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03601 and 33601 Plastic Emblem Adhesive
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3M? Plastic and Emblem Adhesive - Clear PN 03601 & 33601 05/13/21 __________________________________________________________________________________________ Page 1 of 14 Safety Data Sheet Copyright,2021, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 29-0703-8 Version Number: 3.08 Issue Date: 05/13/21 Supercedes Date: 04/08/21 SECTION 1: Identification 1.1. Product identifier 3M? Plastic and Emblem Adhesive - Clear PN 03601 & 33601 Product Identification Numbers 60-4550-3263-5, 60-4550-3264-3, 60-4550-4834-2, 60-4550-5366-4, 60-4550-5621-2, 60-4550-5677-4, 60-4550-9186-2, 60- 4551-0061-4, 70-0713-4940-4, 70-0713-4941-2 7010364266, 7100045880, 7010294867, 7100158731 1.2. Recommended use and restrictions on use Recommended use Automotive, Adhesive for plastic repair and emblem application 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Construction and Home Improvement Markets ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Liquid: Category 2. Serious Eye Damage/Irritation: Category 2A. Skin Sensitizer: Category 1. Reproductive Toxicity: Category 1B. Carcinogenicity: Category 2. Specific Target Organ Toxicity (single exposure): Category 3. 2.2. Label elements Signal word Danger 3M? Plastic and Emblem Adhesive - Clear PN 03601 & 33601 05/13/21 __________________________________________________________________________________________ Page 2 of 14 Symbols Flame | Exclamation mark | Health Hazard | Pictograms Hazard Statements Highly flammable liquid and vapor. Causes serious eye irritation. May cause an allergic skin reaction. May cause drowsiness or dizziness. May damage fertility or the unborn child. Suspected of causing cancer. Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting equipment. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF exposed or concerned: Get medical advice/attention. In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. Storage: Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up. 3M? Plastic and Emblem Adhesive - Clear PN 03601 & 33601 05/13/21 __________________________________________________________________________________________ Page 3 of 14 Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 20% of the mixture consists of ingredients of unknown acute oral toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Methyl Ethyl Ketone 78-93-3 30 - 60 Trade Secret * Vinyl Chloride, Vinyl Acetate, Maleic Acid Polymer 32650-26-3 15 - 40 Trade Secret * Thermoplastic Polyester Trade Secret* 15 - 40 Trade Secret * 4,4'-isopropylidenediphenol-epichlorohydrin polymer 25068-38-6 < 0.5 Trade Secret * Toluene 108-88-3 < 0.5 Trade Secret * Hexane 110-54-3 < 0.2 Trade Secret * Methyl isobutyl ketone 108-10-1 < 0.2 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Allergic skin reaction (redness, swelling, blistering, and itching). Central nervous system depression (headache, dizziness, drowsiness, incoordination, nausea, slurred speech, giddiness, and unconsciousness). 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion 3M? Plastic and Emblem Adhesive - Clear PN 03601 & 33601 05/13/21 __________________________________________________________________________________________ Page 4 of 14 Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. Cover spill area with a fire-extinguishing foam. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. Use personal protective equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation during transfer. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits 3M? Plastic and Emblem Adhesive - Clear PN 03601 & 33601 05/13/21 __________________________________________________________________________________________ Page 5 of 14 If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Methyl isobutyl ketone 108-10-1 ACGIH TWA:20 ppm;STEL:75 ppm A3: Confirmed animal carcin. Methyl isobutyl ketone 108-10-1 OSHA TWA:410 mg/m3(100 ppm) Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human carcin, Ototoxicant Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm Hexane 110-54-3 ACGIH TWA:50 ppm Danger of cutaneous absorption Hexane 110-54-3 OSHA TWA:1800 mg/m3(500 ppm) Methyl Ethyl Ketone 78-93-3 ACGIH TWA:200 ppm;STEL:300 ppm Methyl Ethyl Ketone 78-93-3 OSHA TWA:590 mg/m3(200 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Full Face Shield Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors 3M? Plastic and Emblem Adhesive - Clear PN 03601 & 33601 05/13/21 __________________________________________________________________________________________ Page 6 of 14 For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state Color Liquid Colorless Odor Ketones Odor threshold No Data Available pH No Data Available Melting point No Data Available Boiling Point 176 ?F [Details:CONDITIONS: (MEK)] Flash