3M? Strip-Calk (Black), PN 08578 09/01/21 __________________________________________________________________________________________ Page 1 of 12 Safety Data Sheet Copyright,2021, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 05-9750-0 Version Number: 20.09 Issue Date: 09/01/21 Supercedes Date: 02/27/20 SECTION 1: Identification 1.1. Product identifier 3M? Strip-Calk (Black), PN 08578 Product Identification Numbers ID Number UPC ID Number UPC 60-9800-1955-2 00-51135-08578-3 7000028370 1.2. Recommended use and restrictions on use Recommended use Automotive, Caulk for use in seams, joints, and openings. 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Skin Sensitizer: Category 1A. 2.2. Label elements Signal word Warning Symbols Exclamation mark | 3M? Strip-Calk (Black), PN 08578 09/01/21 __________________________________________________________________________________________ Page 2 of 12 Pictograms Hazard Statements May cause an allergic skin reaction. Precautionary Statements General: Keep out of reach of children. Prevention: Avoid breathing dust/fume/gas/mist/vapors/spray. Wear protective gloves. Contaminated work clothing must not be allowed out of the workplace. Response: IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 3% of the mixture consists of ingredients of unknown acute oral toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Kaolin 1332-58-7 15 - 40 Trade Secret * Oxide Glass Chemicals 65997-17-3 20 - 40 Trade Secret * Polybutylene 9003-29-6 10 - 30 Trade Secret * Polyisobutylene 9003-27-4 5 - 10 Trade Secret * Aluminatesilicate 1327-36-2 < 6 Trade Secret * Limestone 1317-65-3 1 - 5 Trade Secret * Aluminum Distearate 300-92-5 <= 2 Trade Secret * Mica-Group Minerals 12001-26-2 < 1.5 Trade Secret * Quartz Silica 14808-60-7 < 1.5 Trade Secret * Silica 7631-86-9 0.5 - 1.5 Trade Secret * Rheological Additive Trade Secret* 0.1 - 1 Trade Secret * 4,4'-Thiobis(6-Tert-Butyl-M-Cresol) 96-69-5 < 0.4 Trade Secret * Carbon Black 1333-86-4 < 0.2 Trade Secret * Chromium 7440-47-3 < 0.05 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures 3M? Strip-Calk (Black), PN 08578 09/01/21 __________________________________________________________________________________________ Page 3 of 12 Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Allergic skin reaction (redness, swelling, blistering, and itching). 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling 3M? Strip-Calk (Black), PN 08578 09/01/21 __________________________________________________________________________________________ Page 4 of 12 Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. 7.2. Conditions for safe storage including any incompatibilities No special storage requirements. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Mica-Group Minerals 12001-26-2 ACGIH TWA(respirable fraction):0.1 mg/m3 Mica-Group Minerals 12001-26-2 OSHA TWA:20 millions of particles/cu. ft. Limestone 1317-65-3 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Aluminum, insoluble compounds 1327-36-2 ACGIH TWA(respirable fraction):1 mg/m3 A4: Not class. as human carcin DUST, INERT OR NUISANCE 1332-58-7 OSHA TWA(as total dust):15 mg/m3;TWA(as total dust):50 millions of particles/cu. ft.(15 mg/m3);TWA(respirable fraction):5 mg/m3;TWA(respirable fraction):15 millions of particles/cu. ft.(5 mg/m3) Kaolin 1332-58-7 ACGIH TWA(respirable fraction):2 mg/m3 A4: Not class. as human carcin KAOLIN, TOTAL DUST 1332-58-7 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Carbon Black 1333-86-4 ACGIH TWA(inhalable fraction):3 mg/m3 A3: Confirmed animal carcin. Carbon Black 1333-86-4 OSHA TWA:3.5 mg/m3 Quartz Silica 14808-60-7 ACGIH TWA(respirable fraction):0.025 mg/m3 A2: Suspected human carcin. Quartz Silica 14808-60-7 OSHA TWA Table Z- 1(respirable):0.05 mg/m3;TWA Table Z- 3(respirable):0.1 mg/m3;TWA concentration(respirable):0.1 mg/m3(2.4 millions of particles/cu. ft.) Aluminum, insoluble compounds 300-92-5 ACGIH TWA(respirable fraction):1 mg/m3 A4: Not class. as human carcin CERAMIC FIBERS 65997-17-3 ACGIH TWA(as fiber):0.2 fiber/cc A2: Suspected human carcin. 3M? Strip-Calk (Black), PN 08578 09/01/21 __________________________________________________________________________________________ Page 5 of 12 CONTINUOUS FILAMENT GLASS FIBERS, INHALABLE FRACTION 65997-17-3 ACGIH TWA(inhalable fraction):5 mg/m3 A4: Not class. as human carcin Oxide Glass Chemicals 65997-17-3 Manufacturer determined TWA(as non-fibrous, respirable)(8 hours):3 mg/m3;TWA(as non-fibrous, inhalable fraction)(8 hours):10 mg/m3 SPECIAL PURPOSE GLASS FIBERS 65997-17-3 ACGIH TWA(as fiber):1 fiber/cc A3: Confirmed animal carcin. Chromium 7440-47-3 ACGIH TWA(as Cr(0), inhalable fraction):0.5 mg/m3 Chromium 7440-47-3 OSHA TWA(as Cr):1 mg/m3 DUST, INERT OR NUISANCE 7631-86-9 OSHA TWA(as total dust):15 mg/m3;TWA(as total dust):50 millions of particles/cu. ft.