3M? General Trim Adhesive, PN 39187 09/24/21 __________________________________________________________________________________________ Page 1 of 18 Safety Data Sheet Copyright,2021, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 36-1631-5 Version Number: 4.02 Issue Date: 09/24/21 Supercedes Date: 06/09/21 SECTION 1: Identification 1.1. Product identifier 3M? General Trim Adhesive, PN 39187 Product Identification Numbers 60-4550-8984-1 7010328464 1.2. Recommended use and restrictions on use Recommended use Automotive, Aerosol Spray Adhesive This chemical/product is not and cannot be distributed in commerce (as defined in TSCA section 3(5)) or processed (as defined in TSCA section 3(13)) for consumer paint or coating removal. 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Aerosol: Category 1. Gas Under Pressure: Dissolved gas. Serious Eye Damage/Irritation: Category 2B. Skin Sensitizer: Category 1B. Reproductive Toxicity: Category 1B. Carcinogenicity: Category 1B. Simple Asphyxiant. Specific Target Organ Toxicity (single exposure): Category 1. 3M? General Trim Adhesive, PN 39187 09/24/21 __________________________________________________________________________________________ Page 2 of 18 Specific Target Organ Toxicity (single exposure): Category 3. 2.2. Label elements Signal word Danger Symbols Flame | Gas cylinder | Exclamation mark | Health Hazard | Pictograms Hazard Statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes eye irritation. May cause an allergic skin reaction. May cause drowsiness or dizziness. May damage fertility or the unborn child. May cause cancer. May displace oxygen and cause rapid suffocation. Causes damage to organs: cardiovascular system | May cause damage to organs: respiratory system | Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. 3M? General Trim Adhesive, PN 39187 09/24/21 __________________________________________________________________________________________ Page 3 of 18 IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF exposed or concerned: Get medical advice/attention. Specific treatment (see Notes to Physician on this label). Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. 2.3. Hazards not otherwise classified Repeated exposure may cause skin dryness or cracking. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Methyl acetate 79-20-9 15 - 40 Trade Secret * Non-hazardous components (NJTS Reg. No. 04499600- 7411) Trade Secret* 15 - 30 Trade Secret * Dimethyl ether 115-10-6 7 - 13 Trade Secret * Propane 74-98-6 7 - 13 Trade Secret * Hexmethyldisiloxane 107-46-0 1 - 10 Trade Secret * 1,1-Difluoroethane 75-37-6 1 - 5 Trade Secret * Cyclohexane 110-82-7 1 - 5 Trade Secret * Methylene Chloride 75-09-2 < 0.001 Trade Secret * 4-Chlorobenzotrifluoride 98-56-6 < 2 Trade Secret * Hexane 110-54-3 < 0.2 Trade Secret * N-Butyl Acetate 123-86-4 < 2 Trade Secret * Toluene 108-88-3 < 0.2 Trade Secret * NJTS or NJTSRN: New Jersey Trade Secret Registry Number. *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. Get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical 3M? General Trim Adhesive, PN 39187 09/24/21 __________________________________________________________________________________________ Page 4 of 18 attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Irritating to the respiratory tract (coughing, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain). Allergic skin reaction (redness, swelling, blistering, and itching). Central nervous system depression (headache, dizziness, drowsiness, incoordination, nausea, slurred speech, giddiness, and unconsciousness). Target organ effects. See Section 11 for additional details. 4.3. Indication of any immediate medical attention and special treatment required Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Aldehydes During Combustion Hydrocarbons During Combustion Formaldehyde During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Contain spill. Cover spill area with a fire-extinguishing foam. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with applicable 3M? General Trim Adhesive, PN 39187 09/24/21 __________________________________________________________________________________________ Page 5 of 18 local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human carcin, Ototoxicant Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm Hexane 110-54-3 ACGIH TWA:50 ppm Danger of cutaneous absorption Hexane 110-54-3 OSHA TWA:1800 mg/m3(500 ppm) Cyclohexane 110-82-7 ACGIH TWA:100 ppm Cyclohexane 110-82-7 OSHA TWA:1050 mg/m3(300 ppm) Dimethyl ether 115-10-6 AIHA TWA:1880 mg/m3(1000 ppm) N-Butyl Acetate 123-86-4 ACGIH TWA:50 ppm;STEL:150 ppm N-Butyl Acetate 123-86-4 OSHA TWA:710 mg/m3(150 ppm) Propane 74-98-6 ACGIH Limit value not established: simple asphyxiant Propane 74-98-6 OSHA TWA:1800 mg/m3(1000 ppm) Methylene Chloride 75-09-2 ACGIH TWA:50 ppm A3: Confirmed animal carcin. Methylene Chloride 75-09-2 OSHA TWA:25 ppm;STEL:125 ppm 29 CFR 1910.1052, SKIN 1,1-Difluoroethane 75-37-6 AIHA TWA:2700 mg/m3(1000 ppm) Methyl acetate 79-20-9 ACGIH TWA:200 ppm;STEL:250 ppm Methyl acetate 79-20-9 OSHA TWA:610 mg/m3(200 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls 3M? General Trim Adhesive, PN 39187 09/24/21 __________________________________________________________________________________________ Page 6 of 18 Provide ventilated enclosure for curing. Curing enclosures must be exhausted to outdoors or to a suitable emission control device. Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Full Face Shield Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece supplied-air respirator For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state Color Liquid Amber Specific Physical Form: Aerosol Odor Mild Solvent Odor threshold No Data Available pH Not Applicable Melting point No Data Available Boiling Point 140 ?F [Details:Approximately] Flash Point -40 ?F [Details:Approximately] Evaporation rate 1 Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure <= 4137 mmHg Vapor Density 2 3M? General Trim Adhesive, PN 39187 09/24/21 __________________________________________________________________________________________ Page 7 of 18 Density 0.863 g/ml Specific Gravity 0.88 [Ref Std:WATER=1] Solubility in Water Nil Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity 500 centipoise [Details:Approximately] Hazardous Air Pollutants 0.002 lb HAPS/lb solids [Test Method:Calculated] Volatile Organic Compounds 24.5 % weight [Test Method:calculated per CARB title 2] Volatile Organic Compounds 211 g/l [Test Method:calculated SCAQMD rule 443.1] Percent volatile 68.7 % weight [Test Method:Estimated] VOC Less H2O & Exempt Solvents 360 g/l [Test Method:calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat 10.5. Incompatible materials Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Simple Asphyxiation: Signs/symptoms may include increased heart rate, rapid respirations, drowsiness, headache, incoordination, altered judgement, nausea, vomiting, lethargy, seizures, coma, and may be fatal. 3M? General Trim Adhesive, PN 39187 09/24/21 __________________________________________________________________________________________ Page 8 of 18 Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Prolonged or repeated exposure may cause: Dermal Defatting: Signs/symptoms may include localized redness, itching, drying and cracking of skin. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. Single exposure, above recommended guidelines, may cause: Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal. Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation 4-Chlorobenzotrifluoride 98-56-6 Grp. 2B: Possible human carc. International Agency for Research on Cancer Dichloromethane (methylene chloride) 75-09-2 Grp. 2A: Probable human carc. International Agency for Research on Cancer Dichloromethane (Methylene Chloride) 75-09-2 Anticipated human carcinogen National Toxicology Program Carcinogens METHYLENE CHLORIDE 75-09-2 Cancer hazard OSHA Carcinogens Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE >50 mg/l Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Methyl acetate Dermal Rat LD50 > 2,000 mg/kg Methyl acetate Inhalation- Vapor (4 hours) Rat LC50 > 49 mg/l 3M? General Trim Adhesive, PN 39187 09/24/21 __________________________________________________________________________________________ Page 9 of 18 Methyl acetate Ingestion Rat LD50 > 5,000 mg/kg Propane Inhalation- Gas (4 hours) Rat LC50 > 200,000 ppm Non-hazardous components (NJTS Reg. No. 04499600-7411) Dermal Not available LD50 > 2,000 mg/kg Non-hazardous components (NJTS Reg. No. 04499600-7411) Ingestion Not available LD50 > 2,000 mg/kg Dimethyl ether Inhalation- Gas (4 hours) Rat LC50 164,000 ppm Hexmethyldisiloxane Dermal Rabbit LD50 > 2,000 mg/kg Hexmethyldisiloxane Inhalation- Vapor (4 hours) Rat LC50 106 mg/l Hexmethyldisiloxane Ingestion Rat LD50 > 5,000 mg/kg 1,1-Difluoroethane Inhalation- Gas (4 hours) Rat LC50 > 437,000 ppm 1,1-Difluoroethane Ingestion Rat LD50 > 1,500 mg/kg Cyclohexane Dermal Rat LD50 > 2,000 mg/kg Cyclohexane Inhalation- Vapor (4 hours) Rat LC50 > 32.9 mg/l Cyclohexane Ingestion Rat LD50 6,200 mg/kg N-Butyl Acetate Dermal Rabbit LD50 > 5,000 mg/kg N-Butyl Acetate Inhalation- Dust/Mist (4 hours) Rat LC50 1.4 mg/l N-Butyl Acetate Inhalation- Vapor (4 hours) Rat LC50 > 20 mg/l N-Butyl Acetate Ingestion Rat LD50 > 8,800 mg/kg 4-Chlorobenzotrifluoride Dermal Rabbit LD50 > 2,700 mg/kg 4-Chlorobenzotrifluoride Inhalation- Dust/Mist (4 hours) Rat LC50 > 32 mg/l 4-Chlorobenzotrifluoride Inhalation- Vapor (4 hours) Rat LC50 33 mg/l 4-Chlorobenzotrifluoride Ingestion Rat LD50 5,546 mg/kg Toluene Dermal Rat LD50 12,000 mg/kg Toluene Inhalation- Vapor (4 hours) Rat LC50 30 mg/l Toluene Ingestion Rat LD50 5,550 mg/kg Hexane Dermal Rabbit LD50 > 2,000 mg/kg Hexane Inhalation- Vapor (4 hours) Rat LC50 170 mg/l Hexane Ingestion Rat LD50 > 28,700 mg/kg Methylene Chloride Dermal Rat LD50 > 2,000 mg/kg Methylene Chloride Inhalation- Vapor (4 hours) Rat LC50 63.7 mg/l Methylene Chloride Ingestion Rat LD50 1,410 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Methyl acetate Rabbit No significant irritation Propane Rabbit Minimal irritation Non-hazardous components (NJTS Reg. No. 04499600-7411) Professio nal judgeme No significant irritation 3M? General Trim Adhesive, PN 39187 09/24/21 __________________________________________________________________________________________ Page 10 of 18 nt Hexmethyldisiloxane Rabbit No significant irritation Cyclohexane Rabbit Mild irritant N-Butyl Acetate Rabbit Minimal irritation 4-Chlorobenzotrifluoride Rabbit Minimal irritation Toluene Rabbit Irritant Hexane Human and animal Mild irritant Methylene Chloride Rabbit Irritant Serious Eye Damage/Irritation Name Species Value Methyl acetate Rabbit Moderate irritant Propane Rabbit Mild irritant Non-hazardous components (NJTS Reg. No. 04499600-7411) Professio nal judgeme nt No significant irritation Hexmethyldisiloxane Rabbit Mild irritant Cyclohexane Rabbit Mild irritant N-Butyl Acetate Rabbit Moderate irritant 4-Chlorobenzotrifluoride Rabbit No significant irritation Toluene Rabbit Moderate irritant Hexane Rabbit Mild irritant Methylene Chloride Rabbit Severe irritant Skin Sensitization Name Species Value Methyl acetate Human Not classified Non-hazardous components (NJTS Reg. No. 04499600-7411) Not classified Hexmethyldisiloxane Guinea pig Not classified N-Butyl Acetate Multiple animal species Not classified 4-Chlorobenzotrifluoride Mouse Sensitizing Toluene Guinea pig Not classified Hexane Human Not classified Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Methyl acetate In Vitro Not mutagenic Methyl acetate In vivo Not mutagenic Propane In Vitro Not mutagenic Dimethyl ether In Vitro Not mutagenic Dimethyl ether In vivo Not mutagenic Hexmethyldisiloxane In Vitro Not mutagenic Hexmethyldisiloxane In vivo Not mutagenic 1,1-Difluoroethane In