation Light Aromatic Solvent Naphtha Inhalation Not classified for male reproduction Rat NOAEL 1,500 ppm 2 generation Light Aromatic Solvent Naphtha Inhalation Not classified for development Rat NOAEL 500 ppm 2 generation Mesitylene Inhalation Not classified for female reproduction Rat NOAEL 1.2 mg/l 3 months Mesitylene Inhalation Not classified for male reproduction Rat NOAEL 1.2 mg/l 3 months Mesitylene Inhalation Not classified for development Rat NOAEL 1.5 mg/l during gestation Cumene Inhalation Not classified for development Rabbit NOAEL 11.3 mg/l during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration 2-Butoxyethanol Dermal endocrine system Not classified Rabbit NOAEL 902 mg/kg 6 hours 2-Butoxyethanol Dermal liver Not classified Rabbit LOAEL 72 not available 3M? Foaming Engine Degreaser, 08899 04/09/20 __________________________________________________________________________________________ Page 12 of 17 mg/kg 2-Butoxyethanol Dermal kidney and/or bladder Not classified Rabbit LOAEL 451 mg/kg 6 hours 2-Butoxyethanol Dermal blood Not classified Multiple animal species NOAEL Not available 2-Butoxyethanol Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available 2-Butoxyethanol Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available 2-Butoxyethanol Inhalation blood Not classified Multiple animal species NOAEL Not available 2-Butoxyethanol Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available 2-Butoxyethanol Ingestion blood Not classified Multiple animal species NOAEL Not available 2-Butoxyethanol Ingestion kidney and/or bladder Not classified Human NOAEL Not available poisoning and/or abuse Heavy Aromatic Solvent Naphtha Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Heavy Aromatic Solvent Naphtha Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Professio nal judgeme nt NOAEL Not available Heavy Aromatic Solvent Naphtha Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Propane Inhalation cardiac sensitization Causes damage to organs Human NOAEL Not available Propane Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Propane Inhalation respiratory irritation Not classified Human NOAEL Not available 1,2,4-Trimethylbenzene Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available 1,2,4-Trimethylbenzene Inhalation respiratory irritation May cause respiratory irritation official classifica tion NOAEL Not available 1,2,4-Trimethylbenzene Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Butane Inhalation cardiac sensitization Causes damage to organs Human NOAEL Not available Butane Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Butane Inhalation heart Not classified Dog NOAEL 5,000 ppm 25 minutes Butane Inhalation respiratory irritation Not classified Rabbit NOAEL Not available Ethoxylated Lauryl Alcohol Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification similar health hazards NOAEL Not available Ammonium Hydroxide Inhalation respiratory irritation May cause respiratory irritation Human NOAEL not available Light Aromatic Solvent Naphtha Inhalation central nervous system depression May cause drowsiness or dizziness Professio nal judgeme NOAEL Not available 3M? Foaming Engine Degreaser, 08899 04/09/20 __________________________________________________________________________________________ Page 13 of 17 nt Light Aromatic Solvent Naphtha Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Professio nal judgeme nt NOAEL Not available Light Aromatic Solvent Naphtha Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Mesitylene Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Mesitylene Inhalation respiratory irritation May cause respiratory irritation official classifica tion NOAEL Not available Mesitylene Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Naphthalene Ingestion blood Causes damage to organs Human NOAEL Not available poisoning and/or abuse Cumene Inhalation central nervous system depression May cause drowsiness or dizziness Multiple animal species NOAEL Not available not available Cumene Inhalation respiratory irritation May cause respiratory irritation Human LOAEL 0.2 mg/l occupational exposure Cumene Ingestion central nervous system depression May cause drowsiness or dizziness Multiple animal species NOAEL Not available not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration 2-Butoxyethanol Dermal blood Not classified Multiple animal species NOAEL Not available not available 2-Butoxyethanol Dermal endocrine system Not classified Rabbit NOAEL 150 mg/kg/day 90 days 2-Butoxyethanol Inhalation liver Not classified Rat NOAEL 2.4 mg/l 14 weeks 2-Butoxyethanol Inhalation kidney and/or bladder Not classified Rat NOAEL 0.15 mg/l 14 weeks 2-Butoxyethanol Inhalation blood Not classified Rat LOAEL 0.15 mg/l 6 months 2-Butoxyethanol Inhalation endocrine system Not classified Dog LOAEL 1.9 mg/l 8 days 2-Butoxyethanol Ingestion blood Not classified Rat LOAEL 69 mg/kg/day 13 weeks 2-Butoxyethanol Ingestion kidney and/or bladder Not classified Multiple animal species NOAEL Not available not available Fatty Acids Ingestion liver | immune system Not classified Rat NOAEL 2,250 mg/kg/day 108 weeks Fatty Acids