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HSSEDT Everyday Diesel Treatment
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Hot_Shots_HSSEDT16ZSP-EDT-w-LX4-v1p2-1.pdf
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Page 1 of 8 Revision Date: 1/18/2021 SAFETY DATA SHEET SECTION 1: Product and Company Identification EDT (with LX4) Product type: Diesel Fuel Additive Application: Cleaning/Maintenance/Performance. Add to any diesel fuel. Do not ingest. Supplier/Manufacturer: Lubrication Specialties Inc. 3975 Morrow Meadows Drive Mount Gilead, OH 43338 US Phone: (419) 947-2647 Telefax: (415) 946-3554 Email: This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency Telephone number: Within USA and Canada: ChemTel, 24 hrs. +1 (800) 255-3924 Outside USA and Canada:* +1 (703) 741-5970 *Collect calls accepted 24/7 SECTION 2: Hazards Identification Classification of the Substance or Mixture GHS Classification in Accordance with 26 CFR 1940 (OSHA HCS): Physical, Flammable Liquids, 4 Health, Skin corrosion/irritation, 2 Health, Serious Eye Damage/Eye Irritation, 2A Health, Specific target organ toxicity - Single exposure, 3 Health, Acute toxicity, 4 Dermal Health, Acute toxicity, 4 Inhalation Health, Acute toxicity, 4 Oral Health, Carcinogenicity, 2 Health, Aspiration hazard, 1 Environmental, Hazards to the aquatic environment - Chronic, 2 GHS Label Elements, Including Precautionary Statements GHS Signal Word: DANGER GHS Hazard Pictograms: Page 2 of 8 Revision Date: 1/18/2021 GHS Hazard Statements: H227 - Combustible liquid H315 - Causes skin irritation H319 - Causes serious eye irritation H336 - May cause drowsiness or dizziness H335 - May cause respiratory irritation H312 - Harmful in contact with skin H332 - Harmful if inhaled H302 - Harmful if swallowed H351 - Suspected of causing cancer H304 - May be fatal if swallowed and enters airways H411 - Toxic to aquatic life with long lasting effects GHS Precautionary Statements: P210 - Keep away from heat/sparks/open flames/hot surfaces. No smoking P242 - Use non-sparking tools. P243 - Take action to prevent static discharges. P261 - Avoid breathing dust/fume/gas/mist/vapors/spray. P273 - Avoid release to the environment. P280 Wear protective gloves/eye protection/face protection. P301+312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P303+361+353+364 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. P304+340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+313 - IF exposed or concerned: Get medical advice/attention. Hazards not Otherwise Classified or not Covered by GHS When heated above 100 C (212 F) may undergo a self-accelerating, exothermic reaction which causes a rapid rise in temperature and pressure. Rupture of storage vessels and fire should be anticipated in case of such temperature. VAPOR MAY CAUSE FLASH FIRE SECTION 3: Composition/Information on Ingredients Ingredient Name % (Avg) CAS Number 2-ethylhexyl nitrate 42-43% 27247-96-7 Tall Oil Fatty Acid 10% 61790-12-3 TRADE SECRET 6-7% Trade Secret Solvent naptha petroleum, heavy aromatic 6-7% 64742-94-5 TRADE SECRET 6-7% Trade Secret Distillates, petroleum hydrotreated, light 6% 64742-47-8 TRADE SECRET 2-6% Trade Secret 1,2,4-Trimethylbenzene .5-3.5% 95-63-6 Solvent naphtha, petroleum, light aromatic <3% 64742-95-6 Xylene <3% 1330-20-7 Amine Compound <3% 84605-20-9 Naphthalene <2% 91-20-3 1,3,5-Trimethylbenzene <2% 108-67-8 n-Propyl benzene <2% 103-65-1 1,2,3-Trimethylbenzene <1% 526-73-8 Ethyl benzene <1% 100-41-4 ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE TO BATCH VARIATION Page 3 of 8 Revision Date: 1/18/2021 SECTION 4: First Aid Measures Eyes: Immediately flush with gentle but large stream of water for 15 min, lifting upper and lower eyelids