Vitro Some positive data exist, but the data are not sufficient for classification 1,1-Difluoroethane In vivo Some positive data exist, but the data are not sufficient for classification Cyclohexane In Vitro Not mutagenic Cyclohexane In vivo Some positive data exist, but the data are not sufficient for classification N-Butyl Acetate In Vitro Not mutagenic 3M? General Trim Adhesive, PN 39187 09/24/21 __________________________________________________________________________________________ Page 11 of 18 4-Chlorobenzotrifluoride In Vitro Not mutagenic 4-Chlorobenzotrifluoride In vivo Some positive data exist, but the data are not sufficient for classification Toluene In Vitro Not mutagenic Toluene In vivo Not mutagenic Hexane In Vitro Not mutagenic Hexane In vivo Not mutagenic Methylene Chloride In vivo Not mutagenic Methylene Chloride In Vitro Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Dimethyl ether Inhalation Rat Not carcinogenic Hexmethyldisiloxane Inhalation Rat Some positive data exist, but the data are not sufficient for classification 1,1-Difluoroethane Inhalation Rat Some positive data exist, but the data are not sufficient for classification 4-Chlorobenzotrifluoride Inhalation Multiple animal species Carcinogenic Toluene Dermal Mouse Some positive data exist, but the data are not sufficient for classification Toluene Ingestion Rat Some positive data exist, but the data are not sufficient for classification Toluene Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Hexane Dermal Mouse Not carcinogenic Hexane Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Methylene Chloride Inhalation Multiple animal species Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Dimethyl ether Inhalation Not classified for development Rat NOAEL 40,000 ppm during organogenesi s Hexmethyldisiloxane Inhalation Not classified for male reproduction Rat NOAEL 33 mg/l 13 weeks 1,1-Difluoroethane Inhalation Not classified for development Rat NOAEL 50,000 ppm during organogenesi s Cyclohexane Inhalation Not classified for female reproduction Rat NOAEL 24 mg/l 2 generation Cyclohexane Inhalation Not classified for male reproduction Rat NOAEL 24 mg/l 2 generation Cyclohexane Inhalation Not classified for development Rat NOAEL 6.9 mg/l 2 generation N-Butyl Acetate Inhalation Not classified for female reproduction Rat NOAEL 7.1 mg/l premating & during gestation N-Butyl Acetate Inhalation Not classified for development Rat NOAEL 7.1 mg/l premating & during gestation 4-Chlorobenzotrifluoride Ingestion Not classified for female reproduction Rat NOAEL 45 mg/kg/day 1 generation 4-Chlorobenzotrifluoride Ingestion Not classified for male reproduction Rat NOAEL 45 mg/kg/day 1 generation 4-Chlorobenzotrifluoride Ingestion Not classified for development Rat NOAEL 45 mg/kg/day 1 generation 3M? General Trim Adhesive, PN 39187 09/24/21 __________________________________________________________________________________________ Page 12 of 18 4-Chlorobenzotrifluoride Inhalation Not classified for female reproduction Multiple animal species NOAEL 3.7 mg/l 3 months 4-Chlorobenzotrifluoride Inhalation Not classified for male reproduction Multiple animal species NOAEL 1.8 mg/l 3 months Toluene Inhalation Not classified for female reproduction Human NOAEL Not available occupational exposure Toluene Inhalation Not classified for male reproduction Rat NOAEL 2.3 mg/l 1 generation Toluene Ingestion Toxic to development Rat LOAEL 520 mg/kg/day during gestation Toluene Inhalation Toxic to development Human NOAEL Not available poisoning and/or abuse Hexane Ingestion Not classified for development Mouse NOAEL 2,200 mg/kg/day during organogenesi s Hexane Inhalation Not classified for development Rat NOAEL 0.7 mg/l during gestation Hexane Ingestion Toxic to male reproduction Rat NOAEL 1,140 mg/kg/day 90 days Hexane Inhalation Toxic to male reproduction Rat LOAEL 3.52 mg/l 28 days Methylene Chloride Inhalation Not classified for female reproduction Rat