Ingestion hematopoietic system Not classified Rat NOAEL 2,550 mg/kg/day 108 weeks 1,2,4-Trimethylbenzene Inhalation hematopoietic system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.5 mg/l 3 months 1,2,4-Trimethylbenzene Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 0.1 mg/l 3 months 1,2,4-Trimethylbenzene Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure 1,2,4-Trimethylbenzene Inhalation liver | kidney and/or Not classified Rat NOAEL 1.2 3 months 3M? Foaming Engine Degreaser, 08899 04/09/20 __________________________________________________________________________________________ Page 14 of 17 bladder | heart | endocrine system | gastrointestinal tract | immune system mg/l 1,2,4-Trimethylbenzene Ingestion hematopoietic system Not classified Rat NOAEL 600 mg/kg/day 14 days 1,2,4-Trimethylbenzene Ingestion liver | immune system | kidney and/or bladder Not classified Rat NOAEL 1,000 mg/kg/day 28 days Butane Inhalation kidney and/or bladder | blood Not classified Rat NOAEL 4,489 ppm 90 days Ethoxylated Lauryl Alcohol Ingestion gastrointestinal tract | hematopoietic system | liver | nervous system | kidney and/or bladder Not classified Rat NOAEL 590 mg/kg/day 28 days Mesitylene Inhalation hematopoietic system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.5 mg/l 3 months Mesitylene Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 0.1 mg/l 3 months Mesitylene Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Mesitylene Inhalation liver | kidney and/or bladder | heart | endocrine system | gastrointestinal tract | immune system Not classified Rat NOAEL 1.2 mg/l 3 months Mesitylene Ingestion hematopoietic system Not classified Rat NOAEL 600 mg/kg/day 14 days Mesitylene Ingestion liver | immune system | kidney and/or bladder Not classified Rat NOAEL 1,000 mg/kg/day 28 days Naphthalene Dermal blood Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Naphthalene Dermal eyes Not classified Human NOAEL Not available occupational exposure Naphthalene Inhalation respiratory system Causes damage to organs through prolonged or repeated exposure Rat LOAEL 0.01 mg/l 13 weeks Naphthalene Inhalation blood Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Naphthalene Inhalation eyes Not classified Human NOAEL Not available occupational exposure Naphthalene Ingestion blood Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Naphthalene Ingestion eyes May cause damage to organs though prolonged or repeated exposure Rabbit LOAEL 500 mg/kg/day 15 days Cumene Inhalation auditory system | endocrine system | hematopoietic system | liver | nervous system | eyes Not classified Rat NOAEL 59 mg/l 13 weeks Cumene Inhalation kidney and/or bladder Not classified Rat NOAEL 4.9 mg/l 13 weeks Cumene Inhalation respiratory system Not classified Rat NOAEL 59 mg/l 13 weeks Cumene Ingestion kidney and/or bladder | heart | endocrine system | hematopoietic system | liver | respiratory system Not classified Rat NOAEL 769 mg/kg/day 6 months 3M? Foaming Engine Degreaser, 08899 04/09/20 __________________________________________________________________________________________ Page 15 of 17 Aspiration Hazard Name Value Heavy Aromatic Solvent Naphtha Aspiration hazard 1,2,4-Trimethylbenzene Aspiration hazard Light Aromatic Solvent Naphtha Aspiration hazard Mesitylene Aspiration hazard Cumene Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. EPCRA 311/312 Hazard Classifications: Physical Hazards Flammable (gases, aerosols, liquids, or solids) Gas under pressure Health Hazards Aspiration Hazard Carcinogenicity 3M? Foaming Engine Degreaser, 08899 04/09/20 __________________________________________________________________________________________ Page 16 of 17 Serious eye damage or eye irritation Skin Corrosion or Irritation Specific target organ toxicity (single or repeated exposure) Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt 1,2,4-Trimethylbenzene 95-63-6 Trade Secret 1 - 5 Ammonium Hydroxide (AMMONIA COMPOUNDS) 1336-21-6 < 3 2-Butoxyethanol (GLYCOL ETHERS) 111-76-2 7 - 13 Naphthalene 91-20-3 Trade Secret 0.5 - 1.5 Cumene 98-82-8 Trade Secret <= 0.5 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. All required components of this product are listed on the active portion of the TSCA Inventory. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 3 Instability: 0 Special Hazards: None Aerosol Storage Code: 1 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: *4 Flammability: 3 Physical Hazard: 0 Personal Protection: X - See PPE section. Hazardous Material Identification System (HMIS? IV) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS? IV ratings are to be used with a fully implemented HMIS? IV program. HMIS? is a registered mark of the American Coatings Association (ACA). Document Group: 25-9904-1 Version Number: 5.03 Issue Date: 04/09/20 Supercedes Date: 09/04/18 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable 3M? Foaming Engine Degreaser, 08899 04/09/20 __________________________________________________________________________________________ Page 17 of 17 for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M. 3M USA SDSs are available at www.3M.com