occasionally. Get medical attention if irritation develops. Skin: Wash affected area with soap and water. If itching or redness develops, seek medical attention. Contaminated clothing should be removed immediately and washed before reuse. Contaminated shoes should be discarded. Inhalation: Move the person to fresh air. If breathing becomes difficult, contact a physician. Ingestion: Do not induce vomiting. If large amounts were swallowed, give water to rinse mouth, give water to drink, and get medical attention if you feel unwell. Most important symptoms/effects, Acute and delayed: Skin contact: No specific data Ingestion: No specific data Inhalation: No specific data Eye Contact: No specific data SECTION 5: Firefighting Measures Flash Point: >155?F (68?C) Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide. Unsuitable extinguishing media: Water jet. Special Protective Equipment for firefighters: Self-contained breathing apparatus and protective clothing when fighting any chemical fire. Unusual Fire and Explosion Hazards: In case of fire, containers may explode from internal pressure. Cool with water. VAPOR MAY CAUSE FLASH FIRE. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Decomposition products may include NOx, CO, and CO2. Special protective equipment for fire-fighters: Fire-fighters should wear appropriate protective equipment and self- contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. SECTION 6: Accidental Release Measures Personal Precautions: Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard area. Keep personnel removed and upwind of spill. Eliminate all ignition sources. Keep unnecessary and unprotected personnel from entering. Environmental precautions: P273: Avoid release to the environment Page 4 of 8 Revision Date: 1/18/2021 Limit leakage with earth or sand. Do not discharge into the drains/surface water/groundwater. Dispose of absorbed material in accordance with local, state and federal regulations. Methods for containment/ Cleaning up: Initial Containment: Approach release from upwind. Eliminate all sources of ignition ? heat, sparks, flame, electricity, and impact. Contain spilled material with dikes or absorbents. Do not allow material to enter soil, surface water, or sewer system. Stop the source of the leak, if safe to do so. Large Spill: Contain spilled material. Vacuum or sweep up material and place in a disposal container. Absorb residue with inert material (e.g., dry sand or earth,) then place in a chemical waste container. Do not flush to sewer. Use explosion- proof equipment during clean-up. Small Spill: Contain spilled material. Absorb with inert material and place in disposal container. Spills are extremely slippery. Clean up immediately. Miscellaneous: Note that combustible vapors may form an ignitable mixture with air. Vapors may travel considerable distances from spill and flash back, if ignited. Report spills to local authorities and/or the U.S. coast Guard?s National Response Center at (800) 424-8802 as appropriate or required. SECTION 7: Handling and Storage Handling: P261: Avoid breathing vapors or spray mists. P262: Do not get in eyes, on skin, or on clothing P264: Wash thoroughly after handling P280: Wear protective gloves/eye protection Handle with care and avoid spillage on the floor (slippage). Do not cut, weld, drill, grind, braze, pressurize or solder container. Keep away from sources of ignition. Ground and bond containers when transferring material. When heated above 100 C (212 F) may undergo a self-accelerating, exothermic reaction which causes a rapid rise in temperature and pressure. Rupture of storage vessels and fire should be anticipated in case of such temperature. Storage: P402+404: Store in a dry place. Store