NOAEL 5.2 mg/l 2 generation Methylene Chloride Inhalation Not classified for male reproduction Rat NOAEL 5.2 mg/l 2 generation Methylene Chloride Inhalation Not classified for development Multiple animal species NOAEL 4.3 mg/l during gestation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Methyl acetate Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Methyl acetate Inhalation respiratory irritation May cause respiratory irritation Human and animal NOAEL Not available Methyl acetate Inhalation blindness Not classified NOAEL Not available Methyl acetate Ingestion central nervous system depression May cause drowsiness or dizziness NOAEL Not available Propane Inhalation cardiac sensitization Causes damage to organs Human NOAEL Not available Propane Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Propane Inhalation respiratory irritation Not classified Human NOAEL Not available Dimethyl ether Inhalation central nervous system depression May cause drowsiness or dizziness Rat LOAEL 10,000 ppm 30 minutes Dimethyl ether Inhalation cardiac sensitization Some positive data exist, but the data are not sufficient for classification Dog NOAEL 100,000 ppm 5 minutes Hexmethyldisiloxane Inhalation respiratory irritation Not classified Rat NOAEL 33 mg/l 6 hours Hexmethyldisiloxane Ingestion central nervous system depression Not classified Guinea pig LOAEL 22,900 mg/kg not applicable 1,1-Difluoroethane Inhalation cardiac sensitization Causes damage to organs Human and animal NOAEL Not available poisoning and/or abuse 1,1-Difluoroethane Inhalation central nervous system depression May cause drowsiness or dizziness Human and NOAEL 100,000 ppm 3M? General Trim Adhesive, PN 39187 09/24/21 __________________________________________________________________________________________ Page 13 of 18 animal 1,1-Difluoroethane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Not available NOAEL Not available not available Cyclohexane Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Cyclohexane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human and animal NOAEL Not available Cyclohexane Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available N-Butyl Acetate Inhalation respiratory system May cause damage to organs Rat LOAEL 2.6 mg/l 4 hours N-Butyl Acetate Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available not available N-Butyl Acetate Inhalation respiratory irritation May cause respiratory irritation Human NOAEL Not available not available N-Butyl Acetate Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Toluene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Toluene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Toluene Inhalation immune system Not classified Mouse NOAEL 0.004 mg/l 3 hours Toluene Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Hexane Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available not available Hexane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Rabbit NOAEL Not available 8 hours Hexane Inhalation respiratory system Not classified Rat NOAEL 24.6 mg/l 8 hours Methylene Chloride Dermal blood Some positive data exist, but the data are not sufficient for classification Rat NOAEL Not available 4 hours Methylene Chloride Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available occupational exposure Methylene Chloride Inhalation blood Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Methylene Chloride Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Methyl acetate Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 28 days Methyl acetate Inhalation endocrine system | hematopoietic system | liver | immune system | kidney and/or bladder Not classified Rat NOAEL 6.1 mg/l 28 days Dimethyl ether Inhalation hematopoietic system Not classified Rat NOAEL 25,000 ppm 2 years Dimethyl ether Inhalation liver Not classified Rat NOAEL 30 weeks 3M? General Trim Adhesive, PN 39187 09/24/21 __________________________________________________________________________________________ Page 14 of 18 20,000 ppm Hexmethyldisiloxane Dermal liver | kidney and/or bladder Not classified Rat NOAEL 1,000 mg/kg/day 28 days Hexmethyldisiloxane Inhalation kidney and/or bladder Not classified Rat NOAEL 4 mg/l 13 weeks Hexmethyldisiloxane Inhalation hematopoietic system Not classified Rat NOAEL 33 mg/l 13 weeks Hexmethyldisiloxane Inhalation liver Not classified Multiple animal species NOAEL 29 mg/l 15 days Hexmethyldisiloxane Inhalation heart | endocrine system | immune system | nervous system | respiratory system Not classified Rat NOAEL 33 mg/l 13 weeks 1,1-Difluoroethane Inhalation hematopoietic system | kidney and/or bladder | respiratory system Not classified Rat NOAEL 25,000 ppm 2 years Cyclohexane Inhalation liver Not classified Rat NOAEL 24 mg/l 90 days Cyclohexane Inhalation auditory system Not classified Rat NOAEL 1.7 mg/l 90 days Cyclohexane Inhalation kidney and/or bladder Not classified Rabbit NOAEL 2.7 mg/l 10 weeks Cyclohexane Inhalation hematopoietic system Not classified Mouse NOAEL 24 mg/l 14 weeks Cyclohexane Inhalation peripheral nervous system Not classified Rat NOAEL 8.6 mg/l 30 weeks N-Butyl Acetate Inhalation olfactory system Not classified Rat NOAEL 2.4 mg/l 14 weeks N-Butyl Acetate Inhalation liver | kidney and/or bladder Not classified Rabbit NOAEL 7.26 mg/l 13 days 4-Chlorobenzotrifluoride Inhalation liver Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 1.8 mg/l 3 months 4-Chlorobenzotrifluoride Inhalation heart Not classified Multiple animal species LOAEL 15 mg/l 3 months 4-Chlorobenzotrifluoride Inhalation endocrine system | gastrointestinal tract | hematopoietic system Not classified Multiple animal species NOAEL 15 mg/l 3 months 4-Chlorobenzotrifluoride Inhalation immune system Not classified Multiple animal species LOAEL 15 mg/l 3 months 4-Chlorobenzotrifluoride Inhalation nervous system Not classified Multiple animal species NOAEL 15 mg/l 3 months 4-Chlorobenzotrifluoride Inhalation kidney and/or bladder Not classified Multiple animal species LOAEL 15 mg/l 3 months 4-Chlorobenzotrifluoride Inhalation respiratory system | vascular system | bone, teeth, nails, and/or hair | eyes Not classified Multiple animal species NOAEL 15 mg/l 3 months 4-Chlorobenzotrifluoride Ingestion hematopoietic system | liver | kidney and/or bladder | heart | endocrine system | eyes Not classified Rat NOAEL 500 mg/kg/day 90 days Toluene Inhalation auditory system | eyes | olfactory system Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Toluene Inhalation nervous system May cause damage to organs Human NOAEL Not poisoning 3M? General Trim Adhesive, PN 39187 09/24/21 __________________________________________________________________________________________ Page 15 of 18 though prolonged or repeated exposure available and/or abuse Toluene Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 2.3 mg/l 15 months Toluene Inhalation heart | liver | kidney and/or bladder Not classified Rat NOAEL 11.3 mg/l 15 weeks Toluene Inhalation endocrine system Not classified Rat NOAEL 1.1 mg/l 4 weeks Toluene Inhalation immune system Not classified Mouse NOAEL Not available 20 days Toluene Inhalation bone, teeth, nails, and/or hair Not classified Mouse NOAEL 1.1 mg/l 8 weeks Toluene Inhalation hematopoietic system | vascular system Not classified Human NOAEL Not available occupational exposure Toluene Inhalation gastrointestinal tract Not classified Multiple animal species NOAEL 11.3 mg/l 15 weeks Toluene Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 625 mg/kg/day 13 weeks Toluene Ingestion heart Not classified Rat NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion liver | kidney and/or bladder Not classified Multiple animal species NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion hematopoietic system Not classified Mouse NOAEL 600 mg/kg/day 14 days Toluene Ingestion endocrine system Not classified Mouse NOAEL 105 mg/kg/day 28 days Toluene Ingestion immune system