(15 mg/m3);TWA(respirable fraction):5 mg/m3;TWA(respirable fraction):15 millions of particles/cu. ft.(5 mg/m3) SILICA, AMORPHOUS 7631-86-9 OSHA TWA:20 millions of particles/cu. ft.;TWA concentration:0.8 mg/m3 4,4'-Thiobis(6-Tert-Butyl-M- Cresol) 96-69-5 ACGIH TWA(inhalable fraction):1 mg/m3 A4: Not class. as human carcin 4,4'-Thiobis(6-Tert-Butyl-M- Cresol) 96-69-5 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls No engineering controls required. 8.2.2. Personal protective equipment (PPE) Eye/face protection None required. Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Neoprene Nitrile Rubber Polyvinyl Chloride 3M? Strip-Calk (Black), PN 08578 09/01/21 __________________________________________________________________________________________ Page 6 of 12 If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - Neoprene Apron ? Nitrile Respiratory protection Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state Color Solid Black Specific Physical Form: Viscous putty Odor Not Determined Odor threshold No Data Available pH Not Applicable Melting point No Data Available Boiling Point Not Applicable Flash Point No flash point Evaporation rate Not Applicable Flammability (solid, gas) Not Classified Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable Vapor Pressure Not Applicable Vapor Density Not Applicable Density 1.920 g/cm3 Specific Gravity 1.920 [Ref Std:WATER=1] Solubility in Water Slight (less than 10%) Solubility- non-water Slight (less than 10%) Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity No Data Available Hazardous Air Pollutants 0.0004 lb HAPS/lb solids [Test Method:Calculated] Volatile Organic Compounds 0 g/l [Test Method:calculated SCAQMD rule 443.1] Volatile Organic Compounds 0 % weight [Test Method:calculated per CARB title 2] Percent volatile 0 % weight VOC Less H2O & Exempt Solvents 0 g/l [Test Method:calculated SCAQMD rule 443.1] Solids Content 77.6 % weight SECTION 10: Stability and reactivity 10.1. Reactivity This material is considered to be non reactive under normal use conditions. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 3M? Strip-Calk (Black), PN 08578 09/01/21 __________________________________________________________________________________________ Page 7 of 12 10.4. Conditions to avoid Sparks and/or flames 10.5. Incompatible materials Not determined 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: No known health effects. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Contact with the eyes during product use is not expected to result in significant irritation. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Carcinogenicity: Ingredient CAS No. Class Description Regulation SILICA, CRYS AIRRESP 14808-60-7 Known human carcinogen National Toxicology Program Carcinogens Carbon Black 1333-86-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Quartz Silica 14808-60-7 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Oxide Glass Chemicals Dermal LD50 estimated to be > 5,000 mg/kg 3M? Strip-Calk (Black), PN 08578 09/01/21 __________________________________________________________________________________________ Page 8 of 12 Oxide Glass Chemicals Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg Kaolin Dermal LD50 estimated to be > 5,000 mg/kg Kaolin Ingestion Human LD50 > 15,000 mg/kg Polybutylene Dermal Rat LD50 > 10,250 mg/kg Polybutylene Ingestion Rat LD50 > 34,600 mg/kg Polyisobutylene Dermal LD50 estimated to be > 5,000 mg/kg Polyisobutylene Ingestion Rat LD50 > 2,000 mg/kg Aluminatesilicate Dermal LD50 estimated to be > 5,000 mg/kg Aluminatesilicate Ingestion LD50 estimated to be > 5,000 mg/kg Limestone Dermal Rat LD50 > 2,000 mg/kg Limestone Inhalation- Dust/Mist (4 hours) Rat LC50 3 mg/l Limestone Ingestion Rat LD50 6,450 mg/kg Quartz Silica Dermal LD50 estimated to be > 5,000 mg/kg Quartz Silica Ingestion LD50 estimated to be > 5,000 mg/kg Silica Dermal Rabbit LD50 > 5,000 mg/kg Silica Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l Silica Ingestion Rat LD50 > 5,110 mg/kg Mica-Group Minerals Dermal LD50 estimated to be > 5,000 mg/kg Mica-Group Minerals Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg 4,4'-Thiobis(6-Tert-Butyl-M-Cresol) Dermal Rabbit LD50 > 5,010 mg/kg 4,4'-Thiobis(6-Tert-Butyl-M-Cresol) Ingestion Rat LD50 2,315 mg/kg Carbon Black Dermal Rabbit LD50 > 3,000 mg/kg Carbon Black Ingestion Rat LD50 > 8,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Oxide Glass Chemicals Professio nal judgeme nt No significant irritation Kaolin Professio nal judgeme nt No significant irritation Polybutylene Rabbit Minimal irritation Polyisobutylene Rabbit No significant irritation Limestone Rabbit No significant irritation