in a closed container P403+233: Store in a well-ventilated place. Keep container tightly closed Protect from moisture. Do not store together with acids. Keep out of direct sunlight Keep away from sources of ignition. General Hygiene Practices: Eating drinking and smoking should be prohibited in areas where this material is handled, stored and processed Special Packaging Requirements: None Incompatible Materials: Oxidizing material. Avoid prolonged contact with porous materials. May burn or react violently to fluorine/oxygen mixtures. SECTION 8: Exposure Controls/Personal Protection Occupational exposure limits: Under conditions which may generate mists, Observe exposure limits for Oil Mist (NOC): Page 5 of 8 Revision Date: 1/18/2021 ACGIH: TWA: 5 mg/m3 Respirable; STEL 10mg/m3 Respirable OSHA: TWA: 5 mg/m3 Respirable. NIOSH REL: TWA 10mg/m3 Respirable. Ingredient CAS# Exposure limits Light Aromatic Solvent Naptha (Petroluem) 64742-95-6 OSHA TWA: 500ppm 1,2,4-Trimethylbenzene 95-63-6 ACGIH TWA: 25ppm Xylene 1330-20-7 OSHA TWA: 100ppm; 435 mg/m3 Naphthalene 91-20-3 OSHA TWA: 10 ppm, 50 mg/m3 Trade Secret - OSHA PEL: 100 ppm, 600 mg/m3 1,3,5-Trimethylbenzene 108-67-8 ACGIH TWA: 25ppm Personal Protective Equipment Hands: Use impervious gloves. Eyes: Wear safety glasses with side shields. Skin: Wear protective clothing, wash hands thoroughly after handling. Respiratory: Respiratory protection is recommended if ventilation is limited. Appropriate Engineering Controls: Good ventilation sufficient to control worker exposure to airborne contaminants Environmental exposure Controls: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation Other measures: Have access to an eye wash station. Launder contaminated clothing before reuse. Use good industrial hygiene practices in handling this material. SECTION 9: Physical and Chemical Properties Appearance Physical State: Liquid Color: Amber Odor: Hydrocarbon-like Odor threshold: Not available pH: Not available Melting point: Not determined Boiling point: Not available Flash point: >155?F (68?C) Evaporation rate: Not available Flammability (solid, gas): Not available Lower and upper explosive (flammable) limits: Not available Vapor pressure: Not available Vapor density: Not available Relative density: .924 Solubility: Not available Page 6 of 8 Revision Date: 1/18/2021 Partition coefficient: n- Octanol/water: Not available Auto-ignition temperature: Not available Decomposition temperature: Not available Viscosity: Not available Volatility: Not available VOC (w/w): Not available SECTION 10: Stability and reactivity Reactivity: No specific test data available Chemical Stability: May be unstable at temperatures greater than 100?C (212?F). Conditions to Avoid: High temperatures above 50?C (122?F)., sources of ignition. Incompatible Materials: Oxidizing material. Avoid prolonged contact with porous materials. May burn or react violently to fluorine/oxygen mixtures. Hazardous Decomposition Products: Products of combustion: NOx, COx SECTION 11: Toxicological Information Likely Routes of Exposure: Dermal, eye, inhalation, ingestion Acute Toxicity Ingredient Result Species Dose/ATE Comments 2-Ethylhexylnitrate LD50 Dermal Rabbit >5000 mg/kg LD50 Oral Rat >10000 mg/kg Amine compound LD50 Dermal Rat >2000 mg/kg 1,2,4-Trimethylbenzene LD50 Inhalation Rat 18000 mg/m3/4h vapor LD50 Oral Rat 3400-6000 mg/kg - LD50 Dermal Rabbit 3160 mg/kg - Tall Oil Fatty Acid LD50 Dermal Rabbit >2000 mg/kg/14days No death at this dose LD50 Oral Rat >10000 mg/kg/14days No death at this dose Trade Secret ATEmix Dermal - 3000 mg/kg - Light aromatic solvent Naphtha (petroleum) LD50 Dermal Rabbit >3160 mg/kg LD50 Oral Rat 3492 mg/kg LC50 Inhalation Rat 6193 mg/m3/4h Vapor Xylene LC50 