Not classified Mouse NOAEL 105 mg/kg/day 4 weeks Hexane Inhalation peripheral nervous system Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Hexane Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Mouse LOAEL 1.76 mg/l 13 weeks Hexane Inhalation liver Not classified Rat NOAEL Not available 6 months Hexane Inhalation kidney and/or bladder Not classified Rat LOAEL 1.76 mg/l 6 months Hexane Inhalation hematopoietic system Not classified Mouse NOAEL 35.2 mg/l 13 weeks Hexane Inhalation auditory system | immune system | eyes Not classified Human NOAEL Not available occupational exposure Hexane Inhalation heart | skin | endocrine system Not classified Rat NOAEL 1.76 mg/l 6 months Hexane Ingestion peripheral nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,140 mg/kg/day 90 days Hexane Ingestion endocrine system | hematopoietic system | liver | immune system | kidney and/or bladder Not classified Rat NOAEL Not available 13 weeks Methylene Chloride Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat LOAEL 6.95 mg/l 2 years Methylene Chloride Inhalation liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.17 mg/l 2 years Methylene Chloride Inhalation respiratory system Some positive data exist, but the data are not sufficient for Multiple animal LOAEL 35 mg/l 8 weeks 3M? General Trim Adhesive, PN 39187 09/24/21 __________________________________________________________________________________________ Page 16 of 18 classification species Methylene Chloride Inhalation heart Not classified Human NOAEL Not available Methylene Chloride Inhalation immune system Not classified Rat NOAEL 18 mg/l 28 days Methylene Chloride Ingestion liver Some positive data exist, but the data are not sufficient for classification Rat LOAEL 1,200 mg/kg/day 3 months Methylene Chloride Ingestion blood Not classified Rat NOAEL 249 mg/kg/day 2 years Methylene Chloride Ingestion kidney and/or bladder Not classified Rat NOAEL 1,469 mg/kg/day 3 months Methylene Chloride Ingestion eyes Not classified Rat NOAEL 249 mg/kg/day 104 weeks Aspiration Hazard Name Value Cyclohexane Aspiration hazard Toluene Aspiration hazard Hexane Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 3M? General Trim Adhesive, PN 39187 09/24/21 __________________________________________________________________________________________ Page 17 of 18 EPCRA 311/312 Hazard Classifications: Physical Hazards Flammable (gases, aerosols, liquids, or solids) Gas under pressure Health Hazards Carcinogenicity Hazard Not Otherwise Classified (HNOC) Reproductive toxicity Respiratory or Skin Sensitization Serious eye damage or eye irritation Simple Asphyxiant Specific target organ toxicity (single or repeated exposure) Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Cyclohexane 110-82-7 Trade Secret 1 - 5 This material contains a chemical which requires export notification under TSCA Section 12[b]: Ingredient (Category if applicable) C.A.S. No Regulation Status Methylene Chloride 75-09-2 Toxic Substances Control Act (TSCA) 6 Banned or Restricted Use Chemicals Applicable Additional TSCA Information This chemical/product is not and cannot be distributed in commerce (as defined in TSCA section 3(5)) or processed (as defined in TSCA section 3(13)) for consumer paint or coating removal. 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. All required components of this product are listed on the active portion of the TSCA Inventory. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 4 Instability: 0 Special Hazards: None Aerosol Storage Code: 3 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar 3M? General Trim Adhesive, PN 39187 09/24/21 __________________________________________________________________________________________ Page 18 of 18 emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 36-1631-5 Version Number: 4.02 Issue Date: 09/24/21 Supercedes Date: 06/09/21 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M. 3M USA SDSs are available at www.3M.com