Quartz Silica Professio nal judgeme nt No significant irritation Silica Rabbit No significant irritation 4,4'-Thiobis(6-Tert-Butyl-M-Cresol) Rabbit Mild irritant Carbon Black Rabbit No significant irritation Serious Eye Damage/Irritation Name Species Value Oxide Glass Chemicals Professio nal judgeme nt No significant irritation Kaolin Professio nal judgeme nt No significant irritation 3M? Strip-Calk (Black), PN 08578 09/01/21 __________________________________________________________________________________________ Page 9 of 12 Polybutylene Rabbit Mild irritant Polyisobutylene Rabbit No significant irritation Limestone Rabbit No significant irritation Silica Rabbit No significant irritation 4,4'-Thiobis(6-Tert-Butyl-M-Cresol) Rabbit Moderate irritant Carbon Black Rabbit No significant irritation Skin Sensitization Name Species Value Silica Human and animal Not classified 4,4'-Thiobis(6-Tert-Butyl-M-Cresol) Guinea pig Sensitizing Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Oxide Glass Chemicals In Vitro Some positive data exist, but the data are not sufficient for classification Quartz Silica In Vitro Some positive data exist, but the data are not sufficient for classification Quartz Silica In vivo Some positive data exist, but the data are not sufficient for classification Silica In Vitro Not mutagenic Carbon Black In Vitro Not mutagenic Carbon Black In vivo Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Oxide Glass Chemicals Inhalation Multiple animal species Some positive data exist, but the data are not sufficient for classification Kaolin Inhalation Multiple animal species Not carcinogenic Quartz Silica Inhalation Human and animal Carcinogenic Silica Not Specified Mouse Some positive data exist, but the data are not sufficient for classification Carbon Black Dermal Mouse Not carcinogenic Carbon Black Ingestion Mouse Not carcinogenic Carbon Black Inhalation Rat Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Limestone Ingestion Not classified for development Rat NOAEL 625 mg/kg/day premating & during gestation Silica Ingestion Not classified for female reproduction Rat NOAEL 509 mg/kg/day 1 generation Silica Ingestion Not classified for male reproduction Rat NOAEL 497 mg/kg/day 1 generation Silica Ingestion Not classified for development Rat NOAEL 1,350 mg/kg/day during organogenesi 3M? Strip-Calk (Black), PN 08578 09/01/21 __________________________________________________________________________________________ Page 10 of 12 s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Limestone Inhalation respiratory system Not classified Rat NOAEL 0.812 mg/l 90 minutes Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Oxide Glass Chemicals Inhalation respiratory system Not classified Human NOAEL not available occupational exposure Kaolin Inhalation pneumoconiosis Causes damage to organs through prolonged or repeated exposure Human NOAEL NA occupational exposure Kaolin Inhalation pulmonary fibrosis Not classified Rat NOAEL Not available Polybutylene Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.07 mg/l 2 weeks Polybutylene Inhalation liver Not classified Rat NOAEL 0.7 mg/l 2 weeks Limestone Inhalation respiratory system Not classified Human NOAEL Not available occupational exposure Quartz Silica Inhalation silicosis Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Silica Inhalation respiratory system | silicosis Not classified Human NOAEL Not available occupational exposure Mica-Group Minerals Inhalation pneumoconiosis Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Carbon Black Inhalation pneumoconiosis Not classified Human NOAEL Not available occupational exposure Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of waste product in a permitted industrial waste facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable 3M? Strip-Calk (Black), PN 08578 09/01/21 __________________________________________________________________________________________ Page 11 of 12 waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. EPCRA 311/312 Hazard Classifications: Physical Hazards Not applicable Health Hazards Respiratory or Skin Sensitization 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. All required components of this product are listed on the active portion of the TSCA Inventory. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 1 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 05-9750-0 Version Number: 20.09 Issue Date: 09/01/21 Supercedes Date: 02/27/20 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to 3M? Strip-Calk (Black), PN 08578 09/01/21 __________________________________________________________________________________________ Page 12 of 12 determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M. 3M USA SDSs are available at www.3M.com