Point 20 ?F [Test Method:Tagliabue Closed Cup] [Details:CONDITIONS: (methyl ethyl ketone)] Evaporation rate 2.7 [Ref Std:WATER=1] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) 1.80 % volume Flammable Limits(UEL) 10 % volume Vapor Pressure 91 mmHg [Details:CONDITIONS: @ 68F] Vapor Density 2.41 [Ref Std:AIR=1] Density 0.950 g/ml Specific Gravity 0.95 [Ref Std:WATER=1] Solubility in Water Slight (less than 10%) [Details:Very slight] Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature 404 ?C [Details:MEK] Decomposition temperature No Data Available Viscosity Approximately 8,500 centipoise Hazardous Air Pollutants < 0.0001 lb HAPS/lb solids [Test Method:Calculated] Volatile Organic Compounds 58.7 % weight [Test Method:calculated per CARB title 2] Percent volatile 59.2 % weight VOC Less H2O & Exempt Solvents 558 g/l [Test Method:calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Sparks and/or flames Heat 10.5. Incompatible materials Not determined 10.6. Hazardous decomposition products 3M? Plastic and Emblem Adhesive - Clear PN 03601 & 33601 05/13/21 __________________________________________________________________________________________ Page 7 of 14 Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Contact with the skin during product use is not expected to result in significant irritation. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: May be harmful if swallowed. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation Methyl isobutyl ketone 108-10-1 Grp. 2B: Possible human carc. International Agency for Research on Cancer Toxicological Data 3M? Plastic and Emblem Adhesive - Clear PN 03601 & 33601 05/13/21 __________________________________________________________________________________________ Page 8 of 14 If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE >50 mg/l Overall product Ingestion No data available; calculated ATE2,000 - 5,000 mg/kg Methyl Ethyl Ketone Dermal Rabbit LD50 > 8,050 mg/kg Methyl Ethyl Ketone Inhalation- Vapor (4 hours) Rat LC50 34.5 mg/l Methyl Ethyl Ketone Ingestion Rat LD50 2,737 mg/kg Thermoplastic Polyester Dermal LD50 estimated to be > 5,000 mg/kg Thermoplastic Polyester Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg 4,4'-isopropylidenediphenol-epichlorohydrin polymer Dermal Rat LD50 > 1,600 mg/kg 4,4'-isopropylidenediphenol-epichlorohydrin polymer Ingestion Rat LD50 > 1,000 mg/kg Toluene Dermal Rat LD50 12,000 mg/kg Toluene Inhalation- Vapor (4 hours) Rat LC50 30 mg/l Toluene Ingestion Rat LD50 5,550 mg/kg Methyl isobutyl ketone Dermal Rabbit LD50 > 16,000 mg/kg Methyl isobutyl ketone Inhalation- Vapor (4 hours) Rat LC50 >8.2,<16.4 mg/l Methyl isobutyl ketone Ingestion Rat LD50 3,038 mg/kg Hexane Dermal Rabbit LD50 > 2,000 mg/kg Hexane Inhalation- Vapor (4 hours) Rat LC50 170 mg/l Hexane Ingestion Rat LD50 > 28,700 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Methyl Ethyl Ketone Rabbit Minimal irritation 4,4'-isopropylidenediphenol-epichlorohydrin polymer Rabbit Mild irritant Toluene Rabbit Irritant Methyl isobutyl ketone Rabbit Mild irritant Hexane Human and animal Mild irritant Serious Eye Damage/Irritation Name Species Value Methyl Ethyl Ketone Rabbit Severe irritant 4,4'-isopropylidenediphenol-epichlorohydrin polymer Rabbit Moderate irritant Toluene Rabbit Moderate irritant Methyl isobutyl ketone Rabbit Mild irritant Hexane Rabbit Mild irritant Skin Sensitization Name Species Value 4,4'-isopropylidenediphenol-epichlorohydrin polymer Human and animal Sensitizing Toluene Guinea pig Not classified Methyl isobutyl ketone Guinea Not classified 3M? Plastic and Emblem Adhesive - Clear PN 03601 & 33601 05/13/21 __________________________________________________________________________________________ Page 9 of 14 pig Hexane Human Not classified Respiratory Sensitization Name Species Value 4,4'-isopropylidenediphenol-epichlorohydrin polymer Human Not classified Germ Cell Mutagenicity Name Route Value Methyl Ethyl Ketone In Vitro Not mutagenic 4,4'-isopropylidenediphenol-epichlorohydrin polymer In vivo Not mutagenic 4,4'-isopropylidenediphenol-epichlorohydrin polymer In Vitro Some positive data exist, but the data are not sufficient for classification Toluene In Vitro Not mutagenic Toluene In vivo Not mutagenic Methyl isobutyl ketone In Vitro Not mutagenic Hexane In Vitro Not mutagenic Hexane In vivo Not mutagenic Carcinogenicity Name Route Species Value Methyl Ethyl Ketone Inhalation Human Not carcinogenic 4,4'-isopropylidenediphenol-epichlorohydrin polymer Dermal Mouse Some positive data exist, but the data are not sufficient for classification Toluene Dermal Mouse Some positive data exist, but the data are not sufficient for classification Toluene Ingestion Rat Some positive data exist, but the data are not sufficient for classification Toluene Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Methyl isobutyl ketone Inhalation Multiple animal species