Inhalation Rat 5000 ppm/4h Gas LD50 Dermal Rabbit >1700 mg/kg LD50 Oral Rat 4300 mg/kg Trade Secret LD50 Dermal Rabbit >19000 mg/kg - LD50 Oral Rat 5135 mg/kg - Naphthalene LD50 Dermal Rat >2500 mg/kg - LD50 Oral Rat >2600 mg/kg - LC50 Inhalation Rat >100ppm/8hrs Gas 1,3,5 Trimethylbenzene LC50 Inhalation Rat 24000 mg/m3/4hrs Vapor LD50 Oral Rat 5000mg/kg Sensitization: None known. Germ Cell Mutagenicity: None known. Page 7 of 8 Revision Date: 1/18/2021 Carcinogenicity: Naphthalene, IARC 2B Reproductive toxicity: None known. Specific target organ systemic toxicity (repeated exposure): None known. SECTION 12: Ecological Information Ecotoxicity 1,2,4-Trimethylbenzene LC50 4910 ug/l Marine water Crustaceans-Elasmopus pectenicrus 48 hrs LC50 22.4 mg/l Fresh water Fish ? Tilapia zillii 96hrs 1,3,5-Trimethylbenzene LC50 12520-15050 ug/l Fresh water fish-Carassius auratus 96 hrs Chrinic NOEC 400 ug/l Fresh water Daphnia-Daphnia magna 21days Xylene LC50 8500 ug/l Marine water Crustaceans-Palaemonetes Pugio 48hrs LC50 13400 ug/l Fresh water Fish-Pimephales promelas 96hr Tall oil Fatty Acids: EC50 Bacteria (Pseudomonas putida): > 10000 mg/L 16hr ECL50 Green algae (Selenastrum capricornutum): > 1000 mg/L 72 hr Growth rate; OECD 201 EL50 Water flea (Daphnia magna): > 1000 mg/L 48 hr OECD 202 LL50 Zebra danio (Danio rerio): > 10000 mg/L 96hr Trade Secret: LC50 Fathead minnow (Pimephales promelas): > 1000 mg/L Mortality 1hr LC50 Fathead minnow (Pimephales promelas): > 285 mg/L Mortality 24hr LC50 Fathead minnow (Pimephales promelas): > 252 mg/L Mortality 48hr LC50 Fathead minnow (Pimephales promelas): > 205 mg/L Mortality 72hr LC50 Fathead minnow (Pimephales promelas): > 205 mg/L Mortality 96hr Avoid exposing to the environment. Toxic to aquatic organisms. May cause long term adverse effects in the aquatic environment. Based on calculations. This product contains components which may be persistent in the environment. Chronic hazards to Aquatic Environment: No specific data available Persistence and Degradability: No specific data available Mobility in Soil: No specific data available PBT/VPvB Assessment: No specific data available Other Adverse Effects: No specific data available Additonal ecological information: Information given is based on data on the ingredients and the ecotoxicology of similar products. SECTION 13: Disposal Considerations Disposal methods: Disposal of this product should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority. Waste should not be disposed of untreated into the sewer. Empty containers may retain some product residues. SECTION 14: Transportation Information NA1993, Combustible liquid, n.o.s., Combustible liquid, PGIII, (Contains 2-Ethylhexylnitrate, Petroleum Naphtha), (Marine pollutant) Page 8 of 8 Revision Date: 1/18/2021 Not regulated by US DOT in containers less than 119 gallons. IMDG & IATA: UN3082, Environmentally Hazardous Substance, liquid, nos, (2-Ethylhexylnitrate, Petroleum Naphtha), 9, III. Marine pollutant. SECTION 15: Regulatory Information US federal regulations Use as animal feed is prohibited. This product is not known to be a ?Hazardous Chemical? as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All known components are on the U.S. EPA TSCA Inventory List. WARNING This product can expose you to chemicals including Naphthalene and Ethylbenzene, which are known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov. SECTION 16: Other Information Date of Issue: 1/18/2021 Date of Previous Issue: 2/11/2020 Version: 1.2 This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or completeness and is provided ?AS IS?. It is the user's responsibility to satisfy him/herself as to the suitability of such information for his/her own particular use.