Safety Data Sheet Issue Date: 07-May-2018 Revision Date: 24-Aug-20 Version 1 _____________________________________________________________________________________________ Page 1 / 9 1. IDENTIFICATION Product Identifier Product Name Wipe-R-Clean -20?F Windshield Washer Fluid Other means of identification SDS#/Product Code 434526-35, 434555 UN/ID No UN1993 Recommended use of the chemical and restrictions on use Recommended Use Windshield washer fluid. Details of the supplier of the safety data sheet Manufacturer Address FMP 1380 Corporate Center Curve, Suite 200 Eagan, MN 55121 Phone: 888-784-0802 Emergency Telephone Number Emergency Telephone (24 hr) INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America) 2. HAZARDS IDENTIFICATION Appearance Blue liquid Physical state Liquid Odor Alcohol Classification Acute toxicity - Oral Category 4 Acute toxicity - Dermal Category 3 Acute toxicity - Inhalation (Vapors) Category 3 Specific target organ toxicity (single exposure) Category 1 Flammable Liquids Category 3 Signal Word Danger Hazard statements Harmful if swallowed Toxic in contact with skin Toxic if inhaled Causes damage to organs Flammable liquid and vapor Precautionary Statements - Prevention Wipe-R-Clean -20?F Windshield Washer Fluid Revision Date: 24-Aug-20 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 2 / 9 Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Use only outdoors or in a well-ventilated area Do not breathe dust/fume/gas/mist/vapors/spray Keep away from heat/sparks/open flames/hot surfaces. ? No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof equipment Use only non-sparking tools Take precautionary measures against static discharge Keep cool Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response IF exposed: Call a POISON CENTER or doctor IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower Call a POISON CENTER or doctor if you feel unwell Wash contaminated clothing before reuse IF INHALED: Remove person to fresh air and keep comfortable for breathing Call a POISON CENTER or doctor IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell Rinse mouth IN CASE OF FIRE: Use CO2, dry chemical, or foam to extinguish Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep container tightly closed Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No. Weight-% Methanol 67-56-1 30-32 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** 4. FIRST AID MEASURES First Aid Measures General Advice Provide this SDS to medical personnel for treatment. Eye Contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a poison control center or doctor for treatment advice. Skin Contact IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Call a poison center or doctor/physician if you feel unwell. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. Ingestion IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse Wipe-R-Clean -20?F Windshield Washer Fluid Revision Date: 24-Aug-20 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 3 / 9 mouth. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. If large quantities are swallowed, get emergency medical help immediately. Most important symptoms and effects Symptoms Harmful if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes damage to organs. Can cause irritation to eyes and mucous membranes. Sore throat, shortness of breath, coughing and congestion. Irritation, itching, dermatitis. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Small Fire Dry chemical. Carbon dioxide (CO2). Foam. Large Fire Water spray or fog. Foam. Unsuitable Extinguishing Media High volume water jet. Specific Hazards Arising from the Chemical Flammable liquid and vapor. Vapors may travel to source of ignition and flash back. Closed containers may explode if exposed to extreme heat. Hazardous Combustion Products Carbon monoxide. Carbon dioxide (CO2). Explosion Data Sensitivity to Static Discharge Take precautionary measures against static discharge. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Ventilate area of leak or spill. Use personal protection recommended in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Remove all sources of ignition. No smoking in spill area. Environmental precautions Environmental precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Clean-Up Dike with suitable absorbent material like granulated clay. Gather and store in a sealed container pending a waste disposal evaluation. Wipe-R-Clean -20?F Windshield Washer Fluid Revision Date: 24-Aug-20 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 4 / 9 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Wash face, hands and any exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Do not breathe dust/fume/gas/mist/vapors/spray. Keep away from heat/sparks/open flames/hot surfaces. ? No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion proof equipment. Use only non-sparking tools. Take precautionary measures against static discharges. Keep cool. Wear protective gloves/protective clothing and eye/face protection. Conditions for safe storage, including any incompatibilities Storage Conditions Keep container tightly closed and store in a cool, dry and well-ventilated place. Store locked up. Incompatible Materials Strong acids. Strong reducing agents. Strong oxidizing agents. Magnesium. Water-reactive materials. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Methanol 67-56-1 STEL: 250 ppm TWA: 200 ppm S* TWA: 200 ppm TWA: 260 mg/m3 (vacated) TWA: 200 ppm (vacated) TWA: 260 mg/m3 (vacated) STEL: 250 ppm (vacated) STEL: 325 mg/m3 (vacated) S* IDLH: 6000 ppm TWA: 200 ppm TWA: 260 mg/m3 STEL: 250 ppm STEL: 325 mg/m3 Appropriate engineering controls Engineering Controls Apply technical measures to comply with the occupational exposure limits. Showers. Eyewash stations. Local exhaust ventilation recommended. Individual protection measures, such as personal protective equipment Eye/Face Protection Wear chemical safety goggles. Skin and Body Protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Respiratory Protection Under normal conditions, respirator is not normally required. If the exposure limit is exceeded and engineering controls are not feasible, a half face piece particulate respirator (NIOSH type N95 or better filters) may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full face piece particulate respirator (NIOSH type N100 filter) may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids, Glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full face piece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in Oxygen-deficient atmospheres. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Wipe-R-Clean -20?F Windshield Washer Fluid Revision Date: 24-Aug-20 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 5 / 9 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Blue liquid Odor Alcohol Color Blue Odor Threshold Not determined Property Values Remarks ? Method pH 8.0 Melting point / freezing point -28.9 ?C / -20.02 ?F Boiling Point / Boiling Range 87 ?C / 188.6 ?C Flash Point 33 ?C / 91.4 ?F Evaporation Rate 2.1 (butyl acetate = 1) Flammability (Solid, Gas) Liquid - Not Applicable Flammability Limit in Air Upper Flammability Limit 6% Lower Flammability Limit 36% Vapor Pressure 128 hPa @ 20?C (68?F) Vapor Density 1.11 (Air=1) Relative Density 0.952 Water Solubility Soluble in water Solubility in other solvents Not determined Partition Coefficient Not determined Autoignition temperature Not determined Decomposition Temperature Not determined Kinematic Viscosity Not determined Dynamic Viscosity Not determined Explosive Properties Not determined Oxidizing Properties Not determined Other Information VOC Content 31% Density 7.9422 lb/gal 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to Avoid Avoid temperatures exceeding the flash point. Heat, flames and sparks. Incompatible Materials Strong acids. Strong reducing agents. Strong oxidizing agents. Magnesium. Water-reactive materials. Hazardous Decomposition Products Carbon monoxide. Carbon dioxide (CO2). Wipe-R-Clean -20?F Windshield Washer Fluid Revision Date: 24-Aug-20 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 6 / 9 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact Avoid contact with eyes. Skin Contact Toxic in contact with skin. Inhalation Toxic if inhaled. Ingestion Harmful if swallowed. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Methanol 67-56-1 = 6200 mg/kg ( Rat ) = 15800 mg/kg ( Rabbit ) = 15840 mg/kg ( Rabbit ) = 22500 ppm ( Rat ) 8 h = 64000 ppm ( Rat ) 4 h Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity Based on the information provided, this product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. STOT - single exposure Causes damage to organs. Numerical measures of toxicity The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 331.68 mg/kg ATEmix (dermal) 995.00 mg/kg ATEmix (inhalation-dust/mist) 1.66 mg/L ATEmix (inhalation-vapor) 9.95 mg/L 12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Chemical Name Partition Coefficient Methanol 67-56-1 -0.77 Other Adverse Effects Not determined Wipe-R-Clean -20?F Windshield Washer Fluid Revision Date: 24-Aug-20 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 7 / 9 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. US EPA Waste Number Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes Methanol 67-56-1 Included in waste stream: F039 U154 California Hazardous Waste Status Chemical Name California Hazardous Waste Status Methanol 67-56-1 Toxic Ignitable 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT 1 Gallon = Limited Quantity; 55 and 250 Gallon = Fully Regulated (see below) UN/ID No UN1993 Proper Shipping Name Flammable liquids, n.o.s. (Methanol) Hazard Class 3 Packing Group III IATA 1 Gallon = Fully Regulated (see below, PI 355); 55 and 250 Gallon = Forbidden UN/ID No UN1992 Proper Shipping Name Flammable liquid, toxic, n.o.s. (Methanol) Hazard Class 3 Subsidiary Hazard Class 6.1 Packing Group III IMDG 1 Gallon = Limited Quantity; 55 and 250 Gallon = Fully Regulated (see below) UN/ID No UN1992 Proper Shipping Name Flammable liquid, toxic, n.o.s. (Methanol) Hazard Class 3 Subsidiary Hazard Class 6.1 Packing Group III 15. REGULATORY INFORMATION International Inventories Chemical Name TSCA DSL/NDSL EINECS/E LINCS ENCS IECSC KECL PICCS AICS Methanol X X X X X X X X Wipe-R-Clean -20?F Windshield Washer Fluid Revision Date: 24-Aug-20 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 8 / 9 Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) Methanol 67-56-1 5000 lb RQ 5000 lb final RQ RQ 2270 kg final RQ SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals. Chemical Name California Proposition 65 Methanol - 67-56-1 Developmental U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania Methanol 67-56-1 X X X Wipe-R-Clean -20?F Windshield Washer Fluid Revision Date: 24-Aug-20 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 9 / 9 16. OTHER INFORMATION NFPA Health Hazards Not determined Flammability Not determined Instability Not determined Special Hazards Not determined HMIS Health Hazards Not determined Flammability Not determined Physical hazards Not determined Personal Protection Not determined Issue Date: 07-May-2018 Revision Date: 24-Aug-20 Revision Note: Revised Section 14 information Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet A D D ITIO N A L P R O D U C T IN FO R M A TIO N D IS C LO S U R E ?20?W indshield?W asher?Fluid CA S# R aw ?M aterial Functional?Purpose Lists?O f?Concern Links?to?Lists?of?Concern 7732?18?5 W ater 67?56?1 M ethanol Reduces?freeze?point CA ?Prop?65 U S?N TP?Reproductive?or?D evelopm ental?Toxicants CA ?N on?Cancer?H azards https://oehha.ca.gov/proposition?65/proposition?65?lis t https://ntp.niehs.nih.gov/w hatw estudy/assessm ents/noncancer/com pleted/index.htm l https://oehha.ca.gov/air/general?info/oehha?acute?8?hour?and?chronic?reference?exposure?level?rel?sum m ary https://ntp.niehs.nih.gov/ntp/ohat/m ethanol/m ethanol_m onograph.pdf 3734?33?6 D enatonium ?Benzoate Bittering?agent W ithheld?1116737* Patent?Blue?D ye?L85000 D ye/colorant *W ERKS?N U M BER https://leginfo.legislature.ca.gov/faces/billN avClient.xhtm l?bill_id=201720180SB258