Carcinogenic Hexane Dermal Mouse Not carcinogenic Hexane Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Methyl Ethyl Ketone Inhalation Not classified for development Rat LOAEL 8.8 mg/l during gestation 4,4'-isopropylidenediphenol- epichlorohydrin polymer Ingestion Not classified for female reproduction Rat NOAEL 750 mg/kg/day 2 generation 4,4'-isopropylidenediphenol- epichlorohydrin polymer Ingestion Not classified for male reproduction Rat NOAEL 750 mg/kg/day 2 generation 4,4'-isopropylidenediphenol- epichlorohydrin polymer Dermal Not classified for development Rabbit NOAEL 300 mg/kg/day during organogenesi s 4,4'-isopropylidenediphenol- epichlorohydrin polymer Ingestion Not classified for development Rat NOAEL 750 mg/kg/day 2 generation Toluene Inhalation Not classified for female reproduction Human NOAEL Not available occupational exposure Toluene Inhalation Not classified for male reproduction Rat NOAEL 2.3 mg/l 1 generation Toluene Ingestion Toxic to development Rat LOAEL 520 mg/kg/day during gestation Toluene Inhalation Toxic to development Human NOAEL Not available poisoning and/or abuse 3M? Plastic and Emblem Adhesive - Clear PN 03601 & 33601 05/13/21 __________________________________________________________________________________________ Page 10 of 14 Methyl isobutyl ketone Inhalation Not classified for female reproduction Multiple animal species NOAEL 8.2 mg/l 2 generation Methyl isobutyl ketone Ingestion Not classified for male reproduction Rat NOAEL 1,000 mg/kg/day 13 weeks Methyl isobutyl ketone Inhalation Not classified for male reproduction Multiple animal species NOAEL 8.2 mg/l 2 generation Methyl isobutyl ketone Inhalation Not classified for development Mouse NOAEL 12.3 mg/l during organogenesi s Hexane Ingestion Not classified for development Mouse NOAEL 2,200 mg/kg/day during organogenesi s Hexane Inhalation Not classified for development Rat NOAEL 0.7 mg/l during gestation Hexane Ingestion Toxic to male reproduction Rat NOAEL 1,140 mg/kg/day 90 days Hexane Inhalation Toxic to male reproduction Rat LOAEL 3.52 mg/l 28 days Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Methyl Ethyl Ketone Inhalation central nervous system depression May cause drowsiness or dizziness official classifica tion NOAEL Not available Methyl Ethyl Ketone Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Methyl Ethyl Ketone Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Methyl Ethyl Ketone Ingestion liver Not classified Rat NOAEL Not available not applicable Methyl Ethyl Ketone Ingestion kidney and/or bladder Not classified Rat LOAEL 1,080 mg/kg not applicable Toluene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Toluene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Toluene Inhalation immune system Not classified Mouse NOAEL 0.004 mg/l 3 hours Toluene Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Methyl isobutyl ketone Inhalation central nervous system depression May cause drowsiness or dizziness Human LOAEL 0.1 mg/l 2 hours Methyl isobutyl ketone Inhalation respiratory irritation May cause respiratory irritation Human NOAEL 0.9 mg/l 7 minutes Methyl isobutyl ketone Inhalation vascular system Not classified Dog NOAEL Not available not available Methyl isobutyl ketone Ingestion central nervous system depression May cause drowsiness or dizziness Rat LOAEL 900 mg/kg not applicable Hexane Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available not available Hexane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Rabbit NOAEL Not available 8 hours Hexane Inhalation respiratory system Not classified Rat NOAEL 24.6 mg/l 8 hours Specific Target Organ Toxicity - repeated exposure 3M? Plastic and Emblem Adhesive - Clear PN 03601 & 33601 05/13/21 __________________________________________________________________________________________ Page 11 of 14 Name Route Target Organ(s) Value Species Test Result Exposure Duration Methyl Ethyl Ketone Dermal nervous system Not classified Guinea pig NOAEL Not available 31 weeks Methyl Ethyl Ketone Inhalation liver | kidney and/or bladder | heart | endocrine system | gastrointestinal tract | bone, teeth, nails, and/or hair | hematopoietic system | immune system | muscles Not classified Rat NOAEL 14.7 mg/l 90 days Methyl Ethyl Ketone Ingestion liver Not classified Rat NOAEL Not available 7 days Methyl Ethyl Ketone Ingestion nervous system Not classified Rat NOAEL 173 mg/kg/day 90 days 4,4'- isopropylidenediphenol- epichlorohydrin polymer Dermal liver Not classified Rat NOAEL 1,000 mg/kg/day 2 years 4,4'- isopropylidenediphenol- epichlorohydrin polymer Dermal nervous system Not classified Rat NOAEL 1,000 mg/kg/day 13 weeks 4,4'- isopropylidenediphenol- epichlorohydrin polymer Ingestion auditory system | heart | endocrine system | hematopoietic system | liver | eyes | kidney and/or bladder Not classified Rat NOAEL 1,000 mg/kg/day 28 days Toluene Inhalation auditory system | eyes | olfactory system Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Toluene Inhalation nervous system May cause damage to organs though prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Toluene Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 2.3 mg/l 15 months Toluene Inhalation heart | liver | kidney and/or bladder Not classified Rat NOAEL 11.3 mg/l 15 weeks Toluene Inhalation endocrine system Not classified Rat NOAEL 1.1 mg/l 4 weeks Toluene Inhalation immune system Not classified Mouse NOAEL Not available 20 days Toluene Inhalation bone, teeth, nails, and/or hair Not classified Mouse NOAEL 1.1 mg/l 8 weeks Toluene Inhalation hematopoietic system | vascular system Not classified Human NOAEL Not available occupational exposure Toluene Inhalation gastrointestinal tract Not classified Multiple animal species NOAEL 11.3 mg/l 15 weeks Toluene Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 625 mg/kg/day 13 weeks Toluene Ingestion heart Not classified Rat NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion liver | kidney and/or bladder Not classified Multiple animal species NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion hematopoietic system Not classified Mouse NOAEL 600 mg/kg/day 14 days Toluene Ingestion endocrine system Not classified Mouse NOAEL 105 mg/kg/day 28 days Toluene Ingestion immune system Not classified Mouse NOAEL 105 mg/kg/day 4 weeks 3M? Plastic and Emblem Adhesive - Clear PN 03601 & 33601 05/13/21 __________________________________________________________________________________________ Page 12 of 14 Methyl isobutyl ketone Inhalation liver Not classified Rat NOAEL 0.41 mg/l 13 weeks Methyl isobutyl ketone Inhalation heart Not classified Multiple animal species NOAEL 0.8 mg/l 2 weeks Methyl isobutyl ketone Inhalation kidney and/or bladder Not classified Multiple animal species NOAEL 0.4 mg/l 90 days Methyl isobutyl ketone Inhalation respiratory system Not classified Multiple animal species NOAEL 4.1 mg/l 14 weeks Methyl isobutyl ketone Inhalation endocrine system | hematopoietic system Not classified Multiple animal species NOAEL 0.41 mg/l 90 days Methyl isobutyl ketone Inhalation nervous system Not classified Multiple animal species NOAEL 0.41 mg/l 13 weeks Methyl isobutyl ketone Ingestion endocrine system | hematopoietic system | liver | kidney and/or bladder Not classified Rat NOAEL 1,000 mg/kg/day 13 weeks Methyl isobutyl ketone Ingestion heart | immune system | muscles | nervous system | respiratory system Not classified Rat NOAEL 1,040 mg/kg/day 120 days Hexane Inhalation peripheral nervous system Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Hexane Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Mouse LOAEL 1.76 mg/l 13 weeks Hexane Inhalation liver Not classified Rat NOAEL Not available 6 months Hexane Inhalation kidney and/or bladder Not classified Rat LOAEL 1.76 mg/l 6 months Hexane Inhalation hematopoietic system Not classified Mouse NOAEL 35.2 mg/l 13 weeks Hexane Inhalation auditory system | immune system | eyes Not classified Human NOAEL Not available occupational exposure Hexane Inhalation heart | skin | endocrine system Not classified Rat NOAEL 1.76 mg/l 6 months Hexane Ingestion peripheral nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,140 mg/kg/day 90 days Hexane Ingestion endocrine system | hematopoietic system | liver | immune system | kidney and/or bladder Not classified Rat NOAEL Not available 13 weeks Aspiration Hazard Name Value Toluene Aspiration hazard Methyl isobutyl ketone Some positive data exist, but the data are not sufficient for classification Hexane Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information 3M? Plastic and Emblem Adhesive - Clear PN 03601 & 33601 05/13/21 __________________________________________________________________________________________ Page 13 of 14 Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. EPCRA 311/312 Hazard Classifications: Physical Hazards Flammable (gases, aerosols, liquids, or solids) Health Hazards Carcinogenicity Reproductive toxicity Respiratory or Skin Sensitization Serious eye damage or eye irritation Specific target organ toxicity (single or repeated exposure) Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Methyl isobutyl ketone 108-10-1 Trade Secret < 0.2 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. All required components of this product are listed on the active portion of the TSCA Inventory. 3M? Plastic and Emblem Adhesive - Clear PN 03601 & 33601 05/13/21 __________________________________________________________________________________________ Page 14 of 14 Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 3 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 29-0703-8 Version Number: 3.08 Issue Date: 05/13/21 Supercedes Date: 04/08/21 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. 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